JEE Main 7 April 2025 Shift 2 question paper with solutions

JEE Main 7 April 2025 Shift 2: all 75 questions in paper order (Maths, Physics, Chemistry) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.

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Maths

Question 1

Maths · Straight Lines and Pair of Straight Lines · Single correct

If the orthocentre of the triangle formed by the lines $y = x + 1$, $y = 4x - 8$ and $y = mx + c$ is at $(3, -1)$, then $m - c$ is:

  1. 0
  2. -2
  3. 4
  4. 2

Answer: (a)

Solution

Solve line PQ and QR. Point Q $\left( \frac{1-c}{m-1}, \frac{1-c}{m-1} + 1 \right)$. $$m_{2H} = \frac{1-c}{m-1} + 2 = \frac{1-c+2m-2}{1-c-3m+3} = \frac{-1}{4}$$ $$m_{2H} = \frac{m-1}{1-c} + 2 = \frac{1-c+2m-2}{1-c-3m+3} = \frac{-1}{4} \cdots (1)$$ Therefore, $m_{PH} = \frac{5}{0} \to \infty$. Thus, the slope of line QR $(m) = 0$. Put the value of $m$ in equation (1): $$\frac{1-c-2}{1-c+3} = \frac{-1}{4} \Rightarrow c = 0$$ So $m - c = 0$. Ans.

Question 2

Maths · Vector Algebra · Single correct

Let $\vec{a}$ and $\vec{b}$ be the vectors of the same magnitude such that $\frac{|\vec{a} + \vec{b}| + |\vec{a} - \vec{b}|}{|\vec{a} + \vec{b}| - |\vec{a} - \vec{b}|} = \sqrt{2} + 1$. Then $\frac{|\vec{a} + \vec{b}|^2}{|\vec{a}|^2}$ is:

  1. 2 + 4$\sqrt{2}$
  2. 1 + $\sqrt{2}$
  3. 2 + $\sqrt{2}$
  4. 4 + 2$\sqrt{2}$

Answer: (c)

Solution

Apply componendo and dividendo $$\frac{2|\bar{a} + \bar{b}|}{2|\bar{a} - \bar{b}|} = \sqrt{2} + 2$$ $$\Rightarrow \frac{|\bar{a} + \bar{b}|}{|\bar{a} - \bar{b}|} = \sqrt{2}$$ $$\Rightarrow |\bar{a} + \bar{b}| = (1 + \sqrt{2})|\bar{a} - \bar{b}|$$ $$\Rightarrow |\bar{a} + \bar{b}|^2 = (3 + 2\sqrt{2})|\bar{a} - \bar{b}|^2$$ $$\Rightarrow 2|\bar{a}|^2 + 2\bar{a} \cdot \bar{b} = (3 + 2\sqrt{2}) \left( 2|\bar{a}|^2 - 2\bar{a} \cdot \bar{b} \right)$$ $$\Rightarrow 2|\bar{a}|^2(2 + 2\sqrt{2}) = 2\bar{a} \cdot \bar{b}(4 + 2\sqrt{2})$$ $$\Rightarrow \frac{\bar{a} \cdot \bar{b}}{|\bar{a}|^2} = \frac{2 + 2\sqrt{2}}{4 + 2\sqrt{2}} = \frac{1}{\sqrt{2}}$$ Now $$\frac{|\bar{a} + \bar{b}|^2}{|\bar{a}|^2} = 1 + \frac{|\bar{b}|^2}{|\bar{a}|^2} + 2\frac{\bar{a} \cdot \bar{b}}{|\bar{a}|^2}$$ $$= 1 + 1 + 2 \left( \frac{1}{\sqrt{2}} \right) = 2 + \sqrt{2}$$

Question 3

Maths · Conic Sections · Single correct

Let $A = \{(\alpha, \beta) \in \mathbf{R} \times \mathbf{R} : |\alpha - 1| \leq 4 \text{ and } |\beta - 5| \leq 6\}$ and $B = \{(\alpha, \beta) \in \mathbf{R} \times \mathbf{R} : 16(\alpha - 2)^2 + 9(\beta - 6)^2 \leq 144\}$

  1. B $\subset$ A
  2. A $\cup$ B = $\{$(x, y) : -4 $\leq$ x $\leq$ 4, -1 $\leq$ y $\leq$ 11$\}$
  3. neither A $\subset$ B nor B $\subset$ A
  4. A $\subset$ B

Answer: (a)

Solution

A: $|x - 1| \leq 4$ and $|y - 5| \leq 6$. (1) $\Rightarrow -4 \leq x - 1 \leq 4 \Rightarrow -6 \leq y - 5 \leq 6$ $\Rightarrow -3 \leq x \leq 5 \Rightarrow -1 \leq y \leq 11$ B: $16(x - 2)^2 + 9(y - 6)^2 \leq 144$ B: $$\frac{(x - 2)^2}{9} + \frac{(y - 6)^2}{16} \leq 1$$ From Diagram $B \subset A$

Question 4

Maths · Relations and Functions · Single correct

If the range of the function $f(x) = \frac{5-x}{x^2-3x+2}$, $x \neq 1, 2$, is $(-\infty, \alpha] \cup [\beta, \infty)$, then $\alpha^2 + \beta^2$ is equal to:

  1. 190
  2. 192
  3. 188
  4. 194

Answer: (d)

Solution

Given $y = \frac{5-x}{x^2 - 3x + 2}$. $yx^2 - 3xy + 2y + x - 5 = 0$ $yz^2 + (-3y + 1)x + (2y - 5) = 0$ Case I: If $y = 0$ (Accepted) $$\Rightarrow x = 5$$ Case II: If $y \neq 0$ $D \geq 0$ $$(-3y + 1)^2 - 4(y)(2y - 5) \geq 0$$ $$9y^2 + 1 - 6y - 8y^2 + 20y \geq 0$$ $$y^2 + 14y + 1 \geq 0$$ $$(y + 7)^2 - 48 \geq 0$$ $$|y + 7| \geq 4\sqrt{3}$$ $$\Rightarrow y + 7 \geq 4\sqrt{3} or y + 7 \leq -4\sqrt{3}$$ $$\Rightarrow y \geq 4\sqrt{3} - 7 or y \leq -4\sqrt{3} - 7$$ From Case I and Case II $$y \in (-\infty, -4\sqrt{3} - 7] \cup [4\sqrt{3} - 7, \infty)$$ So $\alpha = -4\sqrt{3} - 7$ $\beta = 4\sqrt{3} - 7$ $$\Rightarrow a^2 + b^2 = (-4\sqrt{3} - 7)^2 + (4\sqrt{3} - 7)^2$$ $$= 2(48 + 49)$$ $$= 194$$

Question 5

Maths · Probability · Single correct

A bag contains 19 unbiased coins and one coin with head on both sides. One coin drawn at random is tossed and head turns up. If the probability that the drawn coin was unbiased, is $\frac{m}{n}$, $\gcd(m, n) = 1$, then $n^2 - m^2$ is equal to:

  1. \quad 80
  2. \quad 60
  3. \quad 72
  4. \quad 64

Answer: (a)

Solution

The probability of getting a head, $P(H)$, is calculated as follows: $$P(H) = \frac{19}{20} \times \frac{1}{2} + \frac{1}{20} \times 1$$ This accounts for the selection of an unbiased coin and the occurrence of a head, as well as the selection of a biased coin where a head always occurs. The required probability is: $$\frac{19}{20} \times \frac{1}{2} + \frac{1}{20} \times 1 = \frac{19}{21}$$ Thus, $m = 19$ and $n = 21$. Therefore, $$n^2 - m^2 = 441 - 361 = 80$$

Question 6

Maths · Probability (Advanced) · Single correct

Let a random variable X take values 0, 1, 2, 3 with $P(X = 0) = P(X = 1) = p$, $P(X = 2) = P(X = 3)$ and $E \left( X^2 \right) = 2E(X)$. Then the value of $8p - 1$ is :

  1. 0
  2. 2
  3. 1
  4. 3

Answer: (b)

Solution

Given $2p + 2q = \frac{1}{2}$, we have $p + q$. The expected value $E(x^2) = \sum_{i=0}^{3} x_i^2 p(x_i) = 0 \cdot p + 1 \cdot p + 4 \cdot q + 9q = p + 13q$. The expected value $E(x) = \sum_{i=0}^{3} x_i p(x_i) = 0 \cdot p + 1 \cdot p + 2q + 3q = p + 5q$. Thus, $p + 13q = 2(p + 5q)$. Solving gives $p = 3q$. So, $q = \frac{1}{8}$ and $p = \frac{3}{8}$. Therefore, $8p - 1 = 2$. Option (2).

Question 7

Maths · Applications of Integrals · Single correct

If the area of the region $\{(x,y) : 1 + x^2 \leq y \leq \min\{x + 7, 11 - 3x\}\}$ is $A$, then $3A$ is equal to

  1. 50
  2. 49
  3. 46
  4. 47

Answer: (a)

Solution

The area $A$ is given by the integral: $$A = \int_{-2}^{1} (x + 7 - x^2 - 1) \, dx + \int_{1}^{2} (11 + 3x - x^2 - 1) \, dx$$ Evaluating the first integral: $$= \left[ \frac{x^2}{2} + 6x - \frac{x^3}{3} \right]_{-2}^{1}$$ Evaluating the second integral: $$+ \left[ 10x - \frac{3x^2}{2} - \frac{x^3}{3} \right]_{1}^{2}$$ Simplifying gives: $$= \frac{50}{3} \implies 3A = 50$$ Therefore, the correct option is Option (1).

Question 8

Maths · Applications of Derivatives · Single correct

Let $f : \mathbb{R} \to \mathbb{R}$ be a polynomial function of degree four having extreme values at $x = 4$ and $x = 5$. If $\lim_{x \to 0} \frac{f(x)}{x^2} = 5$, then $f'(2)$ is equal to:

  1. 12
  2. 10
  3. 8
  4. 14

Answer: (b)

Solution

Given \[ \lim_{x \to 0} \frac{f(x)}{x^2} = 5 \] and \[ \lim_{x \to 0} \frac{ax^4 + bx^3 + cx^2 + dx + e}{x^2} = 5. \] We have $c = 5$ and $d = e = 0$. Therefore, \[ f(x) = ax^4 + bx^3 + 5x^2. \] The derivative is \[ f'(x) = 4ax^3 + 3bx^2 + 10x = x(4ax^2 + 3bx + 10). \] This function has extrema at $x = 4$ and $x = 5$. Hence, \[ f'(4) = 0 \quad \text{and} \quad f'(5) = 0. \] Solving these equations gives \[ a = \frac{1}{8}, \qquad b = -\frac{3}{2}. \] Therefore, \[ f(2) = \frac{1}{8}\times 2^4 - \frac{3}{2}\times 2^3 + 5\times 2^2. \] Calculating, \[ f(2) = 2 - 12 + 20 = 10.

Question 9

Maths · Trigonometric Functions · Single correct

The number of solutions of the equation $$\cos 2\theta \cos \frac{\theta}{2} + \cos \frac{5\theta}{2} = 2 \cos^3 \frac{5\theta}{2}$$ in $$\left[ -\frac{\pi}{2}, \frac{\pi}{2} \right]$$ is:

  1. 7
  2. 5
  3. 6
  4. 7

Answer: (a)

Solution

Given $\cos 2\theta \cos \frac{\theta}{2} + \cos \frac{5\theta}{2} = 2 \cos^3 \frac{5\theta}{2}$. $$\frac{1}{2} \left( 2 \cos 2\theta \cos \frac{\theta}{2} \right) + \cos \frac{5\theta}{2}$$ $$= \frac{1}{2} \left( \cos \frac{15\theta}{2} + 3 \cos \frac{5\theta}{2} \right)$$ or solving $$\cos \frac{3\theta}{2} = \cos \frac{15\theta}{2}$$ $$\cos \frac{15\theta}{2} - \cos \frac{3\theta}{2} = 0$$ $$2 \sin 30 \sin \frac{9\theta}{2} = 0$$ $$3\theta = n\pi or \frac{90}{2} = m\pi$$ $$\theta = \frac{n\pi}{3} \theta = \frac{2m\pi}{9}$$ $$\theta = \left\{ -\frac{\pi}{2}, \frac{\pi}{3}, 0 \right\}$$ $$\theta = \left\{ -\frac{4\pi}{9}, -\frac{2\pi}{9}, \frac{4\pi}{9}, \frac{2\pi}{9} \right\}$$

Question 10

Maths · Sequences and Series · Single correct

Let $a_n$ be the $n^{th}$ term of an A. P. If $S_n = a_1 + a_2 + a_3 + \ldots + a_n = 700$, $a_6 = 7$ and $S_7 = 7$, then $a_n$ is equal to:

  1. 56
  2. 65
  3. 64
  4. 70

Answer: (c)

Solution

Given $S_n = 700 = \frac{n}{2} [2a + (n-1)d]$...(i) $a_6 = 7 \Rightarrow a + 5d = 7$...(ii) $S_7 = 7 \Rightarrow \frac{7}{2} (2a + 6d) = 7$ $a + 3d = 1$...(iii) Solve (ii) and (iii) $$\frac{n}{2} (-16 + 3n - 3) = 700 \Rightarrow 3n^2 - 19n - 1400 = 0$$ $$(3n + 56)(n - 25) = 0$$ Therefore, $a_{25} = a + 24d = -8 + 24 \times 3$ $= -8 + 72$ $= 64$

Question 11

Maths · Complex Numbers and Quadratic Equations · Single correct

If the locus of $z \in \mathbb{C}$, such that $$\mathrm{Re}\left(\frac{z-1}{2z+i}\right) + \mathrm{Re}\left(\frac{\overline{z}-1}{2\overline{z}-i}\right) = 2$$ is a circle of radius $r$ and center $(a, b)$ then $\frac{15ab}{r^2}$ is equal to:

  1. 24
  2. 12
  3. 18
  4. 16

Answer: (c)

Solution

Given $\($ $\Re$ $\left$( $\frac{z-1}{2z+i}$ $\right$) + $\Re$ $\left$( $\frac{\bar{z}-1}{2\bar{z}-i}$ $\right$) = 2 $\)$. Here, $\[$ $\frac{z-1}{2z+i}$ = $\left$( $\frac{\bar{z}-1}{2\bar{z}-i}$ $\right$) = 2 $\]$ $\[$ $\Rightarrow$ $\Re$ $\left$( $\frac{z-1}{2z+i}$ $\right$) + $\Re$ $\left$( $\frac{z-1}{2z+i}$ $\right$) = 2 $\]$ $\[$ = 2 $\Re$ $\left$( $\frac{z-1}{2z+1}$ $\right$) = 2 $\Rightarrow$ $\Re$ $\left$( $\frac{z-1}{2z+i}$ $\right$) = 1 $\]$ Let $\($ z = x + iy $\)$ $\[$ $\Re$ $\left$( $\frac{(x-1) + iy}{2x + i(2y+1)}$ $\right$) = 1 $\Rightarrow$ $\Re$ $\left$[ $\frac{((x-1) + iy)(2x-i(y+1))}{(2x + i(2y+1))(2x-i(2y+1))}$ $\right$] = 1 $\]$ $\[$ $\Rightarrow$ 2x(x-1) + y(2y+1) = 1 $\]$ $\[$ $\Rightarrow$ 4x^2 + (2y+1)^2 = 1 $\]$ $\[$ $\Rightarrow$ 2x^2 - 2x + 2y^2 + y = 4x^2 + 4y^2 + 1 + 4y $\]$ $\[$ $\Rightarrow$ 2x^2 + 2y^2 + 3y + 2x + 1 = 0 $\]$ $\[$ $\Rightarrow$ x^2 + y^2 + x + $\frac{3}{2}$ y + $\frac{1}{2}$ = 0 $\]$ $\[$ centre = $\left$( -$\frac{1}{2}$, -$\frac{3}{4}$ $\right$), $\ $r = $\sqrt{\frac{1}{4} + \frac{9}{16} - \frac{1}{2}}$ = $\frac{\sqrt{5}}{4}$ $\]$ $\[$ a = -$\frac{1}{2}$, $\ $b = -$\frac{3}{4}$, $\ $r^2 = $\frac{5}{16}$ $\]$ $\[$ 15 $\frac{ab}{r^2}$ = 15 $\times$ $\left$( -$\frac{1}{2}$ $\right$) $\times$ $\left$( -$\frac{3}{4}$ $\right$) $\times$ $\frac{16}{5}$ = 18 $\]$

Question 12

Maths · Conic Sections · Single correct

Let the length of a latus rectum of an ellipse $\frac{x^2}{a^2} + \frac{y^2}{b^2} = 1$ be 10. If its eccentricity is the minimum value of the function $f(t) = t^2 + t + \frac{11}{12}$, $t \in \mathbb{R}$, then $a^2 + b^2$ is equal to:

  1. 125
  2. 126
  3. 120
  4. 115

Answer: (b)

Solution

Length of LR = $\frac{2b^2}{a}$ = 10 $\Rightarrow$ 5a = b^2 $\ldots$ (1) f(t) = t^2 + t + $\frac{11}{12}$ $\frac{df(t)}{dt}$ = 2t + 1 = 0 $\Rightarrow$ t = -$\frac{1}{2}$ Min value of f(t) = $\left$(-$\frac{1}{2}$$\right$)^2 + $\frac{11}{12}$ = $\frac{1}{4}$ - $\frac{1}{2}$ + $\frac{11}{12}$ = $\frac{3 - 6 + 11}{12}$ = $\frac{8}{12}$ = $\frac{2}{3}$ = e e^2 = $\frac{1 - b^2}{a^2}$ $\Rightarrow$ $\frac{4}{9}$ = $\frac{1 - b^2}{a^2}$ $\Rightarrow$ $\frac{b^2}{a^2}$ = $\frac{1 - 4}{a}$ = $\frac{5}{a}$ $\Rightarrow$ b^2 = $\frac{5a^2}{a}$ $\ldots$ (2) From (1) $\&$ (2) 5a = $\frac{5a^2}{a}$ $\Rightarrow$ a = 9, b = $\sqrt{45}$ = 3$\sqrt{5}$ $\therefore$ a^2 + b^2 = 81 + 45 = 126

Question 13

Maths · Differential Equations · Single correct

Let $y = y(x)$ be the solution of the differential equation $(x^2 + 1) y' - 2xy = (x^4 + 2x^2 + 1) \cos x, y(0) = 1$. Then $\int_{-3}^{3} y(x) \, dx$ is:

  1. 24
  2. 36
  3. 30
  4. 18

Answer: (a)

Solution

Given $(x^2 + 1) \frac{dy}{dx} - 2xy = (x^4 + 2x^2 + 1) \cos x$. Rewriting, we have: $$\frac{dy}{dx} - \left( \frac{2x}{x^2 + 1} \right) y = \frac{(x^2 + 1)^2 \cos x}{cx^2 + 1} = (x^2 + 1) \cos x$$ This is a linear differential equation. Let $P = \frac{-2x}{x^2 + 1}$ and $Q = (x^2 + 1) \cos x$. The integrating factor (I.F.) is given by: $$I.F. = e^{\int P dx} = e^{\int \frac{-2x}{x^2 + 1} dx} = \frac{1}{x^2 + 1}$$ Thus, we have: $$y \cdot \frac{1}{x^2 + 1} = \int (x^2 + 1) \cos x \cdot \frac{1}{x^2 + 1} dx$$ This simplifies to: $$y = \sin x + c \implies y \cos = 1 \implies c = 1$$ Therefore, $x^2 + 1$ gives: $$y = (x^2 + 1) (\sin x + 1)$$ Now, integrating from $-3$ to $3$: $$\int_{-3}^{3} y dx = \int_{-3}^{3} (x^2 + 1) (\sin x + 1) dx$$ This becomes: $$dx = \int_{-3}^{3} x^2 \sin x + x^2 \sin x + 1 dx$$ Which simplifies to: $$\implies \int_{-3}^{3} x^2 \sin x dx + \int_{-3}^{3} x^2 dx + \int_{-3}^{3} \sin x dx + \int_{-3}^{3} 1 dx$$ Evaluating these integrals gives: $$= 0 + 18 + 0 + 6 = 24$$

Question 14

Maths · Three Dimensional Geometry · Single correct

If the equation of the line passing through the point $\left(0, -\frac{1}{2}, 0\right)$ and perpendicular to the lines $$\vec{r} = \lambda (\hat{i} + a\hat{j} + b\hat{k})$$ and $$\vec{r} = (\hat{i} - \hat{j} - 6\hat{k}) + \mu (-b\hat{i} + a\hat{j} + 5\hat{k})$$ is $\frac{x-1}{-2} = \frac{y+4}{d} = \frac{z-c}{-4}$, then $a + b + c + d$ is equal to:

  1. 10
  2. 14
  3. 11
  4. 12

Answer: (b)

Solution

Line is $\perp$ to 2 line $\Rightarrow$ line will be parallel to $\left( i + a \hat{j} + b \hat{k} \right) \times \left( -b \hat{i} + a \hat{j} + 5 \hat{k} \right)$. Parallel vector along the required line is $\hat{i} (5a - ab) - \hat{j} \left( b^2 + 5 \right) + \hat{k} (a + ab)$. Dr's of required line $\alpha (5a - ab), - \left( b^2 + 5 \right), (a + ab)$. Also Dr's of required line $\alpha - 2, d, -4$. $$\frac{5a - ab}{-2} = \frac{-\left( b^2 + 5 \right)}{d} = \frac{a + ab}{-4} \ldots (1)$$ Also point $\left( 0, -\frac{1}{2}, 0 \right)$ will lie on $\frac{x - 1}{-2} = \frac{y + 4}{d} = \frac{z - c}{-4}$. $$\frac{0 - 1}{-2} = \frac{-\frac{1}{2} + 4}{d} = \frac{0 - c}{-4} \Rightarrow d = 7, c = 2$$ From (1) $\frac{5a - ab}{-2} = \frac{-b^2 - 5}{7} = \frac{a + ab}{-4}$. $$\frac{5a - ab}{-2} = \frac{a + ab}{-4}; \frac{-b^2 - 5}{7} = \frac{a + ab}{-4}$$ $$-20a + 4ab = -2a - 2ab$$ $$4b^2 + 20 = 70 + 7ab$$ $$18a = 6ab$$ $$b = 3$$ $$36 + 20 = 70 + 21a$$ $$56 = 28a \Rightarrow a = 2$$ $a + b + c + d = 2 + 3 + 2 + 7 = 14$

Question 15

Maths · Conic Sections · Single correct

Let p be the number of all triangles that can be formed by joining the vertices of a regular polygon P of n sides and q be the number of all quadrilaterals that can be formed by joining the vertices of P. If $p + q = 126$, then the eccentricity of the ellipse $\frac{x^2}{16} + \frac{y^2}{n} = 1$ is:

  1. $\frac{3}{4}$
  2. $\frac{1}{2}$
  3. $\frac{\sqrt{7}}{4}$
  4. $\frac{1}{\sqrt{2}}$

Answer: (d)

Solution

Total triangles $\Rightarrow \binom{h}{3}$. Total quadrilaterals $= \binom{h}{4} = q$. $$\binom{n}{3} + \binom{n}{4} = 126 \Rightarrow \binom{n+1}{4} = 126$$ $$\Rightarrow n + 1 = 9 \Rightarrow n = 8$$ $$\frac{x^2}{16} + \frac{y^2}{n} = 1 \Rightarrow \frac{x^2}{16} + \frac{y^2}{8} = 1$$ $$e = \sqrt{1 - \frac{8}{16}} = \sqrt{\frac{8}{16}} = \frac{1}{\sqrt{2}}$$

Question 16

Maths · Three Dimensional Geometry · Single correct

Consider the lines $L_1 : x - 1 = y - 2 = z$ and $L_2 : x - 2 = y = z - 1$. Let the feet of the perpendiculars from the point $P(5, 1, -3)$ on the lines $L_1$ and $L_2$ be $Q$ and $R$ respectively. If the area of the triangle $PQR$ is $A$, then $4A^2$ is equal to:

  1. 139
  2. 147
  3. 151
  4. 143

Answer: (b)

Solution

Given the line $L_1$: $\($ $\frac{x-1}{1}$ = $\frac{y-2}{1}$ = $\frac{z-0}{2}$ $\)$. Let $Q(\lambda + 1, \lambda + 2, \lambda)$. The vector $\overrightarrow{PQ} = (\lambda - 4, \lambda - 1, \lambda + 3)$. The dot product $\overrightarrow{PQ} \cdot \mathbf{m} = 0$. Solving $\lambda - 4 + \lambda + 1 + \lambda + 3 = 0$ gives $3\lambda = 0$, so $\lambda = 0$. Therefore, $Q(1, 2, 0)$. For line $L_2$: $\($ $\frac{x-2}{1}$ = $\frac{y-0}{1}$ = $\frac{z-1}{2}$ $\)$. Let $R(\mu + 2, \mu, \mu + 1)$. The vector $\overrightarrow{PR} = (\mu - 3, \mu - 1, \mu + 4)$. The dot product $\overrightarrow{PR} \cdot \mathbf{n} = 0$. Solving $\mu - 3 + \mu - 1 + \mu + 4 = 0$ gives $\mu = 0$. Therefore, $R(2, 0, 1)$. The area of $\triangle PQR(A)$ is $\frac{1}{2} |\overrightarrow{PQ} \times \overrightarrow{PR}|$. Calculating $A = \frac{1}{2} |(-4\mathbf{i} + \mathbf{j} + 3\mathbf{k}) \times (-3\mathbf{i} + \mathbf{j} + 4\mathbf{k})|$. The cross product is $\frac{1}{2} |7(\mathbf{i} + \mathbf{j} + \mathbf{k})|$. The determinant is: $$\begin{vmatrix} \mathbf{i} & \mathbf{j} & \mathbf{k} \\ -4 & 1 & 3 \\ -3 & 1 & 4 \end{vmatrix} = 7\mathbf{i} + 7\mathbf{j} + 7\mathbf{k}$$ Thus, $4A^2 = 49 \times 3 = 147$.

Question 17

Maths · Relations and Functions · Single correct

The number of real roots of the equation $x|x - 2| + 3|x - 3| + 1 = 0$ is:

  1. 4
  2. 2
  3. 1
  4. 3

Answer: (c)

Solution

For (I) $x < 2$: $$-x^2 + 2x - 3x + 9 + 1 = 0$$ This simplifies to: $$x^2 + x - 10 = 0$$ The solutions are: $$x = \frac{-1 + \sqrt{41}}{2}, \frac{-1 - \sqrt{41}}{2}$$ This case is not valid. For (II) $2 \leq x < 3$: $$x^2 - 2x - 3x + 9 + 1 = 0$$ This simplifies to: $$x^2 - 5x + 10 = 0$$ The discriminant $D < 0$, so there are no real roots. For (III) $x \geq 3$: $$x^2 - 2x + 3x - 9 + 2 = 0$$ This simplifies to: $$x^2 + x - 8 = 0$$ The solutions are: $$x = \frac{-1 + \sqrt{32}}{2}, \frac{-1 - \sqrt{32}}{2}$$ This case is also not valid. There is 1 real root.

Question 18

Maths · Conic Sections · Single correct

Let $e_1$ and $e_2$ be the eccentricities of the ellipse $\frac{x^2}{b^2} + \frac{y^2}{25} = 1$ and the hyperbola $\frac{x^2}{16} - \frac{y^2}{b^2} = 1$, respectively. If $b < 5$ and $e_1 e_2 = 1$, then the eccentricity of the ellipse having its axes along the coordinate axes and passing through all four foci (two of the ellipse and two of the hyperbola) is:

  1. $\frac{4}{5}$
  2. $\frac{3}{5}$
  3. $\frac{\sqrt{7}}{4}$
  4. $\frac{\sqrt{3}}{2}$

Answer: (b)

Solution

Given $e_1^2 = 1 - \frac{b^2}{25}$ and $e_2^2 = 1 - \frac{b^2}{16}$. Therefore, $e_1^2 e_2^2 = 1$. $$\left(1 - \frac{b^2}{25}\right) \left(1 + \frac{b^2}{16}\right) = 1$$ This implies: $$\Rightarrow 2 + \frac{b^2}{16} - \frac{b^2}{25} - \frac{b^4}{400} = 1$$ $$\Rightarrow \frac{9\, b^2}{400} = \frac{b^4}{400}$$ Thus, $b^2 = 9$. The equations are: $$\frac{x^2}{9} + \frac{y^2}{25} = 1$$ $$\frac{x^2}{16} - \frac{y^2}{9} = 0$$ Calculate $e_1$: $$e_1 \sqrt{1 - \frac{9}{25}}$$ $$e_1 = \frac{4}{5}$$ The foci are: $(0, \pm 4)$ and $(\pm 5, 0)$. Ellipse passing through all four foci: $$\frac{x^2}{25} + \frac{y^2}{16} = 1$$ Calculate $e$: $$e = \sqrt{1 - \frac{16}{25}} = \frac{3}{5}$$

Question 19

Maths · Matrices · Single correct

Let the system of equations $$x + 5y - z = 1$$ $$4x + 3y - 3z = 7$$ $$24x + y + \lambda z = \mu$$ $\lambda$, $\mu$ $\in$ $\mathbb{R}$, have infinitely many solutions. Then the number of the solutions of this system, If $x, y, z$ are integers and satisfy $7 \leq x + y + z \leq 77$, is

  1. 3
  2. 6
  3. 5
  4. 4

Answer: (a)

Solution

For infinitely many solutions, $\($ $\Delta$ = 0 $\)$. $\[$ $\begin{vmatrix}$ 1 & 5 & -1 $\\$ 4 & 3 & -3 $\\$ 24 & 1 & $\lambda$ $\\$ $\end{vmatrix}$ = 0 $\]$ $\[$ $\Rightarrow$ 1(3$\lambda$ + 3) - 5(4$\lambda$ + 72) - 1(4 - 72) = 0 $\]$ $\[$ $\Rightarrow$ -17$\lambda$ + 3 - 4 $\times$ 72 - 4 = 0 $\]$ $\[$ $\Rightarrow$ 17$\lambda$ = -289 $\]$ $\[$ $\Rightarrow$ $\lambda$ = -17 $\]$ $\($ $\Delta$_1 = 0 $\)$ $\[$ $\begin{vmatrix}$ 1 & 5 & -1 $\\$ 7 & 3 & -3 $\\$ $\mu$ & 1 & -17 $\\$ $\end{vmatrix}$ = 0 $\]$ $\[$ $\Rightarrow$ 1(-51 + 3$\mu$) - 5(-119 + 3$\mu$) - 1(7 - 3$\mu$) = 0 $\]$ $\[$ $\Rightarrow$ -48 + 595 - 15$\mu$ - 7 + 3$\mu$ = 0 $\]$ $\[$ $\Rightarrow$ 12$\mu$ = 540 $\]$ $\[$ x + 5y = z = 1 $\]$ $\[$ 4x + 3y - 3z = 7 $\]$ $\[$ 24x + y - 17z = 45 $\]$ Let $\($ z = 1 $\)$ $\[$ x + 5y = 1 + $\lambda$ $\times$ 4 $\]$ $\[$ 4x + 3y = 7 + 3$\lambda$ $\]$ $\[$ 4x + 20y = 4 + 4$\lambda$ $\]$ $\[$ -17y = 3 - $\lambda$ $\]$ $\[$ y = $\frac{\lambda - 3}{17}$, x = 1 + $\lambda$ - $\frac{5\lambda - 15}{17}$ $\]$ $\[$ = $\frac{32 - 12\lambda}{17}$ $\]$ $\[$ 7 $\leq$ $\frac{\lambda - 3}{17}$ + $\frac{32 + 12\lambda}{17}$ + $\lambda$ $\leq$ 77 $\]$ $\[$ 7 $\leq$ $\frac{30\lambda + 29}{17}$ $\leq$ 77 $\]$ $\[$ 3 $\leq$ $\lambda$ $\leq$ 42 $\]$ $\[$ $\lambda$ = 3, 20, 37 $\]$

Question 20

Maths · Sequences and Series · Single correct

If the sum of the second, fourth and sixth terms of a G.P. of positive terms is 21 and the sum of its eighth, tenth and twelfth terms is 15309, then the sum of its first nine terms is:

  1. 760
  2. 755
  3. 750
  4. 757

Answer: (d)

Solution

Given $ar + ar^3 + ar^5 = 21$, $ar^7 + ar^9 + ar^{11} = 15309$. Therefore, $ar(1 + r^2 + r^4) = 21$, $ar^7(1 + r^2 + r^4) = 15309$. Dividing equation (2) by equation (1), we get $$\frac{a \cdot r^7}{ar} = \frac{15309}{21}$$ which implies $r^6 = 729$. Therefore, $r = 9$. Now, $$\frac{a \cdot (r^9 - 1)}{r - 1} = \frac{7}{91} (19683 - 1) = \frac{7 \times 19682}{91 \times 2}$$ which simplifies to $$\frac{9841}{13} = 757.$$

Question 21

Maths · Limits and Derivatives · Numerical

If the function $f(x) = \frac{\tan(\tan x) - \sin(\sin x)}{\tan x - \sin x}$ is continuous at $x = 0$, then $f(0)$ is equal to

Answer: 2

Solution

The limit is given by $$\lim_{x \to 0} \frac{\tan(\tan x) - \tan x}{\tan^3 x} + \frac{\tan x - \sin x}{x^3} + \frac{\sin(\sin x) - \sin x}{\sin^3 x} + \frac{\sin x}{x^3}$$ which simplifies to $$\frac{1}{3} + \frac{1}{2} + \frac{1}{6} = 2.$$

Question 22

Maths · Integrals · Fill in the blank

$\int\left(\frac{1}{x}+\frac{1}{x^3}\right)\left(\sqrt[23]{3x^{-24}+x^{-26}}\right)\,dx=-\frac{\alpha}{3(\alpha+1)}\left(3x^\beta+x^\gamma\right)^{\frac{\alpha+1}{\alpha}}+C,\qquad x>0,$ $(\alpha,\beta,\gamma\in\mathbb{Z})$, where $C$ is the constant of integration, then $\alpha+\beta+\gamma$ is equal to _______.

Answer: 19

Solution

Given $$\int \left( \frac{1}{x^2} + \frac{1}{x^4} \right) \left( \frac{3}{x} + \frac{1}{x^3} \right)^{\frac{1}{23}} \, dx$$ using $$t = \frac{3}{x} + \frac{1}{x^3} \Rightarrow dt = -3 \left( \frac{1}{x^2} + \frac{1}{x^4} \right) \, dx$$ $$\int t^{1/23} \, dt = \frac{t^{24/23}}{24/23} + C$$ $$= \left( \frac{24}{23} \right)(-3)$$ $$\Rightarrow \alpha = 23, \beta = -1, \gamma = -3$$ $$\alpha + \beta + \gamma = 19$$

Question 23

Maths · Limits and Derivatives · Numerical

For $t > -1$, let $\alpha_t$ and $\beta_t$ be the roots of the equation $$\left( (t+2)^{\frac{1}{7}} - 1 \right) x^2 + \left( (t+2)^{\frac{1}{6}} - 1 \right) x + \left( (t+2)^{\frac{1}{21}} - 1 \right) = 0$$ If $\lim_{t \to -1^+} \alpha_t = a$ and $\lim_{t \to -1^+} \beta_t = b$, then $72(a+b)^2$ is equal to

Answer: 98

Solution

Given $a + b = \lim_{t \to -1^+} (\alpha + \beta) = \lim_{t \to -1^+} \left( (t+2)^{\frac{1}{6}} - 1 \right)$. Let $t + 2 = y$. Then, $$a + b = \lim_{y \to 1^+} \frac{y^{1/6} - 1}{y^{1/7} - 1} = \frac{7}{6}.$$ Now, $$72(a + b)^2 = 72 \times \frac{49}{36} = 98.$$

Question 24

Maths · Conic Sections · Numerical

Let the lengths of the transverse and conjugate axes of a hyperbola in standard form be $2a$ and $2b$, respectively, and one focus and the corresponding directrix of this hyperbola be $(-5, 0)$ and $5x + 9 = 0$, respectively. If the product of the focal distances of a point $(\alpha, 2\sqrt{5})$ on the hyperbola is $p$, then $4p$ is equal to

Answer: 189

Solution

Equation of hyperbola is $\frac{x^2}{a^2} - \frac{y^2}{b^2} = 1$. Directrix: $x = \frac{-9}{5}$ and corresponding foci $(-5, 0)$. $$\Rightarrow -\frac{a}{e} = -\frac{9}{5} and -ae = -5$$ $$\Rightarrow \frac{9e^2}{5} = 5 \Rightarrow e = \sqrt{\frac{25}{9}} = \frac{5}{3} \Rightarrow a = 3$$ $$\therefore b^2 = a^2 (e^2 - 1) = 9 \left( \frac{25}{9} - 1 \right) = 16$$ Hyperbola $\frac{x^2}{9} - \frac{y^2}{16} = 1$. $(\alpha, 2\sqrt{5})$ lie on it. $$\Rightarrow \frac{\alpha^2}{9} - \frac{20}{16} = 1 \Rightarrow \alpha^2 = \frac{36}{16} \times 9 = \frac{81}{4}$$ Product for distance of $(x_1, y_1)$ from the two foci $$= (ex_1 + a) |ex_1 - a|$$ $$= e^2 x_1^2 - a^2$$ For $(\alpha, 2\sqrt{5}) \Rightarrow P = \frac{25}{9} \cdot \frac{81}{4} - 9 = \frac{189}{4}$$ $$4P = 189$$

Question 25

Maths · Binomial Theorem · Subjective

The sum of the series $$2 \times 1 \times \binom{20}{4} - 3 \times 2 \times \binom{20}{5} + 4 \times 3 \times \binom{20}{6} - 5 \times 4 \times \binom{20}{7} + \ldots + 18 \times 17 \times \binom{20}{20}$$, is equal to

Answer: 34

Solution

Given $ (1-x)^{20} = \binom{20}{0} - \binom{20}{1}x + \binom{20}{2}x^2 - \cdots + \binom{20}{20}x^{20} $. $$ \frac{(1-x)^{20}}{x^2} = \frac{\binom{20}{0}}{x^2} - \frac{\binom{20}{1}}{x} + \binom{20}{2} - \binom{20}{3}x + \binom{20}{4}x^2 \ldots $$ Differentiate twice and put $ x = 1 $: $$ = 6 - \binom{20}{1}(2) + A $$ $$ A = 40 - 6 = 34 $$

Physics

Question 26

Physics · Electric Charges and Fields · Single correct

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : The outer body of an air craft is made of metal which protects persons sitting inside from lightning-strikes. Reason (R) : The electric field inside the cavity enclosed by a conductor is zero. In the light of the above statements, chose the most appropriate answer from the options given below :

  1. Both (A) and (R) are correct and (R) is the correct explanation of (A)
  2. is correct but (R) is not correct
  3. Both (A) and (R) are correct but (R) is not correct explanation of (A)
  4. is not correct but (R) is correct

Answer: (a)

Solution

The electric field of an outside charge is zero inside a conductor.

Question 27

Physics · Nuclei · Single correct

Given below are two statements: one is labelled as Assertion $(A)$ and the other is labelled as Reason $(R)$. Assertion $(A)$: The density of the copper $\left(^{64}_{29}\mathrm{Cu}\right)$ nucleus is greater than that of the carbon $\left(^{12}_{6}\mathrm{C}\right)$ nucleus. Reason $(R)$: The nucleus of mass number $A$ has a radius proportional to $A^{1/3}$. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. is correct but $(R)$ is not correct
  2. is not correct but $(R)$ is correct
  3. Both $(A)$ and $(R)$ are correct and $(R)$ is the correct explanation of $(A)$
  4. Both $(A)$ and $(R)$ are correct but $(R)$ is not the correct explanation of $(A)$

Answer: (b)

Solution

Given $\rho = \frac{M}{V} = \frac{m_n \times A}{\frac{4}{3} \pi R^3} = \frac{m_n \times A}{\frac{4}{3} \pi A R_0^3}$. So $\rho$ is almost constant. $R = R_0 A^{1/3}$ $R \propto A^{1/3}$

Question 28

Physics · Electromagnetic Waves · Single correct

The unit of $\sqrt{\frac{2I}{\epsilon_0 c}}$ is: (I = intensity of an electromagnetic wave, c : speed of light)

  1. $Vm$
  2. $NC$
  3. $Nm$
  4. $NC^{-1}$

Answer: (d)

Solution

Given $$I = \frac{1}{2} \varepsilon_0 E_0^2 \times C$$ We have $$E_0 = \sqrt{\frac{2I}{\varepsilon_0 C}}$$ $E_0$: electric field N/C

Question 29

Physics · Electromagnetic Waves · Single correct

The dimension of $\sqrt{\frac{\mu_0}{\epsilon_0}}$ is equal to that of: $(\mu_0=\text{Vacuum permeability and }\epsilon_0=\text{Vacuum permittivity})$

  1. Voltage
  2. Capacitance
  3. Inductance
  4. Resistance

Answer: (d)

Solution

Given $L = \mu_0 N A / \ell$ and $C = \frac{A \epsilon_0}{d}$. Therefore, $\frac{L}{C} \propto \frac{\mu_0}{\epsilon_0}$. Thus, $\sqrt{\frac{\mu_0}{\epsilon_0}} \propto \sqrt{\frac{L}{C}}$. We have $\frac{L}{C} = \frac{\tau R}{(\tau/R)} = R^2$. Therefore, $\sqrt{\frac{\mu_0}{\epsilon_0}} = R$.

Question 30

Physics · Dual Nature of Radiation and Matter · Single correct

A photo-emissive substance is illuminated with a radiation of wavelength $\lambda_i$ so that it releases electrons with de-Broglie wavelength $\lambda_e$. The longest wavelength of radiation that can emit photoelectron is $\lambda_0$. Expression for de-Broglie wavelength is given by : ( m : mass of the electron, h : Planck's constant and c : speed of light)

  1. $\lambda_e = \sqrt{\frac{h}{2mc} \left( \frac{1}{\lambda_i} - \frac{1}{\lambda_0} \right)}$
  2. $\lambda_e = \sqrt{\frac{h \lambda_0}{2mc}}$
  3. $\lambda_e = \sqrt{\frac{h}{2mc} \left( \frac{1}{\lambda_i} - \frac{1}{\lambda_0} \right)}$
  4. $\lambda_e = \sqrt{\frac{h \lambda_i}{2mc}}$

Answer: (a)

Solution

Given $K.E = E - W$. $\lambda_e = \frac{h}{\sqrt{2mK \cdot E}}$, $E = \frac{hc}{\lambda_i}$, $W = \frac{hc}{\lambda_0}$. $$\frac{h^2}{2m\lambda_e^2} = \frac{hc}{\lambda_i} - \frac{hc}{\lambda_0}$$ $$\lambda_e = \sqrt{\frac{h}{2mc \left( \frac{1}{\lambda_i} - \frac{1}{\lambda_0} \right)}}$$

Question 31

Physics · Gravitation · Single correct

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : The radius vector from the Sun to a planet sweeps out equal areas in equal intervals of time and thus areal velocity of planet is constant. Reason (R) : For a central force field the angular momentum is a constant. In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both (A) and (R) are correct and (R) is the correct explanation of (A)
  2. Both (A) and (R) are correct but (R) is not the correct explanation of (A)
  3. is correct but (R) is not correct
  4. is not correct but (R) is correct

Answer: (a)

Solution

Given $\($ $\frac{dA}{dt}$ = $\frac{L}{2m}$ $\)$. Due to central force, torque is zero and angular momentum is constant.

Question 32

Physics · Kinetic Theory · Single correct

The helium and argon are put in the flask at the same room temperature (300 $\,$ $\mathrm{K}$). The ratio of average kinetic energies (per molecule) of helium and argon is: (Give: Molar mass of helium = 4 $\,$ $\mathrm{g/mol}$, Molar mass of argon = 40 $\,$ $\mathrm{g/mol}$)

  1. 1 : 10
  2. 10 : 1
  3. 1 : $\sqrt{10}$
  4. 1 : 1

Answer: (d)

Solution

Given $K.E = \frac{f}{2} KT$. For He and Ar, $f = 3$. Therefore, $K.E_{He} = 1$ and $K.E_{Ar} = 1$. Hence, the answer is the same for both.

Question 33

Physics · Mechanical Properties of Fluids · Numerical

A capillary tube of radius $0.1\,\mathrm{mm}$ is partly dipped in water (surface tension $70\,\mathrm{dyn/cm}$ and glass-water contact angle $\simeq0^\circ$) with $30^\circ$ inclined with vertical. The length of water risen in the capillary is _______ $\mathrm{cm}$. (Take $g=9.8\,\mathrm{m/s^2}$)

  1. $\frac{82}{5}$
  2. $\frac{57}{2}$
  3. $\frac{71}{5}$
  4. $\frac{68}{5}$

Answer: (a)

Solution

Given the equation for height $h$: $$h = \frac{2T \cos \theta}{\rho g r} = \frac{2 \times 70 \times 1}{1 \times 980 \times 10^{-2}}$$ This simplifies to: $$h = \frac{100}{7} \, cm$$ Using the sine relation: $$\sin 60^\circ = \frac{h}{\ell}$$ Solving for $\ell$: $$\ell = \frac{h \times 2}{\sqrt{3}}$$ Substitute $h$: $$\ell = \frac{100}{7} \times \frac{2}{\sqrt{3}}$$ Simplifying further: $$\ell = \frac{200}{7 \times \sqrt{3}}$$ Finally: $$\ell = 16.49 \, cm$$

Question 34

Physics · Ray Optics and Optical Instruments · Single correct

A mirror is used to produce an image with magnification of $\frac{1}{4}$. If the distance between object and its image is $40 \, \mathrm{cm}$, then the focal length of the mirror is ________

  1. 10 cm
  2. 12.7 cm
  3. 10.7 cm
  4. 15 cm

Answer: (c)

Solution

Given $m = -\frac{v}{u} = -\left(\frac{v}{-u}\right) = \frac{v}{u}$. $$\frac{1}{4} = \frac{v}{u} \implies u = 4v$$ $v + u = 40$ $5v = 40$ $v = 8 \, \mathrm{cm}$ $u = 32 \, \mathrm{cm}$ $$\frac{1}{v} + \frac{1}{u} = \frac{1}{f}$$ $$\frac{1}{8} - \frac{1}{32} = \frac{1}{f}$$ $$\frac{4 - 1}{32} = \frac{1}{f}$$ $$\frac{3}{32} = \frac{1}{f}$$ $f = \frac{32}{3} = 10.7 \, \mathrm{cm}$

Question 35

Physics · Electric Charges and Fields · Single correct

A dipole with two electric charges of $2 \mu \mathrm{C}$ magnitude each, with separation distance $0.5 \mu \, \mathrm{m}$, is placed between the plates of a capacitor such that its axis is parallel to an electric field established between the plates when a potential difference of $5 \, \mathrm{V}$ is applied. Separation between the plates is $0.5 \, \mathrm{mm}$. If the dipole is rotated by $30^\circ$ from the axis, it tends to realign in the direction due to a torque. The value of torque is:

  1. $5 \times 10^{-9} \, \mathrm{Nm}$
  2. $5 \times 10^{-3} \, \mathrm{Nm}$
  3. $2.5 \times 10^{-12} \, \mathrm{Nm}$
  4. $2.5 \times 10^{-9} \, \mathrm{Nm}$

Answer: (a)

Solution

Given $E = \frac{V}{d} = \frac{5}{5 \times 10^{-4}} = 10^4 \, \mathrm{V/m}$. $\tau = PE \sin \theta$ Where $P = qa = 2 \times 10^{-6} \times 5 \times 10^{-7}$ $= 1 \times 10^{-12} \, \mathrm{C \cdot m}$ $\tau = 1 \times 10^{-12} \times 10^4 \times \frac{1}{2} = 5 \times 10^{-9} \, \mathrm{N \cdot m}$

Question 36

Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct

Consider the following logic circuit. The output is $Y = 0$ when:

  1. $A = 1$ and $B = 1$
  2. $A = 0$ and $B = 1$
  3. $A = 1$ and $B = 0$
  4. $A = 0$ and $B = 0$

Answer: (a)

Solution

Given the logic circuit, we have the following expressions: $$Y_1 = A \cdot B, \quad Y_2 = \overline{A} + B$$ The output $Y$ is given by: $$Y = \overline{Y_1} \cdot Y_2 = \overline{Y_1} + \overline{Y_2}$$ Substituting the expressions for $Y_1$ and $Y_2$: $$Y = \overline{A \cdot B} + A + \overline{B}$$ This simplifies to: $$Y = \overline{A} + \overline{B} + A \cdot \overline{B}$$ The truth table for $Y$ is: $$ \begin{array}{ccc} A & B & Y \\ 0 & 0 & 1 \\ 1 & 0 & 1 \\ 0 & 1 & 1 \\ 1 & 1 & 0 \end{array} $$

Question 37

Physics · Physical World, Units and Measurements · Single correct

Match List-I with List-II. \begin{tabular}{|l|l|} \hline \textbf{LIST-I} & \textbf{LIST-II} \\ \hline A. Mass density & I. $[ML^2T^{-3}]$ \\ \hline B. Impulse & II. $[MLT^{-1}]$ \\ \hline C. Power & III. $[ML^2T^0]$ \\ \hline D. Moment of inertia & IV. $[ML^{-2}T^0]$ \\ \hline \end{tabular} Choose the correct answer from the options given below

  1. \text{(A)-(IV), (B)-(II), (C)-(III), (D)-(I)}
  2. \text{(A)-(I), (B)-(III), (C)-(IV), (D)-(II)}
  3. \text{(A)-(IV), (B)-(II), (C)-(I), (D)-(III)}
  4. \text{(A)-(II), (B)-(III), (C)-(IV), (D)-(I)}

Answer: (c)

Solution

Q14. (A) Mass density = $\frac{M}{V} = M^1 L^{-3}$ ...(iv) (3) (B) Impulse = $M \times u = M^1 L^1 T^{-1}$ ....(ii) (C) Power = $F \cdot V = M^1 L^2 T^{-3}$ ....(i) (D) Moment of inertia = $M r^2 = M^1 L^2$ ...(iii)

Question 38

Physics · Waves · Single correct

The equation of a wave travelling on a string is $y = \sin[20\pi x + 10\pi t]$, where $x$ and $t$ are distance and time in SI units. The minimum distance between two points having the same oscillating speed is:

  1. 5.0 cm
  2. 20 cm
  3. 10 cm
  4. 2.5 cm

Answer: (a)

Solution

Minimum distance between 2 points having same speed is $\frac{\lambda}{2}$. $\lambda = \frac{2\pi}{k} = \frac{1}{10} \, \mathrm{m} = 10 \, \mathrm{cm}$ Distance $= \frac{\lambda}{2} = 5 \, \mathrm{cm}$

Question 39

Physics · Ray Optics and Optical Instruments · Single correct

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R) Assertion (A) : Refractive index of glass is higher than that of air. Reason (R) : Optical density of a medium is directly proportionate to its mass density which results in a proportionate refractive index. In the light of the above statements, choose the most appropriate answer from the options given below :

  1. (A) is not correct but (R) is correct
  2. Both (A) and (R) are correct and (R) is the correct explanation of (A)
  3. (A) is correct but (R) is not correct
  4. Both (A) and (R) are correct but (R) is not the correct explanation of (A)

Answer: (c)

Solution

Refractive index has no relation with mass density because both have different meaning. Hence reason is incorrect. So (A) is correct but (R) is not correct.

Question 40

Physics · Magnetism and Matter · Single correct

Given below are two statements: one is labelled as Assertion $(A)$ and the other is labelled as Reason $(R)$. Assertion $(A)$: Magnetic monopoles do not exist. Reason $(R)$: Magnetic field lines are continuous and form closed loops. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both $(A)$ and $(R)$ are correct but $(R)$ is not the correct explanation of $(A)$
  2. $(A)$ is correct but $(R)$ is not correct
  3. Both $(A)$ and $(R)$ are correct and $(R)$ is the correct explanation of $(A)$
  4. $(A)$ is not correct but $(R)$ is correct

Answer: (c)

Solution

Both statements are correct and reason is also the correct explanation of assertion.

Question 41

Physics · Work, Energy and Power · Single correct

Which one of the following forces cannot be expressed in terms of potential energy?

  1. Coulomb's force
  2. Gravitational force
  3. Frictional force
  4. Restoring force

Answer: (c)

Solution

Potential energy is defined for conservative force only. It is not defined for non-conservative force i.e. frictional force.

Question 42

Physics · Kinetic Theory · Single correct

Match List-I with List-II. \begin{tabular}{|l|l|} \hline \textbf{LIST-I} & \textbf{LIST-II} \\ \hline A. Isothermal & I. $\Delta W$ (work done) $= 0$ \\ \hline B. Adiabatic & II. $\Delta Q$ (supplied heat) $= 0$ \\ \hline C. Isobaric & III. $\Delta U$ (change in internal energy) $\neq 0$ \\ \hline D. Isochoric & IV. $\Delta U = 0$ \\ \hline \end{tabular} Choose the correct answer from the options given below

  1. \text{(A)-(III), (B)-(II), (C)-(I), (D)-(IV)}
  2. \text{(A)-(IV), (B)-(I), (C)-(III), (D)-(II)}
  3. \text{(A)-(IV), (B)-(II), (C)-(III), (D)-(I)}
  4. \text{(A)-(II), (B)-(IV), (C)-(I), (D)-(III)}

Answer: (c)

Solution

Q10. (A) Isothermal $\rightarrow \Delta T = 0 \rightarrow \Delta U = 0$ (IV) (B) Adiabatic $\rightarrow \Delta Q = 0$ (II) (C) Isobaric $\rightarrow \Delta P = 0 \rightarrow \Delta U \neq 0$ (III) (D) Isochoric $\rightarrow \Delta V = 0 \rightarrow \Delta W = 0$ (I)

Question 43

Physics · Motion in a Plane · Single correct

A helicopter flying horizontally with a speed of $360 \, \mathrm{km/h}$ at an altitude of $2 \, \mathrm{km}$, drops an object at an instant. The object hits the ground at a point $O$, $20 \, \mathrm{s}$ after it is dropped. Displacement of 'O' from the position of helicopter where the object was released is: (use acceleration due to gravity $g = 10 \, \mathrm{m/s^2}$ and neglect air resistance)

  1. $2\sqrt{5} \, \mathrm{km}$
  2. $4 \, \mathrm{km}$
  3. $7.2 \, \mathrm{km}$
  4. $2\sqrt{2} \, \mathrm{km}$

Answer: (d)

Solution

Given $u = 360 \times \frac{5}{18} = 100 \, \mathrm{m/s}$. $x = u \times t = 2 \times 10^3 \, \mathrm{m}$. $t = \sqrt{\frac{2H}{g}} \implies H = \frac{t^2 g}{2}$. $H = \frac{400 \times 10}{2}$. $H = 2000 \, \mathrm{m}$. $D = \sqrt{x^2 + H^2}$. $D = 2\sqrt{2} \, \mathrm{km}$.

Question 44

Physics · Laws of Motion · Single correct

An object with mass $500 \, \mathrm{g}$ moves along x-axis with speed $v = 4\sqrt{x} \, \mathrm{m/s}$. The force acting on the object is:

  1. 8 N
  2. 5 N
  3. 6 N
  4. 4 N

Answer: (d)

Solution

Given $F = M \times a$. $v = \frac{4}{\sqrt{x}}$. $v^2 = 16x$. $2v \frac{dv}{dx} = 16$. $v dv = \frac{16}{2} = 8$. $F = 0.5 \times 8 = 4 \mathrm{N}$.

Question 45

Physics · Ray Optics and Optical Instruments · Single correct

A transparent block A having refractive index $\mu = 1.25$ is surrounded by another medium of refractive index $\mu = 1.0$ as shown in figure. A light ray is incident on the flat face of the block with incident angle $\theta$ as shown in figure. What is the maximum value of $\theta$ for which light suffers total internal reflection at the top surface of the block?

  1. $\tan^{-1}(4/3)$
  2. $\tan^{-1}(3/4)$
  3. $\sin^{-1}(3/4)$
  4. $\cos^{-1}(3/4)$

Answer: (c)

Solution

Given $r + \theta_C = 90^\circ$. $\mu_1 \sin \theta = \mu_2 \sin r$. Therefore, $$\sin \theta = \frac{\mu_2}{\mu_1} \sin(90^\circ - \theta_C)$$ $$\sin \theta = \frac{\mu_2}{\mu_1} \cos \theta_C$$ $$\sin \theta_C = \frac{\mu_1}{\mu_2}$$ Now, $$\sin \theta = \frac{\mu_2}{\mu_1} \sqrt{1 - \frac{\mu_1^2}{\mu_2^2}}$$ $$\sin \theta = \sqrt{\frac{\mu_2^2 - \mu_1^2}{\mu_1^2}} = \sqrt{\frac{25}{16} - 1}$$ $$\sin \theta = \frac{3}{4}$$ Therefore, $$\theta = \sin^{-1}\left(\frac{3}{4}\right)$$

Question 46

Physics · Electrostatic Potential and Capacitance · Fill in the blank

A parallel plate capacitor has charge $5 \times 10^{-6} \, \mathrm{C}$. A dielectric slab is inserted between the plates and almost fills the space between the plates. If the induced charge on one face of the slab is $4 \times 10^{-6} \, \mathrm{C}$ then the dielectric constant of the slab is _________.

Answer: 5

Solution

Given $Q_{in} = Q_0 \left(1 - \frac{1}{K}\right)$. $4 \times 10^{-6} = 5 \times 10^{-6} \left(1 - \frac{1}{K}\right)$ Solving for $K$: $$1 - \frac{1}{K} = \frac{4}{5}$$ $$K = 5$$

Question 47

Physics · Alternating Current · Numerical

An inductor of reactance 100$\Omega$, a capacitor of reactance 50$\Omega$, and a resistor of resistance 50$\Omega$ are connected in series with an AC source of 10 $\mathrm{V}$, 50 $\mathrm{Hz}$. Average power dissipated by the circuit is $\mathrm{W}$.

Answer: 1

Solution

Given $P = V_{rms} I_{rms} \cos \phi$. (1) $P = V_{rms} \times \frac{V_{rms}}{z} \times \frac{R}{z}$ $P = \frac{V_{rms}^2 \times R}{z^2}$ $z = \sqrt{R^2 + (x_L - x_C)^2}$ $Z = 50 \sqrt{2} \, \Omega$ $P = \frac{100 \times 50}{2500 \times 2} = 1 \, W$

Question 48

Physics · Thermal Properties of Matter · Fill in the blank

Two cylindrical rods A and B made of different materials, are joined in a straight line. The ratio of lengths, radii and thermal conductivities of these rods are: $\frac{L_A}{L_B} = \frac{1}{2}$, $\frac{r_A}{r_B} = 2$ and $\frac{K_A}{K_B} = \frac{1}{2}$. The free ends of rods A and B are maintained at 400 K, 200 K, respectively. The temperature of rods interface is _______ K, when equilibrium is established.

Answer: 360

Solution

Given $R_1 = \frac{\ell_1}{K_1 A_1}$, $R_2 = \frac{\ell_2}{K_2 A_2}$. The rate of heat transfer is given by $\frac{dQ}{dt} = \frac{\Delta T}{R}$. Therefore, $$\left( \frac{dQ}{dt} \right)_1 = \left( \frac{dQ}{dt} \right)_2$$ $$\frac{400 - T}{R_1} = \frac{T - 200}{R_2}$$ $$\frac{400 - T}{T - 200} = \frac{R_1}{R_2} = \left( \frac{\ell_1}{\ell_2} \right) \left( \frac{r_2}{r_1} \right)^2 \times \frac{K_2}{K_1}$$ $$= \frac{1}{2} \times \left( \frac{1}{2} \right)^2 \times 2$$ $$= \left( \frac{1}{4} \right)$$ Solving, $$\frac{400 - T}{T - 200} = \frac{1}{4}$$ $$1600 - 4T = T - 200$$ $$5T = 1800$$ $$T = 360 \, \mathrm{K}$$

Question 49

Physics · Electric Charges and Fields · Numerical

The electric field in a region is given by $\vec{E} = (2\hat{i} + 4\hat{j} + 6\hat{k}) \times 10^3 \, \mathrm{N/C}$. The flux of the field through a rectangular surface parallel to $x - z$ plane is $6.0 \, \mathrm{Nm^2C^{-1}}$. The area of the surface is $\mathrm{cm^2}$.

Answer: 15

Solution

Given $\phi = \vec{E} \cdot \vec{A} = (2\hat{i} + 4\hat{j} + 6\hat{k}) \times 10^3 \cdot A \hat{j}$. $6 = 4 \times 10^3 \, \mathrm{A}$ $A = 1.5 \times 10^{-3} \, \mathrm{m^2}$ $= 15 \, \mathrm{cm^2}$

Question 50

Physics · System of Particles and Rotational Motion · Subjective

$M$ and $R$ be the mass and radius of a disc. A small disc of radius $R/3$ is removed from the bigger disc as shown in the figure. The moment of inertia of the remaining part of bigger disc about an axis $AB$ passing through the centre $O$ and perpendicular to the plane of disc is $\frac{4}{x}MR^2$. The value of $x$ is _______.

Answer: 9

Solution

Without cavity $I_1 = \frac{MR^2}{2}$. Mass of removed disc $= \frac{M}{\pi R^2} \times \left(\frac{R}{3}\right)^2 \pi = \left(\frac{M}{9}\right)$. M.I. of removed disc $I_2 = \frac{M}{9} \left(\frac{R}{3}\right)^2 + \frac{M}{9} \times \left(\frac{2R}{3}\right)^2 = \frac{MR^2}{18}$. $I = I_1 - I_2 = \frac{MR^2}{2} - \frac{MR^2}{18} = \frac{4MR^2}{9}$. $(n = 9)$

Chemistry

Question 51

Chemistry · Biomolecules · Single correct

Given below are two statements: Statement (I): On hydrolysis, oligo peptides give rise to fewer number of $\alpha$-amino acids while proteins give rise to a large number of $\beta$-amino acids. Statement (II): Natural proteins are denatured by acids which convert the water soluble form of fibrous proteins to their water insoluble form. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both statement I and statement II are correct
  2. Statement I is incorrect but Statement II is correct
  3. Both statement I and statement II are incorrect
  4. Statement I is correct but Statement II is incorrect

Answer: (c)

Solution

(i) Protein does not give $\beta$-amino acid on hydrolysis. (ii) Fibrous proteins are not water soluble. So both statements are wrong.

Question 52

Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct

Mixture of 1 g each of chlorobenzene, aniline and benzoic acid is dissolved in 50 mL ethyl acetate and placed in a separating funnel, 5 M NaOH (30 mL) was added in the same funnel. The funnel was shaken vigorously and then kept aside. The ethyl acetate layer in the funnel contains:

  1. benzoic acid
  2. benzoic acid and aniline
  3. chlorobenzene and aniline
  4. benzoic acid and chlorobenzene

Answer: (d)

Solution

Chlorobenzene reacts with $\mathrm{NaOH}$ and shows no reaction. Aniline reacts with $\mathrm{NaOH}$ and shows no reaction. Benzoic acid reacts with $\mathrm{NaOH}$ to form sodium benzoate and water. Organic layer in funnel are mixture of chlorobenzene and aniline.

Question 53

Chemistry · Thermodynamics · Single correct

The hydration energies of $\mathrm{K^+}$ and $\mathrm{Cl^-}$ are $-x$ and $-y\,\mathrm{kJ/mol}$ respectively. If lattice energy of $\mathrm{KCl}$ is $-z\,\mathrm{kJ/mol}$, then the heat of solution of $\mathrm{KCl}$ is:

  1. $+x - y - z$
  2. $x + y + z$
  3. $z - (x + y)$
  4. $-z - (x + y)$

Answer: (c)

Solution

The dissolution of $\mathrm{KCl_{(s)}}$ in water can be represented as: $$\mathrm{KCl_{(s)} + H_2O \xrightarrow{\Delta H \ sol.} K^+_{(aq)} + Cl^-_{(aq)}}$$ The lattice energy (L.E.) and hydration energy (H.E.) are involved in the process. The lattice energy is the energy required to separate $\mathrm{KCl_{(s)}}$ into $\mathrm{K^+_{(g)}}$ and $\mathrm{Cl^-_{(g)}}$. The hydration energy is the energy released when $\mathrm{K^+_{(g)}}$ and $\mathrm{Cl^-_{(g)}}$ are solvated to form $\mathrm{K^+_{(aq)}}$ and $\mathrm{Cl^-_{(aq)}}$. The enthalpy change of solution $\Delta H_{Sol.}$ is given by: $$\Delta H_{Sol.} = L.E. + (H.E.)_{K^+_{(g)}} + (H.E.)_{Cl^-_{(g)}}$$ $$= Z - x - y$$ $$= z - (x + y)$$

Question 54

Chemistry · Chemical Kinetics and Nuclear Chemistry · Single correct

A(g) → B(g) + C(g) is a first order reaction. \begin{tabular}{|c|c|c|} \hline \textbf{Time} & $T$ & $\infty$ \\ \hline $P_{\text{system}}$ & $P_t$ & $P_{\infty}$ \\ \hline \end{tabular} The reaction was started with reactant A only. Which of the following expression is correct for rate constant k?

  1. k = $\frac{1}{t}$ $\ln$ $\frac{2(P_\infty - P_t)}{P_t}$
  2. k = $\frac{1}{t}$ $\ln$ $\frac{P_\infty}{P_t}$
  3. k = $\frac{1}{t}$ $\ln$ $\frac{P_\infty}{2(P_\infty - P_t)}$
  4. k = $\frac{1}{t}$ $\ln$ $\frac{P_\infty}{(P_\infty - P_t)}$

Answer: (c)

Solution

For the reaction $A_{(g)} \rightarrow B_{(g)} + C_{(g)}$, the initial conditions and changes in pressure are given as follows: At $t = 0$, the pressure is $P^o$ for $A_{(g)}$, and $0$ for $B_{(g)}$ and $C_{(g)}$. At $t = t$, the pressure is $P^o - x$ for $A_{(g)}$, and $x$ for $B_{(g)}$ and $C_{(g)}$. At $t = \infty$, the pressure is $0$ for $A_{(g)}$, and $P^o$ for $B_{(g)}$ and $C_{(g)}$. The total pressure at time $t$ is given by: $$P_t = P^o + x \Rightarrow x = P_t - P^o = \frac{P_\infty}{2}$$ At equilibrium, $P_\infty = 2P^o \Rightarrow P^o = \frac{P_\infty}{2}$. The rate constant $k$ is given by: $$k = \frac{1}{t} \ln \frac{P^o}{P^o - x}$$ Substituting the expression for $x$: $$k = \frac{1}{t} \ln \frac{P_\infty}{2(P_\infty - P_t)}$$

Question 55

Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct

"P" is an optically active compound with molecular formula $C_6H_{12}O$. When "P" is treated with 2,4-dinitrophenylhydrazine, it gives a positive test. However, in presence of Tollens reagent, "P" gives a negative test. Predict the structure of "P".

Answer: (b)

Solution

The compound $P$ is given as $\mathrm{CH_3-C-CH(CH_3)(CH_2CH_3)}$ with a chiral center. It does not give Tollen's test, indicating it is not an aldehyde. The compound reacts with $2,4$-DNP ($\mathrm{NH_2-NH}$) to form a hydrazone derivative, indicating the presence of a carbonyl group. The reaction with $2,4$-DNP confirms the presence of a ketone group.

Question 56

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

Choose the incorrect trend in the atomic radii $(r)$ of the elements:

  1. $r_{\mathrm{Br}} < r_{\mathrm{K}}$
  2. $r_{\mathrm{Mg}} < r_{\mathrm{Al}}$
  3. $r_{\mathrm{Rb}} < r_{\mathrm{Cs}}$
  4. $r_{\mathrm{Rb}} < r_{\mathrm{Cs}}$

Answer: (b)

Solution

In a period from left to right atomic size decreases.

Question 57

Chemistry · Co-ordination Compounds · Single correct

Match List-I with List-II Choose the correct answer from the options given below :

  1. (A)-(II), (B)-(III), (C)-(I), (D)-(IV)
  2. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
  3. (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
  4. (A)-(IV), (B)-(III), (C)-(I), (D)-(II)

Answer: (c)

Solution

Aromatic halide give nucleophilic substitution reaction at high temperature or in presence of $-I/-M$ group rate of reaction high even at low temperature.

Question 58

Chemistry · Thermodynamics · Single correct

The correct statement amongst the following is:

  1. The term 'standard state' implies that the temperature is $0^\circ \mathrm{C}$
  2. The standard state of pure gas is the pure gas at a pressure of 1 bar and temperature $273 \, \mathrm{K}$
  3. $\Delta_f H^{\theta}_{298}$ is zero for $\mathrm{O}(g)$
  4. $\Delta_f H^{\theta}_{500}$ is zero for $\mathrm{O}_2(g)$

Answer: (d)

Solution

For standard state, pressure is 1 bar and temperature is specified only. Therefore, $$ (\Delta H_f^\circ)_{\mathrm{O_2,(g)}} = 0 $$

Question 59

Chemistry · Solutions · Single correct

Liquid A and B form an ideal solution. The vapour pressure of pure liquids A and B are 350 and 750 mm Hg respectively at the same temperature. If $x_A$ and $x_B$ are the mole fraction of A and B in solution while $y_A$ and $y_B$ are the mole fraction of A and B in vapour phase then:

  1. $\frac{x_A}{x_B} < \frac{y_A}{y_B}$
  2. $\frac{x_A}{x_B} = \frac{y_A}{y_B}$
  3. $\frac{x_A}{x_B} > \frac{y_A}{y_B}$
  4. $(x_A - y_A) < (x_B - y_B)$

Answer: (c)

Solution

Given $P_A^o < P_B^o$. Therefore, $\($ $\frac{P_A^o}{P_B^o}$ < 1 $\)$. The equation for $y_A$ is given by: $$ y_A = \frac{P_A^o}{P_B^o} x_A $$ The other variables are $y_B$, $x_A$, and $x_B$.

Question 60

Chemistry · The d-and f-Block Elements · Single correct

'X' is the number of acidic oxides among $VO_2, V_2O_3, CrO_3, V_2O_5$ and $Mn_2O_7$. The primary valency of cobalt in $[Co(H_2NCH_2CH_2NH_2)_3]_2(SO_4)_3$ is Y. The value of X + Y is:

  1. 5
  2. 4
  3. 2
  4. 3

Answer: (a)

Solution

$CrO_3$ = Acidic $Mn_2O_7$ = Acidic $\therefore\ x=2$ \[ \overset{\mathrm{III}}{[Co(H_2NCH_2CH_2NH_2)_3]_2(SO_4)_3} \;\rightleftharpoons\; 2\overset{\mathrm{III}}{[Co(H_2NCH_2CH_2NH_2)_3]^{3+}} +3SO_4^{2-} \] $\therefore$ Primary valency $=3$ $\therefore\ x+y=5$

Question 61

Chemistry · Amines · Single correct

The descending order of basicity of following amines is:

  1. B > E > D > A > C
  2. E > D > B > A > C
  3. E > D > A > B > C
  4. E > A > D > C > B

Answer: (b)

Solution

The order of basicity is given as $E > D > B > A > C$. The localized electron pair in $[\mathrm{CH_3}]_2\mathrm{NH}$ is more than in $\mathrm{CH_3}-\mathrm{NH}_2$, which makes it more basic. The presence of $+M$ effect in $\mathrm{OMe}$ increases basicity, while $-I$ and $-M$ effects in $\mathrm{NO_2}$ decrease basicity.

Question 62

Chemistry · Co-ordination Compounds · Single correct

Match List-I with List-II \begin{tabular}{|c|l|c|c|c|} \hline & List-I & & \multicolumn{2}{c|}{List-II} \\ \hline & Complex & & Primary valency & Secondary valency \\ \hline (A) & [Co(en)$_2$Cl$_2$]Cl & (I) & 3 & 6 \\ \hline (B) & [Pt(NH$_3$)$_2$Cl(NO$_2$)] & (II) & 3 & 4 \\ \hline (C) & Hg[Co(SCN)$_4$] & (III) & 2 & 6 \\ \hline (D) & [Mg(EDTA)]$^{2-}$ & (IV) & 2 & 4 \\ \hline \end{tabular} Choose the correct answer from the options given below :

  1. (A)-(III), (B)-(I), $(C)$-(II), (D)-(IV)
  2. (A)-(I), (B)-(IV), $(C)$-(II), (D)-(III)
  3. (A)-(I), (B)-(III), $(C)$-(II), (D)-(IV)
  4. (A)-(II), (B)-(III), $(C)$-(IV), (D)-(I)

Answer: (b)

Solution

Primary valency = Oxidation state. Secondary valency = Co-ordination number. $$ \begin{array}{|c|l|c|c|c|} \hline & \mathrm{Complex} & & \mathrm{Primary} & \mathrm{Secondary} \\ & & & \mathrm{valency} & \mathrm{valency} \\ \hline (A) & [Co(en)_2Cl_2]Cl & (I) & 3 & 6 \\ \hline (B) & [Pt(NH_3)_2Cl(NO_2)] & (II) & 3 & 4 \\ \hline (C) & Hg[Co(SCN)_4] & (III) & 2 & 6 \\ \hline (D) & [Mg(EDTA)]^{2-} & (IV) & 2 & 4 \\ \hline \end{array} $$

Question 63

Chemistry · Co-ordination Compounds · Single correct

Match List-I with List-II Choose the correct answer from the options given below:

  1. $(A)-(III), (B)-(I), (C)-(IV), (D)-(II)$
  2. $(A)-(II), (B)-(IV), (C)-(I), (D)-(III)$
  3. $(A)-(III), (B)-(IV), (C)-(I), (D)-(II)$
  4. $(A)-(II), (B)-(I), (C)-(IV), (D)-(III)$

Answer: (a)

Solution

$(A)$ Solution of chloroform and acetone shows -ve deviation, so maximum boiling azeotrope. $(B)$ Solution of ethanol & water shows +ve deviation. So minimum boiling azeotrope. $(C)$ Solution of benzene and toluene form ideal solution. $\Delta V_{mix} = 0$. $(D)$ Acetic acid in benzene form dimer.

Question 64

Chemistry · Chemical Bonding and Molecular Structure · Single correct

In $\mathrm{SO}_2$, $\mathrm{NO}_2^-$ and $\mathrm{N}_3^-$ the hybridizations at the central atom are respectively:

  1. $\mathrm{sp}^2, \mathrm{sp}^2$ and $\mathrm{sp}$
  2. $\mathrm{sp}^2, \mathrm{sp}$ and $\mathrm{sp}$
  3. $\mathrm{sp}^2, \mathrm{sp}^2$ and $\mathrm{sp}^2$
  4. $\mathrm{sp}, \mathrm{sp}^2$ and $\mathrm{sp}$

Answer: (a)

Solution

Question 65

Chemistry · Co-ordination Compounds · Single correct

The number of unpaired electrons responsible for the paramagnetic nature of the following complex species are

  1. 1, 5, 4, 2
  2. 1, 5, 5, 2
  3. 1, 1, 4, 2
  4. 1, 4, 4, 2

Answer: (a)

Solution

For $[\mathrm{Fe(CN)}_6]^{3-}$, $\mathrm{Fe}^{3+}$ has $3d^5$ configuration with $t_{2g}^{2,2,1} e_g^{0,0}$ resulting in unpaired $e^- = 1$. For $[\mathrm{FeF}_6]^{3-}$, $\mathrm{Fe}^{3+}$ has $3d^5$ configuration with $t_{2g}^{1,1,1} e_g^{1,1}$ resulting in unpaired $e^- = 5$. For $[\mathrm{CoF}_6]^{3-}$, $\mathrm{Co}^{3+}$ has $3d^6$ configuration with $t_{2g}^{2,1,1} e_g^{1}$ resulting in unpaired $e^- = 4$. For $[\mathrm{Mn(CN)}_6]^{3-}$, $\mathrm{Mn}^{3+}$ has $3d^4$ configuration with $t_{2g}^{2,1,1} e_g^{0,0}$ resulting in unpaired $e^- = 2$.

Question 66

Chemistry · Hydrocarbons · Single correct

The number of optically active products obtained from the complete ozonolysis of the given compound is :

  1. 2
  2. 0
  3. 1
  4. 4

Answer: (b)

Solution

The given compound undergoes ozonolysis with $\mathrm{O_3}$, $\mathrm{Zn}$, and $\mathrm{H_2O}$. The reaction results in the formation of $2 \ \mathrm{CH_3CHO} + 2 \ \mathrm{HCHO}$. Both products are optically inactive.

Question 67

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

Given below are two statements: In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Statement I is correct but statement II is incorrect
  2. Statement I is incorrect but statement II is correct
  3. Both statement I and statement II are incorrect
  4. Both statement I and statement II are correct

Answer: (a)

Solution

Question 68

Chemistry · Classification of Elements and Periodicity in Properties · Multiple correct

The extra stability of half-filled subshell is due to

  1. Symmetrical distribution of electrons
  2. Smaller coulombic repulsion energy
  3. The presence of electrons with the same spin in non-degenerate orbitals
  4. Larger exchange energy
  5. Relatively smaller shielding of electrons by one another

Answer: (b)

Solution

Extra stability of half filled is due to: (i) Symmetrical distribution of electrons (ii) Large exchange energy (iii) Smaller coulombic repulsion (iv) Smaller shielding of electrons by one another

Question 69

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

The correct statements from the following are : (A) $Tl^{3+}$ is a powerful oxidising agent (B) $Al^{3+}$ does not get reduced easily $(C)$ Both $Al^{3+}$ and $Tl^{3+}$ are very stable in solution (D) $Tl^{+}$ is more stable than $Tl^{3+}$ (E) $Al^{3+}$ and $Tl^{+}$ are highly stable Choose the correct answer from the options given below :

  1. (A), (B), $(C)$, (D) and (E)
  2. (A), (B), (D) and (E) only
  3. (B), (D) and (E) only
  4. (A), $(C)$ and (D) only

Answer: (b)

Solution

(i) True, $\mathrm{Tl}^+$ is more stable than $\mathrm{Tl}^{3+}$, due to inert pair effect. So $\mathrm{Tl}^{3+}$ is a powerful oxidising agent. (ii) True, $E^0_{\mathrm{Al}^{3+}/\mathrm{Al}} = -1.66 \, \mathrm{V}$. So it is difficult to reduce $\mathrm{Al}^{3+}$. So $\mathrm{Al}^{3+}$ is highly stable. (iii) False, as $\mathrm{Tl}^{3+}$ is unstable. (iv) True, $\mathrm{Tl}^+$ is more stable than $\mathrm{Tl}^{3+}$. (v) True, $\mathrm{Al}^{3+}$ and $\mathrm{Tl}^+$ are highly stable.

Question 70

Chemistry · Electrochemistry · Single correct

Given below are two statements : 1 M aqueous solution of each of Cu($\mathrm{NO}$_3)_2, $\mathrm{AgNO}$_3, $\mathrm{Hg}$_2($\mathrm{NO}$_3)_2; $\mathrm{Mg}$($\mathrm{NO}$_3)_2 are electrolysed using inert electrodes, Given : $E^\theta_{\mathrm{Ag}^+/\mathrm{Ag}} = 0.80 \, \mathrm{V}$, $E^\theta_{\mathrm{Hg}_2^{2+}/\mathrm{Hg}} = 0.79 \, \mathrm{V}$, $E^\theta_{\mathrm{Cu}^{2+}/\mathrm{Cu}} = 0.24 \, \mathrm{V}$ and $E^\theta_{\mathrm{Mg}^{2+}/\mathrm{Mg}} = -2.37 \, \mathrm{V}$ Statement (I) : With increasing voltage, the sequence of deposition of metals on the cathode will be Ag, Hg and Cu Statement (II) : Magnesium will not be deposited at cathode instead oxygen gas will be evolved at the cathode. In the light of the above statement, choose the most appropriate answer from the options given below

  1. Both statement I and statement II are incorrect
  2. Statement I is correct but statement II is incorrect
  3. Both statement I and statement II are correct
  4. Statement I is incorrect but statement II is correct

Answer: (b)

Solution

Statement-II: At cathode, instead of $\mathrm{Mg}$, $\mathrm{H_2O_{(\ell)}}$ will reduce and evolve $\mathrm{H_2}$ gas.

Question 71

Chemistry · Equilibrium · Numerical

Only litre buffer solution was prepared by adding 0.10 mol each of NH$_3$ and NH$_4$Cl in deionised water. The change in pH on addition of 0.05 mol of HCl to the above solution is ________ $\times 10^{-2}$, (Nearest integer) (Given : pK$_b$ of NH$_3$ = 4.745 and $\log_{10} 3 = 0.477$)

Answer: 48

Solution

Given $\($ pOH = pK_b + $\log$ $\left$[ $\frac{\mathrm{NH_4^+}}{\mathrm{NH_3}}$ $\right$] $\)$. $\($ pOH = 4.745 $\)$. On adding 0.05 mole HCl: $\($ $\mathrm{NH_3}$ + $\mathrm{H^+}$ $\rightarrow$ $\mathrm{NH_4^+}$ $\)$. $\($ 0.1 0.05 0.1 $\)$. $\($ 0.05 0 0.15 $\)$. $\($ pOH' = 4.745 + $\log$ 3 $\)$. $\($ pOH' - pOH = 0.477 $\)$. $\($ 14 - pH' - 14 + pH = 0.477 $\)$. $\($ $\Delta$ pH = 0.477 $\)$. $\($ = 4.7 $\times$ 10^{-2} $\approx$ 48 $\times$ 10^{-2} $\)$.

Question 72

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Numerical

In Dumas' method 292 mg of an organic compound released 50 mL of nitrogen gas ($N_2$) at 300 K temperature and 715 mm Hg pressure. The percentage composition of ' N ' in the organic compound is ________ % (Nearest integer) (Aqueous tension at 300 K = 15 mmHg)

Answer: 18

Solution

$$n_{\mathrm{N_2}} = \frac{P_{\mathrm{N_2}} \cdot V}{RT}$$ Substituting the values: $$n_{\mathrm{N_2}} = \frac{700}{760} \times \frac{50}{1000} \times \frac{1}{0.0821 \times 300}$$ The number of moles of $\mathrm{N}$ is: $$n_{\mathrm{N}} = 2 \times n_{\mathrm{N_2}}$$ The mass of $\mathrm{N}$ is: $$Mass of \mathrm{N} = 2 \times n_{\mathrm{N}} \times 14$$ The percentage of $\mathrm{N}$ is: $$\% \mathrm{N} = \frac{mass of \mathrm{N}}{mass of organic compound} \times 100$$ Substituting the values: $$\% \mathrm{N} = \frac{700}{760} \times \frac{50}{1000} \times \frac{2 \times 14}{0.0821 \times 300} \times \frac{1000}{292} \times 100$$ The percentage of $\mathrm{N}$ is $18\%$.

Question 73

Chemistry · Some Basic Concepts of Chemistry · Numerical

Butane reacts with oxygen to produce carbon dioxide and water following the equation given below $$\mathrm{C_4H_{10}(g) + \frac{13}{2}O_2(g) \rightarrow 4CO_2(g) + 5H_2O(l)}$$ If 174.0 $\mathrm{\, kg}$ of butane is mixed with 320.0 $\mathrm{\, kg}$ of O_2, the volume of water formed in litres is . (Nearest integer)

Answer: 138

Solution

Given the reaction: $$\mathrm{C_4H_{10} + \frac{13}{2} O_2 \rightarrow 4CO_2 + 5H_2O}$$ Initial amounts: $$3 \times 10^3 10 \times 10^3$$ Moles of $\mathrm{H_2O}$ formed $= n_{H_2O} = 5 \times \frac{2}{13} \times 10 \times 10^3$ Then $w_{H_2O} = \frac{10^5}{13} \times 18$ $$= 1.3846 \times 10^5 \ \mathrm{g}$$ Volume of $\mathrm{H_2O}$ will be $= 138.46$ litre. Ans. 138

Question 74

Chemistry · Co-ordination Compounds · Numerical

The number of paramagnetic metal complex species among $[Co(NH_3)_6]^{3+}$, $[Co(C_2O_4)_3]^{3-}$, $[MnCl_6]^{3-}$, $[Mn(CN)_6]^{3-}$, $[CoF_6]^{3-}$, $[Fe(CN)_6]^{3-}$ and $[FeF_6]^{3-}$ with same number of unpaired electrons is ________.

Answer: 2

Solution

Question 75

Chemistry · Hydrocarbons · Numerical

Identify the structure of the final product (D) in the following sequence of the reactions: Total number of $sp^2$ hybridised carbon atoms in product D is.

Answer: 7

Solution

The reaction sequence is as follows: Ph-$\mathrm{C}$-$\mathrm{CH_3}$ $\xrightarrow{\mathrm{PCl_5}, \Delta}$ $\mathrm{Ph}$-$\mathrm{C}$-$\mathrm{CH_3}$ + $\mathrm{POCl_3}$ This forms compound [A]. [A] $\xrightarrow{3 eq. \mathrm{NaNH_2} | \mathrm{NH_3}}$ $\mathrm{Ph}$-$\mathrm{C}$ $\equiv$ $\mathrm{CNa}$ This forms compound [B]. [B] $\xrightarrow{Acidify}$ $\mathrm{Ph}$-$\mathrm{C}$ $\equiv$ $\mathrm{CH}$ This forms compound [C]. [C] $\xrightarrow{1. \mathrm{B_2H_6} 2. \mathrm{H_2O_2} | \mathrm{OH^-}}$ $\mathrm{Ph}$-$\mathrm{CH}$ = $\mathrm{CH}$ Tautomerisation leads to: $\mathrm{Ph}$-$\mathrm{CH_2}$-$\mathrm{C}$-$\mathrm{H}$ This forms compound [D]. The number of sp^2 C-atoms in product D = 7 NTA Ans. = 7 ALLEN Ans. = 7