JEE Main 29 January 2024 Shift 1 question paper with solutions
JEE Main 29 January 2024 Shift 1: all 90 questions in paper order (Maths, Physics, Chemistry) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.
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Maths
Question 1
Maths · Sequences and Series · Single correct
If in a G.P. of 64 terms, the sum of all the terms is 7 times the sum of the odd terms of the G.P, then the common ratio of the G.P. is equal to
7
4
5
6
Answer: (d)
Solution
Given the series $a + ar + ar^2 + ar^3 + \ldots + ar^{63}$. This can be expressed as $7 \left( a + ar^2 + ar^4 + \ldots + ar^{62} \right)$. Therefore, we have: $$\frac{a \left( 1 - r^{64} \right)}{1 - r} = \frac{7a \left( 1 - r^{64} \right)}{1 - r^2}$$ Solving for $r$, we find $r = 6$.
Question 2
Maths · Sequences and Series · Single correct
In an A.P., the sixth terms $a_6 = 2$. If the $a_1 a_4 a_5$ is the greatest, then the common difference of the A.P., is equal to
Maths · Complex Numbers and Quadratic Equations · Single correct
If $z = \frac{1}{2} - 2i$, is such that $|z + 1| = \alpha z + \beta (1 + i)$, $i = \sqrt{-1}$ and $\alpha, \beta \in \mathbb{R}$, then $\alpha + \beta$ is equal to
-4
3
2
-1
Answer: (b)
Solution
Given $z = \frac{1}{2} - 2i$. The equation $|z + 1| = \alpha z + \beta (1 + i)$ is given. Substituting $z = \frac{1}{2} - 2i$, we have: $$\left| \frac{3}{2} - 2i \right| = \frac{\alpha}{2} - 2\alpha i + \beta + \beta i$$ This can be rewritten as: $$\left| \frac{3}{2} - 2i \right| = \left( \frac{\alpha}{2} + \beta \right) + (\beta - 2\alpha)i$$ We have $\beta = 2\alpha$ and $\frac{\alpha}{2} + \beta = \sqrt{\frac{9}{4} + 4}$. Solving these, we find $\alpha + \beta = 3$.
Question 6
Maths · Limits and Derivatives · Single correct
$\lim\limits_{x\to\frac{\pi}{2}} \left( \dfrac{1}{\left(x-\frac{\pi}{2}\right)^2} \int_{x^3}^{\left(\frac{\pi}{2}\right)^3} \cos\!\left(\dfrac{1}{t^3}\right)\,dt \right)$ is equal to
$\frac{3\pi}{8}$
$\frac{3\pi^2}{4}$
$\frac{3\pi^2}{8}$
$\frac{3\pi}{4}$
Answer: (c)
Solution
Using L'hopital rule $$= \lim_{x \to \frac{\pi}{2}} \frac{0 - \cos x \times 3x^2}{2 \left( x - \frac{\pi}{2} \right)}$$ $$= \lim_{x \to \frac{\pi}{2}} \frac{\sin \left( x - \frac{\pi}{2} \right)}{2 \left( x - \frac{\pi}{2} \right)} \times \frac{3\pi^2}{4}$$ $$= \frac{3\pi^2}{8}$$
Question 7
Maths · Properties of Triangles · Single correct
In a $\triangle ABC$, suppose $y = x$ is the equation of the bisector of the angle $B$ and the equation of the side $AC$ is $2x - y = 2$. If $2AB = BC$ and the point $A$ and $B$ are respectively $(4, 6)$ and $(\alpha, \beta)$, then $\alpha + 2\beta$ is equal to
42
39
48
45
Answer: (a)
Solution
Given the ratio $AD : DC = 1 : 2$. We have the equation $$\frac{4 - \alpha}{6 - \alpha} = \frac{10}{8}.$$ Solving for $\alpha$, we find $\alpha = \beta$. Therefore, $\alpha = 14$ and $\beta = 14$.
Question 8
Maths · Vector Algebra · Single correct
Let $\vec{a}$, $\vec{b}$ and $\vec{c}$ be three non-zero vectors such that $\vec{b}$ and $\vec{c}$ are non-collinear if $\vec{a} + 5\vec{b}$ is collinear with $\vec{c}$, $\vec{b} + 6\vec{c}$ is collinear with $\vec{a}$ and $\vec{a} + \alpha \vec{b} + \beta \vec{c} = \vec{0}$, then $\alpha + \beta$ is equal to
35
30
-30
-25
Answer: (a)
Solution
Given $\vec{a} + 5 \vec{b} = \lambda \vec{c}$ and $\vec{b} + 6 \vec{c} = \mu \vec{a}$. Eliminating $\vec{a}$, we have $$\lambda \vec{c} - 5 \vec{b} = \frac{6}{\mu} \vec{c} + \frac{1}{\mu} \vec{b}.$$ Therefore, $\mu = -\frac{1}{5}$ and $\lambda = -30$. Thus, $\alpha = 5$ and $\beta = 30$.
Question 9
Maths · Properties of Triangles · Single correct
Let $( 5, \frac{a}{4})$, be the circumcenter of a triangle with vertices A(a, -2), B(a, 6) and C $(\frac{a}{4}, -2)$. Let $\alpha$ denote the circumradius, $\beta$ denote the area and $\gamma$ denote the perimeter of the triangle. Then $\alpha$ + $\beta$ + $\gamma$ is
For $x \in \left( -\frac{\pi}{2}, \frac{\pi}{2} \right)$, if $y(x) = \int \frac{\csc x + \sin x}{x \sec x + \tan x \sin^2 x} \, dx$ and $\lim_{x \to \left( \frac{\pi}{2} \right)^-} y(x) = 0$ then $y\left( \frac{\pi}{4} \right)$ is equal to
If $\alpha$, $-\frac{\pi}{2} < \alpha < \frac{\pi}{2}$ is the solution of $4 \cos \theta + 5 \sin \theta = 1$, then the value of $\tan \alpha$ is
$\frac{10 - \sqrt{10}}{6}$
$\frac{10 - \sqrt{10}}{12}$
$\frac{\sqrt{10} - 10}{12}$
$\frac{\sqrt{10} - 10}{6}$
Answer: (c)
Solution
Given $4 + 5 \tan \theta = \sec \theta$. Squaring: $$24 \tan^2 \theta + 40 \tan \theta + 15 = 0$$ $$\tan \theta = \frac{-10 \pm \sqrt{10}}{12}$$ and $\tan \theta = -\left(\frac{10 + \sqrt{10}}{12}\right)$ is Rejected. (3) is correct.
Question 12
Maths · Differential Equations · Single correct
A function $y = f(x)$ satisfies $$f(x) \sin 2x + \sin x - (1 + \cos^2 x) f'(x) = 0$$ with condition $f(0) = 0$. Then $f\left(\frac{\pi}{2}\right)$ is equal to
Maths · Three Dimensional Geometry · Single correct
Let O be the origin and the position vector of A and B be $2\hat{i} + 2\hat{j} + \hat{k}$ and $2\hat{i} + 4\hat{j} + 4\hat{k}$ respectively. If the internal bisector of $\angle AOB$ meets the line $AB$ at $C$, then the length of $OC$ is
$\frac{2}{3}\sqrt{31}$
$\frac{2}{3}\sqrt{34}$
$\frac{3}{4}\sqrt{34}$
$\frac{3}{2}\sqrt{31}$
Answer: (b)
Solution
The length of $OC$ is calculated as follows: $$\frac{\sqrt{136}}{3} = \frac{2\sqrt{34}}{3}.$$
Question 14
Maths · Relations and Functions · Single correct
Consider the function $f : \left[ \frac{1}{2}, 1 \right] \to \mathbb{R}$ defined by $f(x) = 4\sqrt{2}x^3 - 3\sqrt{2}x - 1$. Consider the statements (I) The curve $y = f(x)$ intersects the $x$-axis exactly at one point (II) The curve $y = f(x)$ intersects the $x$-axis at $x = \cos \frac{\pi}{12}$ Then
Let $A = \begin{bmatrix} 1 & 0 & 0 \\ 0 & \alpha & \beta \\ 0 & \beta & \alpha \end{bmatrix}$ and $|2A|^3 = 2^{21}$ where $\alpha, \beta \in \mathbb{Z}$, Then a value of $\alpha$ is
Maths · Three Dimensional Geometry · Single correct
Let $PQR$ be a triangle with $R(-1, 4, 2)$. Suppose $M(2, 1, 2)$ is the mid point of $PQ$. The distance of the centroid of $\triangle PQR$ from the point of intersection of the line $\frac{x-2}{0} = \frac{y}{2} = \frac{z+3}{-1}$ and $\frac{x-1}{1} = \frac{y+3}{-3} = \frac{z+1}{1}$ is
69
9
$\sqrt{69}$
$\sqrt{99}$
Answer: (c)
Solution
Centroid G divides MR in 1 : 2. G(1, 2, 2). Point of intersection A of given lines is (2, -6, 0). AG = $\sqrt{69}$.
Question 17
Maths · Relations and Functions · Single correct
Let R be a relation on $\mathbb{Z} \times \mathbb{Z}$ defined by $(a, b)R(c, d)$ if and only if $ad - bc$ is divisible by 5. Then R is
Reflexive and symmetric but not transitive
Reflexive but neither symmetric not transitive
Reflexive, symmetric and transitive
Reflexive and transitive but not symmetric
Answer: (a)
Solution
Question 18
Maths · Integrals · Single correct
If the value of the integral $$\int_{\frac{\pi}{2}}^{-\frac{\pi}{2}} \left( \frac{x^2 \cos x}{1+\pi^x} + \frac{1+\sin^2 x}{1+e^{\sin x^{2033}}} \right) dx = \frac{\pi}{4} (\pi + a) - 2,$$ then the value of $a$ is
3
$-\frac{3}{2}$
2
$\frac{3}{2}$
Answer: (a)
Solution
Given $$I = \int_{-\pi/2}^{\pi/2} \left( \frac{x^2 \cos x}{1 + \pi^x} + \frac{1 + \sin^2 x}{1 + e^{\sin x^{2023}}} \right) \, dx$$ $$I = \int_{-\pi/2}^{\pi/2} \left( \frac{x^2 \cos x}{1 + \pi^{-x}} + \frac{1 + \sin^2 x}{1 + e^{\sin(-x)^{2023}}} \right) \, dx$$ On adding, we get $$2I = \int_{-\pi/2}^{\pi/2} \left( x^2 \cos x + 1 + \sin^2 x \right) \, dx$$ On solving $$I = \frac{\pi^2}{4} + \frac{3\pi}{4} - 2$$ a = 3
Question 19
Maths · Continuity and Differentiability · Single correct
Suppose $$f(x) = \frac{(2^x + 2^{-x}) \tan x \sqrt{\tan^{-1}(x^2 - x + 1)}}{(7x^2 + 3x + 1)^3}$$ Then the value of $f'(0)$ is equal to
Let A be a square matrix such that $AA^T = I$. Then $\frac{1}{2} A \left[ \left( A + A^T \right)^2 + \left( A - A^T \right)^2 \right]$ is equal to
$A^2 + I$
$A^3 + I$
$A^2 + A^T$
$A^3 + A^T$
Answer: (d)
Solution
Given $AA^\top = I = A^\top A$. On solving the given expression, we get $$\frac{1}{2} A \left[ A^2 + \left(A^\top\right)^2 + 2 \, A \, A^\top + A^2 + \left(A^\top\right)^2 - 2 \, A \, A \, A^\top \right]$$ $$= A \left[ A^2 + \left(A^\top\right)^2 \right] = A^3 + A^\top$$
Question 21
Maths · Conic Sections · Numerical
Equation of two diameters of a circle are $2x - 3y = 5$ and $3x - 4y = 7$. The line joining the points $\left(-\frac{22}{7}, -4\right)$ and $\left(-\frac{1}{7}, 3\right)$ intersects the circle at only one point $P(\alpha, \beta)$. Then $17\beta - \alpha$ is equal to
Answer: 2
Solution
Centre of circle is (1, -1). Equation of AB is $7x - 3y + 10 = 0$ (i). Equation of CP is $3x + 7y + 4 = 0$ (ii). Solving (i) and (ii): $$\alpha = \frac{-41}{29}, \beta = \frac{1}{29} \therefore 17\beta - \alpha = 2$$
Question 22
Maths · Permutations and Combinations · Numerical
All the letters of the word "GTWENTY" are written in all possible ways with or without meaning and these words are written as in a dictionary. The serial number of the word "GTWENTY" IS
Answer: 553
Solution
Words starting with E = 360 Words starting with GE = 60 Words starting with GN = 60 Words starting with GTE = 24 Words starting with GTN = 24 Words starting with GTT = 24 GTWENTY = 1 Total = 553
Question 23
Maths · Complex Numbers and Quadratic Equations · Numerical
Let $\alpha, \beta$ be the roots of the equation $x^2 - x + 2 = 0$ with $\mathrm{Im}(\alpha) > \mathrm{Im}(\beta)$. Then $\alpha^6 + \alpha^4 + \beta^4 - 5\alpha^2$ is equal to
Let $f(x) = 2^x - x^2$, $x \in \mathbb{R}$. If $m$ and $n$ are respectively the number of points at which the curves $y = f(x)$ and $y = f'(x)$ intersects the $x$-axis, then the value of $m + n$ is
If the points of intersection of two distinct conics $x^2 + y^2 = 4b$ and $\frac{x^2}{16} + \frac{y^2}{b^2} = 1$ lie on the curve $y^2 = 3x^2$, then $3\sqrt{3}$ times the area of the rectangle formed by the intersection points is
Answer: 432
Solution
Putting $y^2 = 3x^2$ in both the conics. We get $x^2 = b$ and $\frac{b}{16} + \frac{3}{b} = 1$. Therefore, $b = 4, 12$ ( $b = 4$ is rejected because curves coincide). Thus, $b = 12$. Hence points of intersection are $(\pm \sqrt{12}, \pm 6)$ which implies area of rectangle $= 432$.
Question 26
Maths · Differential Equations · Numerical
If the solution curve $y = y(x)$ of the differential equation $(1 + y^2)\left(1 + \log_e x\right) dx + x dy = 0, x > 0$ passes through the point $(1, 1)$ and $y(e) = \frac{\alpha - \tan\left(\frac{3}{2}\right)}{\beta + \tan\left(\frac{3}{2}\right)}$, then $\alpha + 2\beta$ is
Answer: 3
Solution
Given $\($ $\int$ $\left$( $\frac{1}{x}$ + $\frac{\ln x}{x}$ $\right$) dx + $\int$ $\frac{dy}{1+y^2}$ = 0 $\)$ $\($ $\ln$ x + $\frac{(\ln x)^2}{2}$ + $\tan$^{-1} y = C $\)$ Put $\($ x = y = 1 $\)$ $\($ $\therefore$ C = $\frac{\pi}{4}$ $\)$ $\($ $\Rightarrow$ $\ln$ x + $\frac{(\ln x)^2}{2}$ + $\tan$^{-1} y = $\frac{\pi}{4}$ $\)$ Put $\($ x = e $\)$ $\($ $\Rightarrow$ y = $\tan$ $\left$( $\frac{\pi}{4}$ - $\frac{3}{2}$ $\right$) = $\frac{1 - \tan \frac{3}{2}}{1 + \tan \frac{3}{2}}$ $\)$ $\($ $\therefore$ $\alpha$ = 1, $\beta$ = 1 $\)$ $\($ $\Rightarrow$ $\alpha$ + 2$\beta$ = 3 $\)$
Question 27
Maths · Statistics · Numerical
If the mean and variance of the data 65, 68, 58, 44, 48, 45, 60, $\alpha$, $\beta$, 60 where $\alpha > \beta$ are 56 and 66.2 respectively, then $\alpha^2 + \beta^2$ is equal to
The area (in sq. units) of the part of circle $x^2 + y^2 = 169$ which is below the line $5x - y = 13$ is $$\frac{\pi \alpha}{2 \beta} - \frac{65}{2} + \frac{\alpha}{\beta} \sin^{-1} \left( \frac{12}{13} \right)$$ where $\alpha, \beta$ are coprime numbers. Then $\alpha + \beta$ is equal to
If $\frac{{^{11}C_1}}{2} + \frac{{^{11}C_2}}{3} + \ldots + \frac{{^{11}C_9}}{10} = \frac{n}{m}$ with $\gcd(n, m) = 1$, then $n + m$ is equal to
Answer: 2041
Solution
Given $$\sum_{r=1}^{9} \frac{{^{11}C_r}}{{r+1}}$$ This is equal to $$\frac{1}{12} \sum_{r=1}^{9} {^{12}C_{r+1}}$$ Which simplifies to $$\frac{1}{12} \left[ 2^{12} - 2^6 \right] = \frac{2035}{6}$$ Therefore, $m + n = 2041$.
Question 30
Maths · Three Dimensional Geometry · Numerical
A line with direction ratios 2, 1, 2 meets the lines $x = y + 2 = z$ and $x + 2 = 2y = 2z$ respectively at the point $P$ and $Q$. if the length of the perpendicular from the point $(1, 2, 12)$ to the line $PQ$ is $l$, then $l^2$ is
Answer: 65
Solution
Let $\mathrm{P}(t, t-2, t)$ and $\mathrm{Q}(2s-2, s, s)$. D.R's of $\mathrm{PQ}$ are $2, 1, 2$. $$\frac{2s-2-t}{2} = \frac{s-t+2}{1} = \frac{s-t}{2}$$ implies $t = 6$ and $s = 2$. Therefore, $\mathrm{P}(6, 4, 6)$ and $\mathrm{Q}(2, 2, 2)$. $$\mathrm{PQ} : \frac{x-2}{2} = \frac{y-2}{1} = \frac{z-2}{2} = \lambda$$ Let $\mathrm{F}(2\lambda + 2, \lambda + 2, 2\lambda + 2)$. $\mathrm{A}(1, 2, 12)$. $$\overrightarrow{\mathrm{AF}} \cdot \overrightarrow{\mathrm{PQ}} = 0$$ Therefore, $\lambda = 2$. So $\mathrm{F}(6, 4, 6)$ and $\mathrm{AF} = \sqrt{65}$.
Physics
Question 31
Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct
In the given circuit, the breakdown voltage of the Zener diode is 3.0 $\mathrm{V}$. What is the value of $I_2$?
The electric current through a wire varies with time as $I = I_0 + \beta \, t$. where $I_0 = 20 \, \mathrm{A}$ and $\beta = 3 \, \mathrm{A/s}$. The amount of electric charge crossed through a section of the wire in 20 s is :
Physics · Mechanical Properties of Fluids · Single correct
Given below are two statements: Statement I : If a capillary tube is immersed first in cold water and then in hot water, the height of capillary rise will be smaller in hot water. Statement II : If a capillary tube is immersed first in cold water and then in hot water, the height of capillary rise will be smaller in cold water. In the light of the above statements, choose the most appropriate from the options given below
Both Statement I and Statement II are true
Both Statement I and Statement II are false
Statement I is true but Statement II is false
Statement I is false but Statement II is true
Answer: (c)
Solution
Surface tension will be less as temperature increases $$h = \frac{2T \cos \theta}{\rho gr}$$ Height of capillary rise will be smaller in hot water and larger in cold water.
Question 34
Physics · Ray Optics and Optical Instruments · Single correct
A convex mirror of radius of curvature 30 cm forms an image that is half the size of the object. The object distance is :
-15 $\mathrm{cm}$
45 $\mathrm{cm}$
-45 $\mathrm{cm}$
15 $\mathrm{cm}$
Answer: (a)
Solution
Given $R = 30 \, \mathrm{cm}$. $f = R/2 = +15 \, \mathrm{cm}$. Magnification $(m) = \pm \frac{1}{2}$. For convex mirror, virtual image is formed for real object. Therefore, $m$ is $+\mathrm{ve}$. $$\frac{1}{2} = \frac{f}{f - u}$$ $$u = -15 \, \mathrm{cm}$$
Question 35
Physics · Electric Charges and Fields · Single correct
Two charges of $5Q$ and $-2Q$ are situated at the points $(3a, 0)$ and $(-5a, 0)$ respectively. The electric flux through a sphere of radius '4a' having center at origin is:
$\frac{2Q}{\varepsilon_0}$
$\frac{5Q}{\varepsilon_0}$
$\frac{7Q}{\varepsilon_0}$
$\frac{3Q}{\varepsilon_0}$
Answer: (b)
Solution
The $5Q$ charge is inside the spherical region. The flux through the sphere is given by $$\frac{5Q}{\varepsilon_0}.$$
Question 36
Physics · Motion in a Straight Line · Single correct
A body starts moving from rest with constant acceleration covers displacement $S_1$ in first $(p - 1)$ seconds and $S_2$ in first $p$ seconds. The displacement $S_1 + S_2$ will be made in time:
$(2p + 1)\,\mathrm{s}$
$\sqrt{(2p^2 - 2p + 1)}\,\mathrm{s}$
$(2p - 1)\,\mathrm{s}$
$(2p^2 - 2p + 1)\,\mathrm{s}$
Answer: (b)
Solution
Given $S_1$ in first $(p-1)$ sec and $S_2$ in first $p$ sec. $S_1 = \frac{1}{2} a (p-1)^2$ $S_2 = \frac{1}{2} a (p)^2$ $S_1 + S_2 = \frac{1}{2} a t^2$ $(p-1)^2 + p^2 = t^2$ $t = \sqrt{2p^2 + 1 - 2p}$
Question 37
Physics · Work, Energy and Power · Single correct
The potential energy function (in $J$) of a particle in a region of space is given as $U = (2x^2 + 3y^3 + 2z)$. Here $x$, $y$ and $z$ are in meter. The magnitude of $x$ - component of force (in $N$) acting on the particle at point $P(1, 2, 3)$ m is :
2
6
4
8
Answer: (c)
Solution
Given $U = 2x^2 + 3y^3 + 2z$ $$F_x = -\frac{\partial U}{\partial x} = -4x$$ At $x = 1$ magnitude of $F_x$ is $4 \mathrm{N}$
Question 38
Physics · Mathematics in Physics · Single correct
The resistance $R = \frac{V}{I}$ where $V = (200 \pm 5) \, \mathrm{V}$ and $I = (20 \pm 0.2) \, \mathrm{A}$, the percentage error in the measurement of $R$ is:
3.5%
7%
3%
5.5%
Answer: (a)
Solution
Given $R = \frac{V}{I}$. According to error analysis, $$\frac{dR}{R} = \frac{dV}{V} + \frac{dI}{I}$$ $$\frac{dR}{R} = \frac{5}{200} + \frac{0.2}{20}$$ $$\frac{dR}{R} = \frac{7}{200}$$ The percentage error is $$\frac{dR}{R} \times 100 = \frac{7}{200} \times 100 = 3.5\%$$
Question 39
Physics · Work, Energy and Power · Single correct
A block of mass $100 \, \mathrm{kg}$ slides over a distance of $10 \, \mathrm{m}$ on a horizontal surface. If the co-efficient of friction between the surfaces is $0.4$, then the work done against friction (in J) is:
4200
3900
4000
4500
Answer: (c)
Solution
Given $m = 100 \, \mathrm{kg}$, $s = 10 \, \mathrm{m}$, $\mu = 0.4$. As $f = \mu mg = 0.4 \times 100 \times 10 = 400 \, \mathrm{N}$. Now $W = f \cdot s = 400 \times 10 = 4000 \, \mathrm{J}$.
Question 40
Physics · Electromagnetic Waves · Single correct
Match List I with List II Chose the correct answer from the options given below
A-IV, B-I, C-III, D-II
A-II, B-III, C-I, D-IV
A-IV, B-III, C-I, D-II
A-I, B-II, C-III, D-IV
Answer: (c)
Solution
Ampere-Maxwell law $$\oint \vec{B} \cdot \vec{dl} = \mu_0 i_c + \mu_0 \varepsilon_0 \frac{d \phi_E}{dt}$$ Faraday law $$\oint \vec{E} \cdot \vec{d} = -\frac{d \phi_B}{dt}$$ Gauss' law for electricity $$\oint \vec{E} \cdot \vec{dA} = \frac{Q}{\varepsilon_0}$$ Gauss' law for magnetism $$\oint \vec{B} \cdot \vec{dA} = 0$$
Question 41
Physics · Motion in a Plane · Single correct
If the radius of curvature of the path of two particles of same mass are in the ratio 3:4, then in order to have constant centripetal force, their velocities will be in the ratio of:
$\sqrt{3} : 2$
$1 : \sqrt{3}$
$\sqrt{3} : 1$
$2 : \sqrt{3}$
Answer: (a)
Solution
Given $m_1 = m_2$ and $\frac{r_1}{r_2} = \frac{3}{4}$. As centripetal force $F = \frac{mv^2}{r}$. In order to have constant (same in this question) centripetal force $F_1 = F_2$. $$\frac{m_1 v_1^2}{r_1} = \frac{m_2 v_2^2}{r_2}$$ $$\Rightarrow \frac{v_1}{v_2} = \sqrt{\frac{r_1}{r_2}} = \frac{\sqrt{3}}{2}$$
Question 42
Physics · Current Electricity · Single correct
A galvanometer having coil resistance $10 \, \Omega$ shows a full scale deflection for a current of $3 \, \mathrm{mA}$. For it to measure a current of $8 \, \mathrm{A}$, the value of the shunt should be:
$3 \times 10^{-3} \, \Omega$
$4.85 \times 10^{-3} \, \Omega$
$3.75 \times 10^{-3} \, \Omega$
$2.75 \times 10^{-3} \, \Omega$
Answer: (c)
Solution
Given $G = 10 \, \Omega$. $I_g = 3 \, \mathrm{mA}$. $I = 8 \, \mathrm{A}$. In case of conversion of galvanometer into ammeter. We have $I_g G = (I - I_g) S$. $$S = \frac{I_g G}{I - I_g}$$ $$S = \frac{(3 \times 10^{-3}) \times 10}{8 - 0.003} = 3.75 \times 10^{-3} \, \Omega$$
Question 43
Physics · Work, Energy and Power · Single correct
The de-Broglie wavelength of an electron is the same as that of a photon. If velocity of electron is 25$\%$ of the velocity of light, then the ratio of K.E. of electron and K.E. of photon will be:
$\frac{1}{1}$
$\frac{1}{8}$
$\frac{8}{1}$
$\frac{1}{4}$
Answer: (b)
Solution
For photon $$E_p = \frac{hc}{\lambda_p} \Rightarrow \lambda_p = \frac{hc}{E_p}$$ For electron $$\lambda_e = \frac{h}{m_e v_e} = \frac{h v_e}{2 K_e}$$ Given $v_c = 0.25c$ $$\lambda_e = \frac{h \times 0.25c}{2 K_e} = \frac{hc}{8 K_e}$$ Also $\lambda_p = \lambda_e$ $$\frac{hc}{E_p} = \frac{hc}{8 K_e}$$ $$\frac{K_e}{E_p} = \frac{1}{8}$$
Question 44
Physics · Current Electricity · Single correct
The deflection in moving coil galvanometer falls from 25 divisions to 5 division when a shunt of 24\,$\Omega$ is applied. The resistance of galvanometer coil will be :
12\,$\Omega$
96\,$\Omega$
48\,$\Omega$
100\,$\Omega$
Answer: (b)
Solution
Let $x = current/division$. Initially, $I_g = 25x$. After applying shunt: $I_g = 5x$ and $I - I_g = 20x$ with a $24 \, \Omega$ resistor. Now $5x \times G = 20x \times 24$. Solving for $G$: $$G = 4 \times 24$$ $$G = 96 \, \Omega$$
Question 45
Physics · Ray Optics and Optical Instruments · Single correct
A biconvex lens of refractive index 1.5 has a focal length of 20 $\mathrm{\ cm}$ in air. Its focal length when immersed in a liquid of refractive index 1.6 will be:
A thermodynamic system is taken from an original state $A$ to an intermediate state $B$ by a linear process as shown in the figure. It's volume is then reduced to the original value from $B$ to $C$ by an isobaric process. The total work done by the gas from $A$ to $B$ and $B$ to $C$ would be :
At what distance above and below the surface of the earth a body will have same weight, (take radius of earth as R.)
$\sqrt{5}R - R$
$\frac{\sqrt{3}R - R}{2}$
$\frac{R}{2}$
$\frac{\sqrt{5}R - R}{2}$
Answer: (d)
Solution
Given $\($ g_p = $\frac{gR^2}{(R+h)^2}$ $\)$ and $\($ g_q = g $\left$( 1 - $\frac{h}{R}$ $\right$) $\)$. Equating $\($ g_p = g_q $\)$, we have: $$ \frac{g}{\left( 1 + \frac{h}{R} \right)^2} = g \left( 1 - \frac{h}{R} \right) $$ $$ \left( 1 - \frac{h^2}{R^2} \right) \left( 1 + \frac{h}{R} \right) = 1 $$ Take $\($ $\frac{h}{R}$ = x $\)$. So, $$ x^3 - x + x^2 = 0 $$ $$ x = \frac{\sqrt{5} - 1}{2} $$ $$ h = \frac{R}{2} (\sqrt{5} - 1) $$
Question 48
Physics · Alternating Current · Single correct
A capacitor of capacitance $100\mu F$ is charged to a potential of $12 \, \mathrm{V}$ and connected to a $6.4 \, \mathrm{mH}$ inductor to produce oscillations. The maximum current in the circuit would be:
The explosive in a Hydrogen bomb is a mixture of $_1H^2$, $_1H^3$ and $_3Li^6$ in some condensed form. The chain reaction is given by $$_5Li^6 + _0n^1 \rightarrow _2He^4 + _1H^3$$ $$_1H^2 + _1H^3 \rightarrow _2He^4 + _0n^1$$ During the explosion the energy released is approximately [Given : M(Li) = 6.01690 amu. M($_1H^2$) = 2.01471 amu. M($_2He^4$) = 4.00388 amu, and 1 amu = 931.5 MeV]
Two vessels A and B are of the same size and are at same temperature. A contains 1 g of hydrogen and B contains 1 g of oxygen. $P_A$ and $P_B$ are the pressures of the gases in A and B respectively, then $\frac{P_A}{P_B}$ is :
16
8
4
32
Answer: (a)
Solution
Given $V_A = V_B$ and $T_A = T_B$, we have $$\frac{P_A V_A}{P_B V_B} = \frac{n_A R T_A}{n_B R T_B}.$$ This simplifies to $$\frac{P_A}{P_B} = \frac{n_A}{n_B}.$$ Substituting the given values, $$\frac{P_A}{P_B} = \frac{1/2}{1/32} = 16.$$
Question 51
Physics · Atoms · Numerical
When a hydrogen atom going from $n = 2$ to $n = 1$ emits a photon, its recoil speed is $\frac{x}{5}$ m/s. Where $x =$ _______. (Use : mass of hydrogen atom $= 1.6 \times 10^{-27} \, \mathrm{kg}$)
Answer: 17
Solution
Given $\Delta E = 10.2 \, \mathrm{eV}$. Recoil speed $(v)$ is given by $$v = \frac{\Delta E}{mc}$$ Substituting the values, $$v = \frac{10.2 \, \mathrm{eV}}{1.6 \times 10^{-27} \times 3 \times 10^8}$$ $$= \frac{10.2 \times 1.6 \times 10^{-19}}{1.6 \times 10^{-27} \times 3 \times 10^8}$$ $$v = 3.4 \, \mathrm{m/s} = \frac{17}{5} \, \mathrm{m/s}$$ Therefore, $x = 17$.
Question 52
Physics · Motion in a Plane · Numerical
A ball rolls off the top of a stairway with horizontal velocity $u$. The steps are $0.1 \, \mathrm{m}$ high and $0.1 \, \mathrm{m}$ wide. The minimum velocity $u$ with which that ball just hits the step 5 of the stairway will be $\sqrt{x} \, \mathrm{ms}^{-1}$ where x = _______ [use $g = 10 \, \mathrm{m/s}^2$].
Answer: 2
Solution
The ball needs to just cross 4 steps to just hit the 5th step. Therefore, horizontal range (R) = 0.4 m. $$R = u \cdot t$$ Similarly, in the vertical direction, $$h = \frac{1}{2} g t^2$$ $$0.4 = \frac{1}{2} g t^2$$ $$0.4 = \frac{1}{2} g \left( \frac{0.4}{u} \right)^2$$ $$u^2 = 2$$ $$u = \sqrt{2} \, \mathrm{m/s}$$ Therefore, $$x = 2$$
Question 53
Physics · Electromagnetic Induction · Numerical
A square loop of side 10 cm and resistance 0.7 $\Omega$ is placed vertically in east-west plane. A uniform magnetic field of 0.20 T is set up across the plane in north east direction. The magnetic field is decreased to zero in 1 s at a steady rate. Then, magnitude of induced emf is $\sqrt{x} \times 10^{-3}$ V. The value of $x$ is _____
Answer: 2
Solution
Given $\vec{A} = (0.1)^{2} \hat{j}$ and $\vec{B} = \frac{0.2}{\sqrt{2}} \hat{i} + \frac{0.2}{\sqrt{2}} \hat{j}$. The magnitude of induced emf is given by $$c = \frac{\Delta \phi}{\Delta t} = \frac{\vec{B} \cdot \vec{A} - 0}{1} = \sqrt{2} \times 10^{-3} \, \mathrm{V}$$
Question 54
Physics · System of Particles and Rotational Motion · Numerical
A cylinder is rolling down on an inclined plane of inclination $60^{\circ}$. Its acceleration during rolling down will be $\left( \frac{x}{\sqrt{3}} \right)$ m/s$^2$, where $x$ = _____ (use $g = 10$ m/s$^2$).
The magnetic potential due to a magnetic dipole at a point on its axis situated at a distance of 20 cm from its center is $1.5 \times 10^{-5} \, \mathrm{Tm}$.The magnetic moment of the dipole is $\mathrm{A\,m}^2$. (Given: $\frac{\mu_0}{4\pi} = 10^{-7}\,\mathrm{T\,m\,A}^{-1}$)
In a double slit experiment shown in figure, when light of wavelength 400 nm is used, dark fringe is observed at $P$. If $D = 0.2 \, \mathrm{m}$, the minimum distance between the slits $S_1$ and $S_2$ is ______ mm.
A 16 $\Omega$ wire is bend to form a square loop. A 9 V battery with internal resistance 1$\Omega$ is connected across one of its sides. If a 4$\mu$F capacitor is connected across one of its diagonals, the energy stored by the capacitor will be $\frac{x}{2}$ $\mu$J. where x = .
Answer: 81
Solution
Given the circuit, we calculate the current $I$ using the formula $I = \frac{V}{R_{eq}}$. Thus, $$I = \frac{9}{1 + \frac{12 \times 4}{12 + 4}} = \frac{9}{4}$$ Next, we find $I_1$: $$I_1 = \frac{9}{4} \times \frac{4}{16} = \frac{9}{16}$$ The voltage difference $V_A - V_B$ is given by: $$V_A - V_B = I_1 \times 8 = \frac{9}{16} \times 8 = \frac{9}{2} \, V$$ The energy $U$ is calculated as: $$\therefore \, U = \frac{1}{2} \times 4 \times \frac{81}{4} \, \mu J$$ Simplifying, we get: $$\therefore \, U = \frac{81}{2} \, \mu J$$ Therefore, $$\therefore \, x = 81$$
Question 58
Physics · Oscillations · Fill in the blank
When the displacement of a simple harmonic oscillator is one third of its amplitude, the ratio of total energy to the kinetic energy is $\frac{x}{8}$, where x = ____ .
Answer: 9
Solution
Let total energy $= E = \frac{1}{2} K A^2$. $$U = \frac{1}{2} K \left( \frac{A}{3} \right)^2 = \frac{K A^2}{2 \times 9} = \frac{E}{9}$$ $$KE = E - \frac{E}{9} = \frac{8E}{9}$$ Ratio $\frac{Total}{KE} = \frac{E}{\frac{8E}{9}} = \frac{9}{8}$ $x = 9$
Question 59
Physics · Electric Charges and Fields · Numerical
An electron is moving under the influence of the electric field of a uniformly charged infinite plane sheet S having surface charge density $+\sigma$. The electron at $t = 0$ is at a distance of 1 m from S and has a speed of 1 m/s. The maximum value of $\sigma$ if the electron strikes S at $t = 1$ s is $\alpha \left[ \frac{m \varepsilon_0}{e} \right] \frac{C}{m^2}$ the value of $\alpha$ is
Physics · Mechanical Properties of Fluids · Numerical
In a test experiment on a model aeroplane in wind tunnel, the flow speeds on the upper and lower surfaces of the wings are $70 \, \mathrm{ms^{-1}}$ and $65 \, \mathrm{ms^{-1}}$ respectively. If the wing area is $2 \, \mathrm{m^2}$ the lift of the wing is N. (Given density of air = $1.2 \, \mathrm{kg \, m^{-3}}$)
Answer: 810
Solution
Given the equation for force: $$F = \frac{1}{2} \rho \left( v_1^2 - v_2^2 \right) A$$ Substitute the values: $$F = \frac{1}{2} \times 1.2 \times \left( 70^2 - 65^2 \right) \times 2$$ The calculated force is: $$= 810 \, \mathrm{N}$$
Chemistry
Question 61
Chemistry · Classification of Elements and Periodicity in Properties · Single correct
Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R: Assertion A: The first ionisation enthalpy decreases across a period. Reason R: The increasing nuclear charge outweighs the shielding across the period. In the light of the above statements, choose the most appropriate from the options given below:
Both A and R are true and R is the correct explanation of A
A is true but R is false
A is false but R is true
Both A and R are true but R is NOT the correct explanation of A
Answer: (c)
Solution
First ionisation energy increases along the period. Along the period $Z$ increases which outweighs the shielding effect.
Question 62
Chemistry · Biomolecules · Single correct
Match List I with List II \begin{tabular}{|l|l|} \hline \textbf{LIST-I} & \textbf{LIST-II} \\ \textbf{(Substances)} & \textbf{(Element Present)} \\ \hline A. Ziegler catalyst & I. Rhodium \\ \hline B. Blood Pigment & II. Cobalt \\ \hline C. Wilkinson catalyst & III. Iron \\ \hline D. Vitamin B$_{12}$ & IV. Titanium \\ \hline \end{tabular} Choose the correct answer from the options given below:
Chemistry · The d-and f-Block Elements · Single correct
In chromyl chloride test for confirmation of $\mathrm{Cl}^-$ ion, a yellow solution is obtained. Acidification of the solution and addition of amyl alcohol and 10$\%$ $\mathrm{H}_2\mathrm{O}_2$ turns organic layer blue indicating formation of chromium pentoxide. The oxidation state of chromium in that is
+6
+5
+10
+3
Answer: (a)
Solution
In a basic medium, $\mathrm{Cl^-} + \mathrm{K_2Cr_2O_7} + \mathrm{H_2SO_4} \rightarrow \mathrm{CrO_2Cl_2}$ (yellow solution) $\rightarrow \mathrm{CrO_4^{2-}} + \mathrm{Cl^-}$ (yellow solution). The reaction sequence is as follows: 1. Acidification 2. Amyl alcohol 3. 10$\%$ $\mathrm{H_2O_2}$ This leads to the formation of $\mathrm{CrO_5}$ (blue compound).
Question 64
Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct
The difference in energy between the actual structure and the lowest energy resonance structure for the given compound is
electromeric energy
resonance energy
ionization energy
hyperconjugation energy
Answer: (b)
Solution
The difference in energy between the actual structure and the lowest energy resonance structure for the given compound is known as resonance energy.
Question 65
Chemistry · Classification of Elements and Periodicity in Properties · Single correct
Given below are two statements: Statement I: The electronegativity of group 14 elements from Si to Pb gradually decreases. Statement II: Group 14 contains non-metallic, metallic, as well as metalloid elements. In the light of the above statements, choose the most appropriate from the options given below:
Statement I is false but Statement II is true
Statement I is true but Statement II is false
Both Statement I and Statement II are true
Both Statement I and Statement II are false
Answer: (a)
Solution
The electronegativity values for elements from Si to Pb are almost same. So Statement I is false.
Question 66
Chemistry · Structure of Atom · Single correct
The correct set of four quantum numbers for the valence electron of rubidium atom $(Z = 37)$ is:
$5, 0, 0, +\frac{1}{2}$
$5, 0, 1, +\frac{1}{2}$
$5, 1, 0, +\frac{1}{2}$
$5, 1, 1, +\frac{1}{2}$
Answer: (a)
Solution
Rb = [$\mathrm{Kr}$] 5s^1 n = 5 l = 0 m = 0 s = +1/2 or -1/2
Question 67
Chemistry · Hydrocarbons · Single correct
The major product (P) in the following reaction is
Answer: (d)
Solution
The reaction involves the addition of concentrated HBr to the given compound. The alkene group undergoes electrophilic addition with HBr, leading to the formation of a carbocation intermediate. The bromide ion then attacks the carbocation, resulting in the formation of the product with a bromine atom added to the alkene carbon. The excess HBr ensures complete conversion, leading to the final product.
Question 68
Chemistry · Hydrocarbons · Single correct
The arenium ion which is not involved in the bromination of Aniline is
Answer: (c)
Solution
Since $-\mathrm{NH_2}$ group is o/p directing hence arenium ion will not be formed by attack at meta position i.e. $Nc1cccc(Br)c1$. Hence Answer is (3)
Question 69
Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct
Appearance of blood red colour, on treatment of the sodium fusion extract of an organic compound with $\mathrm{FeSO_4}$ in presence of concentrated $\mathrm{H_2SO_4}$ indicates the presence of element/s
Br
N
N and S
S
Answer: (c)
Solution
The reaction starts with $\mathrm{Fe^{2+}}$ which is converted to $\mathrm{Fe^{3+}}$ in the presence of $\mathrm{H^+}$ and concentrated $\mathrm{H_2SO_4}$. Then, $\mathrm{Fe^{3+}}$ reacts with $\mathrm{SCN^-}$ to form $\mathrm{Fe(SCN)_3}$, which has a blood red color. The appearance of blood red color indicates the presence of both nitrogen and sulphur.
Question 70
Chemistry · Haloalkanes and Haloarenes · Single correct
Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R : Assertion A : Aryl halides cannot be prepared by replacement of hydroxyl group of phenol by halogen atom. Reason R : Phenols react with halogen acids violently. In the light of the above statements, choose the most appropriate from the options given below:
Both A and R are true but R is NOT the correct explanation of A
A is false but R is true
A is true but R is false
Both A and R are true and R is the correct explanation of A
Answer: (c)
Solution
Assertion (A): Given statement is correct because in phenol hydroxyl group cannot be replaced by halogen atom. Reason (R): Given reason is false. Hence Assertion (A) is correct but Reason (R) is false.
Question 71
Chemistry · Hydrocarbons · Single correct
Identify product A and product B:
A:
A:
A:
A:
Answer: (d)
Solution
The reaction of the given alkene with $\mathrm{Cl_2}$ can proceed via two different mechanisms. Under the influence of $h\nu$, a free radical mechanism occurs, leading to the formation of Product A. In the presence of $\mathrm{CCl_4}$, an electrophilic addition reaction takes place on the alkene, resulting in Product B. Hence, the correct answer is option (4).
Question 72
Chemistry · The p-Block Elements (Group-13 and 14) · Single correct
Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct
The interaction between $\pi$ bond and lone pair of electrons present on an adjacent atom is responsible for
Hyperconjugation
Inductive effect
Electromeric effect
Resonance effect
Answer: (d)
Solution
It is a type of conjugation responsible for resonance.
Question 74
Chemistry · The d-and f-Block Elements · Single correct
$KMnO_4$ decomposes on heating at $513 \, \mathrm{K}$ to form $O_2$ along with
$MnO_2$ & $K_2O_2$
$K_2MnO_4$ & $Mn$
$Mn$ & $KO_2$
$K_2MnO_4$ & $MnO_2$
Answer: (d)
Solution
The reaction is given by the equation: $$\mathrm{KMnO_4} \xrightarrow{\Delta} \mathrm{K_2MnO_4} + \mathrm{MnO_2} + \mathrm{O_2}.$$
Question 75
Chemistry · Co-ordination Compounds · Single correct
In which one of the following metal carbonyls, CO forms a bridge between metal atoms?
$\mathrm{[Co_2(CO)_8]}$
$\mathrm{[Mn_2(CO)_{10}]}$
$\mathrm{[Os_3(CO)_{12}]}$
$\mathrm{[Ru_3(CO)_{12}]}$
Answer: (a)
Solution
Question 76
Chemistry · Biomolecules · Single correct
Type of amino acids obtained by hydrolysis of proteins is:
$\beta$
$\alpha$
$\delta$
$\gamma$
Answer: (b)
Solution
Proteins are natural polymers composed of $\alpha$-amino acids which are connected by peptide linkages. Hence proteins upon acidic hydrolysis produce $\alpha$-amino acids.
Question 77
Chemistry · Hydrocarbons · Single correct
The final product A formed in the following multistep reaction sequence is
Answer: (a)
Solution
The reaction sequence involves the following steps: 1. The alkene undergoes hydration in the presence of $\mathrm{H_2O}$ and $\mathrm{H^+}$ to form an alcohol. 2. The alcohol is oxidized using $\mathrm{CrO_3}$ to form a ketone. 3. The ketone undergoes Wolff-Kishner reduction with $\mathrm{NH_2NH_2}$ and $\mathrm{KOH}$ under heat to form an alkane.
Question 78
Chemistry · Thermodynamics · Single correct
Which of the following is not correct?
$\Delta G$ is negative for a spontaneous reaction
$\Delta G$ is positive for a spontaneous reaction
$\Delta G$ is zero for a reversible reaction
$\Delta G$ is positive for a non-spontaneous reaction
Answer: (b)
Solution
$(\Delta G)_{P,T} = (+)\,\text{ve}$ for non-spontaneous process
Question 79
Chemistry · Redox Reactions · Single correct
Chlorine undergoes disproportionation in alkaline medium as shown below: $a\ \mathrm{Cl_2(g)}$ $+\,b\ \mathrm{OH^{-}(aq)}$$\rightarrow$ $c\ \mathrm{ClO^{-}(aq)}$ $+\,d\ \mathrm{Cl^{-}(aq)}$ $+\,e\ \mathrm{_2O(l)}$ The values of $a,\ b,\ c$ and $d$ in the balanced redox reaction are respectively:
1, 2, 1 and 1
2, 2, 1 and 3
3, 4, 4 and 2
2, 4, 1 and 3
Answer: (a)
Solution
The reaction involves the reduction and oxidation of chlorine. The oxidation states change as follows: $$\mathrm{Cl_2} \rightarrow \mathrm{Cl^-} + \mathrm{ClO^-}$$ The balanced equation is: $$\mathrm{Cl_2} + 2\mathrm{\overline{O}H} \rightarrow \mathrm{Cl^-} + \mathrm{ClO^-} + \mathrm{H_2O}$$
Question 80
Chemistry · The d-and f-Block Elements · Single correct
In alkaline medium. $\mathrm{MnO_4^-}$ oxidises $\mathrm{I^-}$ to
$\mathrm{IO_4^-}$
$\mathrm{IO^-}$
$\mathrm{I_2}$
$\mathrm{IO_3^-}$
Answer: (d)
Solution
In an alkaline medium, the reaction is given by: $$2\mathrm{MnO_4^-} + \mathrm{H_2O} + \mathrm{I^-} \rightarrow 2\mathrm{MnO_2} + 2\mathrm{OH^-} + \mathrm{IO_3^-}$$
Question 81
Chemistry · Chemical Bonding and Molecular Structure · Numerical
Number of compounds with one lone pair of electrons on central atom amongst following is _______ $\mathrm{O}_3$, $\mathrm{H}_2\mathrm{O}$, $\mathrm{SF}_4$, $\mathrm{ClF}_3$, $\mathrm{NH}_3$, $\mathrm{BrF}_5$, $\mathrm{XeF}_4$
Answer: 4
Solution
Question 82
Chemistry · Electrochemistry · Numerical
The mass of zinc produced by the electrolysis of zinc sulphate solution with a steady current of 0.015 A for 15 minutes is _______ $\times 10^{-4}$ g. (Atomic mass of zinc = 65.4 amu)
Answer: 46
Solution
The reaction is given by: $\mathrm{Zn}^{2+} + 2e^- \rightarrow \mathrm{Zn}$. The formula for weight is: $W = Z \times i \times t$. Substituting the values: $W = \frac{65.4}{2 \times 96500} \times 0.015 \times 15 \times 60$ $= 45.75 \times 10^{-4}\,\mathrm{gm}$
Question 83
Chemistry · Chemical Kinetics and Nuclear Chemistry · Numerical
For a reaction taking place in three steps at same temperature, overall rate constant $K = \frac{K_1 \, K_2}{K_3}$. If $E_{a_1}$, $E_{a_2}$ and $E_{a_3}$ are 40, 50 and 60 $\,$ $\mathrm{kJ/mol}$$ respectively, the overall $E_a$ is \, \mathrm{kJ/mol}.
For the reaction $\mathrm{N_2O_4(g)} \rightleftharpoons 2\mathrm{NO_2(g)}$, $K_p = 0.492\,\mathrm{atm}$ at $300\,\mathrm{K}$. $K_c$ for the reaction at same temperature is $\underline{\hspace{1cm}} \times 10^{-2}$. (Given: $R = 0.082\,\mathrm{L\,atm\,mol^{-1}\,K^{-1}}$)
A solution of $\mathrm{H_2SO_4}$ is $31.4\%$ $\mathrm{H_2SO_4}$ by mass and has a density of $1.25 \, \mathrm{g/mL}$. The molarity of the $\mathrm{H_2SO_4}$ solution is _________ M (nearest integer). [Given molar mass of $\mathrm{H_2SO_4} = 98 \, \mathrm{g \, mol}^{-1}$]
The osmotic pressure of a dilute solution is $7 \times 10^5 \, \mathrm{Pa}$ at $273 \, \mathrm{K}$. Osmotic pressure of the same solution at $283 \, \mathrm{K}$ is ______ $\times 10^4 \, \mathrm{Nm}^{-2}$.
Number of compounds among the following which contain sulphur as heteroatom is ______ Furan, Thiophene, Pyridine, Pyrrole, Cysteine, Tyrosine
Answer: 2
Solution
The image shows the structures of thiophene and cysteine. Thiophene is a five-membered aromatic ring containing sulfur. Cysteine is an amino acid with a thiol group (SH) and a carboxyl group (COOH).
Question 88
Chemistry · Chemical Bonding and Molecular Structure · Numerical
The number of species from the following which are paramagnetic and have bond order equal to one is $\underline{\hspace{2cm}}$. $H_2$, $He_2^+$, $O_2^+$, $N_2^{2-}$, $O_2^{2-}$, $F_2$, $Ne_2^+$, $B_2$
Chemistry · Aldehydes, Ketones and Carboxylic Acids · Numerical
From the compounds given below, number of compounds which give positive Fehling's test is _______ Benzaldehyde, Acetaldehyde, Acetone, Acetophenone, Methanal, 4-nitrobenzaldehyde, cyclohexane carbaldehyde.
Answer: 3
Solution
Acetaldehyde ($\mathrm{CH_3CHO}$), Methanal ($\mathrm{HCHO}$), and cyclohexane carbaldehyde.
Question 90
Chemistry · Hydrocarbons · Numerical
Consider the given reaction. The total number of oxygen atoms present per molecule of the product $(P)$ is
Answer: 1
Solution
Hence total number of oxygen atom present per molecule is 1.