JEE Main 22 January 2025 Shift 1 question paper with solutions

JEE Main 22 January 2025 Shift 1: all 75 questions in paper order (Maths, Physics, Chemistry) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.

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Maths

Question 1

Maths · Sets · Single correct

The number of non-empty equivalence relations on the set $\{1,2,3\}$ is:

  1. 6
  2. 5
  3. 7
  4. 4

Answer: (b)

Solution

Let $R$ be the required relation. $A = \{(1,1), (2,2), (3,3)\}$ (i) $|R| = 3$, when $R = A$ (ii) $|R| = 5$, e.g. $R = A \cup \{(1,2), (2,1)\}$ Number of $R$ can be $[3]$ (iii) $R = \{1,2,3\} \times \{1,2,3\}$ Ans. (5)

Question 2

Maths · Applications of Integrals · Single correct

Let $f : \mathbb{R} \to \mathbb{R}$ be a twice differentiable function such that $f(x+y) = f(x)f(y)$ for all $x, y \in \mathbb{R}$. If $f'(0) = 4a$ and $f$ satisfies $f''(x) - 3a f'(x) - f(x) = 0$, $a > 0$, then the area of the region $R = \{(x, y) \mid 0 \leq y \leq f(ax), 0 \leq x \leq 2\}$ is:

  1. $e^2 - 1$
  2. $e^2 + 1$
  3. $e^4 + 1$
  4. $e^4 - 1$

Answer: (a)

Solution

Given $f(x+y) = f(x) \cdot f(y)$. (1) $\Rightarrow f(x) = e^{\lambda x}$, $f'(0) = 4a$ $\Rightarrow f'(x) = \lambda e^{\lambda x} \Rightarrow \lambda = 4a$ So, $f(x) = e^{4ax}$ $f''(x) - 3af'(x) - f(x) = 0$ $\Rightarrow \lambda^2 - 3a\lambda - 1 = 0$ $\Rightarrow 16a^2 - 12a^2 - 1 = 0 \Rightarrow 4a^2 = 1 \Rightarrow a = \frac{1}{2}$ $F(x) = e^{2x}$ Area $= \int_0^2 e^x \, dx = e^2 - 1$

Question 3

Maths · Straight Lines and Pair of Straight Lines · Single correct

Let the triangle PQR be the image of the triangle with vertices (1,3), (3,1) and (2,4) in the line $x + 2y = 2$. If the centroid of $\triangle PQR$ is the point $(\alpha, \beta)$, then $15(\alpha - \beta)$ is equal to:

  1. 19
  2. 24
  3. 21
  4. 22

Answer: (d)

Solution

The centroid $G''(\alpha, \beta)$ of $\triangle PQR$ is the image of the centroid of the given triangle $P'Q'R'$. Centroid of $\triangle P'Q'R' = \left( \frac{1+3+2}{3}, \frac{3+1+4}{3} \right) = G' \left( 2, \frac{8}{3} \right)$. Image of $G \left( 2, \frac{8}{3} \right)$ with respect to the line $x + 2y = 2$ is $(\alpha, \beta)$. Then $$\frac{\alpha - 2}{1} = \frac{\beta - \frac{8}{3}}{2} = \frac{-2 \left( 2 + \frac{16}{3} - 2 \right)}{1 + 4}$$ Therefore, $$\frac{\alpha - 2}{1} = \frac{\beta - \frac{8}{3}}{2} = \frac{-32}{15}$$ Thus, $$\alpha = -\frac{2}{15}$$ and $$\beta = -\frac{8}{5}$$ Then $$15(\alpha - \beta) = 15 \left( -\frac{2}{15} + \frac{24}{15} \right) = 22$$

Question 4

Maths · Complex Numbers and Quadratic Equations · Single correct

Let $z_1$, $z_2$ and $z_3$ be three complex numbers on the circle $|z| = 1$ with $\arg(z_1) = \frac{-\pi}{4}$, $\arg(z_2) = 0$ and $\arg(z_3) = \frac{\pi}{4}$. If $\left| z_1 \overline{z_2} - z_2 \overline{z_3} + z_3 \overline{z_1} \right|^2 = \alpha + \beta \sqrt{2}$, $\alpha, \beta \in \mathbb{Z}$, then the value of $\alpha^2 + \beta^2$ is:

  1. 24
  2. 29
  3. 41
  4. 31

Answer: (b)

Solution

Given $|z| = 1$. For $\arg(z_1) = -\frac{\pi}{4}$, $\arg(z_2) = 0$, $\arg(z_3) = \frac{\pi}{4}$, we have: $$z_1 = |1| e^{-\frac{\pi}{4}i} = \frac{1}{\sqrt{2}} - \frac{i}{\sqrt{2}}$$ $$z_2 = 1 + 0i$$ $$z_3 = \frac{1}{\sqrt{2}} + \frac{i}{\sqrt{2}}$$ $$z_1 \overline{z_2} = 1 - i$$ $$z_2 \overline{z_3} = \frac{1 - i}{\sqrt{2}}$$ $$(1 + i)^2$$ $$z_3 \overline{z_1} = 2$$ $$z_1 \overline{z_2} + z_2 \overline{z_3} + z_3 \overline{z_1} = \sqrt{2} + i(1 - \sqrt{2})$$ $$|z_1 \overline{z_2} + z_2 \overline{z_3} + z_3 \overline{z_1}|^2 = 5 - 2\sqrt{2}$$ $$\alpha = 5, \beta = -2$$ $$\alpha^2 + \beta^2 = 29$$

Question 5

Maths · Inverse Trigonometric Functions · Single correct

Using the principal values of the inverse trigonometric functions, the sum of the maximum and the minimum values of $16\left((\sec^{-1}x)^2 + (\csc^{-1}x)^2\right)$ is:

  1. 24$\pi$^2
  2. 22$\pi$^2
  3. 31$\pi$^2
  4. 18$\pi$^2

Answer: (b)

Solution

Given $16(\sec^{-1} x)^2 + (\csc^{-1} x)^2$. Let $\sec^{-1} x = a \in [0, \pi] - \left\{ \frac{\pi}{2} \right\}$. Then $\csc^{-1} x = \frac{\pi}{2} - a$. This becomes: $$= 16 \left[ a^2 + \left( \frac{\pi}{2} - a \right)^2 \right] = 16 \left[ 2a^2 - \pi a + \frac{\pi^2}{4} \right]$$ For $\max|_{a=\pi}$: $$= 16 \left[ 2\pi^2 - \pi^2 + \frac{\pi^2}{4} \right] = 20\pi^2$$ For $\min|_{a=\frac{\pi}{4}}$: $$= 16 \left[ 2 \times \frac{\pi^2}{16} - \frac{\pi^2}{4} \right] = 2\pi^2$$ Sum $= 22\pi^2$

Question 6

Maths · Probability (Advanced) · Single correct

A coin is tossed three times. Let $X$ denote the number of times a tail follows a head. If $\mu$ and $\sigma^2$ denote the mean and variance of $X$, then the value of $64 \left( \mu + \sigma^2 \right)$ is:

  1. 51
  2. 64
  3. 32
  4. 48

Answer: (d)

Solution

The mean $\mu$ is calculated as $\mu = \sum x_i P_i = \frac{1}{2}$. The variance $\sigma^2$ is calculated as $\sigma^2 = \sum x_i^2 P_i - \mu^2 = \frac{1}{2} - \frac{1}{4} = \frac{1}{4}$. Therefore, $64 (\mu + \sigma^2) = 64 \left[ \frac{1}{2} + \frac{1}{4} \right] = 64 \times \frac{3}{4} = 48$.

Question 7

Maths · Sequences and Series · Single correct

Let $a_1, a_2, a_3, \ldots$ be a G.P. of increasing positive terms. If $a_1 a_5 = 28$ and $a_2 + a_4 = 29$, then $a_6$ is equal to

  1. 628
  2. 812
  3. 526
  4. 784

Answer: (d)

Solution

Given $a_1 \cdot a_5 = 28 \Rightarrow a \cdot ar^4 = 28 \Rightarrow a^2 r^4 = 28 \ldots (1)$ $a_2 + a_4 = 29 \Rightarrow ar + ar^3 = 29$ $\Rightarrow ar(1 + r^2) = 29$ $\Rightarrow a^2 r^2 (1 + r^2)^2 = (29)^2 \ldots (2)$ By Eq. (1) and (2) $$\frac{r^2}{(1 + r^2)^2} = \frac{28}{29 \times 29}$$ $$\Rightarrow \frac{r}{1 + r^2} = \frac{\sqrt{28}}{29} \Rightarrow r = \sqrt{28}$$ $$\therefore a^2 r^4 = 28 \Rightarrow a^2 \times (28)^2 = 28$$ $$\Rightarrow a = \frac{1}{\sqrt{28}}$$ $$\therefore a_6 = ar^5 = \frac{1}{\sqrt{28}} \times (28)^{\frac{5}{2}} = 784$$

Question 8

Maths · Three Dimensional Geometry · Single correct

Let $L_1 : \frac{x-1}{2} = \frac{y-2}{3} = \frac{z-3}{4}$ and $L_2 : \frac{x-2}{3} = \frac{y-4}{4} = \frac{z-5}{5}$ be two lines. Then which of the following points lies on the line of the shortest distance between $L_1$ and $L_2$?

  1. $(\\frac{14}{3}, -3, \\frac{22}{3})$
  2. $(-\\frac{5}{3}, -7, 1)$
  3. $( 2, 3, \\frac{1}{3})$
  4. $(\\frac{8}{3}, -1, \\frac{1}{3})$

Answer: (a)

Solution

Given the lines: $$L_1: \frac{x-1}{2} = \frac{y-2}{3} = \frac{z-3}{4}$$ $$L_2: \frac{x-2}{3} = \frac{y-4}{4} = \frac{z-5}{5}$$ Points on the lines are: $$P(2\lambda + 1, 3\lambda + 2, 4\lambda + 3)$$ $$Q(3\mu + 2, 4\mu + 4, 5\mu + 5)$$ Direction ratios of $PQ$ are $ $. The vector $PQ$ is given by: $$PQ = \begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ 2 & 3 & 4 \\ 3 & 4 & 5 \end{vmatrix} = -\hat{i} + 2\hat{j} - \hat{k}$$ Equating the direction ratios: $$2\lambda - 3\mu - 1 = -1$$ $$3\lambda - 4\mu - 2 = 2$$ $$4\lambda - 5\mu - 2 = -1$$ Solving these equations, we find: $$\lambda = 3, \mu = 6$$ Thus, the points are: $$P \left( 5, 13, 3 \right)$$ $$Q \left( 3, 10, 25 \right)$$ Direction ratios of $PQ$ are $ $. Therefore, the line equation is: $$\frac{y - 5}{1} = \frac{y - 3}{-2} = \frac{y - 13}{1}$$

Question 9

Maths · Continuity and Differentiability · Single correct

The product of all solutions of the equation $e^{5(\log_e x)^2 + 3} = x^8, x > 0$, is:

  1. $e^{8/5}$
  2. $e^{6/5}$
  3. $e^2$
  4. $e$

Answer: (a)

Solution

Given $e^{5(\ln x)^2 + 3} = x^8$. Taking natural logarithm on both sides, we have: $$\ln e^{5(\ln x)^2 + 3} = \ln x^8$$ This simplifies to: $$5(\ln x)^2 + 3 = 8 \ln x$$ Let $\ln x = t$. Then: $$5t^2 - 8t + 3 = 0$$ The sum of the roots $t_1 + t_2 = \frac{8}{5}$. The product of the roots $\ln x_1 x_2 = \frac{8}{5}$. Thus, $x_1 x_2 = e^{8/5}$.

Question 10

Maths · Sequences and Series · Single correct

If $\sum_{r=1}^{n} T_r = \frac{(2n-1)(2n+1)(2n+3)(2n+5)}{64}$, then $\lim_{n \to \infty} \sum_{r=1}^{n} \left( \frac{1}{T_r} \right)$ is equal to :

  1. 0
  2. $\frac{2}{3}$
  3. 1
  4. $\frac{1}{3}$

Answer: (b)

Solution

Given $T_n = S_n - S_{n-1}$. Therefore, $T_n = \frac{1}{8} (2n - 1)(2n + 1)(2n + 3)$. Thus, $\frac{1}{T_n} = \frac{8}{(2n - 1)(2n + 1)(2n + 3)}$. The limit is $\lim_{n \to \infty} \sum_{r=1}^{n} \frac{1}{T_r} = \lim_{n \to \infty} 8 \sum_{r=1}^{n} \frac{1}{(2n - 1)(2n + 1)(2n + 3)}$. This equals $\lim_{n \to \infty} \frac{8}{4} \sum \left( \frac{1}{(2n - 1)(2n + 1)} - \frac{1}{(2n + 1)(2n + 3)} \right)$. Therefore, $= \lim_{n \to \infty} 2 \left[ \left( \frac{1}{1.3} - \frac{1}{3.5} \right) + \left( \frac{1}{3.5} - \frac{1}{5.7} \right) + \cdots \right]$. This simplifies to $= \frac{2}{3}$.

Question 11

Maths · Permutations and Combinations · Single correct

From all the English alphabets, five letters are chosen and are arranged in alphabetical order. The total number of ways, in which the middle letter is ' M ', is :

  1. 5148
  2. 6084
  3. 4356
  4. 14950

Answer: (a)

Solution

Selection of two letters before M and selection of two letters after M. $$= \binom{12}{2} \times \binom{13}{2} = 5148$$

Question 12

Maths · Differential Equations · Single correct

Let $x = x(y)$ be the solution of the differential equation $y^2 \, dx + \left( x - \frac{1}{y} \right) \, dy = 0$. If $x(1) = 1$, then $x\left( \frac{1}{2} \right)$ is:

  1. $\frac{1}{2} + e$
  2. $3 + e$
  3. $3 - e$
  4. $\frac{3}{2} + e$

Answer: (c)

Solution

Given $y^2 dx + \left( x - \frac{1}{y} \right) dy = 0$. Rearrange to $y^2 dx = \left( \frac{1}{y} - x \right) dy$. This implies $\frac{y^2 dx}{dy} = \frac{1}{y} - x$. Rearrange to $\frac{dx}{dy} + \frac{x}{y^2} = \frac{1}{y^3}$. The integrating factor is $I.F. = e^{\int \frac{1}{y^2} dy} = e^{-\frac{1}{y}}$. Therefore, the solution is $xe^{-\frac{1}{y}} = \int e^{-\frac{1}{y}} \times \frac{1}{y^3} dy + C$. Let $-\frac{1}{y} = t$, then $\frac{1}{y^2} dy = dt$. This implies $xe^{-\frac{1}{y}} = -\int e^t dt + C$. Therefore, $xe^{-\frac{1}{y}} = -e^t (t - 1) + C$. This implies $xe^{-\frac{1}{y}} = -e^{-\frac{1}{y}} \left( -\frac{1}{y} - 1 \right) + C$. Given $x(1) = 1$, $e^{-1} = -e^{-1}(-2) + C$. This implies $C = -e^{-1}$. Therefore, $x = \frac{1}{y} - 1 - e^{-1 + \frac{1}{y}}$. Finally, $x\left( \frac{1}{2} \right) = 3 - e$.

Question 13

Maths · Conic Sections · Single correct

Let the parabola $y = x^2 + px - 3$, meet the coordinate axes at the points $P$, $Q$ and $R$. If the circle $C$ with centre at $(-1, -1)$ passes through the points $P$, $Q$ and $R$, then the area of $\triangle PQR$ is:

  1. 7
  2. 4
  3. 6
  4. 5

Answer: (c)

Solution

Given $y = x^2 + px - 3$. Let $P(\alpha, 0)$, $Q(\beta, 0)$, $R(0, -3)$. Circle with centre $(-1, -1)$ is $(x + 1)^2 + (y + 1)^2 = r^2$. Passes through $(0, -3)$. $$1^2 + (-2)^2 = r^2$$ $$r^2 = 5$$ $$(x + 1)^2 + (y + 1)^2 = 5$$ Put $y = 0$. $$(x + 1)^2 = 5 - 1$$ $$(x + 1)^2 = 4$$ $$x + 1 = \pm 2$$ $$x = 1 or x = -3$$ Therefore, $P(1,0)$ and $Q(-3,0)$. Area of $\triangle PQR = \frac{1}{2} \begin{vmatrix} 1 & 0 & 1 \\ -3 & 0 & 1 \\ 0 & -3 & 1 \end{vmatrix} = 6$

Question 14

Maths · Conic Sections · Single correct

A circle $C$ of radius 2 lies in the second quadrant and touches both the coordinate axes. Let $r$ be the radius of a circle that has centre at the point (2, 5) and intersects the circle $C$ at exactly two points. If the set of all possible values of $r$ is the interval $(\alpha, \beta)$, then $3\beta - 2\alpha$ is equal to:

  1. 10
  2. 15
  3. 12
  4. 14

Answer: (b)

Solution

The distance between $C_1$ and $C_2$ is calculated as follows: $$C_1C_2 = \sqrt{(2 + 2)^2 + (5 - 2)^2}$$ $$= \sqrt{16 + 9}$$ $$= 5$$ Given $r + 2 > 5$, we have: $$r > 3$$ And given $r < 5 + 2$, we have: $$r < 7$$ Therefore, $\alpha = 3$ and $\beta = 7$. Calculating $3\beta - 2\alpha$ gives: $$3\beta - 2\alpha = 3(7) - 2(3) = 21 - 6 = 15$$

Question 15

Maths · Integrals · Single correct

Let for $f(x) = 7 \tan^8 x + 7 \tan^6 x - 3 \tan^4 x - 3 \tan^2 x$, $I_1 = \int_0^{\pi/4} f(x) \, dx$ and $I_2 = \int_0^{\pi/4} x f(x) \, dx$. Then $7I_1 + 12I_2$ is equal to:

  1. 2
  2. 1
  3. 2$\pi$
  4. $\pi$

Answer: (b)

Solution

Given $f(x) = 7 \tan^8 x + 7 \tan^6 x - 3 \tan^4 x - 3 \tan^2 x$. This can be rewritten as $7 \tan^6 x (1 + \tan^2 x) - 3 \tan^2 x (1 + \tan^2 x)$. Simplifying, we have $(7 \tan^6 x - 3 \tan^2 x) (1 + \tan^2 x)$. This further simplifies to $(7 \tan^6 x - 3 \tan^2 x) \sec^2 x$. Let $I_1 = \int_0^{\pi/4} f(x) dx = \int_0^{\pi/4} (7 \tan^6 x - 3 \tan^2 x) \sec^2 x \, dx$. Evaluating, we get: $$= \left( \frac{7 \tan^7 x}{7} - \frac{3 \tan^3 x}{3} \right) \bigg|_0^{\pi/4} = 1 - 1 = 0.$$ Now, let $I_2 = \int_0^{\pi/4} x f(x) dx = \int_0^{\pi/4} x (7 \tan^6 x - 3 \tan^2 x) \sec^2 x \, dx$. This becomes: $$= x (\tan^7 x - \tan^3 x) \bigg|_0^{\pi/4} - \int_0^{\pi/4} 1 \cdot (\tan^7 x - \tan^3 x) \, dx.$$ Simplifying further: $$= 0 - \int_0^{\pi/4} \tan^3 x (\tan^2 x - 1) (\tan^2 x + 1) \, dx.$$ This evaluates to: $$= \int_0^{\pi/4} (\tan^3 x - \tan^5 x) \sec^2 x \, dx = \frac{\tan^4 x}{4} - \frac{\tan^6 x}{6} \bigg|_0^{\pi/4}.$$ Finally, we have: $$= \frac{1}{12}.$$ Hence $7I_1 + 12I_2 = 1$.

Question 16

Maths · Continuity and Differentiability · Single correct

Let $f(x)$ be a real differentiable function such that $f(0) = 1$ and $f(x+y) = f(x)f'(y) + f'(x)f(y)$ for all $x, y \in \mathbb{R}$. Then $\sum_{n=1}^{100} \log_e f(n)$ is equal to:

  1. 2525
  2. 5220
  3. 2384
  4. 2406

Answer: (a)

Solution

Given $f(x+y) = f(x) \cdot f(y) + f(x) \cdot f(y)$ for all $x, y \in \mathbb{R}$. And $f(0) = 1$. Now replace $x$ by zero and $y$ by zero, we get $$f(0) = f(0)f(0) + f(0)f(0)$$ $$1 = f(0) + f(0)$$ Therefore, $f'(0) = \frac{1}{2}$. Now replace $y$ by zero in equation (i), we get $$f(x) = \frac{1}{2} f(x) + f'(x)$$ or, $\frac{1}{2} f(x) = f'(x)$ then $f'(x) = \frac{1}{2}$ $f(x) = \frac{1}{2}$ Hence $\ln |f(x)| = \frac{x}{2} + c$ Put $x = 0$, we get $c = 0$ Therefore, $\ln |f(x)| = \frac{x}{2}$ Then $\sum_{n=1}^{100} \ln(f(\eta)) = \left( \frac{1}{2} + \frac{2}{2} + \frac{3}{2} + \ldots + \frac{100}{2} \right)$ $$= \frac{5050}{2} = 2525$$

Question 17

Maths · Sets · Single correct

Let $A = \{1, 2, 3, \ldots, 10\}$ and $B = \left\{ \frac{m}{n} : m, n \in A, m < n and \gcd(m, n) = 1 \right\}$. Then $n(B)$ is equal to:

  1. 36
  2. 31
  3. 37
  4. 29

Answer: (b)

Solution

Given $A = \{1, 2, \ldots, 10\}$. Define $B = \left\{ \frac{m}{n} \mid m, n \in A, m < n, \gcd(m, n) = 1 \right\}$. Calculate $n(B)$. For $n = 2$, we have $\left\{ \frac{1}{2} \right\}$. For $n = 3$, we have $\left\{ \frac{1}{3}, \frac{2}{3} \right\}$. For $n = 4$, we have $\left\{ \frac{1}{4}, \frac{3}{4} \right\}$. For $n = 5$, we have $\left\{ \frac{1}{5}, \frac{2}{5}, \frac{3}{5}, \frac{4}{5} \right\}$. For $n = 6$, we have $\left\{ \frac{1}{6}, \frac{5}{6} \right\}$. For $n = 7$, we have $\left\{ \frac{1}{7}, \frac{2}{7}, \frac{3}{7}, \frac{4}{7}, \frac{5}{7}, \frac{6}{7} \right\}$. For $n = 8$, we have $\left\{ \frac{1}{8}, \frac{3}{8}, \frac{5}{8}, \frac{7}{8} \right\}$. For $n = 9$, we have $\left\{ \frac{1}{9}, \frac{2}{9}, \frac{4}{9}, \frac{5}{9}, \frac{7}{9}, \frac{8}{9} \right\}$. For $n = 10$, we have $\left\{ \frac{1}{10}, \frac{3}{10}, \frac{7}{10}, \frac{9}{10} \right\}$. Thus, $n(B) = 31$.

Question 18

Maths · Applications of Integrals · Single correct

The area of the region, inside the circle $(x - 2\sqrt{3})^2 + y^2 = 12$ and outside the parabola $y^2 = 2\sqrt{3}x$ is:

  1. $3\pi + 8$
  2. $6\pi - 16$
  3. $3\pi - 8$
  4. $6\pi - 8$

Answer: (b)

Solution

Required area is given by $$2 \int_{0}^{2\sqrt{3}} \left( \sqrt{4\sqrt{3}x - x^2} - \sqrt{2\sqrt{3}x} \right) \, dx$$ This simplifies to $$= 2 \int_{0}^{2\sqrt{3}} \left( \sqrt{12 - (x - 2\sqrt{3})^2} - \sqrt{2\sqrt{3}x} \right) \, dx$$ Evaluating the integral, we have $$= 2 \left[ \frac{x - 2\sqrt{3}}{2} \sqrt{12 - (x - 2\sqrt{3})^2} + \frac{12}{2} \sin^{-1} \left( \frac{x - 2\sqrt{3}}{2\sqrt{3}} \right) - \frac{\sqrt{2\sqrt{3}x^3}}{3/2} \right]_{0}^{2\sqrt{3}}$$ This results in $$= 2 \{ 3\pi - 8 \}$$ Finally, the area is $$= 6\pi - 16 sq. units.$$

Question 19

Maths · Probability · Single correct

Two balls are selected at random one by one without replacement from a bag containing 4 white and 6 black balls. If the probability that the first selected ball is black, given that the second selected ball is also black, is $\frac{m}{n}$, where $\gcd(m, n) = 1$, then $m + n$ is equal to:

  1. 4
  2. 14
  3. 13
  4. 11

Answer: (b)

Solution

Bag contains 4 white and 6 black balls. $A$: first ball selected is black. $B$: Second ball is also black. $$P\left( \frac{A}{B} \right) = \frac{\frac{6}{10} \times \frac{5}{9}}{\frac{4}{10} \times \frac{6}{9} + \frac{6}{10} \times \frac{5}{9}} = \frac{30}{24 + 30}$$ $$= \frac{30}{54} = \frac{5}{9}$$ $m + n = 5 + 9 = 14$

Question 20

Maths · Conic Sections · Single correct

Let the foci of a hyperbola be (1, 14) and (1, -12). If it passes through the point (1, 6), then the length of its latus-rectum is:

  1. $\frac{24}{5}$
  2. $\frac{25}{6}$
  3. $\frac{144}{5}$
  4. $\frac{288}{5}$

Answer: (d)

Solution

Given $be = 13$, $b = 5$. $a^2 = b^2 (e^2 - 1)$ $= b^2 e^2 - b^2$ $= 169 - 25 = 144$ The length of the latus rectum $\ell (LR) = \frac{2a^2}{b} = \frac{2 \times 144}{5} = \frac{288}{5}$.

Question 21

Maths · Continuity and Differentiability · Numerical

Let the function, $$f(x) = \begin{cases} -3ax^2 - 2, & x 1$, $b \in \mathbb{R}$. If the area of the region enclosed by $y = f(x)$ and the line $y = -20$ is $\alpha + \beta \sqrt{3}$, $\alpha, \beta \in \mathbb{Z}$, then the value of $\alpha + \beta$ is

Answer: 34

Solution

Given that $f(x)$ is continuous and differentiable. At $x = 1$, $LHL = RHL$, $LHD = RHD$ $$-3a - 2 = a^2 + b, -6a = b$$ $$a = 2; b = -12$$ $$f(x) = \begin{cases} -6x^2 - 2, & x < 1 \\ 4 - 12x, & x \geq 1 \end{cases}$$ Area $= \int_{-\sqrt{3}}^1 (-6x^2 - 2 + 20) \, dx + \int_1^2 (4 - 12x + 20) \, dx$ $$= 16 + 12\sqrt{3} + 6 = 22 + 12\sqrt{3}$$ Therefore, $\alpha + \beta = 34$

Question 22

Maths · Binomial Theorem · Fill in the blank

If $\sum_{r=0}^{5} \frac{{^{11}C_{2r+1}}}{2r+2} = \frac{m}{n}, \gcd(m, n) = 1$, then $m - n$ is equal to

Answer: 2035

Solution

(1 + x)^{11} = $\binom{11}{0}$ + $\binom{11}{1}$x + $\binom{11}{2}$x^2 + $\cdots$ + $\binom{11}{11}$x^{11} $\int$_0^1 (1 + x)^{11} $\,$ dx = $\int$_0^1 ($\binom{11}{0}$ + $\binom{11}{1}$x + $\binom{11}{2}$x^2 + $\cdots$ + $\binom{11}{11}$x^{11}) $\,$ dx $\frac{(1-x)^{12}}{12}$ $\bigg$|_0^1 = $\left$[ $\binom{11}{0}$x + $\frac{\binom{11}{1}x^2}{2}$ + $\frac{\binom{11}{2}x^3}{3}$ + $\cdots$ + $\frac{\binom{11}{11}x^{12}}{12}$ $\right$]_0^1 2^{12} - 1 = $\binom{11}{0}$ + $\frac{\binom{11}{1}}{2}$ + $\frac{\binom{11}{2}}{3}$ + $\cdots$ + $\frac{\binom{11}{11}}{12}$ $\cdots$ (1) Now, $\int$_{-1}^0 (1 + x)^{11} $\,$ dx = $\int$_{-1}^0 ($\binom{11}{0}$ + $\binom{11}{1}$x + $\binom{11}{2}$x^2 + $\cdots$ + $\binom{11}{11}$x^{11}) $\,$ dx $\frac{(1+x)^{12}}{12}$ $\bigg$|_{-1}^0 = $\left$[ $\binom{11}{0}$x + $\frac{\binom{11}{1}x^2}{2}$ + $\frac{\binom{11}{2}x^3}{3}$ + $\cdots$ + $\frac{\binom{11}{11}x^{12}}{12}$ $\right$]_{-1}^0 $\frac{1}{12}$ = $\binom{11}{0}$ - $\frac{\binom{11}{1}}{2}$ + $\frac{\binom{11}{2}}{3}$ $\cdots$ (1) - (2) = $\frac{2^{12} - 2}{12}$ = 2 $\left$[ $\frac{\binom{11}{1}}{2}$ + $\frac{\binom{11}{3}}{4}$ + $\cdots$ $\right$] $\Rightarrow$ $\sum$_{r=0}^5 $\frac{\binom{11}{2r+1}}{2r+2}$ = $\frac{2^{11} - 1}{12}$ = $\frac{2047}{12}$ = $\frac{m}{n}$ = 2047 - 12 = 2035

Question 23

Maths · Determinants · Fill in the blank

Let $A$ be a square matrix of order 3 such that $\det(A) = -2$ and $\det(3 \mathrm{adj}(-6 \mathrm{adj}(3A))) = 2^{m+n} \cdot 3^{mn}$, $m > n$. Then $4m + 2n$ is equal to ______.

Answer: 34

Solution

As $A adj A = |A| I$, $\det(\lambda A) = \lambda^n \det A$. $$\det(3 adj(-6 adj(3A))) = 3^3 \det(adj(-6 adj(3A)))$$ $$= 3^3 (-6 adj(3A))^2$$ $$= 3^3 (-6)^6 |3A|^4$$ $$= 3^9 2^6 \cdot 3^{12} \cdot (-2)^4$$ $$= 3^{21} \cdot 2^{10}$$ Now comparing with given condition $$2^{m+n} 3^{mn} = 2^{10} \cdot 3^{21}$$ $$m+n = 10, \; mn = 21$$ $$\Rightarrow \; m = 7, \; n = 3 \; (m > n)$$ $$\therefore \; 4m + 2n = 28 + 6 = 34$$

Question 24

Maths · Three Dimensional Geometry · Numerical

Let $L_1 : \frac{x-1}{3} = \frac{y-1}{-1} = \frac{z+1}{0}$ and $L_2 : \frac{x-2}{2} = \frac{y}{0} = \frac{z+4}{\alpha}$, $\alpha \in \mathbb{R}$, be two lines, which intersect at the point $B$. If $P$ is the foot of perpendicular from the point $A(1, 1, -1)$ on $L_2$, then the value of $26\alpha(PB)^2$ is ________

Answer: 216

Solution

Point $B$ $$(3\lambda + 1, -\lambda + 1, -1) \equiv (2\mu + 2, 0, \alpha \mu - 4)$$ $$3\lambda + 1 = 2\mu + 2$$ $$-\lambda + 1 = 0$$ $$-1 = \alpha \mu - 4$$ $$\lambda = 1, \mu = 1, \alpha = 3$$ $$B(4, 0, -1)$$ Let Point $P'$ is $(2\delta + 2, 0, 3\delta - 4)$ Dr's of $AP$ $ $ $$AP \perp L_2 \Rightarrow \delta = \frac{7}{13}$$ $$P \left( \frac{40}{13}, 0, \frac{-31}{13} \right)$$ $$\therefore 26\alpha (PB)^2 = 26 \times 3 \times \left( \frac{144}{169} + \frac{324}{169} \right)$$ $$= 216$$

Question 25

Maths · Vector Algebra · Numerical

Let $\vec{c}$ be the projection vector of $\vec{b} = \lambda \hat{i} + 4 \hat{k}, \lambda > 0$, on the vector $\vec{a} = \hat{i} + 2 \hat{j} + 2 \hat{k}$. If $|\vec{a} + \vec{c}| = 7$, then the area of the parallelogram formed by the vectors $\vec{b}$ and $\vec{c}$ is _______

Answer: 16

Solution

Given $\vec{c} = \left( \frac{\vec{b} \cdot \vec{a}}{|\vec{b}|} \right) \frac{\vec{a}}{|\vec{a}|} = \left( \frac{\lambda + 8}{9} \right) (\hat{i} + 2\hat{j} + 2\hat{k})$. The magnitude $|\vec{a} + \vec{c}| = 7$. This implies: $$\left( \frac{\lambda + 8}{9} + 1 \right) \hat{i} + \left( \frac{2(\lambda + 8)}{9} + 2 \right) \hat{j} + \left( \frac{2(\lambda + 8)}{9} + 2 \right) \hat{k} \bigg| = 7$$ Squaring both sides: $$\left( \frac{\lambda + 8}{9} + 1 \right)^2 + \left( \frac{2(\lambda + 8)}{9} + 2 \right)^2 + \left( \frac{2(\lambda + 8)}{9} + 2 \right)^2 = 49$$ Solving gives $\lambda = 4$. Therefore, $\vec{c} = \frac{4}{3} \hat{i} + \frac{8}{3} \hat{j} + \frac{8}{3} \hat{k}$. The area of the parallelogram is given by: $$\begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ \frac{4}{3} & \frac{8}{3} & \frac{8}{3} \\ 4 & 8 & 4 \end{vmatrix} = 16$$

Physics

Question 26

Physics · Experimental Physics · Single correct

Given below are two statements: Statement I: In a vernier callipers, one vernier scale division is always smaller than one main scale division. Statement II: The vernier constant is given by one main scale division multiplied by the number of vernier scale divisions. In the light of the above statements, choose the correct answer from the options given below.

  1. Statement I is true but Statement II is false
  2. Statement I is false but Statement II is true
  3. Both Statement I and Statement II are false
  4. Both Statement I and Statement II are true

Answer: (a)

Solution

In general one vernier scale division is smaller than one main scale division but in some modified cases it may be not correct. Also least count is given by one main scale division / number of vernier scale division for normal vernier calliper.

Question 27

Physics · Electric Charges and Fields · Single correct

A line charge of length $'\frac{a}{2}'$ is kept at the center of an edge $BC$ of a cube $ABCDEFGH$ having edge length $'a'$ as shown in the figure. If the density of line charge is $\lambda$ C per unit length, then the total electric flux through all the faces of the cube will be _______. (Take, $\varepsilon_0$ as the free space permittivity)

  1. $\frac{\lambda a}{2 \varepsilon_0}$
  2. $\frac{\lambda a}{4 \varepsilon_0}$
  3. $\frac{\lambda a}{16 \varepsilon_0}$
  4. $\frac{\lambda a}{8 \varepsilon_0}$

Answer: (d)

Solution

Charge of the line charge $= \frac{a \lambda}{2}$ Portion of wire inside cube $= \frac{1}{4}$ Therefore, $q_{en} = \frac{1}{4} \left( \frac{a \lambda}{2} \right) = \frac{a \lambda}{8}$ $$\phi = \frac{q_{en}}{\varepsilon_0} = \frac{a \lambda}{8 \varepsilon_0}$$

Question 28

Physics · Current Electricity · Single correct

Sliding contact of a potentiometer is in the middle of the potentiometer wire having resistance $R_p = 1\Omega$ as shown in the figure. An external resistance of $R_e = 2\Omega$ is connected via the sliding contact.

  1. 0.9 A
  2. 1.35 A
  3. 0.3 A
  4. 1.0 A

Answer: (d)

Solution

The equivalent resistance $R_{eq}$ is calculated as follows: $$R_{eq} = 0.5 + \frac{0.5 \times 2}{2 + 0.5} = \left( \frac{5}{10} + \frac{10}{25} \right) \, \Omega$$ Simplifying, we have: $$= \frac{45}{50} = \frac{9}{10} = 0.9$$ Therefore, the current $i$ is: $$i = \frac{0.9}{0.9} = 1 \, \mathrm{A}$$

Question 29

Physics · Wave Optics · Single correct

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion-(A): If Young's double slit experiment is performed in an optically denser medium than air, then the consecutive fringes come closer. Reason-(R): The speed of light reduces in an optically denser medium than air while its frequency does not change. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both (A) and (R) are true but (R) is not the correct explanation of (A)
  2. Both (A) and (R) are true and (R) is the correct explanation of (A)
  3. is true but (R) is false
  4. is false but (R) is true

Answer: (b)

Solution

Given, $\beta$ (fringe width) $=\dfrac{\lambda D}{d}$ In a denser medium, $\lambda \downarrow \Rightarrow \beta \downarrow$ $\Rightarrow$ fringes come closer. Also, $\mu=\dfrac{c}{v}$ $\Rightarrow v=\dfrac{c}{\mu}$ Frequency remains the same. $\Rightarrow \mu=\dfrac{\lambda_{\mathrm{vac}}\,f}{\lambda_{\mathrm{med}}\,f}$ $\Rightarrow \lambda_{\mathrm{med}}=\dfrac{\lambda_{\mathrm{vac}}}{\mu}$.

Question 30

Physics · Thermal Properties of Matter · Single correct

Two spherical bodies of same materials having radii 0.2 m and 0.8 m are placed in same atmosphere. The temperature of the smaller body is 800 K and temperature of the bigger body is 400 K. If the energy radiated from the smaller body is E, the energy radiated from the bigger body is (assume, effect of the surrounding temperature to be negligible),

  1. 16 E
  2. E
  3. 64 E
  4. 256 E

Answer: (b)

Solution

Given $\($ $\frac{d \theta}{dt}$ = $\sigma$ $\varepsilon$ A T^4 $\Rightarrow$ P $\propto$ A T^4 $\)$. $\($ P_{smaller} = (0.2)^2 $\times$ 800^4 $\)$ $\($ P_{larger} = (0.8)^2 $\times$ 400^4 $\)$ $\($ $\frac{1}{16}$ $\times$ 16 = 1 $\)$ Therefore, $\($ P_{larger} = P_{smaller} $\)$.

Question 31

Physics · Thermal Properties of Matter · Single correct

An amount of ice of mass $10^{-3} \, \mathrm{kg}$ and temperature $-10^\circ \mathrm{C}$ is transformed to vapour of temperature $110^\circ \mathrm{C}$ by applying heat. The total amount of work required for this conversion is, (Take, specific heat of ice $= 2100 \, \mathrm{Jkg^{-1} \, K^{-1}}$, specific heat of water $= 4180 \, \mathrm{Jkg^{-1} \, K^{-1}}$, specific heat of steam $= 1920 \, \mathrm{Jkg^{-1} \, K^{-1}}$, Latent heat of ice $= 3.35 \times 10^5 \, \mathrm{Jkg^{-1}}$ and Latent heat of steam $= 2.25 \times 10^6 \, \mathrm{Jkg^{-1}}$)

  1. 3043 J
  2. 3024 J
  3. 3003 J
  4. 3022 J

Answer: (a)

Solution

Given: $$\Delta Q_1 = m \times S_1 \times \Delta T = 10^{-3} \times 2100 \times 10 = 21 \, \mathrm{J}$$ $$\Delta Q_2 = m \times L_f = 10^{-3} \times 3.35 \times 10^5 = 335 \, \mathrm{J}$$ $$\Delta Q_3 = m \times S_w \times \Delta T = 10^{-3} \times 4180 \times 100 = 418 \, \mathrm{J}$$ $$\Delta Q_4 = m \times L_v = 10^{-3} \times 2.25 \times 10^6 = 2250 \, \mathrm{J}$$ $$\Delta Q_5 = m \times S_v \times \Delta T = 10^{-3} \times 1920 \times 10 = 19.2 \, \mathrm{J}$$ $$\Delta Q_{net} = 3043.2 \, \mathrm{J}$$

Question 32

Physics · Dual Nature of Radiation and Matter · Single correct

An electron in the ground state of the hydrogen atom has the orbital radius of $5.3 \times 10^{-11} \, \mathrm{m}$ while that for the electron in third excited state is $8.48 \times 10^{-10} \, \mathrm{m}$. The ratio of the de Broglie wavelengths of electron in the excited state to that in the ground state is

  1. 3
  2. 16
  3. 9
  4. 4

Answer: (b)

Solution

Given $\lambda = \frac{h}{mv}$. $mvr = \frac{nh}{2\pi}$ $mv = \frac{2\pi nh}{2\pi r}$ $\lambda = \frac{2\pi rh}{nh} = \frac{r}{n}$ $\lambda \propto \frac{r}{n}$ $\frac{\lambda_1}{\lambda_4} = \frac{r_1 n_4}{n_1 r_4} = \frac{5.3 \times 10^{-11} \times 4}{1 \times 84.8 \times 10^{-11}}$ $\frac{\lambda_1}{\lambda_4} = \frac{1}{4}$

Question 33

Physics · Ray Optics and Optical Instruments · Single correct

In the diagram given below, there are three lenses formed. Considering negligible thickness of each of them as compared to $|R_1|$ and $|R_2|$, i.e., the radii of curvature for upper and lower surfaces of the glass lens, the power of the combination is

  1. $\frac{1}{6} \left( \frac{1}{|R_1|} - \frac{1}{|R_2|} \right)$
  2. $-\frac{1}{6} \left( \frac{1}{|R_1|} + \frac{1}{|R_2|} \right)$
  3. $\frac{1}{6} \left( \frac{1}{|R_1|} + \frac{1}{|R_2|} \right)$
  4. $-\frac{1}{6} \left( \frac{1}{|R_1|} - \frac{1}{|R_2|} \right)$

Answer: (d)

Solution

The equivalent power is given by $p_{eq} = p_1 + p_2 + p_3$. For $p_1$, we have: $$p_1 = \left( \frac{4}{3} - 1 \right) \left( 1 \over \infty - \frac{1}{|R_1|} \right)$$ Simplifying, we get: $$p_1 = \left( \frac{1}{3|R_1|} \right)$$ For $p_2$, we have: $$p_2 = \left( \frac{1}{2} \right) \left( 1 \over -|R_1| - \frac{1}{|R_2|} \right)$$ Simplifying, we get: $$p_2 = \frac{1}{2} \left( \frac{1}{|R_2|} - \frac{1}{|R_1|} \right)$$ For $p_3$, we have: $$p_3 = \left( \frac{1}{3} \right) \left( 1 \over -|R_2| - \frac{1}{\infty} \right) = -\frac{1}{3|R_2|}$$ Thus, the equivalent power is: $$p_{eq} = \frac{1}{3} \left( \frac{1}{|R_1|} \right) - \frac{1}{2} \left( \frac{1}{|R_1|} - \frac{1}{|R_2|} \right)$$ Simplifying further: $$p_{eq} = -\frac{1}{6} \left( \frac{1}{|R_1|} - \frac{1}{|R_2|} \right)$$

Question 34

Physics · Electric Charges and Fields · Single correct

An electron is made to enter symmetrically between two parallel and equally but oppositely charged metal plates, each of 10 cm length. The electron emerges out of the electric field region with a horizontal component of velocity $10^6 \, \mathrm{m/s}$. If the magnitude of the electric field between the plates is $9.1 \, \mathrm{V/cm}$, then the vertical component of velocity of electron is (mass of electron $= 9.1 \times 10^{-31} \, \mathrm{kg}$ and charge of electron $= 1.6 \times 10^{-19} \, \mathrm{C}$)

  1. 0
  2. $1 \times 10^6 \, \mathrm{m/s}$
  3. $16 \times 10^6 \, \mathrm{m/s}$
  4. $16 \times 10^4 \, \mathrm{m/s}$

Answer: (c)

Solution

Given $t = \frac{\ell}{V_x} = \frac{10 \times 10^{-2}}{10^6} = 10^{-7}$. Therefore, $V_y = u_y + a_y t$. Since $V_y = 0 + \frac{eE}{m} \times 10^{-7}$, we have $V_y = \frac{1.6 \times 10^{-19}}{9.1 \times 10^{-31}} \times 9.1 \times 10^{-2} \times 10^{-7}$. Thus, $V_y = 16 \times 10^6$.

Question 35

Physics · Current Electricity · Single correct

Which of the following resistivity ( $\rho$ ) v/s temperature (T) curves is most suitable to be used in wire bound standard resistors?

Answer: (d)

Solution

Resistivity is independent of temperature for wire bound resistors.

Question 36

Physics · Waves · Single correct

A closed organ and an open organ tube are filled by two different gases having same bulk modulus but different densities $\rho_1$ and $\rho_2'$, respectively. The frequency of $9^{th}$ harmonic of closed tube is identical with $4^{th}$ harmonic of open tube. If the length of the closed tube is $10 \, \mathrm{cm}$ and the density ratio of the gases is $\rho_1 : \rho_2 = 1 : 16$, then the length of the open tube is :

  1. $\frac{15}{7} \, \mathrm{cm}$
  2. $\frac{20}{7} \, \mathrm{cm}$
  3. $\frac{15}{9} \, \mathrm{cm}$
  4. $\frac{20}{9} \, \mathrm{cm}$

Answer: (d)

Solution

The 9th harmonic of a closed pipe is given by $9 V_1 = 4 \ell_1$. The 4th harmonic of an open pipe is given by $2 V_2 = \ell_2$. Therefore, $$\frac{9}{4 \ell_1} \sqrt{\frac{B}{\rho_1}} = \frac{2}{\ell_2} \sqrt{\frac{B}{\rho_2}} \implies \frac{\ell_2}{\ell_1} = \frac{8}{9} \sqrt{\frac{\rho_1}{\rho_2}}.$$ Thus, $$\ell_2 = \ell_1 \times \frac{8}{9} \times \frac{1}{4} = \frac{20}{9} \, cm.$$

Question 37

Physics · System of Particles and Rotational Motion · Single correct

A uniform circular disc of radius ' R ' and mass ' M ' is rotating about an axis perpendicular to its plane and passing through its centre. A small circular part of radius $R/2$ is removed from the original disc as shown in the figure. Find the moment of inertia of the remaining part of the original disc about the axis as given above.

  1. $\frac{7}{32} MR^2$
  2. $\frac{9}{32} MR^2$
  3. $\frac{17}{32} MR^2$
  4. $\frac{13}{32} MR^2$

Answer: (d)

Solution

Step 1: Moment of Inertia of the Original Disc The moment of inertia of a uniform circular disc of mass $M$ and radius $R$ about its central axis (perpendicular to its plane) is given by: $$I_{original} = \frac{1}{2} M R^2$$ Step 2: Moment of Inertia of the Removed Part The removed part is a smaller disc of radius $R/2$. Since, the original disc has uniform mass distribution, the mass of the smaller disc (proportional to its area) is: $$M_{removed} = M \times \frac{\pi (R/2)^2}{\pi R^2} = M \times \frac{1}{4} = \frac{M}{4}$$ The moment of inertia of a smaller disc about its own center is: $$I_{removed, center} = \frac{1}{2} M_{removed} \left( \frac{R}{2} \right)^2$$ $$I_{removed, center} = \frac{1}{2} \times \frac{M}{4} \times \frac{R^2}{4} = \frac{1}{32} M R^2$$ $$I_{removed} = I_{removed, center} + M_{removed} d^2$$ $$I_{removed} = \frac{1}{32} M R^2 + \left( \frac{M}{4} \times \frac{R^2}{4} \right)$$ $$I_{removed} = \frac{1}{32} M R^2 + \frac{1}{16} M R^2$$ $$I_{removed} = \frac{1}{32} M R^2 + \frac{2}{32} M R^2 = \frac{3}{32} M R^2$$ Step 3: Moment of Inertia of the Remaining Part The moment of inertia of the remaining part is: $$I_{remaining} = I_{original} - I_{removed}$$ $$I_{remaining} = \frac{1}{2} M R^2 - \frac{3}{32} M R^2$$ $$I_{remaining} = \frac{16}{32} M R^2 - \frac{3}{32} M R^2$$ $$I_{remaining} = \frac{13}{32} M R^2$$

Question 38

Physics · Gravitation · Single correct

A small point of mass $m$ is placed at a distance $2R$ from the centre $'O'$ of a big uniform solid sphere of mass $M$ and radius $R$. The gravitational force on '$m$' due to $M$ is $F_1$. A spherical part of radius $R/3$ is removed from the big sphere as shown in the figure and the gravitational force on $m$ due to remaining part of $M$ is found to be $F_2$. The value of ratio $F_1 : F_2$ is

  1. 12 : 11
  2. 11 : 10
  3. 12 : 9
  4. 16 : 9

Answer: (a)

Solution

Given $$F_1 = \frac{GMm}{(2R)^2} \cdots (1)$$ $$F_2 = \frac{GMm}{(2R)^2} - \left( G \left( \frac{M}{27} \right) m \left( \frac{4R}{3} \right)^2 \right)$$ $$F_2 = \frac{11}{48} \frac{GMm}{R^2} \cdots (2)$$ The ratio $F_1 : F_2 = 12 : 11$.

Question 39

Physics · Dual Nature of Radiation and Matter · Single correct

The work functions of cesium (Cs) and lithium (Li) metals are 1.9 $\mathrm{eV}$ and 2.5 $\mathrm{eV}$, respectively. If we incident a light of wavelength 550 $\mathrm{nm}$ on these two metal surfaces, then photo-electric effect is possible for the case of

  1. Both Cs and Li
  2. Neither Cs nor Li
  3. Cs only
  4. Li only

Answer: (c)

Solution

Step 1: Calculate the Energy of the Incident Photon. The energy of a photon is given by the equation: $E = \frac{hc}{\lambda}$ where: $h = 6.626 \times 10^{-34} \, \mathrm{J \cdot s}$ (Planck's constant), $c = 3.0 \times 10^8 \, \mathrm{m/s}$ (speed of light), $\lambda = 550 \, \mathrm{nm} = 550 \times 10^{-9} \, \mathrm{m}$. First, calculate the photon energy in joules: $$E = \frac{(6.626 \times 10^{-34})(3.0 \times 10^8)}{550 \times 10^{-9}}$$ $$E = \frac{1.9878 \times 10^{-25}}{550 \times 10^{-9}}$$ $$E = 3.615 \times 10^{-19} \, \mathrm{J}$$ Convert this to electron volts (eV) using $1 \, \mathrm{eV} = 1.6 \times 10^{-19} \, \mathrm{J}$: $$E = \frac{3.615 \times 10^{-19}}{1.6 \times 10^{-19}}$$ $$E \approx 2.26 \, \mathrm{eV}$$ Step 2: Compare Photon Energy with Work Functions. Cesium ($\phi_{\mathrm{Cs}} = 1.9 \, \mathrm{eV}$). Since $E_{\mathrm{photon}} = 2.26 \, \mathrm{eV}$ is greater than $\phi_{\mathrm{Cs}} = 1.9 \, \mathrm{eV}$, photoelectric emission occurs. Lithium ($\phi_{\mathrm{Li}} = 2.5 \, \mathrm{eV}$). Since $E_{\mathrm{photon}} = 2.26 \, \mathrm{eV}$ is less than $\phi_{\mathrm{Li}} = 2.5 \, \mathrm{eV}$, photoelectric emission does not occur. Conclusion: Photoelectric effect is possible only for Cesium (Cs), but not for Lithium (Li).

Question 40

Physics · Physical World, Units and Measurements · Single correct

If $B$ is magnetic field and $\mu_0$ is permeability of free space, then the dimensions of $(B/\mu_0)$ is

  1. $ML^2 \, T^{-2} \, A^{-1}$
  2. $MT^{-2} \, A^{-1}$
  3. $L^{-1} \, A$
  4. $LT^{-2} \, A^{-1}$

Answer: (c)

Solution

For a current carrying loop at centre $$B = \frac{\mu_0 i}{2R}$$ Therefore, $$\frac{B}{\mu_0} \equiv \frac{i}{R} \equiv \left[ AL^{-1} \right]$$

Question 41

Physics · Work, Energy and Power · Single correct

A bob of mass $m$ is suspended at a point $O$ by a light string of length $l$ and left to perform vertical motion (circular) as shown in figure. Initially, by applying horizontal velocity $v_0$ at the point 'A', the string becomes slack when, the bob reaches at the point 'D'. The ratio of the kinetic energy of the bob at the points $B$ and $C$ is ______.

  1. 1
  2. 2
  3. 4
  4. 3

Answer: (b)

Solution

Given $\($ $\frac{1}{2}$ mv_A^2 = $\frac{1}{2}$ mv_B^2 + mgh $\)$ $\($ $\Rightarrow$ $\frac{1}{2}$ m(5g $\ell$) = $\frac{1}{2}$ mv_B^2 + mg $\frac{\ell}{2}$ $\)$ $\($ $\Rightarrow$ $\frac{5mg\ell}{2}$ - $\frac{mg\ell}{2}$ = $\mathrm{KE}$_B $\)$ $\($ $\Rightarrow$ $\mathrm{KE}$_B = 2mg$\ell$ $\)$ $\($ $\frac{1}{2}$ mv_C^2 = $\frac{1}{2}$ mv_D^2 + mg $\frac{\ell}{2}$ $\)$ $\($ $\Rightarrow$ $\mathrm{KE}$_C = $\frac{1}{2}$ mg$\ell$ + mg $\frac{\ell}{2}$ = mg$\ell$ $\)$ $\($ $\Rightarrow$ $\frac{\mathrm{KE}_B}{\mathrm{KE}_C}$ = 2 $\)$

Question 42

Physics · Current Electricity · Single correct

Given below are two statements: Statement-I: The equivalent emf of two nonideal batteries connected in parallel is smaller than either of the two emfs. Statement-II: The equivalent internal resistance of two nonideal batteries connected in parallel is smaller than the internal resistance of either of the two batteries. In the light of the above statements, choose the correct answer from the options given below.

  1. Both Statement-I and Statement-II are false
  2. Statement-I is false but Statement-II is true
  3. Both Statement-I and Statement-II are true
  4. Statement-I is true but Statement-II is false

Answer: (b)

Solution

In parallel connections $$\frac{1}{r_{eq}} = \frac{1}{r_1} + \frac{1}{r_2}$$ $$E_{eq} = \frac{E_1}{r_1} + \frac{E_2}{r_2}$$ If $E_1 = E_2$ and $r_1 = r_2$, then $E_{eq} = E_1 = E_2$. Therefore, Statement I is false. $r_{eq}$ is less than both $r_1$ and $r_2$. Therefore, Statement II is true.

Question 43

Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct

Which of the following circuits represents a forward biased diode? Choose the correct answer from the options given below:

  1. $(A)$ and $(D)$ only
  2. $(B)$, $(D)$ and $(E)$ only
  3. $(C)$ and $(E)$ only
  4. $(B)$, $(C)$ and $(E)$ only

Answer: (d)

Solution

For forward bias, the potential of the $p$ side should be higher than the $n$ side.

Question 44

Physics · Electrostatic Potential and Capacitance · Single correct

A parallel-plate capacitor of capacitance $40 \, \mu \mathrm{F}$ is connected to a $100 \, \mathrm{V}$ power supply. Now the intermediate space between the plates is filled with a dielectric material of dielectric constant $K = 2$. Due to the introduction of dielectric material, the extra charge and the change in the electrostatic energy in the capacitor, respectively, are

  1. 4 mC and 0.2 J
  2. 8 mC and 2.0 J
  3. 2 mC and 0.4 J
  4. 2 mC and 0.2 J

Answer: (a)

Solution

Given $\Delta q = (KC - C)V$ $$= 40 \times 10^{-6} \times 100$$ $$= 4000 \times 10^{-3} = 4 \, \mathrm{mC}$$ $\Delta U = \frac{1}{2} C'V^2 - \frac{1}{2} CV^2 = \frac{1}{2} (K - 1)CV^2$ $$= \frac{1}{2} CV^2 (2 - 1)$$ $$= \frac{1}{2} CV^2 = \frac{1}{2} \times 40 \times 10^{-6} \times 10000$$ $$= 0.2 \, \mathrm{J}$$

Question 45

Physics · Ray Optics and Optical Instruments · Single correct

Given is a thin convex lens of glass (refractive index $\mu$) and each side having radius of curvature $R$. One side is polished for complete reflection. At what distance from the lens, an object be placed on the optic axis so that the image gets formed on the object itself?

  1. $R/\mu$
  2. $R/(2\mu - 3)$
  3. $\mu R$
  4. $R/(2\mu - 1)$

Answer: (d)

Solution

Given the equation: $$ -\frac{1}{f_{eq}} = \frac{2}{f_l} - \frac{1}{f_m} $$ Substituting the values, we have: $$ = 2(\mu - 1) \frac{2}{R} + \frac{2}{R} $$ Simplifying further: $$ -\frac{1}{f_{eq}} = \frac{2(2\mu - 1)}{R} $$ Thus, $$ f_{eq} = -\frac{R}{2(2\mu - 1)} $$ For a concave mirror, the object should be at $2f$ for the image to be at the same point. Therefore, the distance is: $$ Distance = \frac{R}{(2\mu - 1)} $$

Question 46

Physics · Mechanical Properties of Fluids · Numerical

Two soap bubbles of radius 2 cm and 4 cm, respectively, are in contact with each other. The radius of curvature of the common surface, in cm, is _______.

Answer: 4

Solution

Given $$R = \frac{R_2 R_1}{R_2 - R_1} = \frac{4 \times 2}{2} = 4 \, \mathrm{cm}$$

Question 47

Physics · Ray Optics and Optical Instruments · Numerical

The driver sitting inside a parked car is watching vehicles approaching from behind with the help of his side view mirror, which is a convex mirror with radius of curvature $R = 2 \, \mathrm{m}$. Another car approaches him from behind with a uniform speed of $90 \, \mathrm{km/hr}$. When the car is at a distance of $24 \, \mathrm{m}$ from him, the magnitude of the acceleration of the image of the car in the side view mirror is ' $a$ '. The value of $100 \, a$ is ____ $\mathrm{m/s^2}$.

Answer: 8

Solution

Image distance, $v = \frac{uf}{u-f} = \frac{-24 \cdot 1}{-24 - 1} = \frac{24}{25}$. Magnification, $m = -\frac{v}{u} = -\frac{24}{25(-24)} = \frac{1}{25}$. Mirror formula, $\frac{1}{v} + \frac{1}{u} = \frac{1}{f}$. Differentiating with respect to time gives, $$-\frac{1}{v^2} \frac{dv}{dt} + \frac{1}{u^2} \frac{du}{dt} = 0$$ here, $\frac{dv}{dt} = v_1; \frac{du}{dt} = v_0$. $$\Rightarrow v_1 = -\frac{v^2}{u^2} v_0 = -\frac{24^2}{25} \times 25 = -\frac{1}{25}$$ Again, differentiating with respect to time gives, $$\Rightarrow a_I = -2 \frac{vv'u - vu'v}{u^2} v_0 = -2 \frac{vv_1u - v v_0}{u^2}$$ $$\Rightarrow a_I = -2 \frac{24}{25} - \frac{1}{25} - 24 - \frac{24}{25} 25$$ $$\Rightarrow a_I = -2 \frac{-24^2}{25}$$ $$\Rightarrow a_I = -\frac{2}{25} \, \mathrm{ms^{-2}}$$ Thus, $100 a_I = 100 \times \frac{2}{25} = 8$

Question 48

Physics · Thermal Properties of Matter · Numerical

Three conductors of same length having thermal conductivity $k_1$, $k_2$ and $k_3$ are connected as shown in figure. Area of cross sections of $1^{st}$ and $2^{nd}$ conductor are same and for $3^{rd}$ conductor it is double of the $1^{st}$ conductor. The temperatures are given in the figure. In steady state condition, the value of $\theta$ is ______ $^{\circ}\mathrm{C}$. (Given : $k_1 = 60\,\mathrm{J}\,\mathrm{s}^{-1}\,\mathrm{m}^{-1}\,\mathrm{K}^{-1}$, $k_2 = 120\,\mathrm{J}\,\mathrm{s}^{-1}\,\mathrm{m}^{-1}\,\mathrm{K}^{-1}$, $k_3 = 135\,\mathrm{J}\,\mathrm{s}^{-1}\,\mathrm{m}^{-1}\,\mathrm{K}^{-1}$)

Answer: 40

Solution

Given the resistances: $$R_1 = \frac{2L}{K_1 A}$$ $$R_2 = \frac{2L}{K_2 A}$$ $$R_3 = \frac{L}{K_3 A}$$ Using the equation: $$\frac{\theta - 100}{\frac{R_1 R_2}{R_1 + R_2}} + \frac{\theta - 0}{R_3} = 0$$ Solving for $\theta$, we find: $$\theta = 40$$

Question 49

Physics · System of Particles and Rotational Motion · Numerical

The position vectors of two 1 kg particles, (A) and (B), are given by $\vec{r}_A = \left( \alpha_1 t^2 \hat{i} + \alpha_2 t \hat{j} + \alpha_3 t \hat{k} \right) \, \mathrm{m}$ and $\vec{r}_B = \left( \beta_1 t \hat{i} + \beta_2 t^2 \hat{j} + \beta_3 t \hat{k} \right) \, \mathrm{m}$, respectively; $(\alpha_1 = 1 \, \mathrm{m/s^2}, \alpha_2 = 3 \, \mathrm{m/s}, \alpha_3 = 2 \, \mathrm{m/s}, \beta_1 = 2 \, \mathrm{m/s}, \beta_2 = -1 \, \mathrm{m/s^2}, \beta_3 = 4p \, \mathrm{m/s})$, where $t$ is time, $n$ and $p$ are constants. At $t = 1 \, \mathrm{s}$, $|\vec{V}_A| = |\vec{V}_B|$ and velocities $\vec{V}_A$ and $\vec{V}_B$ of the particles are orthogonal to each other. At $t = 1 \, \mathrm{s}$, the magnitude of angular momentum of particle (A) with respect to the position of particle (B) is $\sqrt{L} \, \mathrm{kg \, m^2 \, s^{-1}}$. The value of $L$ is ________.

Answer: 90

Solution

At $t = 1$. $$r_{AB} = -1\hat{i} + (3n + 1)\hat{j} + (2 - 4p)\hat{k}$$ At $t = 1$: $$v_A = 2\hat{i} + 3n\hat{j} + 2\hat{k}$$ $$v_B = 2\hat{i} - 2\hat{j} + 4p\hat{k}$$ $$\vec{v}_A - \vec{v}_B = 0, 4 - 6n + 8p = 0$$ $$|v_A| = |v_B| (3n)^2 + 4 = 4 + 16p^2$$ $$3n = -4p$$ $$4 + 16p = 0$$ $$p = -\frac{1}{4}, n = \frac{1}{3}$$ $$r_{AB} = -\hat{i} + 2\hat{j} + 3\hat{k}$$ $$v_A = 2\hat{i} + \hat{j} + 2\hat{k}$$ Therefore, $L = m |\vec{r}_{AB} \times \vec{v}_A| = 90$

Question 50

Physics · Motion in a Plane · Numerical

A particle is projected at an angle of $30^\circ$ from horizontal at a speed of $60 \, \mathrm{m/s}$. The height traversed by the particle in the first second is $h_0$ and height traversed in the last second, before it reaches the maximum height, is $h_1$. The ratio $h_0 : h_1$ is ____ [Take, $g = 10 \, \mathrm{m/s^2}$]

Answer: 5

Solution

Given $60 \sin 30^\circ = 30$. Calculate $S_1$ as follows: $$S_1 = 30 \times 1 - \frac{1}{2} \times 10 \times 1 = 25$$ Calculate $S_3$ as follows: $$S_3 = 30 + \left( \frac{-10}{2} \right) \times (2 \times 3 - 1) = 5$$ Finally, we have: $$S_1 = \frac{25}{5} = 5$$ $$S_3 = 5$$

Chemistry

Question 51

Chemistry · Electrochemistry · Single correct

A solution of aluminium chloride is electrolysed for 30 minutes using a current of 2 A. The amount of the aluminium deposited at the cathode is [Given : molar mass of aluminium and chlorine are $27 \, \mathrm{g \, mol^{-1}}$ and $35.5 \, \mathrm{g \, mol^{-1}}$ respectively. Faraday constant $= 96500 \, \mathrm{C \, mol^{-1}}$]

  1. 1.660 g
  2. 0.336 g
  3. 0.441 g
  4. 1.007 g

Answer: (b)

Solution

The reaction is $\mathrm{Al^{1+++} + 3e^- \rightarrow Al}$. Moles of electron $= \frac{2 \times 30 \times 60}{96500}$ $$= \frac{36}{965}$$ Moles of $\mathrm{Al} = \frac{36}{3 \times 965}$ $$= \frac{12}{965}$$ Mass of $\mathrm{Al} = \frac{12}{965} \times 27$ $$= 0.336 \, \mathrm{gm}$$

Question 52

Chemistry · Chemical Kinetics and Nuclear Chemistry · Single correct

Which of the following statement is not true for radioactive decay?

  1. Decay constant increases with increase in temperature.
  2. Amount of radioactive substance remained after three half lives is $\frac{1}{8}$ th of original amount.
  3. Decay constant does not depend upon temperature.
  4. Half life is ln 2 times of $\frac{1}{rate constant}$.

Answer: (a)

Solution

For radioactive decay, decay constant does not depend upon temperature because for radioactive decay activation energy is zero.

Question 53

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

How many different stereoisomers are possible for the given molecule? $$\mathrm{CH_3-CH-CH=CH-CH_3}$$ $$\mathrm{|}$$ $$\mathrm{OH}$$

  1. 2
  2. 1
  3. 4
  4. 3

Answer: (c)

Solution

The compound has 4 stereoisomers: $R$ cis, $R$ trans, $S$ cis, $S$ trans.

Question 54

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

Which of the following electronegativity order is incorrect?

  1. Mg < Be < B < N
  2. S < Cl < O < F
  3. Al < Si < C < N
  4. Al < Mg < B < N

Answer: (d)

Solution

The electronegativity (E.N.) values on the Pauling scale are given for the elements: Li: $1$, Be: $1.5$, B: $2$, C: $2.5$, N: $3$, O: $3.5$, F: $4.0$. For another set of elements: Na: $0.9$, Mg: $1.2$, Al: $1.5$, Si: $1.8$, P: $2.1$, S: $2.5$, Cl: $3.0$. The correct order of electronegativity is $Mg < Al < B < N$.

Question 55

Chemistry · The d-and f-Block Elements · Single correct

Lanthanoid ions with $4f^7$ configuration are : (A) Eu$^{2+}$ (B) Gd$^{3+}$ ($C$) Eu$^{3+}$ (D) Tb$^{3+}$ (E) Sm$^{2+}$ Choose the correct answer from the options given below :

  1. (A) and (D) only
  2. (B) and ($C$) only
  3. (A) and (B) only
  4. (B) and (E) only

Answer: (c)

Solution

The electronic configurations are given as follows: For $^{63}\mathrm{Eu}^{2+}$: $$[\mathrm{Xe}]4f^76s^0$$ For $_{64}\mathrm{Gd}^{3+}$: $$[\mathrm{Xe}]4f^56d^06s^0$$ For $_{63}\mathrm{Eu}^{3+}$: $$[\mathrm{Xe}]4f^66s^0$$ For $_{65}\mathrm{Tb}^{3+}$: $$[\mathrm{Xe}]4f^86s^0$$ For $_{62}\mathrm{Sm}^{2+}$: $$[\mathrm{Xe}]4f^66s^0$$ The correct answer is $\mathrm{Eu}^{2+}$ and $\mathrm{Gd}^{3+}$.

Question 56

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

Match List-I with List-II. Choose the correct answer from the options given below :

  1. (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
  2. (A)-(IV), (B)-(I), (C)-(III), (D)-(II)
  3. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
  4. (A)-(II), (B)-(III), (C)-(IV), (D)-(I)

Answer: (a)

Solution

Ionic radii: $\mathrm{Al^{3+} < Mg^{2+} < Na^+ < F^-}$. Ionisation energy: $\mathrm{B < C < O < N}$. Metallic character: $\mathrm{B < Al < Mg < K}$. Electron negativity: $\mathrm{Si < P < S < Cl}$.

Question 57

Chemistry · Biomolecules · Single correct

Which of the following acids is a vitamin?

  1. Adipic acid
  2. Ascorbic acid
  3. Saccharic acid
  4. Aspartic acid

Answer: (b)

Solution

Vitamin-C is Ascorbic acid.

Question 58

Chemistry · Thermodynamics · Single correct

A liquid when kept inside a thermally insulated closed vessel at $25^\circ \mathrm{C}$ was mechanically stirred from outside. What will be the correct option for the following thermodynamic parameters?

  1. $\Delta U 0$
  2. $\Delta U = 0, q = 0, w = 0$
  3. $\Delta U > 0, q = 0, w > 0$
  4. $\Delta U = 0, q 0$

Answer: (d)

Solution

Thermally insulated implies $q = 0$ from the first law. $$\Delta U = q + w$$ $$\Delta U = w$$ Since $w > 0$, $\Delta U > 0$.

Question 59

Chemistry · Structure of Atom · Single correct

Radius of the first excited state of Helium ion is given as : $a_0 \rightarrow$ radius of first stationary state of hydrogen atom.

  1. $r = 4a_0$
  2. $r = 2a_0$
  3. $r = \frac{a_0}{2}$
  4. $r = \frac{a_0}{4}$

Answer: (c)

Solution

Given $\($ r = a_0 $\left$( $\frac{n^2}{z}$ $\right$) $\)$. Substituting $\($ n = 2 $\)$ and $\($ z = 2 $\)$, we have: $$ r = a_0 (2)^2 \left( \frac{1}{2} \right) $$ Simplifying, we get: $$ r = 2a_0 $$

Question 60

Chemistry · Haloalkanes and Haloarenes · Single correct

Given below are two statements: Statement I: $CH_3 - O - CH_2 - Cl$ will undergo $S_N1$ reaction though it is a primary halide. Statement II: will not undergo $S_N2$ reaction very easily though it is a primary halide. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both Statement I and Statement II are incorrect
  2. Both Statement I and Statement II are correct
  3. Statement I is incorrect but Statement II is correct
  4. Statement I is correct but Statement II is incorrect

Answer: (b)

Solution

Both statement-I and statement-II are correct. Statement - I: $CH_3-O-\overset{\oplus}{CH_2}$ is highly stable carbocation. Statement - II: Due to hindrance, $\mathrm{S_N2}$ will not take place easily.

Question 61

Chemistry · Hydrocarbons · Single correct

Given below are two statements: Statement I: One mole of propyne reacts with excess of sodium to liberate half a mole of $\mathrm{H}_2$ gas. Statement II: Four g of propyne reacts with $\mathrm{NaNH}_2$ to liberate $\mathrm{NH}_3$ gas which occupies $224 \, \mathrm{mL}$ at STP. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Statement I is incorrect but Statement II is correct
  2. Both Statement I and Statement II are correct
  3. Statement I is correct but Statement II is incorrect
  4. Both Statement I and Statement II are incorrect

Answer: (c)

Solution

Statement-I is correct. Moles of $\mathrm{C_3H_4} = \frac{4}{40} = 0.1$ mole. $$\mathrm{CH_3 - C \equiv CH + NaNH_2 \rightarrow CH_3 - C \equiv C^-Na^+ + NH_3}$$ $0.1$ mole $0.1$ mole Volume of $\mathrm{NH_3} = (0.1)(22.4) = 2.24 \, \mathrm{L}$ Statement-II is incorrect.

Question 62

Chemistry · Equilibrium · Single correct

A vessel at 1000 K contains $\mathrm{CO}_2$ with a pressure of 0.5 atm. Some of $\mathrm{CO}_2$ is converted into $\mathrm{CO}$ on addition of graphite. If total pressure at equilibrium is 0.8 atm, then $K_p$ is:

  1. 1.8 atm
  2. 0.3 atm
  3. 3 atm
  4. 0.18 atm

Answer: (b)

Solution

The reaction is given as $\mathrm{CO_2(g) + C(s) \rightleftharpoons 2CO(g)}$. Initially, the concentration of $\mathrm{CO_2}$ is $0.5$. At equilibrium, the concentration of $\mathrm{CO_2}$ is $0.5 - x$ and the concentration of $\mathrm{CO}$ is $2x$. The total pressure is given by $P_{total} = 0.5 + x = 0.8$. Solving for $x$, we find $x = 0.3$. The equilibrium constant $K_P$ is calculated as $$K_P = \frac{(0.6)^2}{0.2} = 1.8.$$

Question 63

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

The IUPAC name of the following compound is :

  1. Methyl-6-carboxy-2,5-dimethylhexanoate.
  2. 2-Carboxy-5-methoxycarbonylhexane.
  3. 6-Methoxycarbonyl-2,5-dimethylhexanoic acid.
  4. Methyl-5-carboxy-2-methylhexanoate.

Answer: (c)

Solution

The compound shown is 6-Methoxycarbonyl-2,5-dimethylhexanoic acid.

Question 64

Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct

Which of the following electrolyte can be used to obtain $\mathrm{H_2 S_2 O_8}$ by the process of electrolysis?

  1. Dilute solution of sodium sulphate.
  2. Acidified dilute solution of sodium sulphate.
  3. Dilute solution of sulphuric acid
  4. Concentrated solution of sulphuric acid

Answer: (d)

Solution

Theory based. At anode: $$2\mathrm{HSO}_4^- \rightarrow \mathrm{H}_2\mathrm{S}_2\mathrm{O}_8 + 2e^-$$

Question 65

Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct

The compounds which give positive Fehling's test are : Choose the correct answer from the options given below :

  1. (A), (D) and (E) Only
  2. (C), (D) and (E) Only
  3. (A), (C) and (D) Only
  4. (A), (B) and (C) Only

Answer: (b)

Solution

Aliphatic aldehyde, $\alpha$-hydroxy ketone gives Fehlings solution test.

Question 66

Chemistry · Co-ordination Compounds · Single correct

In which of the following complexes the CFSE, $\Delta_o$ will be equal to zero?

  1. $[\mathrm{Fe(en)}_3] \mathrm{Cl}_3$
  2. $\mathrm{K}_4[\mathrm{Fe(CN)}_6]$
  3. $[\mathrm{Fe(NH}_3)_6] \mathrm{Br}_2$
  4. $\mathrm{K}_3[\mathrm{Fe(SCN)}_6]$

Answer: (d)

Solution

For the complex $\mathrm{K_3[Fe(SCN)_6]}$, the electronic configuration of $\mathrm{Fe^{3+}}$ is $[\mathrm{Ar}]3d^5$. The weak field ligand (W.F.L.) causes the splitting of the $d$ orbitals into $e_g^2$ and $t_{2g}^3$. Calculation of CFSE: $$= (-0.4 \times 3 + 0.6 \times 2) \Delta_0$$ $$= 0 \Delta_0$$

Question 67

Chemistry · Solutions · Single correct

Arrange the following solutions in order of their increasing boiling points. (i) $10^{-4} \mathrm{M}$ NaCl (ii) $10^{-4} \mathrm{M}$ Urea (iii) $10^{-3} \mathrm{M}$ NaCl (iv) $10^{-2} \mathrm{M}$ NaCl

  1. < (ii) < (iii) < (iv)
  2. (iv) < (iii) < (i) < (ii)
  3. (ii) < (i) $\equiv$ (iii) < (iv)
  4. (ii) < (i) < (iii) < (iv)

Answer: (d)

Solution

For $10^{-4} \, M \mathrm{NaCl}$, $i = 2$. For $10^{-4} \, M$ Urea, $i = 1$. For $10^{-3} \, M \mathrm{MgCl_2}$, $i = 3$. For $10^{-2} \, M \mathrm{NaCl}$, $i = 2$. More the value of $i$, more will be the elevation in boiling point hence increasing order of boiling point is $10^{-4} \, M$ Urea $< 10^{-4} \, M \mathrm{NaCl} < 10^{-3} \, M \mathrm{MgCl_2} < 10^{-2} \, M \mathrm{NaCl}$.

Question 68

Chemistry · Amines · Single correct

The products formed in the following reaction sequence are:

Answer: (c)

Solution

The reaction sequence starts with the nitration of benzene to form nitrobenzene. The first step involves bromination using $\mathrm{Br_2/AcOH}$ to give bromonitrobenzene. Next, reduction with $\mathrm{Sn/HCl}$ converts the nitro group to an amino group, forming bromoaniline. Diazotization with $\mathrm{NaNO_2 + HCl}$ produces the diazonium salt. Finally, the reaction with ethanol ($\mathrm{EtOH}$) yields the final product, bromoethoxybenzene.

Question 69

Chemistry · Co-ordination Compounds · Single correct

From the magnetic behaviour of $[NiCl_4]^{2-}$ (paramagnetic) and $[Ni(CO)_4]$ (diamagnetic), choose the correct geometry and oxidation state.

  1. $[NiCl_4]^{2-}$ : Ni$^{\mathrm{II}}$, tetrahedral $[Ni(CO)_4]$ : Ni$^{\mathrm{II}}$, square planar
  2. $[NiCl_4]^{2-}$ : Ni$^{\mathrm{II}}$, square planar $[Ni(CO)_4]$ : Ni(0), square planar
  3. $[NiCl_4]^{2-}$ : Ni$^{\mathrm{II}}$, tetrahedral $[Ni(CO)_4]$ : Ni(0), tetrahedral
  4. $[NiCl_4]^{2-}$ : Ni(0), tetrahedral $[Ni(CO)_4]$ : Ni(0), square planar

Answer: (c)

Solution

For $[NiCl_4]^{2-}$, $Ni^{+2}$ has the configuration $[Ar] 3d^8 4s^0 \rightarrow sp^3$, Tetrahedral. The number of unpaired electrons is 2, making it paramagnetic. For $[Ni(CO)_4]$, $Ni(0)$ rearranges to $[Ar] 3d^{10} 4s^0$. There are no unpaired electrons, making it $sp^3$, Tetrahedral, and Diamagnetic.

Question 70

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

The incorrect statements regarding geometrical isomerism are : (A) Propene shows geometrical isomerism. (B) Trans isomer has identical atoms/groups on the opposite sides of the double bond. (C) Cis-but-2-ene has higher dipole moment than trans-but-2-ene. (D) 2-methylbut-2-ene shows two geometrical isomers. (E) Trans-isomer has lower melting point than cis isomer. Choose the correct answer from the options given below :

  1. and (E) Only
  2. , (D) and (E) Only
  3. and (C) Only
  4. , (D) and (E) Only

Answer: (b)

Solution

Q13. (A) $\mathrm{CH_3 - CH = CH_2}$. GI is not possible. (B) Trans isomer has identical atoms/groups on the opposite side of double bond. (C) $>$ (dipole moment only) (D) $\mathrm{H_3C - C = CH - CH_3}$ $\newline$ $\mathrm{CH_3}$$ \newline 2-methylbut-2-ene (does not show GI) (E) $>$ (Melting point)

Question 71

Chemistry · Some Basic Concepts of Chemistry · Numerical

Some $CO_2$ gas was kept in a sealed container at a pressure of 1 atm and at 273 K. This entire amount of $CO_2$ gas was later passed through an aqueous solution of $Ca(OH)_2$. The excess unreacted $Ca(OH)_2$ was later neutralized with 0.1 M of 40 mL HCl. If the volume of the sealed container of $CO_2$ was $x$, then $x$ is ______ cm$^3$ (nearest integer). [Given : The entire amount of $CO_2 (g)$ reacted with exactly half the initial amount of $Ca(OH)_2$ present in the aqueous solution.]

Answer: 22400

Solution

Let moles of $\mathrm{CO_2} = n$ moles of $\mathrm{Ca(OH)_2}$ total initially $= 2n$ excess $\mathrm{Ca(OH)_2} = n$ gm equivalent of $\mathrm{(45) \ Ca(OH)_2} = gm equivalent of HCl$. $$n \times 2 = 0.1 \times \frac{40}{1000} \times 1$$ $$n = 2 \times 10^{-3}$$ Volume of $\mathrm{CO_2} = 2 \times 10^{-3} \times 22400 = 44.8 \, \mathrm{cm^3}$$

Question 72

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Numerical

In Carius method for estimation of halogens, 180 mg of an organic compound produced 143.5 mg of AgCl. The percentage composition of chlorine in the compound is _______ %. (Given : molar mass in g mol$^{-1}$ of Ag : 108, Cl : 35.5)

Answer: 20

Solution

Given $\($ n_{Cl} = n_{AgCl} = $\frac{143.5 \times 10^{-3}}{143.5}$ = 10^{-3} $\)$. $\($ $\%$ Cl = $\frac{10^{-3} \times 35.5}{180 \times 10^{-3}}$ $\times$ 100 = 19.72 $\)$.

Question 73

Chemistry · Chemical Bonding and Molecular Structure · Numerical

\[ \mathrm{A} \rightarrow \mathrm{B} \] The number of molecules/ions that show linear geometry among the following is: $\mathrm{SO_2},\ \mathrm{BeCl_2},\ \mathrm{CO_2},\ \mathrm{N_3^-},\ \mathrm{NO_2},\ \mathrm{F_2O},\ \mathrm{XeF_2},\ \mathrm{NO_2^+},\ \mathrm{I_3^-},\ \mathrm{O_3}$.

Answer: 6

Solution

For $\mathrm{Cl} - \mathrm{Be} - \mathrm{Cl}$ and $\mathrm{N} \equiv \mathrm{N} : \rightarrow \mathrm{O}$, the hybridization is $sp$, linear. For $\mathrm{N}^- = \mathrm{N}^+ = \mathrm{N}^-$ and $\mathrm{O} = \mathrm{N}^+ = \mathrm{O}$, the hybridization is $sp$, linear. Like $\mathrm{I}_3^-$, $\mathrm{XeF}_2 \rightarrow sp^3d_1$, Linear. Answer is 4.

Question 74

Chemistry · Chemical Kinetics and Nuclear Chemistry · Numerical

The molecule A changes into its isomeric form B by following first-order kinetics at a temperature of $1000\,\mathrm{K}$. If the energy barrier with respect to the reactant energy for this isomeric transformation is $191.48\,\mathrm{kJ\,mol^{-1}}$ and the frequency factor is $10^{20}\,\mathrm{s^{-1}}$, then the time required for $50\%$ of the molecules of A to become B is $\underline{\hspace{1cm}}$ picoseconds (nearest integer). [Given: $R=8.314\,\mathrm{J\,K^{-1}\,mol^{-1}}$]

Answer: 69

Solution

Given $t_{1/2} = \frac{0.693}{K}$. $K = A e^{-E_a/RT}$ $$= 10^{20} \times e^{-\frac{191.48 \times 10^3}{8.314 \times 1000}}$$ $$= 10^{20} \times e^{-23.031} = 10^{20} \times e^{-\ln 10 \times 10}$$ $$= \frac{10^{20}}{10^{10}} = 10^{10} sec.$$ $t_{1/2} = \frac{0.693}{10^{10}} = 6.93 \times 10^{-11}$ $$= 69.3 \times 10^{-12} sec.$$

Question 75

Chemistry · Amines · Numerical

Consider the following sequence of reactions: Molar mass of the product formed (A) is _____ gmol$^{-1}$.

Answer: 154

Solution

The reaction sequence involves the conversion of a nitro group to an amine group using $\mathrm{Sn + HCl}$. This is followed by diazotization with $\mathrm{NaNO_2 + HCl}$ at $0^\circ \mathrm{C}$ to form a diazonium salt. The diazonium salt is then reacted with $\mathrm{Cu_2Cl_2}$ to form a chlorobenzene derivative. Finally, the reaction with sodium in dry ether leads to the formation of biphenyl ($\mathrm{C_{12}H_{10}}$). The molar mass is calculated as follows: $$Molar mass = 120 \times 12 + 10 \times 1 = 154$$