JEE Main 25 January 2023 Shift 2 question paper with solutions
JEE Main 25 January 2023 Shift 2: all 90 questions in paper order (Physics, Chemistry, Maths) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.
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Physics
Question 1
Physics · Current Electricity · Single correct
Choose the correct answer from the options given below:
A-II, B-III, C-IV, D-I
A-III, B-I, C-II, D-IV
A-I, B-III, C-IV, D-II
A-I, B-II, C-III, D-IV
Answer: (b)
Solution
Given $$Y = \frac{Stress}{Strain} = \frac{F/A}{\Delta \ell / \ell} = \frac{[MLT^{-2}]}{[L^2]} = [ML^{-1}T^{-2}]$$ $$F = 6 \pi \eta r v \Rightarrow \eta = \frac{F}{6 \pi r v}$$ $$[\eta] = \frac{[MLT^{-2}]}{[L][LT^{-1}]} = [ML^{-1}T^{-1}]$$ $$E = h \nu \Rightarrow h = \frac{E}{\nu} = \frac{[ML^2T^{-2}]}{[T^{-1}]} = [ML^2T^{-1}]$$ Work function has same dimension as that of energy, so $[\phi] = [ML^2T^{-2}]$
Question 2
Physics · Motion in a Straight Line · Single correct
The distance travelled by a particle is related to time $t$ as $x = 4t^2$. The velocity of the particle at $t = 5 \, \mathrm{s}$ is .
40 $\mathrm{ms}^{-1}$
25 $\mathrm{ms}^{-1}$
20 $\mathrm{ms}^{-1}$
8 $\mathrm{ms}^{-1}$
Answer: (a)
Solution
Given $x = 4t^2$. The velocity $v$ is given by the derivative $\frac{dx}{dt} = 8t$. At $t = 5$ sec, $v = 8 \times 5 = 40 \, \mathrm{m/s}$.
Question 3
Physics · Motion in a Plane · Single correct
Two objects are projected with same velocity 'u' however at different angles $\alpha$ and $\beta$ with the horizontal. If $\alpha + \beta = 90^\circ$, the ratio of horizontal range of the first object to the 2nd object will be:
Consider a block kept on an inclined plane (inclined at 45$^\circ$) as shown in the figure. If the force required to just push it up the incline is 2 times the force required to just prevent it from sliding down, the coefficient of friction between the block and inclined plane ($\mu$) is equal to:
0.33
0.60
0.25
0.50
Answer: (a)
Solution
Given the forces acting on the block, we have: $$F_1 = mg \sin 45^\circ + f = mg \sin 45^\circ + \mu N$$ Substituting the values, we get: $$F_1 = \frac{mg}{\sqrt{2}} + \mu mg \cos 45^\circ$$ Simplifying further: $$F_1 = \frac{mg}{\sqrt{2}} (1 + \mu)$$ For the second block: $$F_2 = mg \sin 45^\circ - f = mg \sin 45^\circ - \mu N$$ This simplifies to: $$= \frac{mg}{\sqrt{2}} (1 - \mu)$$ Given that $F_1 = 2F_2$, we have: $$\frac{mg}{\sqrt{2}} (1 + \mu) = 2 \frac{mg}{\sqrt{2}} (1 - \mu)$$ Solving for $\mu$: $$1 + \mu = 2 - 2\mu$$ $$\mu = 1/3 = 0.33$$
Question 5
Physics · System of Particles and Rotational Motion · Numerical
A nucleus disintegrates into two smaller parts, which have their velocities in the ratio 3 : 2. The ratio of their nuclear sizes will be $\left( \frac{x}{3} \right)^{\frac{1}{3}}$. The value of 'x' is :
Answer: 2
Solution
Given $\frac{v_1}{v_2} = \frac{3}{2}$. Since $m_1 v_1 = m_2 v_2$, we have $\frac{m_1}{m_2} = \frac{2}{3}$. Since nuclear mass density is constant, $$\frac{m_1}{\frac{4}{3} \pi r_1^3} = \frac{m_2}{\frac{4}{3} \pi r_2^3}$$ This implies $$\left( \frac{r_1}{r_2} \right)^3 = \frac{m_1}{m_2}$$ Therefore, $$\frac{r_1}{r_2} = \left( \frac{2}{3} \right)^{\frac{1}{3}}$$ So, $x = 2$.
Question 6
Physics · Work, Energy and Power · Numerical
A body of mass $1\,\text{kg}$ collides head on elastically with a stationary body of mass $3\,\text{kg}$. After collision, the smaller body reverses its direction of motion and moves with a speed of $2\,\text{m/s}$. The initial speed of the smaller body before collision is________\[ {\text{m/s}} \]
Answer: 4
Solution
Given the initial conditions, we have: $$1 \times u_1 = -2 + 3v \implies u_1 = -2 + 3v (1)$$ $$1 = \frac{v + 2}{u_1} \implies v + 2 = u_1 (2)$$ Solving equations (1) and (2), we find: $$u_1 = 4 \, \mathrm{m/s}$$
Question 7
Physics · System of Particles and Rotational Motion · Numerical
If a solid sphere of mass 5 kg and a disc of mass 4 kg have the same radius. Then the ratio of moment of inertia of the disc about a tangent in its plane to the moment of inertia of the sphere about its tangent will be $\frac{x}{7}$. The value of $x$ is _______.
Answer: 5
Solution
The tangent will be $\frac{x}{7}$. The value of $x$ is given. For the solid sphere: Given $m_1 = 5 \, \mathrm{kg}$ and radius $= R$. $$I_1 = \frac{2}{5} m_1 R^2 + m_1 R^2$$ Simplifying, we have: $$I_1 = m_1 R^2 \left( \frac{7}{5} \right)$$ Thus, $$I_1 = 7 R^2$$ For the disc: Given $m_2 = 4 \, \mathrm{kg}$ and radius $= R$. $$I_2 = \frac{m_2 R^2}{4} + m_2 R^2$$ Simplifying, we have: $$I_2 = \frac{5}{4} m_2 R^2$$ Thus, $$I_2 = 5 R^2$$
Question 8
Physics · Gravitation · Single correct
A body of mass is taken from earth surface to the height $h$ equal to twice the radius of earth $(R_e)$, the increase in potential energy will be : (g = acceleration due to gravity on the surface of Earth)
$3mgR_e$
$\frac{1}{3}mgR_e$
$\frac{2}{3}mgR_e$
$\frac{1}{2}mgR_e$
Answer: (c)
Solution
The potential energy is given by $$U = \frac{-G M_e m}{r}$$ The initial potential energy is $$U_i = \frac{-G M_e m}{R_e}$$ The final potential energy is $$U_f = \frac{-G M_e m}{(R_e + h)} = \frac{-G M_e m}{R_e + 2R_e}$$ which simplifies to $$\frac{-G M_e m}{3R_e}$$ The increase in internal energy $\Delta U$ is given by $U_f - U_i$: $$\Delta U = \frac{2}{3} \frac{G M_e m}{R_e}$$ This can be rewritten as $$\frac{2}{3} \frac{G M_e}{R_e^2} m R_e$$ which simplifies to $$\frac{2}{3} mg R_e$$
Question 9
Physics · Gravitation · Multiple correct
Every planet revolves around the sun in an elliptical orbit: A. The force acting on a planet is inversely proportional to square of distance from sun. B. Force acting on planet is inversely proportional to product of the masses of the planet and the sun C. The centripetal force acting on the planet is directed away from the sun. D. The square of time period of revolution of planet around sun is directly proportional to cube of semi-major axis of elliptical orbit. Choose the correct answer from the options given below:
A and D only
C and D only
B and C only
A and C only
Answer: (a)
Solution
Given $$F = \frac{G m_1 m_2}{r^2}$$ Therefore, $$F \propto \frac{1}{r^2}$$ Also, $$F \propto m_1 m_2$$ This force provides centripetal force and acts towards the sun. Thus, $$T^2 \propto a^3$$ (Kepler's third law)
Question 10
Physics · Mechanical Properties of Fluids · Numerical
A spherical drop of liquid splits into 1000 identical spherical drops. If $u_i$ is the surface energy of the original drop and $u_f$ is the total surface energy of the resulting drops, the (ignoring evaporation). $$ \frac{u_f}{u_i} = \left( \frac{10}{x} \right) $$. Then value of $x$ is _____ :
Answer: 1
Solution
Surface Tension = T R : Radius of bigger drop r : Radius of smaller drop Volume will remain same $$\frac{4}{3} \pi R^3 = 1000 \times \frac{4}{3} \pi r^3$$ R = 10 r $$u_i = T \cdot 4 \pi R^2$$ $$u_f = T \cdot 4 \pi r^2 \times 1000$$ $$\frac{u_f}{u_i} = \frac{1000 r^2}{R^2}$$ $$\frac{u_f}{u_i} = \frac{10}{1}$$ So, x = 1
Question 11
Physics · Thermodynamics · Single correct
According to law of equipartition of energy the molar specific heat of a diatomic gas at constant volume where the molecule has one additional vibrational mode is :-
$\frac{9}{2} R$
$\frac{5}{2} R$
$\frac{3}{2} R$
$\frac{7}{2} R$
Answer: (d)
Solution
Diatomic gas molecules have three translational degrees of freedom, two rotational degrees of freedom, and it is given that it has one vibrational mode. So there are two additional degrees of freedom corresponding to one vibrational mode, so the total degree of freedom is $7$. $$C_V = \frac{fR}{2} = \frac{7R}{2}$$
Question 12
Physics · Thermodynamics · Single correct
The graph between two temperature scales P and Q is shown in the figure. Between upper fixed point and lower fixed point there are 150 equal divisions of scale P and 100 divisions on scale Q. The relationship for conversion between the two scales is given by:
$\frac{t_Q}{150} = \frac{t_P - 180}{100}$
$\frac{t_Q}{100} = \frac{t_P - 30}{150}$
$\frac{t_P}{180} = \frac{t_Q - 40}{100}$
$\frac{t_P}{100} = \frac{t_Q - 180}{150}$
Answer: (b)
Solution
The reading on scale minus the lower fixed point divided by the upper fixed point minus the lower fixed point is constant. $$\frac{t_P - 30}{180 - 30} = \frac{t_Q - 0}{100 - 0}$$ Simplifying gives: $$\frac{t_P - 30}{150} = \frac{t_Q}{100}$$
Question 13
Physics · Thermodynamics · Single correct
Match List I with List II :
A-II, B-I, C-III, D-IV
A-II, B-I, C-IV, D-III
A-I, B-II, C-IV, D-III
A-I, B-II, C-III, D-IV
Answer: (b)
Solution
Given $\Delta U = n C_V \Delta T$. For isothermal process $T$ is constant. So $\Delta U = 0$. A $\longrightarrow$ II. Adiabatic process $\Delta Q = 0$. $\Delta Q = \Delta U + \Delta W$. $\Delta U = -\Delta W$. Work done by gas is positive. So $\Delta U$ is negative. B $\longrightarrow$ I. For Isochoric process $\Delta W = 0$. C $\longrightarrow$ IV. For Isobaric process $\Delta W = P \Delta V \neq 0$. $\Delta U = n C_V \Delta T \neq 0$. Heat absorbed goes partly to increase internal energy and partly do work.
Question 14
Physics · Oscillations · Single correct
A particle executes simple harmonic motion between $x = -A$ and $x = +A$. If time taken by particle to go from $x = 0$ to $\frac{A}{2}$ is $2\,\mathrm{s}$; then time taken by particle in going from $x = \frac{A}{2}$ to $A$ is:
$3\,\mathrm{s}$
$2\,\mathrm{s}$
$1.5\,\mathrm{s}$
$4\,\mathrm{s}$
Answer: (d)
Solution
Let time from 0 to A/2 is $t_1$ and from A/2 to A is $t_2$. Then $\omega t_1 = \pi/6$ and $\omega t_2 = \pi/3$. $$\frac{t_1}{t_2} = \frac{1}{2}$$ $$t_2 = 2t_1 = 2 \times 2 = 4 sec$$
Question 15
Physics · Waves · Single correct
Match List I with List II
A-III, B-IV, C-II, D-I
A-I, B-II, C-IV, D-III
A-I, B-IV, C-III, D-II
A-III, B-II, C-I, D-IV
Answer: (a)
Solution
NCERT fact based
Question 16
Physics · Waves · Numerical
A train blowing a whistle of frequency $320 \, \mathrm{Hz}$ approaches an observer standing on the platform at a speed of $66 \, \mathrm{m/s}$. The frequency observed by the observer will be (given speed of sound = $330 \, \mathrm{ms}^{-1}$) _______Hz.
Answer: 400
Solution
The apparent frequency $f_{app}$ is given by the formula: $$f_{app} = f \left( \frac{v}{v - v_s} \right)$$ Substituting the given values: $$= 320 \left( \frac{330}{330 - 66} \right)$$ $$= 400 \, Hz$$
Question 17
Physics · Electric Charges and Fields · Single correct
A point charge of 10 μC is placed at the origin. At what location on the X-axis should a point charge of 40 μC be placed so that the net electric field is zero at $x=2\,\mathrm{cm}$ on the X-axis?
$x = 6\,\mathrm{cm}$
$x = 4\,\mathrm{cm}$
$x = 8\,\mathrm{cm}$
$x = -4\,\mathrm{cm}$
Answer: (a)
Solution
Given the equation for potential energy: $$E_P = \frac{K \times 10}{2^2} - \frac{K \times 40}{(x_0 - 2)^2} = 0$$ Simplifying the equation, we have: $$\frac{1}{2} = \frac{2}{x_0 - 2}$$ Solving for $x_0$, we get: $$x_0 - 2 = 4$$ Therefore, $$x_0 = 6 \, cm$$
Question 18
Physics · Electrostatic Potential and Capacitance · Numerical
A capacitor has capacitance $5 \, \mu \mathrm{F}$ when it's parallel plates are separated by air medium of thickness $d$. A slab of material of dielectric constant $1.5$ having area equal to that of plates but thickness $\frac{d}{2}$ is inserted between the plates. Capacitance of the capacitor in the presence of slab will be_______$\mu$$\mathrm{F}$.
The resistance of a wire is 5 $\Omega$. It's new resistance in ohm if stretched to 5 times of it's original length will be :
625
5
125
25
Answer: (c)
Solution
Given $R_{initial} = \frac{\rho \ell}{A} = 5 \Omega$. The volume of wire is constant in stretching, so $V_i = V_f$. Therefore, $A_i \ell_i = A_f \ell_f$. We have $A \ell = A'(5 \ell)$. Thus, $A' = \frac{A}{5}$. The final resistance is $R_f = \frac{\rho \ell_f}{A_f} = \frac{\rho (5 \ell)}{\frac{A}{5}}$. This simplifies to $= 25 \left( \frac{\rho \ell}{A} \right) = 25 \times 5 = 125 \Omega$.
Question 20
Physics · Current Electricity · Numerical
Two cells are connected between points A and B as shown. Cell 1 has emf of 12 V and internal resistance of 3$\Omega$. Cell 2 has emf of 6V and internal resistance of 6$\Omega$. An external resistor R of 4$\Omega$ is connected across A and B. The current flowing through R will be ______ A.
Answer: 1
Solution
The equivalent voltage $E_{eq}$ is calculated as follows: $$E_{eq} = \frac{12}{3} - \frac{6}{6} \Bigg/ \frac{1}{3} + \frac{1}{6}$$ This simplifies to: $$E_{eq} = 6 \, \mathrm{V}$$ The equivalent resistance $r_{eq}$ is: $$r_{eq} = 2 \, \Omega$$ The resistance $R$ is: $$R = 4 \, \Omega$$ In the circuit, the current $i$ is given by: $$i = \frac{6}{2 + 4} = 1 \, \mathrm{A}$$
Question 21
Physics · Moving Charges and Magnetism · Single correct
For a moving coil galvanometer, the deflection in the coil is 0.05 rad when a current of 10 $\mathrm{mA}$ is passed through it. If the torsional constant of suspension wire is 4.0 $\times$ 10$^{-5}$ $\mathrm{N\,m\,rad^{-1}}$, the magnetic field is 0.01 $\mathrm{T}$ and the number of turns in the coil is 200, the area of each turn (in $\mathrm{cm^2}$) is:
2.0
1.0
1.5
0.5
Answer: (b)
Solution
Given $\tau = K \theta$ and $\mathrm{NiAB} = K \theta$. $$A = \frac{K \theta}{\mathrm{NiB}} = \frac{4 \times 10^{-5} \times 0.05}{200 \times 10^{-3} \times 0.01}$$ On solving $A = 10^{-4} \, \mathrm{m^2} = 1 \, \mathrm{cm^2}$.
Question 22
Physics · Moving Charges and Magnetism · Numerical
Two long parallel wires carrying currents 8A and 15 A in opposite directions are placed at a distance of 7 cm from each other. A point P is at equidistant from both the wires such that the lines joining the point P to the wires are perpendicular to each other. The magnitude of magnetic field at P is ______ $\times \, 10^{-6} \, \mathrm{T}$. (Given : $\sqrt{2} = 1.4$)
Answer: 68
Solution
Magnetic fields due to both wires will be perpendicular to each other. $B_1 = \frac{\mu_0 i_1}{2 \pi d}$, $B_2 = \frac{\mu_0 i_2}{2 \pi d}$ $$B_{net} = \sqrt{B_1^2 + B_2^2} \Rightarrow \frac{\mu_0}{2 \pi d} \sqrt{i_1^2 + i_2^2}$$ $$\Rightarrow \frac{4 \pi \times 10^{-7}}{2 \pi \times (7/\sqrt{2}) \times 10^{-2}} \times \sqrt{8^2 + 15^2} (d = \frac{7}{\sqrt{2}} \, cm)$$ $$\Rightarrow 68 \times 10^{-6} \, T$$
Question 23
Physics · Electromagnetic Induction · Single correct
A wire of length 1 m moving with velocity 8 m/s at right angles to a magnetic field of 2T. The magnitude of induced emf, between the ends of wire will be ________:
20 V
8 V
12 V
16 V
Answer: (d)
Solution
Induced emf across the ends $= B v \ell$ $$= 2 \times 8 \times 1 = 16 \, \mathrm{V}$$
Question 24
Physics · Alternating Current · Numerical
A series LCR circuit is connected to an AC source of 220 V, 50 Hz. The circuit contains a resistance $R = 80 \, \Omega$, an inductor of inductive reactance $X_L = 70 \, \Omega$, and a capacitor of capacitive reactance $X_C = 130 \, \Omega$. The power factor of circuit is $\frac{x}{10}$. The value of $x$ is :
Answer: 8
Solution
Given the formula for the power factor, we have: $$\cos \phi = \frac{R}{Z} = \frac{R}{\sqrt{R^2 + (X_C - X_L)^2}}$$ Substituting the given values: $$\cos \phi = \frac{80}{\sqrt{(80)^2 + (60)^2}}$$ Simplifying further: $$\cos \phi = \frac{80}{100} \Rightarrow \frac{8}{10}$$
Question 25
Physics · Electric Charges and Fields · Single correct
Match List I with List II : Choose the correct answer from the options given below :
A-IV, B-I, C-II, D-III
A-I, B-II, C-III, D-IV
A-III, B-IV, C-I, D-II
A-II, B-III, C-IV, D-I
Answer: (a)
Solution
Gauss's Law of electrostatics $$\phi = \oint \vec{E} \cdot d\vec{s} = \frac{q}{\varepsilon_0}$$ Faraday's law $$\oint \vec{E} \cdot d\vec{l} = -\frac{d\phi_B}{dt}$$ Gauss's law of magnetism $$\oint \vec{B} \cdot d\vec{A} = 0$$ Ampere's Maxwell law $$\oint \vec{B} \cdot d\vec{l} = \mu_0 i_C + \mu_0 \varepsilon_0 \frac{d\phi_E}{dt}$$ Where $i_C$: Conduction current $\varepsilon_0 \frac{d\phi_E}{dt}$: Displacement current
Question 26
Physics · Ray Optics and Optical Instruments · Single correct
The light rays from an object have been reflected towards an observer from a standard flat mirror, the image observed by the observer are :-
B and D only
B and C only
A and D only
A, C and D only
Answer: (a)
Solution
Plane mirror forms erect, same sized, laterally inverted and virtual image of real object.
Question 27
Physics · Ray Optics and Optical Instruments · Fill in the blank
An object is placed on the principal axis of convex lens of focal length 10 cm as shown. A plane mirror is placed on the other side of lens at a distance of 20 cm. The image produced by the plane mirror is 5 cm inside the mirror. The distance of the object from the lens is ___ cm.
Answer: 30
Solution
Given $f = 10 \, \mathrm{cm}$. $$\frac{1}{v} - \frac{1}{u} = \frac{1}{f}$$ $$\frac{1}{15} - \frac{1}{-u} = \frac{1}{10}$$ $$\Rightarrow \frac{1}{u} = \frac{1}{10} - \frac{1}{15}$$ On solving we get value of $u$ as $30 \, \mathrm{cm}$.
Question 28
Physics · Dual Nature of Radiation and Matter · Single correct
Given below are two statements : Statement I : Stopping potential in photoelectric effect does not depend on the power of the light source. Statement II : For a given metal, the maximum kinetic energy of the photoelectron depends on the wavelength of the incident light. In the light of above statements, choose the most appropriate answer from the options given below.
Statement I is incorrect but statement II is correct
Both Statement I and Statement II are incorrect
Statement I is correct but statement II is incorrect
Both statement I and statement II are correct
Answer: (d)
Solution
Stopping potential $V_S = \frac{\mathrm{KE_{max}}}{e}$ $$V_S = \frac{\frac{hC}{\lambda} - \phi}{e}$$ Stopping potential does not depend on intensity or power of light used, it only depends on frequency or wavelength of incident light. So both statements I and II are correct.
Question 29
Physics · Atoms · Single correct
The energy levels of an atom is shown is figure. Which one of these transitions will result in the emission of a photon of wavelength 124.1 nm? Given $h = 6.62 \times 10^{-34} \mathrm{Js}$
B
A
C
D
Answer: (d)
Solution
The wavelength $\lambda$ is given by the formula $\lambda = \frac{hc}{\Delta E}$. For $\Delta E_A = 2.2 \, \mathrm{eV}$, $\Delta E_B = 5.2 \, \mathrm{eV}$, $\Delta E_C = 3 \, \mathrm{eV}$, and $\Delta E_D = 10 \, \mathrm{eV}$, we calculate the wavelengths as follows: For $\lambda_A$: $$\lambda_A = \frac{6.62 \times 10^{-34} \times 3 \times 10^8}{2.2 \times 1.6 \times 10^{-19}}$$ $$= \frac{12.41 \times 10^{-7}}{2.2} \, \mathrm{m}$$ $$= \frac{1241}{2.2} \, \mathrm{nm} = 564 \, \mathrm{nm}$$ For $\lambda_B$: $$\lambda_B = \frac{1241}{5.2} \, \mathrm{nm} = 238.65 \, \mathrm{nm}$$ For $\lambda_C$: $$\lambda_C = \frac{1241}{3} \, \mathrm{nm} = 413.66 \, \mathrm{nm}$$ For $\lambda_D$: $$\lambda_D = \frac{1241}{10} = 124.1 \, \mathrm{nm}$$
Question 30
Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct
Statement I : When a Si sample is doped with Boron, it becomes P type and when doped by Arsenic it becomes N-type semi conductor such that P-type has excess holes and N-type has excess electrons. Statement II : When such P-type and N-type semi-conductors, are fused to make a junction, a current will automatically flow which can be detected with an externally connected ammeter. In the light of above statements, choose the most appropriate answer from the options given below.
Both Statement I and statement II are incorrect
Statement I is incorrect but statement II is correct
Both Statement I and statement II are correct
Statement I is correct but statement II is incorrect
Answer: (d)
Solution
Statement I is correct. When P-N junction is formed, an electric field is generated from N-side to P-side due to which barrier potential arises and majority charge carrier cannot flow through the junction due to barrier potential, so current is zero unless we apply forward bias voltage.
Chemistry
Question 31
Chemistry · Hydrocarbons · Fill in the blank
Number of hydrogen atoms per molecule of a hydrocarbon A having $85.8\%$ carbon is ________ (Given: Molar mass of A $= 84 \, \mathrm{g \, mol^{-1}}$)
Answer: 12
Solution
Element C has a percentage of 85.8. The moles are calculated as $\frac{85.8}{12} = 7.15$ with a mole ratio of 1. Element H has a percentage of 14.2. The moles are calculated as $\frac{14.2}{1} = 14.2$ with a mole ratio of 2. The empirical formula is $\mathrm{(CH_2)}$. Solving for $n$: $$14 \times n = 84$$ $$n = 6$$ Therefore, the molecular formula is $\mathrm{C_6H_{12}}$.
Question 32
Chemistry · Chemical Bonding and Molecular Structure · Numerical
The number of given orbitals which have electron density along the axis is $p_x, p_y, p_z, d_{xy}, d_{yz}, d_{xz}, d_{z^2}, d_{x^2-y^2}$
Answer: 5
Solution
$p_x$, $p_y$, $p_z$, $d_{z^2}$, and $d_{x^2-y^2}$ are axial orbitals.
Question 33
Chemistry · Chemical Bonding and Molecular Structure · Single correct
Statement I :- Dipole moment is a vector quantity and by convention it is depicted by a small arrow with tail on the negative centre and head pointing towards the positive centre. Statement II :- The crossed arrow of the dipole moment symbolizes the direction of the shift of charges in the molecules. In the light of the above statements, choose the most appropriate answer from the options given below :-
Both Statement I and Statement II are correct.
Statement I is incorrect but Statement II is correct.
Both Statement I and Statement II are incorrect.
Statement I is correct but Statement II is incorrect.
Answer: (d)
Solution
Statement II: The crossed arrow symbolises the direction of the shift of electron density in the molecule.
Question 34
Chemistry · Thermodynamics · Numerical
28.0 \, $\mathrm{L}$ of $\mathrm{CO}_2$ is produced on complete combustion of 16.8 \, $\mathrm{L}$ gaseous mixture of ethene and methane at $25^\circ \mathrm{C}$ and 1 \, $\mathrm{atm}$. Heat evolved during the combustion process is _______________ \, $\mathrm{kJ}$. Given: $\Delta H_C (\mathrm{CH}_4)$ = -900 \, $\mathrm{kJ}$ \, $\mathrm{mol}^{-1}$ $\Delta H_C$ ($\mathrm{C}_2\mathrm{H}_4$) = -1400 \, $\mathrm{kJ}$ \, $\mathrm{mol}^{-1}$
Match List I with List II Choose the correct answer from the options given below :-
A-IV, B-I, C-II, D-III
A-IV, B-III, C-I, D-II
A-II, B-III, C-IV, D-I
A-IV, B-III, C-II, D-I
Answer: (d)
Solution
Cobalt catalyst leads to Methanol production. Syn gas leads to Coal gasification: $$\left( \mathrm{C_{(Red\, hot\, coke)}} + \mathrm{H_2O(g)} \rightarrow \mathrm{CO} + \mathrm{H_2} \right)$$ Nickel catalyst leads to Water gas production. Brine solution leads to Production: $$\left( \mathrm{(aq.\, NaCl)} \right)$$ $$\left( \begin{array}{c} \mathrm{H_2} \rightarrow Cathode \\ \mathrm{Cl_2} \rightarrow anode \end{array} \right)$$
Question 37
Chemistry · The s-Block Elements · Single correct
Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R Assertion A :- The alkali metals and their salts impart characteristic colour to reducing flame. Reason R :- Alkali metals can be detected using flame tests. In the light of the above statements, choose the most appropriate answer form the options given below
Both A and R are correct but R is NOT the correct explanation of A.
A is correct but R is not correct.
A is not correct but R is correct
Both A and R are correct and R is the correct explanation of A.
Answer: (c)
Solution
The alkali metals and their salts impart characteristic colour to oxidizing flame.
Question 38
Chemistry · The s-Block Elements · Single correct
Which one among the following metals is the weakest reducing agent?
K
Rb
Na
Li
Answer: (c)
Solution
Sodium have lowest oxidation potential in alkali metals. Hence it is weakest reducing agent among alkali metals.
Question 39
Chemistry · Classification of Elements and Periodicity in Properties · Single correct
Which of the following represents the correct order of metallic character of the given elements?
Si < Be < Mg < K
Be < Si < Mg < K
K < Mg < Be < Si
Be < Si < K < Mg
Answer: (a)
Solution
Metallic character increases down the group and decreases along the period.
Question 40
Chemistry · The p-Block Elements (Group-13 and 14) · Single correct
Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R. Assertion A :- Carbon forms two important oxides – CO and CO$_2$. CO is neutral whereas CO$_2$ is acidic in nature. Reason R :- CO$_2$ can combine with water in a limited way to form carbonic acid, while CO is sparingly soluble in water. In the light of the above statements, choose the most appropriate answer from the options given below :-
Both A and R are correct but R is NOT the correct explanation of A.
Both A and R are correct and R is the correct explanation of A.
A is not correct but R is correct.
A is correct but R is not correct.
Answer: (b)
Solution
The oxide which form acid on dissolving in water is acidic oxide.
Question 41
Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct
Match List I with List II. \begin{tabular}{|c|p{5.5cm}|c|p{3.5cm}|} \hline \multicolumn{2}{|c|}{List I} & \multicolumn{2}{c|}{List II} \\ \multicolumn{2}{|c|}{Isomeric pairs} & \multicolumn{2}{c|}{Type of isomers} \\ \hline A. & Propanamine and N-Methylethanamine & I. & Metamers \\ \hline B. & Hexan-2-one and Hexan-3-one & II. & Positional isomers \\ \hline C. & Ethanamide and Hydroxyethanimine & III. & Functional isomers \\ \hline D. & o-nitrophenol and p-nitrophenol & IV. & Tautomers \\ \hline \end{tabular}
A-III, B-IV, C-I, D-II
A-IV, B-III, C-I, D-II
A-II, B-III, C-I, D-IV
A-III, B-I, C-IV, D-II
Answer: (d)
Solution
A. Propanamine and N-Methylethanamine are functional isomers. B. Hexan-2-one and Hexan-3-one are metamers. C. Ethanamide and Hydroxyethanimine are tautomers. D. o-Nitrophenol and p-nitrophenol are positional isomers.
Question 42
Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct
The isomeric deuterated bromide with molecular formula $\mathrm{C_4H_8DBr}$ having two chiral carbon atoms is
2-Bromo-1-deuterobutane
2-Bromo-2-deuterobutane
2-Bromo-3-deuterobutane
2-Bromo-1-deutero-2-methylpropane
Answer: (c)
Solution
Question 43
Chemistry · Some Basic Concepts of Chemistry · Single correct
What is the mass ratio of ethylene glycol ($C_2H_6O_2$, molar mass = 62 $\mathrm{g/mol}$) required for making 500 $\mathrm{g}$ of 0.25 molal aqueous solution and 250 $\mathrm{mL}$ of 0.25 molar aqueous solution?
1 : 1
3 : 1
2 : 1
1 : 2
Answer: (c)
Solution
Assume: Mass of solvent $\approx$ Mass of solution Case I: $$0.25 = \frac{W_1}{62} \times \frac{1000}{500}$$ Case II: $$0.25 = \frac{W_2}{62} \times \frac{1000}{250}$$ $$W_1 = 2$$
Question 44
Chemistry · Solutions · Numerical
The number of pairs of the solution having the same value of the osmotic pressure from the following is ________. (Assume 100$\%$ ionization)
Given $\pi = iCRT$. Therefore, $\pi \propto iC$. A, B, D, and E have the same value of osmotic pressure.
Question 45
Chemistry · Electrochemistry · Numerical
$Pt(s)|H_2(g)(1\,bar)|H^+(aq)(1M)\parallel M^{3+}(aq),M^+(aq)|Pt(s)$ The $E_{\mathrm{cell}}$ for the given cell is $0.1115 \, \mathrm{V}$ at $298 \, \mathrm{K}$ when $\frac{[M^+(\mathrm{aq})]}{[M^{3+}(\mathrm{aq})]} = 10^a$ The value of $a$ is ________ Given : $E^0_{M^{3+}/M^+} = 0.2 \, \mathrm{V}$ $\frac{2.303 \, RT}{F} = 0.059 \, \mathrm{V}$
Answer: 3
Solution
Overall reaction: $$\mathrm{H_2}_{(g)} + \mathrm{M^{3+}}_{(aq)} \rightarrow \mathrm{M^+}_{(aq)} + 2\mathrm{H^+}_{(aq)}$$ The cell potential is given by: $$E_{Cell} = E^\circ_{Cathode} - E^\circ_{anode} - \frac{0.059}{2} \log \frac{[\mathrm{M^+}] \times 1^2}{[\mathrm{M^{+3}}] \times 1}$$ Substituting the values: $$0.1115 = 0.2 - \frac{0.059}{2} \log \frac{[\mathrm{M^+}]}{[\mathrm{M^{+3}}]}$$ Solving for the concentration ratio: $$3 = \log \frac{[\mathrm{M^+}]}{[\mathrm{M^{+3}}]}$$ Therefore, $a = 3$.
Question 46
Chemistry · Chemical Kinetics and Nuclear Chemistry · Multiple correct
A first order reaction has the rate constant, $k = 4.6 \times 10^{-3} \, \mathrm{s}^{-1}$. The number of correct statement/s from the following is/are ________. Given : $\log 3 = 0.48$
Reaction completes in 1000 s.
The reaction has a half-life of 500 s.
The time required for 10$\%$ completion is 25 times the time required for 90$\%$ completion.
The degree of dissociation is equal to $(1 - e^{-kt})$.
The rate and the rate constant have the same unit.
Based on the given figure, the number of correct statement/s is/are
Surface tension is the outcome of equal attractive and repulsion forces acting on the liquid molecule in bulk.
Surface tension is due to uneven forces acting on the molecules present on the surface.
The molecule in the bulk can never come to the liquid surface.
The molecules on the surface are responsible for vapour pressure if the system is a closed system.
Answer: (b)
Solution
B and D options are correct
Question 48
Chemistry · Surface Chemistry · Numerical
The number of incorrect statement/s from the following is/are ________
Water vapours are adsorbed by anhydrous calcium chloride.
There is a decrease in surface energy during adsorption.
As the adsorption proceeds, $\Delta H$ becomes more and more negative.
Adsorption is accompanied by decrease in
Answer: (b)
Solution
'A' water vapours are absorbed by calcium chloride. C. As the adsorption proceeds, $\Delta H$ becomes less and less negative.
Question 49
Chemistry · General Principles and Processes of Isolation of Elements · Single correct
Given below are two statements :- Statement I :- In froth floatation method a rotating paddle agitates the mixture to drive air out of it. Statement II :- Iron pyrites are generally avoided for extraction of iron due to environmental reasons. In the light of the above statements, choose the correct answer from the options given below :-
Both Statement I and Statement II are true
Statement I is false but Statement II is true
Statement I is true but Statement II is false
Both Statement I and Statement II are false
Answer: (b)
Solution
In froth floatation method a rotating paddle draws in air and stirs the pulp.
Question 50
Chemistry · Analytical Chemistry · Single correct
A chloride salt solution acidified with dil. $\mathrm{HNO_3}$ gives a curdy white precipitate, [A], on addition of $\mathrm{AgNO_3}$. [A] on treatment with $\mathrm{NH_4OH}$ gives a clear solution, B.
$H[AgCl_3]$ & $[Ag(NH_3)_2]Cl$
$H[AgCl_3]$ & $(NH_4)[Ag(OH)_2]$
$AgCl$ & $[Ag(NH_3)_2]Cl$
$AgCl$ & $(NH_4)[Ag(OH)_2]$
Answer: (c)
Solution
The reaction of $\mathrm{Cl^-}$ with $\mathrm{AgNO_3}$ produces $\mathrm{AgCl}$, which is a curdy white precipitate. $$\mathrm{Cl^- + AgNO_3 \rightarrow AgCl}$$ This is labeled as $[A]$. Next, $\mathrm{AgCl}$ reacts with $\mathrm{NH_4OH}$ to form a soluble complex $\mathrm{[Ag(NH_3)_2]Cl}$. $$\mathrm{AgCl + NH_4OH \rightarrow [Ag(NH_3)_2]Cl}$$ This is labeled as $[B]$ (Soluble Complex).
Question 51
Chemistry · The d-and f-Block Elements · Single correct
Potassium dichromate acts as a strong oxidizing agent in acidic solution. During this process, the oxidation state changes from
+3 to +1
+6 to +3
Answer: (b)
Solution
The reaction is given by: $$14\mathrm{H}^+ + 6\mathrm{e}^- + \mathrm{Cr_2O_7}^{-2} \rightarrow 2\mathrm{Cr}^{+3} + 7\mathrm{H_2O}$$
Question 52
Chemistry · Co-ordination Compounds · Single correct
Match List I with List II Choose the correct answer from the options given below :-
A-IV, B-I, C-III, D-II
A-III, B-II, C-I, D-IV
A-III, B-I, C-II, D-IV
A- II, B-III, C-IV, D-I
Answer: (b)
Solution
Given the relationship $E = \frac{hc}{\lambda}$, we have $E \propto \frac{1}{\lambda}$. Therefore, $\Delta(CFSE) \propto \frac{1}{\lambda_{absorb}} \propto$ strength of ligand.
Question 53
Chemistry · Co-ordination Compounds · Numerical
The total number of moles of $\mathrm{AgCl}$ precipitated on addition of excess $\mathrm{AgNO_3}$ to one mole each of the following complexes: $[\mathrm{Co(NH_3)_4Cl_2}]\mathrm{Cl}$, $[\mathrm{Ni(H_2O)_6}]\mathrm{Cl}_2$, $[\mathrm{Pt(NH_3)_2Cl_2}]$ and $[\mathrm{Pd(NH_3)_4}]\mathrm{Cl}_2$ is:
Answer: 5
Solution
[$\mathrm{Co(NH_3)_4Cl_2}$]$\mathrm{Cl}$ $\Rightarrow$ Gives 1 mole AgCl [$\mathrm{Ni(H_2O)_6}$]$\mathrm{Cl_2}$ $\Rightarrow$ Gives 2 moles AgCl [$\mathrm{Pt(NH_3)_2Cl_2}$] $\Rightarrow$ Gives No AgCl [$\mathrm{Pd(NH_3)_4}$]$\mathrm{Cl_2}$ $\Rightarrow$ Gives 2 moles AgCl Total number of moles of AgCl = 5 mole
Question 54
Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct
Find out the major product from the following reaction.
Answer: (a)
Solution
Question 55
Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct
'A' in the given reaction is
Answer: (b)
Solution
Question 56
Chemistry · Chemistry in Everyday Life · Single correct
Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R Assertion A :- Butylated hydroxyl anisole when added to butter increases its shelf life. Reason R :- Butylated hydroxyl anisole is more reactive towards oxygen than food. In the light of the above statements, choose the most appropriate answer from the options given below :-
Both A and R are correct and R is the correct explanation of A.
A is correct but R is not correct.
A is not correct but R is correct.
Both A and R are correct but R is NOT the correct explanation of A.
Answer: (a)
Solution
Butylated hydroxyl anisole is an antioxidant
Question 57
Chemistry · Alcohols, Phenols and Ethers · Numerical
Number of compounds giving (i) red colouration with ceric ammonium nitrate and also (ii) positive iodoform test from the following is
Answer: 3
Solution
Question 58
Chemistry · Equilibrium · Single correct
Match List I with List II Choose the correct answer from the options given below :-
A-I, B-IV, C-II, D-III
A-III, B-II, C-I, D-IV
A-III, B-II, C-IV, D-I
A-III, B-IV, C-II, D-I
Answer: (d)
Solution
Basic strength is proportional to $\frac{1}{pK_b}$. Order for $pK_b$: A > B > D > C.
Question 59
Chemistry · Polymers · Single correct
\begin{tabular}{|l|l|} \hline \textbf{List-I} & \textbf{List-II} \\ \hline (A) Glyptal & (I) Flexible pipes \\ \hline (B) Neoprene & (II) Synthetic wool \\ \hline (C) Acrilan & (III) Paints and Lacquers \\ \hline (D) LDP & (IV) Gaskets \\ \hline \end{tabular} Choose the correct answer from the options given below :-
A-III, B-II, C-IV, D-I
A-III, B-IV, C-II, D-I
A-III, B-IV, C-I, D-II
A-III, B-I, C-IV, D-II
Answer: (b)
Solution
Fact based
Question 60
Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct
A. Ammonium salts produce haze in atmosphere. B. Ozone gets produced when atmospheric oxygen reacts with chlorine radicals. C. Polychlorinated biphenyls act as cleansing solvents. D. 'Blue baby' syndrome occurs due to the presence of excess of sulphate ions in water. Choose the correct answer from the options given below :-
A, B and C only
B and C only
A and D only
A and C only
Answer: (d)
Solution
B. $\mathrm{Cl} + \mathrm{O_3} \longrightarrow \mathrm{O_2} + \mathrm{ClO}$ D. 'Blue baby' syndrome occurs due to the presence of excess of nitrate ions in water.
Maths
Question 61
Maths · Complex Numbers and Quadratic Equations · Fill in the blank
Let $a \in \mathbb{R}$ and let $\alpha$, $\beta$ be the roots of the equation $x^2 + \frac{1}{4}60x + a = 0$. If $\alpha^4 + \beta^4 = -30$, then the product of all possible values of $a$ is _____.
Answer: 45
Solution
Given $x^2 + 60^{\frac{1}{4}} x + a = 0$ with roots $\alpha$ and $\beta$. We have $\alpha + \beta = -60^{\frac{1}{4}}$ and $\alpha \beta = a$. Given $\alpha^4 + \beta^4 = -30$. This implies $$\left(\alpha^2 + \beta^2\right)^2 - 2\alpha^2 \beta^2 = -30$$ which further implies $$\left((\alpha + \beta)^2 - 2\alpha \beta\right)^2 - 2a^2 = -30$$ Substituting the known values, we get $$\left(60^{\frac{1}{2}} - 2a\right)^2 - 2a^2 = -30$$ Expanding, $$60 + 4a^2 - 4a \times 60^{\frac{1}{2}} - 2a^2 = -30$$ Simplifying, $$2a^2 - 4 \cdot 60^{\frac{1}{2}} a + 90 = 0$$ The product is $$\frac{90}{2} = 45$$
Question 62
Maths · Complex Numbers and Quadratic Equations · Single correct
Let $z$ be a complex number such that $$\left| \frac{z - 2i}{z + i} \right| = 2, z \neq -i.$$ Then $z$ lies on the circle of radius 2 and centre
(2, 0)
(0, 0)
(0, 2)
(0, -2)
Answer: (d)
Solution
Given $(z - 2i)(\overline{z} + 2i) = 4(z + i)(\overline{z} - i)$. Expanding both sides, we have: $$z \overline{z} + 4 + 2i(z - \overline{z}) = 4(z \overline{z} + 1 + i(\overline{z} - z))$$ Simplifying, we get: $$3z \overline{z} - 6i(z - \overline{z}) = 0$$ Separating real and imaginary parts, we have: $$x^2 + y^2 - 2i(2iy) = 0$$ This simplifies to: $$x^2 + y^2 + 4y = 0$$
Question 63
Maths · Permutations and Combinations · Single correct
The number of numbers, strictly between 5000 and 10000 can be formed using the digits 1,3,5,7,9 without repetition, is
6
12
120
72
Answer: (d)
Solution
Numbers between 5000 and 10000. Using digits 1, 3, 5, 7, 9. The first digit can be 5, 7, or 9, giving 3 options. The second digit can be any of the 4 remaining digits. The third digit can be any of the 3 remaining digits. The fourth digit can be any of the 2 remaining digits. Total numbers are calculated as follows: $$3 \times 4 \times 3 \times 2 = 72$$
Question 64
Maths · Permutations and Combinations · Numerical
Suppose Anil's mother wants to give 5 whole fruits to Anil from a basket of 7 red apples, 5 white apples and 8 oranges. If in the selected 5 fruits, at least 2 orange, at least one red apple and at least one white apple must be given, then the number of ways, Anil's mother can offer 5 fruits to Anil is
Answer: 6860
Solution
7 Red apple (RA), 5 white apple (WA), 8 oranges (O) 5 fruits to be selected (Note: fruits taken different) Possible selections: (2O, 1RA, 2WA) or (2O, 2RA, 1WA) or (3O, 1RA, 1WA) $$\Rightarrow \binom{8}{2} \binom{7}{1} \binom{5}{2} + \binom{8}{2} \binom{7}{2} \binom{5}{1} + \binom{8}{3} \binom{7}{1} \binom{5}{1}$$ $$\Rightarrow 1960 + 2940 + 1960$$ $$\Rightarrow 6860$$
Question 65
Maths · Relations and Functions · Single correct
Let $f(x) = 2^n + \lambda$, $\lambda \in \mathbb{R}$, $n \in \mathbb{N}$, and $f(4)=133$, $f(5)=255$. Then the sum of all the positive integer divisors of $(f(3)-f(2))$ is
61
60
58
59
Answer: (b)
Solution
Given $f(x) = 2x^n + \lambda$. $f(4) = 133$ $f(5) = 255$ $133 = 2 \times 4^n + \lambda$ (1) $255 = 2 \times 5^n + \lambda$ (2) Subtracting (1) from (2): $$122 = 2(5^n - 4^n)$$ $$\Rightarrow 5^n - 4^n = 61$$ Therefore, $n = 3$ and $\lambda = 5$. Now, $f(3) - f(2) = 2(3^3 - 2^3) = 38$. The number of divisors is $1, 2, 19, 38$; their sum is $60$.
Question 66
Maths · Sequences and Series · Fill in the blank
For the two positive numbers $a$, $b$, if $a$, $b$ and $\frac{1}{18}$ are in a geometric progression, while $\frac{1}{a}$, $10$ and $\frac{1}{b}$ are in an arithmetic progression, then, $16a + 12b$ is equal to _____.
Answer: 3
Solution
Given $a, b, \frac{1}{18} \to GP$. $$\frac{a}{18} = b^2 ..... (i)$$ Given $\frac{1}{a}, 10, \frac{1}{b} \to AP$. $$\frac{1}{a} + \frac{1}{b} = 20$$ This implies $a + b = 20ab$, from equation (i); we get $$18b^2 + b = 360b^3$$ $$\Rightarrow 360b^2 - 18b - 1 = 0 \{\because b \neq 0\}$$ $$\Rightarrow b = \frac{18 \pm \sqrt{324 + 1440}}{720}$$ $$\Rightarrow b = \frac{18 + \sqrt{1764}}{720} \{\because b > 0\}$$ $$\Rightarrow b = \frac{1}{12}$$ $$\Rightarrow a = 18 \times \frac{1}{144} = \frac{1}{8}$$ Now, $16a + 12b = 16 \times \frac{1}{8} + 12 \times \frac{1}{12} = 3$
The remainder when $(2023)^{2023}$ is divided by 35
Answer: 7
Solution
$(2023)^{2023}$ $=(2030-7)^{2023}$ $=(35K-7)^{2023}$ $={}^{2023}C_{0}(35K)^{2023}(-7)^{0} +{}^{2023}C_{1}(35K)^{2022}(-7) +\cdots +{}^{2023}C_{2023}(-7)^{2023}$ $=35N-7^{2023}$ Now, $-7^{2023}$ $=-7\times7^{2022}$ $=-7(7^{2})^{1011}$ $=-7(50-1)^{1011}$ $=-7\left( {}^{1011}C_{0}50^{1011} -{}^{1011}C_{1}50^{1010} +\cdots +{}^{1011}C_{1011} \right)$ $=-7(5\lambda-1)$ $=-35\lambda+7$ $\therefore$ when $(2023)^{2023}$ is divided by $35,$ the remainder is $7.$
Question 69
Maths · Trigonometric Functions · Numerical
If m and n respectively are the numbers of positive and negative value of $\theta$ in the interval $[-\pi, \pi]$ that satisfy the equation $\cos 2 \theta \cos \frac{\theta}{2} = \cos 3 \theta \cos \frac{9 \theta}{2}$, then mn is equal to ____.
Maths · Straight Lines and Pair of Straight Lines · Numerical
A triangle is formed by X-axis, Y-axis and the line $3x + 4y = 60$. Then the number of points $P(a, b)$ which lie strictly inside the triangle, where $a$ is an integer and $b$ is a multiple of $a$, is_____.
Answer: 31
Solution
Given the equation $2\alpha + 24 - 12\alpha + 3 = 0$. Simplifying, we have $9\alpha + 27 = 0$. Solving for $\alpha$, we get $\alpha = -3$, $\beta = 5$. So $BC = \sqrt{122}$ and $(BC)^2 = 122$. If $x = 1$, $y = \frac{57}{4} = 14.25$. For the points $(1, 1)$, $(1, 2)$ to $(1, 14)$, this gives $14$ points. If $x = 2$, $y = \frac{27}{2} = 13.5$. For the points $(2, 2)$, $(2, 4)$ to $(2, 12)$, this gives $6$ points. If $x = 3$, $y = \frac{51}{4} = 12.75$. For the points $(3, 3)$, $(3, 6)$ to $(3, 12)$, this gives $4$ points. If $x = 4$, $y = 12$. For the points $(4, 4)$, $(4, 8)$, this gives $2$ points. If $x = 5$, $y = \frac{45}{4} = 11.25$. For the points $(5, 5)$, $(5, 10)$, this gives $2$ points. If $x = 6$, $y = \frac{21}{2} = 10.5$.If $x = 7$, $y = \frac{39}{4} = 9.75$
Question 71
Maths · Conic Sections · Numerical
Points P(-3,2), Q(9,10) and R($\alpha$,4) lie on a circle C with PR as its diameter. The tangents to C at the points Q and R intersect at the point S. If S lies on the line $2x - ky = 1$, then k is equal to _____.
The equations of two sides of a variable triangle are $x = 0$ and $y = 3$, and its third side is a tangent to the parabola $y^2 = 6x$. The locus of its circumcentre is:
$4y^2 - 18y - 3x - 18 = 0$
$4y^2 + 18y + 3x + 18 = 0$
$4y^2 - 18y + 3x + 18 = 0$
$4y^2 - 18y - 3x + 18 = 0$
Answer: (c)
Solution
Given $y^2 = 6x$ and $y^2 = 4ax$. Therefore, $4a = 6$ implies $a = \frac{3}{2}$. The line equation is $y = mx + \frac{3}{2m}$; $(m \neq 0)$. The coordinates are $h = \frac{6m - 3}{4m^2}$, $k = \frac{6m + 3}{4m}$. Now eliminating $m$, we get $$3h = 2(-2k^2 + 9k - 9)$$ $$4y^2 - 18y + 3x + 18 = 0$$ $$21\alpha + 12(2 - \alpha) + 3 = 0$$
Question 73
Maths · Mathematical Reasoning · Single correct
Let $\Delta$, $\nabla \in \{\land, \lor\}$ be such that $(p \rightarrow q) \Delta (p \lor q)$ is a tautology. Then
$\Delta = \land, \nabla = \lor$
$\Delta = \lor, \nabla = \land$
$\Delta = \lor, \nabla = \lor$
$\Delta = \land, \nabla = \land$
Answer: (c)
Solution
Given $(p \rightarrow q) \Delta (p \lor q)$. Option 1: $\Delta = \land$, $\nabla = \lor$ $\[$ \begin{tabular}{|l|l|l|l|} \hline p & q & (p $\rightarrow$ q) & (p $\lor$ q) & (p $\rightarrow$ q) $\land$ (p $\lor$ q) \\ \hline T & T & T & T & T \\ \hline T & F & F & T & F \\ \hline F & T & T & T & T \\ \hline F & F & T & F & F\\ \hline \end{tabular} Option 2: $\Delta = \lor$, $\nabla = \land$ $\[$ \begin{tabular}{|l|l|l|l|} \hline p & q & (p $\rightarrow$ q) & (p $\lor$ q) & (p $\rightarrow$ q) $\land$ (p $\lor$ q) \\ \hline T & T & T & T & T \\ \hline T & F & F & T & F \\ \hline F & T & T & T & T \\ \hline F & F & T & F & T \\ \hline \end{tabular} Option 3: $\Delta = \lor$, $\nabla = \lor$ $\[$ \begin{tabular}{|l|l|l|l|} \hline p & q & (p $\rightarrow$ q) & (p $\lor$ q) & (p $\rightarrow$ q) $\land$ (p $\lor$ q) \\ \hline T & T & T & T & T \\ \hline T & F & F & T & T \\ \hline F & T & T & T & T \\ \hline F & F & T & F & T \\ \hline \end{tabular} Hence, it is tautology. Option 4: $\Delta = \land$, $\nabla = \land$ $\[$ \begin{tabular}{|l|l|l|l|} \hline p & q & (p $\rightarrow$ q) & (p $\lor$ q) & (p $\rightarrow$ q) $\land$ (p $\lor$ q) \\ \hline T & T & T & T & T \\ \hline T & F & F & F & F \\ \hline F & T & T & F & F \\ \hline F & F & T & F & F \\ \hline \end{tabular}
Question 74
Maths · Matrices · Single correct
Let $A$, $B$, $C$ be $3 \times 3$ matrices such that $A$ is symmetric and $B$ and $C$ are skew-symmetric. Consider the statements (S1) $A^{13} B^{26} - B^{26} A^{13}$ is symmetric (S2) $A^{26} C^{13} - C^{13} A^{26}$ is symmetric Then,
Let $A = \begin{bmatrix} \frac{1}{\sqrt{10}} & \frac{3}{\sqrt{10}} \\ -\frac{3}{\sqrt{10}} & \frac{1}{\sqrt{10}} \end{bmatrix}$ and $B = \begin{bmatrix} 1 & -i \\ 0 & 1 \end{bmatrix}$, where $i = \sqrt{-1}$. If $M = A^{\top} B A$, then the inverse of the matrix $AM^{2023} A^{\top}$ is
Let f: $\mathbb{R}$ $\to$ $\mathbb{R}$ be a function defined by $f(x) = \log_{\sqrt{m}} \left\{ \sqrt{2} (\sin x - \cos x) + m - 2 \right\}$, for some $m$, such that the range of $f$ is $[0, 2]$. Then the value of $m$ is
5
3
2
4
Answer: (a)
Solution
Since, $-\sqrt{2} \leq \sin x - \cos x \leq \sqrt{2}$. Therefore, $-2 \leq \sqrt{2} (\sin x - \cos x) \leq 2$. Assume $\sqrt{2} (\sin x - \cos x) = k$. Then $-2 \leq k \leq 2$ $\ldots$ (i). $f(x) = \log_{\sqrt{m}} (k + m - 2)$. Given, $0 \leq f(x) \leq 2$. So, $0 \leq \log_{\sqrt{m}} (k + m - 2) \leq 2$. This implies $1 \leq k + m - 2 \leq m$. Therefore, $-m + 3 \leq k \leq 2$ $\ldots$ (ii). From eq. (i) $\&$ (ii), we get $-m + 3 = -2$. Thus, $m = 5$.
Question 77
Maths · Relations and Functions · Single correct
The number of functions $f : \{1,2,3,4\} \to \{a \in \mathbb{Z} : |a| \leq 8\}$ satisfying $f(n) + \frac{1}{n} f(n+1) = 1$, $\forall n \in \{1,2,3\}$ is
3
4
1
2
Answer: (d)
Solution
Given the function $f: \{1, 2, 3, 4\} \to \{a \in \mathbb{Z} : |a| \leq 8\}$. The equation is $f(n) + \frac{1}{n} f(n+1) = 1$, for all $n \in \{1, 2, 3\}$. The value $f(n+1)$ must be divisible by $n$. For $f(4)$, the possible values are $-6, -3, 0, 3, 6$. For $f(3)$, the possible values are $-8, -6, -4, -2, 0, 2, 4, 6, 8$. For $f(2)$, the possible values are $-8, \ldots, 8$. For $f(1)$, the possible values are $-8, \ldots, 8$. The value $\frac{f(4)}{3}$ must be odd since $f(3)$ should be even. Therefore, 2 solutions are possible. $\begin{array}{cccc}$ f(4) & f(3) & f(2) & f(1) $\\$ -3 & 2 & 0 & 1 $\\$ 3 & 0 & 1 & 0 $\\$ $\end{array}$
Question 78
Maths · Continuity and Differentiability · Single correct
If the function $$f(x) = \begin{cases} \left(1 + |\cos x|\right) \frac{\lambda}{|\cos x|}, & 0 < x < \frac{\pi}{2} \\ \mu, & x = \frac{\pi}{2} \\ \frac{\cot 6x}{e^{\cot 4x}}, & \frac{\pi}{2} < x < \pi \end{cases}$$ is continuous at $x = \frac{\pi}{2}$, then $$9\lambda + 6 \log_e \mu + \mu^6 - e^{6\lambda}$$ is equal to
Maths · Applications of Derivatives · Single correct
Let the function f(x)=2$x^3$ + (2p-7)$x^2$+3(2p-9)x-6 have a maxima for some value of x 0. Then, the set of all values of p is
$(\frac{9}{2}, \infty)$
$(0, \frac{9}{2})$
$(-\infty, \frac{9}{2})
$(-\frac{9}{2}, \frac{9}{2})$
Answer: (c)
Solution
Given $f(x) = 2x^3 + (2p - 7)x^2 + 3(2p - 9)x - 6$. The derivative is $f'(x) = 6x^2 + 2(2p - 7)x + 3(2p - 9)$. We have $f'(0) < 0$. Therefore, $3(2p - 9) < 0$. Solving gives $p < \frac{9}{2}$. Thus, $p \in \left(-\infty, \frac{9}{2}\right)$.
Question 80
Maths · Integrals · Single correct
The integral $16 \int_{1}^{2} \frac{\mathrm{d}x}{x^3 (x^2 + 2)^2}$ is equal to
$\frac{11}{6} + \log_e 4$
$\frac{11}{12} + \log_e 4$
$\frac{11}{12} - \log_e 4$
$\frac{11}{6} - \log_e 4$
Answer: (d)
Solution
Given $$I = 16 \int_1^2 \frac{dx}{x^3 (x^2 + 2)^2}$$ This can be rewritten as $$= 16 \int_1^2 \frac{dx}{x^3 x^4 \left(1 + \frac{2}{x^2}\right)^2}$$ Let, $$1 + \frac{2}{x^2} = t \implies -\frac{4}{x^3} dx = dt$$ Then, $$I = 4 \int_{\frac{3}{2}}^{\frac{7}{3}} \frac{dt}{\left(\frac{2}{t-1}\right) t^2}$$ This simplifies to $$I = -4 \int_{\frac{3}{2}}^{\frac{7}{3}} \left(\frac{t-1}{2}\right)^2 \frac{dt}{t^2}$$ Further simplifying, $$I = \frac{4}{4} \int_{\frac{3}{2}}^{\frac{7}{3}} \left(1 - \frac{2}{t} + \frac{1}{t^2}\right) dt$$ This results in $$I = -1 \left[t - 2 \ln|t| - \frac{1}{t}\right]_{\frac{3}{2}}^{\frac{7}{3}}$$ Evaluating the integral, $$I = -1 \left[\left(\frac{3}{2} - 2 \ln \frac{3}{2} - \frac{3}{2}\right) - \left(3 - 2 \ln 3 - \frac{1}{3}\right)\right]$$ This simplifies to $$I = -1 \left[2 \ln 2 - \frac{11}{6}\right]$$ Finally, $$I = \frac{11}{6} - \ln 4$$
Question 81
Maths · Integrals · Numerical
If $$\int_{\frac{1}{3}}^{3} |\log_e x| \, dx = \frac{m}{n} \log_e \left( \frac{n^2}{e} \right)$$, where $m$ and $n$ are coprime natural numbers, then $m^2 + n^2 - 5$ is equal to _____.
Let T and C respectively be the transverse and conjugate axes of the hyperbola $16x^2 - y^2 + 64x + 4y + 44 = 0$. Then the area of the region above the parabola $x^2 = y + 4$, below the transverse axis T and on the right of the conjugate axis C is:
$4\sqrt{6} + \frac{44}{3}$
$4\sqrt{6} + \frac{28}{3}$
$4\sqrt{6} - \frac{44}{3}$
$4\sqrt{6} - \frac{28}{3}$
Answer: (b)
Solution
Given the equation $16(x^2 + 4x) - (y^2 - 4y) + 44 = 0$. Simplifying, we have: $$16(x + 2)^2 - 64 - (y - 2)^2 + 4 + 44 = 0$$ $$16(x + 2)^2 - (y - 2)^2 = 16$$ This can be rewritten as: $$\frac{(x + 2)^2}{1} - \frac{(y - 2)^2}{16} = 1$$ The area $A$ is given by the integral: $$A = \int_{2}^{\sqrt{6}} \left(2 - (x^2 - 4)\right) \, dx$$ Simplifying the integral: $$A = \int_{2}^{\sqrt{6}} (6 - x^2) \, dx = \left(6x - \frac{x^3}{3}\right) \bigg|_{2}^{\sqrt{6}}$$ Evaluating the integral: $$A = \left(6\sqrt{6} - \frac{6\sqrt{6}}{3}\right) - \left(-12 + \frac{8}{3}\right)$$ Simplifying further: $$A = \frac{12\sqrt{6}}{3} + \frac{28}{3}$$ Thus, the area is: $$A = 4\sqrt{6} + \frac{28}{3}$$
Question 83
Maths · Differential Equations · Single correct
Let y=y(t) be a solution of the differential equation $$\frac{dy}{dt} + \alpha y = \gamma e^{-\beta t}$$ Where, $\alpha > 0$, $\beta > 0$ and $\gamma > 0$. Then $\lim_{t \to \infty} y(t)$
If the four points, whose position vectors are $3\hat{i}-4\hat{j}+2\hat{k}$, $\hat{i}+2\hat{j}-\hat{k}$, $-2\hat{i}-\hat{j}+3\hat{k}$ and $5\hat{i}-2\alpha\hat{j}+4\hat{k}$ are coplanar, then $\alpha$ is equal to
Maths · Three Dimensional Geometry · Single correct
The foot of perpendicular of the point $(2, 0, 5)$ on the line $\frac{x+1}{2} = \frac{y-1}{5} = \frac{z+1}{-1}$ is $(\alpha, \beta, \gamma)$. Then. Which of the following is NOT correct?
Maths · Three Dimensional Geometry · Fill in the blank
If the shortest distance between the line joining the points (1, 2, 3) and (2, 3, 4), and the line $\frac{x-1}{2} = \frac{y+1}{-1} = \frac{z-2}{0}$ is $\alpha$, then $28\alpha^2$ is equal to ___.
Let N be the sum of the numbers appeared when two fair dice are rolled and let the probability that $N - 2, \sqrt{3N}, N + 2$ are in geometric progression be $\frac{k}{48}$. Then the value of $k$ is
25$\%$ of the population are smokers. A smoker has 27 times more chances to develop lung cancer then a non-smoker. A person is diagnosed with lung cancer and the probability that this person is a smoker is $\frac{k}{10}$. Then the value of $k$ is _____.
Answer: 9
Solution
Let $E_1$ be smokers. The probability $P(E_1) = \frac{1}{4}$. Let $E_2$ be non-smokers. The probability $P(E_2) = \frac{3}{4}$. Let $E$ be diagnosed with lung cancer. The probability $P(E/E_1) = \frac{27}{28}$ and $P(E/E_2) = \frac{1}{28}$. The probability $P(E_1/E)$ is given by: $$P(E_1/E) = \frac{P(E_1)P(E/E_1)}{P(E)}$$ Substituting the values, we have: $$= \frac{\frac{1}{4} \times \frac{27}{28}}{\frac{1}{4} \times \frac{27}{28} + \frac{3}{4} \times \frac{1}{28}} = \frac{\frac{27}{112}}{\frac{30}{112}} = \frac{9}{10}$$ Thus, $K = 9$.