JEE Main 1 February 2024 Shift 2 question paper with solutions

JEE Main 1 February 2024 Shift 2: all 90 questions in paper order (Maths, Physics, Chemistry) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.

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Maths

Question 1

Maths · Continuity and Differentiability · Single correct

Let $f(x) = |2x^2 + 5|x| - 3|, x \in \mathbb{R}$. If $m$ and $n$ denote the number of points where $f$ is not continuous and not differentiable respectively, then $m + n$ is equal to:

  1. 5
  2. 2
  3. 0
  4. 3

Answer: (d)

Solution

Given $f(x) = |2x^2 + 5|x| - 3|$. The graph of $y = 12x^2 + 5x - 3$ is shown. The graph of $f(x)$ is also shown. The number of points of discontinuity is $0 = m$. The number of points of non-differentiability is $3 = n$.

Question 2

Maths · Complex Numbers and Quadratic Equations · Single correct

Let $\alpha$ and $\beta$ be the roots of the equation $px^2 + qx - r = 0$, where $p \neq 0$. If $p, q$ and $r$ be the consecutive terms of a non-constant G.P and $\frac{1}{\alpha} + \frac{1}{\beta} = \frac{3}{4}$, then the value of $(\alpha - \beta)^2$ is:

  1. $\frac{80}{9}$
  2. 9
  3. $\frac{20}{3}$
  4. 8

Answer: (a)

Solution

Given $px^2 + qx - r = 0$ with roots $\alpha$ and $\beta$. Let $p = A$, $q = AR$, $r = AR^2$. Then the equation becomes $Ax^2 + ARx - AR^2 = 0$. Simplifying, we have $x^2 + Rx - R^2 = 0$ with roots $\alpha$ and $\beta$. Therefore, $\frac{1}{\alpha} + \frac{1}{\beta} = \frac{3}{4}$. Thus, $\frac{\alpha + \beta}{\alpha \beta} = \frac{3}{4} \Rightarrow \frac{-R}{-R^2} = \frac{3}{4} \Rightarrow R = \frac{4}{3}$. Now, $(\alpha - \beta)^2 = (\alpha + \beta)^2 - 4\alpha \beta = R^2 - 4 \left(-R^2\right) = 5 \left(\frac{16}{9}\right) = \frac{80}{9}$.

Question 3

Maths · Trigonometric Functions · Single correct

The number of solutions of the equation $4 \sin^2 x - 4 \cos^3 x + 9 - 4 \cos x = 0; \; x \in [-2\pi, 2\pi]$ is :

  1. 1
  2. 3
  3. 2
  4. 0

Answer: (d)

Solution

Given $4 \sin^2 x - 4 \cos^3 x + 9 - 4 \cos x = 0; \; x \in [-2\pi, 2\pi]$. Rearranging, we have: $$4 - 4 \cos^2 x - 4 \cos^3 x + 9 - 4 \cos x = 0$$ Simplifying further: $$4 \cos^3 x + 4 \cos^2 x + 4 \cos x - 13 = 0$$ This implies: $$4 \cos^3 x + 4 \cos^2 x + 4 \cos x = 13$$ However, the left-hand side $\leq 12$ can't be equal to 13.

Question 4

Maths · Integrals · Single correct

The value of $\int_{0}^{1} \left(2x^3 - 3x^2 - x + 1\right)^{\frac{1}{3}} \, dx$ is equal to:

  1. 0
  2. 1
  3. 2
  4. -1

Answer: (a)

Solution

Given $$I = \int_0^1 \left(2x^3 - 3x^2 - x + 1\right)^{\frac{1}{3}} \, dx$$ Using $\int_0^{2a} f(x) \, dx$ where $f(2a - x) = -f(x)$, here $$f(1-x) = f(x)$$ Therefore, $I = 0$

Question 5

Maths · Conic Sections · Single correct

Let P be a point on the ellipse $\frac{x^2}{9} + \frac{y^2}{4} = 1$. Let the line passing through P and parallel to y-axis meet the circle $x^2 + y^2 = 9$ at point Q such that P and Q are on the same side of the x-axis. Then, the eccentricity of the locus of the point R on PQ such that $PR : RQ = 4 : 3$ as P moves on the ellipse, is :

  1. $\frac{11}{19}$
  2. $\frac{13}{21}$
  3. $\frac{\sqrt{139}}{23}$
  4. $\frac{\sqrt{13}}{7}$

Answer: (d)

Solution

Given $h = 3 \cos \theta$ and $k = \frac{18}{7} \sin \theta$. Therefore, the locus is $$\frac{x^2}{9} + \frac{49y^2}{324} = 1.$$ The eccentricity $e$ is calculated as $$e = \sqrt{1 - \frac{324}{49 \times 9}} = \frac{\sqrt{117}}{21} = \frac{\sqrt{13}}{7}.$$

Question 6

Maths · Binomial Theorem · Single correct

Let $m$ and $n$ be the coefficients of seventh and thirteenth terms respectively in the expansion of $\left(\dfrac{1}{3}x^{\frac{1}{3}} + \dfrac{1}{2x^{\frac{2}{3}}}\right)^{18}$. Then $\left(\dfrac{n}{m}\right)^{\frac{1}{3}}$ is:

  1. $\frac{4}{9}$
  2. $\frac{1}{9}$
  3. $\frac{1}{4}$
  4. $\frac{9}{4}$

Answer: (d)

Solution

$$\left(\frac{x^{\frac{1}{3}}}{3} + \frac{x^{\frac{-2}{3}}}{18}\right)^{18}$$ $$t_7 = {}^{18}c_6\left(\frac{x^{\frac{1}{3}}}{3}\right)^{12}\left(\frac{x^{\frac{-2}{3}}}{2}\right)^{6} = {}^{18}c_6\frac{1}{(3)^{12}} \cdot \frac{1}{2^6}$$ $$t_{13} = {}^{18}c_{12}\left(\frac{x^{\frac{1}{3}}}{3}\right)^{6}\left(\frac{x^{\frac{-2}{3}}}{2}\right)^{12} = {}^{18}c_{12}\frac{1}{(3)^{6}} \cdot \frac{1}{2^{12}} \cdot x^{-6}$$ $$m = {}^{18}c_6 \cdot 3^{-12} \cdot 2^{-6} \quad : \quad n = {}^{18}c_{12} \cdot 2^{-12} \cdot 3^{-6}$$ $$\left(\frac{n}{m}\right)^{\frac{1}{3}} = \left(\frac{2^{-12} \cdot 3^{-6}}{3^{-12} \cdot 2^{-6}}\right)^{\frac{1}{3}} = \left(\frac{3}{2}\right)^{2} = \frac{9}{4}$$

Question 7

Maths · Differential Equations · Single correct

Let $\alpha$ be a non-zero real number. Suppose $f : \mathbb{R} \to \mathbb{R}$ is a differentiable function such that $f(0) = 2$ and $\lim_{x \to -\infty} f(x) = 1$. If $f'(x) = \alpha f(x) + 3$, for all $x \in \mathbb{R}$, then $f(-\log_e 2)$ is equal to

  1. 3
  2. 5
  3. 9
  4. 7

Answer: (c)

Solution

Given $f(0) = 2$, $\lim_{x \to -\infty} f(x) = 1$. The equation is $f'(x) - x \cdot f(x) = 3$. The integrating factor is $I.F = e^{-\alpha x}$. Integrating, we have: $$y \left( e^{-\alpha x} \right) = \int 3 \cdot e^{-\alpha x} \, dx$$ This gives: $$f(x) \cdot \left( e^{-\alpha x} \right) = \frac{3 e^{-\alpha x}}{-\alpha} + c$$ At $x = 0$, we have $2 = \frac{-3}{\alpha} + c \implies \frac{3}{\alpha} = c - 2 \ldots (1)$ Thus: $$f(x) = \frac{-3}{\alpha} + c \cdot e^{\alpha x}$$ As $x \to -\infty$, $1 = \frac{-3}{\alpha} + c(0)$ Solving, $\alpha = -3$, therefore $c = 1$. At $f(-\ln 2) = \frac{-3}{\alpha} + c \cdot e^{\alpha x}$: $$1 + e^{3 \ln 2} = 9$$ (But $\alpha$ should be greater than 0 for finite value of $c$)

Question 8

Maths · Three Dimensional Geometry · Single correct

Let $P$ and $Q$ be the points on the line $\frac{x+3}{8} = \frac{y-4}{2} = \frac{z+1}{2}$ which are at a distance of 6 units from the point $R(1, 2, 3)$. If the centroid of the triangle $PQR$ is $(\alpha, \beta, \gamma)$, then $\alpha^2 + \beta^2 + \gamma^2$ is:

  1. 26
  2. 36
  3. 18
  4. 24

Answer: (c)

Solution

Given $P(8\lambda - 3, 2\lambda + 4, 2\lambda - 1)$. PR = 6. $$(8\lambda - 4)^2 + (2\lambda + 2)^2 + (2\lambda - 4)^2 = 36$$ $\lambda = 0, 1$. Hence $P(-3, 4, -1)$ and $Q(5, 6, 1)$. Centroid of $\triangle PQR = (1, 4, 1) \equiv (\alpha, \beta, \gamma)$. $$\alpha^2 + \beta^2 + \gamma^2 = 18$$

Question 9

Maths · Three Dimensional Geometry · Single correct

Consider a $\triangle$ ABC where A(1, 2, 3), B(-2, 8, 0) and C(3, 6, 7). If the angle bisector of $\angle$ BAC meets the line BC at D, then the length of the projection of the vector $\overrightarrow{AD}$ on the vector $\overrightarrow{AC}$ is:

  1. $\frac{37}{2\sqrt{38}}$
  2. $\frac{\sqrt{38}}{2}$
  3. $\frac{39}{2\sqrt{38}}$
  4. $\sqrt{19}$

Answer: (a)

Solution

A(1,3,2); B(-2,8,0); C(3,6,7); $\overrightarrow{AC}=2\hat{i}+3\hat{j}+5\hat{k}$ $AB=\sqrt{9+25+4}=\sqrt{38}$ $AC=\sqrt{4+9+25}=\sqrt{38}$ $\overrightarrow{AD}=\frac{1}{2}\hat{i}-4\hat{j}-\frac{3}{2}\hat{k} =\frac{1}{2}(\hat{i}-8\hat{j}-3\hat{k})$ Length of projection of $\overrightarrow{AD}$ on $\overrightarrow{AC}$ $=\left|\frac{\overrightarrow{AD}\cdot\overrightarrow{AC}}{|\overrightarrow{AC}|}\right| =\frac{37}{2\sqrt{38}}$

Question 10

Maths · Sequences and Series · Single correct

Let $S_n$ denote the sum of the first $n$ terms of an arithmetic progression. If $S_{10}=390$ and the ratio of the tenth and the fifth terms is $15:7$, then $$ S_{15}-S_5 $$ is equal to:

  1. 800
  2. 890
  3. 790
  4. 690

Answer: (c)

Solution

Given $S_{10} = 390$. $$\frac{10}{2} [2a + (10 - 1)d] = 390$$ This implies $2a + 9d = 78 \ldots (1)$. Given $\frac{t_{10}}{t_5} = \frac{15}{7}$, we have $\frac{a + 9d}{a + 4d} = \frac{15}{7}$, which implies $8a = 3d \ldots (2)$. From (1) and (2), $a = 3$ and $d = 8$. Now, $S_{15} - S_{5} = \frac{15}{2} (6 + 14 \times 8) - \frac{5}{2} (6 + 4 \times 8)$. $$= \frac{15 \times 118 - 5 \times 38}{2} = 790$$

Question 11

Maths · Integrals · Single correct

If \[ \int_{0}^{\frac{\pi}{3}} \cos^4 x \, dx = a\pi + b\sqrt{3}, \] where \(a\) and \(b\) are rational numbers, then \(9a + 8b\) is equal to:

  1. 2
  2. 1
  3. 3
  4. $\frac{3}{2}$

Answer: (a)

Solution

The integral to solve is $$\int_0^{\pi/3} \cos^4 x \, dx$$. This can be rewritten as $$\int_0^{\pi/3} \left( \frac{1 + \cos 2x}{2} \right)^2 \, dx$$. Simplifying, we have $$= \frac{1}{4} \int_0^{\pi/3} (1 + 2 \cos 2x + \cos^2 2x) \, dx$$. This becomes $$= \frac{1}{4} \left[ \int_0^{\pi/3} dx + 2 \int_0^{\pi/3} \cos 2x \, dx + \int_0^{\pi/3} \frac{1 + \cos 4x}{2} \, dx \right]$$. Evaluating each integral, we get $$= \frac{1}{4} \left[ \frac{\pi}{3} + (\sin 2x)_0^{\pi/3} + \frac{1}{2} \left( \frac{\pi}{3} \right) + \frac{1}{8} (\sin 4x)_0^{\pi/3} \right]$$. This simplifies to $$= \frac{1}{4} \left[ \frac{\pi}{3} + (\sin 2x)_0^{\pi/3} + \frac{1}{2} \left( \frac{\pi}{3} \right) + \frac{1}{8} (\sin 4x)_0^{\pi/3} \right]$$. Further simplification gives $$= \frac{1}{4} \left[ \frac{\pi}{2} + \frac{\sqrt{3}}{2} + \frac{1}{8} \times \left( -\frac{\sqrt{3}}{2} \right) \right]$$. Finally, we have $$= \frac{\pi}{2} + \frac{7\sqrt{3}}{64}$$. Thus, $a = \frac{1}{8}$ and $b = \frac{7}{64}$. Therefore, $9a + 8b = \frac{9}{8} + \frac{7}{8} = 2$.

Question 12

Maths · Complex Numbers and Quadratic Equations · Single correct

If $z$ is a complex number such that $|z| \geq 1$, then the minimum value of $\left| z + \frac{1}{2}(3 + 4i) \right|$ is: [We changed options. In official NTA paper no option was correct.]

  1. $\frac{5}{2}$
  2. 2
  3. 3
  4. 0

Answer: (d)

Solution

Given $|z| \geq 1$. The minimum value of $|z + \frac{3}{2} + 2i|$ is actually zero.

Question 13

Maths · Relations and Functions · Single correct

If the domain of the function $f(x) = \frac{\sqrt{x^2 - 25}}{(4-x^2)} + \log_{10}(x^2 + 2x - 15)$ is $(-\infty, \alpha) \cup [\beta, \infty)$, then $\alpha^2 + \beta^3$ is equal to:

  1. 140
  2. 175
  3. 150
  4. 125

Answer: (c)

Solution

Given $$f(x) = \frac{\sqrt{x^2 - 25}}{4 - x^2} + \log_{10}(x^2 + 2x - 15)$$ Domain: $x^2 - 25 \geq 0$ implies $x \in (-\infty, -5] \cup [5, \infty)$. $4 - x^2 \neq 0$ implies $x \neq \{-2, 2\}$. $x^2 + 2x - 15 > 0$ implies $(x + 5)(x - 3) > 0$. This implies $x \in (-\infty, -5) \cup (3, \infty)$. Therefore, $x \in (-\infty, -5) \cup [5, \infty)$. Let $\alpha = -5$ and $\beta = 5$. Therefore, $\alpha^2 + \beta^3 = 150$.

Question 14

Maths · Relations and Functions · Single correct

Consider the relations $R_1$ and $R_2$ defined as $aR_1b$ $\iff a^2 + b^2 = 1$ for all $a, b, \in \mathbb{R}$ and $(a, b) R_2(c, d)$ $\iff a + d = b + c$ for all $(a, b), (c, d) \in \mathbb{N} \times \mathbb{N}$. Then

  1. Only $R_1$ is an equivalence relation
  2. Only $R_2$ is an equivalence relation
  3. $R_1$ and $R_2$ both are equivalence relations
  4. Neither $R_1$ nor $R_2$ is an equivalence relation

Answer: (b)

Solution

Question 15

Maths · Three Dimensional Geometry · Single correct

If the mirror image of the point P(3, 4, 9) in the line $\frac{x-1}{3} = \frac{y+1}{2} = \frac{z-2}{1}$ is $(\alpha, \beta, \gamma)$, then $14(\alpha + \beta + \gamma)$ is:

  1. 102
  2. 138
  3. 108
  4. 132

Answer: (c)

Solution

Is $\overrightarrow{\mathrm{PN}} \cdot \mathbf{b} = 0$? $3(3\lambda - 2) + 2(2\lambda - 5) + (\lambda - 7) = 0$ $14\lambda = 23 \Rightarrow \lambda = \frac{23}{14}$ $\mathrm{N} \left( \frac{83}{14}, \frac{32}{14}, \frac{51}{14} \right)$ Therefore, $\frac{\alpha + 3}{2} = \frac{83}{14} \Rightarrow \alpha = \frac{62}{7}$ $\frac{\beta + 4}{2} = \frac{32}{14} \Rightarrow \beta = \frac{4}{7}$ $\frac{\gamma + 9}{2} = \frac{51}{14} \Rightarrow \gamma = \frac{-12}{7}$ Ans. $14(\alpha + \beta + \gamma) = 108$

Question 16

Maths · Limits and Derivatives · Single correct

Let $f(x) = \begin{cases} x - 1, & \text{x is even} \\ 2x, & \text{x is odd} \end{cases} x \in \mathbb{N}$. If for some $a \in \mathbb{N}$, $f(f(f(a))) = 21$, then $\lim_{x \to a^-} \left\{ \frac{|x|^3}{a} - \left[\frac{x}{a}\right] \right\}$, where $[t]$ denotes the greatest integer less than or equal to $t$, is equal to:

  1. 121
  2. 144
  3. 169
  4. 225

Answer: (b)

Solution

Given $$f(x) = \begin{cases} x - 1; & x = even \\ 2x; & x = odd \end{cases}$$ $$f(f(f(a))) = 21$$ C-1: If $a = even$ $$f(a) = a - 1 = odd$$ $$f(f(a)) = 2(a - 1) = even$$ $$f(f(f(a))) = 2a - 3 = 21 \Rightarrow a = 12$$ C-2: If $a = odd$ $$f(a) = 2a = even$$ $$f(f(a)) = 2a - 1 = odd$$ $$f(f(f(a))) = 4a - 2 = 21 (Not possible)$$ Hence $a = 12$ Now $$\lim_{x \to 12^-} \left( \frac{|x|^3}{2} - \left[ \frac{x}{12} \right] \right)$$ $$= \lim_{x \to 12^-} \frac{|x|^3}{12} - \lim_{x \to 12^-} \left[ \frac{x}{12} \right]$$ $$= 144 - 0 = 144.$$

Question 17

Maths · Determinants · Single correct

Let the system of equations $x + 2y + 3z = 5$, $2x + 3y + z = 9$, $4x + 3y + \lambda z = \mu$ have infinite number of solutions. Then $\lambda + 2\mu$ is equal to:

  1. 28
  2. 17
  3. 22
  4. 15

Answer: (b)

Solution

Given the equations: $$x + 2y + 3z = 5$$ $$2x + 3y + z = 9$$ $$4x + 3y + \lambda z = \mu$$ For infinite solutions, the following must hold: $\Delta = \Delta_1 = \Delta_2 = \Delta_3 = 0$. The determinant $\Delta$ is: $$\begin{vmatrix} 1 & 2 & 3 \\ 2 & 3 & 1 \\ 4 & 3 & \lambda \end{vmatrix} = 0 \Rightarrow \lambda = -13$$ The determinant $\Delta_1$ is: $$\begin{vmatrix} 5 & 2 & 3 \\ 9 & 3 & 1 \\ \mu & 3 & -13 \end{vmatrix} = 0 \Rightarrow \mu = 15$$ The determinant $\Delta_2$ is: $$\begin{vmatrix} 1 & 5 & 3 \\ 2 & 9 & 1 \\ 4 & 15 & -13 \end{vmatrix} = 0$$ The determinant $\Delta_3$ is: $$\begin{vmatrix} 1 & 2 & 5 \\ 2 & 3 & 9 \\ 4 & 3 & 15 \end{vmatrix} = 0$$ For $\lambda = -13$, $\mu = 15$, the system of equations has infinite solutions. Hence $\lambda + 2\mu = 17$.

Question 18

Maths · Statistics · Single correct

Consider 10 observation $x_1, x_2, \ldots, x_{10}$ such that $\sum_{i=1}^{10} (x_i - \alpha) = 2$ and $\sum_{i=1}^{10} (x_i - \beta)^2 = 40$, where $\alpha, \beta$ are positive integers. Let the mean and the variance of the observations be $\frac{6}{5}$ and $\frac{84}{25}$ respectively. The $\frac{\beta}{\alpha}$ is equal to:

  1. 2
  2. $\frac{3}{2}$
  3. $\frac{5}{2}$
  4. 1

Answer: (a)

Solution

Given $x_1, x_2, \ldots, x_{10}$, we have $$\sum_{i=1}^{10} (x_i - \alpha) = 2 \Rightarrow \sum_{i=1}^{10} x_i - 10\alpha = 2$$ Therefore, the mean $\mu = \frac{6}{5} = \frac{\sum x_i}{10}$. Thus, $$\sum x_i = 12$$ $$10\alpha + 2 = 12 \Rightarrow \alpha = 1$$ Now, $$\sum_{i=1}^{10} (x_i - \beta)^2 = 40$$ Let $y_i = x_i - \beta$. Therefore, $$\sigma_y^2 = \frac{1}{10} \sum y_i^2 - (\bar{y})^2$$ $$\sigma_x^2 = \frac{1}{10} \sum (x_i - \beta)^2 - \left(\frac{\sum_{i=1}^{10} (x_i - \beta)}{10}\right)^2$$ $$\frac{84}{25} = 4 - \left(\frac{12 - 10\beta}{10}\right)^2$$ Therefore, $$\left(\frac{6 - 5\beta}{5}\right)^2 = 4 - \frac{84}{25} = \frac{16}{25}$$ $$6 - 5\beta = \pm 4 \Rightarrow \beta = \frac{2}{5} (not possible) or \beta = 2$$ Hence, $\frac{\beta}{\alpha} = 2$

Question 19

Maths · Probability · Single correct

Let Ajay will not appear in JEE exam with probability $p = \frac{2}{7}$, while both Ajay and Vijay will appear in the exam with probability $q = \frac{1}{5}$. Then the probability, that Ajay will appear in the exam and Vijay will not appear is :

  1. $\frac{9}{35}$
  2. $\frac{18}{35}$
  3. $\frac{24}{35}$
  4. $\frac{3}{35}$

Answer: (b)

Solution

Given $\overline{P(A)} = \frac{2}{7} = p$. $P(A \cap V) = \frac{1}{5} = q$. $P(A) = \frac{5}{7}$. Ans. $P(A \cap \overline{V}) = \frac{18}{35}$.

Question 20

Maths · Conic Sections · Single correct

Let the locus of the mid points of the chords of circle $x^2 + (y - 1)^2 = 1$ drawn from the origin intersect the line $x + y = 1$ at $P$ and $Q$. Then, the length of $PQ$ is:

  1. $\frac{1}{\sqrt{2}}$
  2. $\sqrt{2}$
  3. $\frac{1}{2}$
  4. 1

Answer: (a)

Solution

Given $mOM \cdot mCM = -1$. Therefore, $\($ $\frac{k}{h}$ $\cdot$ $\frac{k-1}{h}$ = -1 $\)$. Thus, the locus is $x^2 + y(y-1) = 0$. Simplifying, we get $x^2 + y^2 - y = 0$. For $p = \left| \frac{1/2}{\sqrt{2}} \right|$, we have $p = \frac{1}{2\sqrt{2}}$. The length $PQ = 2\sqrt{r^2 - p^2}$. Calculating, $PQ = 2\sqrt{\frac{1}{4} - \frac{1}{8}} = \frac{1}{\sqrt{2}}$.

Question 21

Maths · Sequences and Series · Numerical

If three successive terms of a G.P. with common ratio $r$ $(r > 1)$ are the lengths of the sides of a triangle and $[r]$ denotes the greatest integer less than or equal to $r$, then $3[r] + [-r]$ is equal to :

Answer: 1

Solution

Given $a,\ ar,\ ar^2$ forming a geometric progression. Sum of any two sides is greater than the third side: $a + ar > ar^2$,\quad $a + ar^2 > ar$,\quad $ar + ar^2 > a$ $r^2 - r - 1 0$ is always true. $r^2 + r - 1 > 0$ $$r \in \left(-\infty,\ \frac{-1-\sqrt{5}}{2}\right) \cup \left(\frac{-1+\sqrt{5}}{2},\ \infty\right) \hfill \ldots(2)$$ Taking the intersection of (1) and (2): $$r \in \left(\frac{-1+\sqrt{5}}{2},\ \frac{1+\sqrt{5}}{2}\right)$$ As $r > 1$: $$r \in \left(1,\ \frac{1+\sqrt{5}}{2}\right)$$ $[r] = 1$,\quad $[-r] = -2$ $3[r] + [-r] = 1$

Question 22

Maths · Matrices · Numerical

Let $A = I_2 - MM^T$, where $M$ is real matrix of order 2 $\times$ 1 such that the relation $M^TM=I_1$ holds. If $\lambda$ is a real number such that the relation $AX=\lambda X$ holds for some non-zero real matrix $X$ of order 2 $\times$ 1, then the sum of squares of all possible values of $\lambda$ is equal to :

Answer: 2

Solution

Given $A = I_2 - 2MM^T$. $$A^2 = \left(I_2 - 2MM^T\right) \left(I_2 - 2MM^T\right)$$ $$= I_2 - 2MM^T - 2MM^T + 4MM^TM^T$$ $$= I_2 - 4MM^T + 4MM^T$$ $$= I_2$$ $AX = \lambda X$ $A^2X = \lambda AX$ $X = \lambda (\lambda X)$ $X = \lambda^2 X$ $X (\lambda^2 - 1) = 0$ $\lambda^2 = 1$ $\lambda = \pm 1$ Sum of square of all possible values $= 2$

Question 23

Maths · Applications of Integrals · Numerical

Let $f : (0, \infty) \to R$ and $F(x) = \int_0^x t f(t) dt$. If $F \left(x^2\right) = x^4 + x^5$, then $\sum_{r=1}^{12} f \left(r^2\right)$ is equal to :

Answer: 219

Solution

Given $F^1(x) = x f(x)$ and $F(x^2) = x^4 + x^5$, let $x^2 = t$. Then $F(t) = t^2 + t^{5/2}$. Differentiating, we have $F'(t) = 2t + \frac{5}{2}t^{3/2}$. Therefore, $t \cdot f(t) = 2t + \frac{5}{2}t^{3/2}$, which implies $f(t) = 2 + \frac{5}{2}r^{1/2}$. Now, we calculate the sum: $$\sum_{r=1}^{12} f(r^2) = \sum_{r=1}^{12} \left(2 + \frac{5}{2}r\right)$$ $$= 24 + \frac{5}{2} \left[ \frac{12(13)}{2} \right]$$ $$= 219$$

Question 24

Maths · Continuity and Differentiability · Numerical

If $y = \frac{(\sqrt{x}+1)(x^2-\sqrt{x})}{x\sqrt{x}+x+\sqrt{x}} + \frac{1}{15}\left(3\cos^2 x - 5\right)\cos^3 x$, then $96y'\left(\frac{\pi}{6}\right)$ is equal to :

Answer: 105

Solution

Given $$y = \frac{(\sqrt{x} + 1) \left( x^2 - \sqrt{x} \right)}{x \sqrt{x} + x + \sqrt{x}} + \frac{1}{15} \left( 3 \cos^2 x - 5 \right) \cos^3 x$$ Simplifying, we have $$y = \frac{(\sqrt{x} + 1)(\sqrt{x}) \left( (\sqrt{x})^3 - 1 \right)}{(\sqrt{x}) \left( (\sqrt{x})^2 + (\sqrt{x}) + 1 \right)} + \frac{1}{5} \cos^5 x - \frac{1}{3} \cos^3 x$$ Further simplifying, $$y = (\sqrt{x} + 1)(\sqrt{x} - 1) + \frac{1}{5} \cos^5 x - \frac{1}{3} \cos^3 x$$ Differentiating, $$y' = 1 - \cos^4 x \cdot (\sin x) + \cos^2 x (\sin x)$$ Evaluating at $x = \frac{\pi}{6}$, $$y' \left( \frac{\pi}{6} \right) = 1 - \frac{9}{16} \times \frac{1}{2} + \frac{3}{4} \times \frac{1}{2}$$ Simplifying, $$= \frac{32 - 9 + 12}{32} = \frac{35}{32}$$ Finally, $$= 96 y' \left( \frac{\pi}{6} \right) = 105$$

Question 25

Maths · Vector Algebra · Numerical

Let $\vec{a} = \hat{i} + \hat{j} + \hat{k}$, $\vec{b} = -\hat{i} - 8\hat{j} + 2\hat{k}$ and $\vec{c} = 4\hat{i} + c_2\hat{j} + c_3\hat{k}$ be three vectors such that $\vec{b} \times \vec{a} = \vec{c} \times \vec{a}$. If the angle between the vector $\vec{c}$ and the vector $3\hat{i} + 4\hat{j} + \hat{k}$ is $\theta$, then the greatest integer less than or equal to $\tan^2 \theta$ is :

Answer: 38

Solution

Given $\vec{a} = \hat{i} + \hat{j} + \hat{k}$, $\vec{b} = \hat{i} + 8\hat{j} + 2\hat{k}$, and $\vec{c} = 4\hat{i} + c_2\hat{j} + c_3\hat{k}$. We know $\vec{b} \times \vec{a} = \vec{c} \times \vec{a}$. Therefore, $\left( \vec{b} - \vec{c} \right) \times \vec{a} = 0$. This implies $\vec{b} - \vec{c} = \lambda \vec{\alpha}$, where $\vec{b} = \vec{c} + \lambda \vec{\alpha}$. Substituting, $-\hat{i} - 8\hat{j} + 2\hat{k} = \left( 4\hat{i} + c_2\hat{j} + c_3\hat{k} \right) + \lambda (\hat{i} + \hat{j} + \hat{k})$. Solving, $\lambda + 4 = -1 \Rightarrow \lambda = -5$. $\lambda + c_2 = -8 \Rightarrow c_2 = -3$. $\lambda + c_3 = 2 \Rightarrow c_3 = 7$. Thus, $\vec{c} = 4\hat{i} - 3\hat{j} + 7\hat{k}$. Now, $\cos \theta = \frac{12 - 12 + 7}{\sqrt{26} \cdot \sqrt{74}} = \frac{7}{\sqrt{26} \cdot \sqrt{74}} = \frac{7}{2\sqrt{481}}$. $\tan^2 \theta = \frac{625 \times 3}{49}$. Therefore, $[\tan^2 \theta] = 38$.

Question 26

Maths · Straight Lines and Pair of Straight Lines · Numerical

The lines $L_1$, $L_2$, $\ldots$, $L_{20}$ are distinct. For $n = 1, 2, 3, \ldots, 10$ all the lines $L_{2n-1}$ are parallel to each other and all the lines $L_{2n}$ pass through a given point $P$. The maximum number of points of intersection of pairs of lines from the set $\{L_1, L_2, \ldots, L_{20}\}$ is equal to :

Answer: 101

Solution

Given $L_1$, $L_3$, $L_5$, $-$ $L_{19}$ are parallel. $L_2$, $L_4$, $L_6$, $-$ $L_{20}$ are concurrent. Total points of intersection are calculated as follows: $$\binom{20}{2} - \binom{10}{2} - \binom{10}{2} + 1$$ which equals 101.

Question 27

Maths · Applications of Integrals · Numerical

Three points $O(0, 0)$, $P \left(a, a^2\right)$, $Q \left(-b, b^2\right)$, $a > 0$, $b > 0$, are on the parabola $y = x^2$. Let $S_1$ be the area of the region bounded by the line $PQ$ and the parabola, and $S_2$ be the area of the triangle $OPQ$. If the minimum value of $\frac{S_1}{S_2}$ is $\frac{m}{n}$, $\gcd(m, n) = 1$, then $m + n$ is equal to:

Answer: 7

Solution

Given the points $P(a, a^2)$ and $Q(-b, b^2)$, the area $S_2$ is given by the determinant: $$S_2 = \frac{1}{2} \left| \begin{array}{ccc} 0 & 0 & 1 \\ a & a^2 & 1 \\ -b & b^2 & 1 \end{array} \right| = \frac{1}{2}(ab^2 + a^2b).$$ The line $PQ$ has the equation: $$PQ: -y - a^2 = \frac{a^2 - b^2}{a + b}(x - a).$$ Simplifying, we have: $$y - a^2 = (a - b)x - (a - b)a$$ $$y = (a - b)x + ab.$$ The area $S_1$ is: $$S_1 = \int_{-b}^{a} ((a - b)x + ab - x^2) \, dx$$ Evaluating the integral: $$= (a - b) \frac{x^2}{2} + (ab)x - \frac{x^3}{3} \bigg|_{-b}^{a}$$ $$= \frac{(a-b)^2(a+b)}{2} + ab(a + b) - \frac{(a^3+b^3)}{3}.$$ The ratio $\frac{S_1}{S_2}$ is: $$\frac{S_1}{S_2} = \frac{(a-b)^2(a+b)}{2} + ab(a+b) - \frac{(a^3+b^3)}{3} \cdot \frac{2}{ab^2 + a^2b}$$ $$= \frac{3(a-b)^2 + 6ab - 2(a^2+b^2-ab)}{3ab}$$ $$= \frac{1}{3} \left[ a + \frac{b}{a} + 2 \right].$$ Given $\frac{4}{3} = \frac{m}{n}$, we find $m + n = 7.$

Question 28

Maths · Applications of Integrals · Numerical

The sum of squares of all possible values of $k$, for which area of the region bounded by the parabolas $$2y^2 = kx$$ and $$ky^2 = 2(y-x)$$ is maximum, is equal to :

Answer: 8

Solution

Given $ky^2 = 2(y-x)$ and $2y^2 = kx$. Point of intersection leads to $$ky^2 = \left( \frac{y - 2y^2}{k} \right)$$ For $y = 0$, $ky = 2 \left( 1 - \frac{2y}{k} \right)$. Solving $ky + \frac{4y}{k} = 2$, we find $y = \frac{2}{k+\frac{4}{k}} = \frac{2k}{k^2 + 4}$. The area $A$ is given by $$A = \int_0^{\frac{2k}{k^2+4}} \left( \left( y - \frac{ky^2}{2} \right) - \left( \frac{2y^2}{k} \right) \right) \cdot dy$$ This simplifies to $$= \frac{y^2}{2} - \left( \frac{k}{2} + \frac{2}{k} \right) \cdot \frac{y^3}{3} \bigg|_0^{\frac{2k}{k^2+4}}$$ Evaluating the integral, we have $$= \left( \frac{2k}{k^2+4} \right)^2 \left[ \frac{1}{2} - \frac{k^2 + 4}{2k} \times \frac{1}{3} \times \frac{2k}{k^2+4} \right]$$ This results in $$= \frac{1}{6} \times 4 \times \left( \frac{1}{2} \cdot \frac{k + \frac{4}{k}}{2} \right) \geq 2$$ Thus, $k + \frac{4}{k} \geq 4$. The area is maximum when $k = \frac{4}{k}$. Solving gives $k = 2, -2$.

Question 29

Maths · Differential Equations · Numerical

If $\frac{dx}{dy} = \frac{1+x-y^2}{y}$, $x(1) = 1$, then $5x(2)$ is equal to:

Answer: 5

Solution

$\dfrac{dx}{dy}-\dfrac{x}{y}=\dfrac{1-y^2}{y}$ Integrating factor $=e^{\int -\frac{1}{y}\,dy}$ $=\dfrac{1}{y}$ $\dfrac{x}{y}=\int \dfrac{1-y^2}{y^2}\,dy$ $\dfrac{x}{y}=-\dfrac{1}{y}-y+c$ $x=-1-y^2+cy$ $x(1)=1$ $1=-1-1+c \Rightarrow c=3$ $x=-1-y^2+3y$ $5x(2)=5(-1-4+6)$ $=5$

Question 30

Maths · Straight Lines and Pair of Straight Lines · Numerical

Let $ABC$ be an isosceles triangle in which $A$ is at $(-1, 0)$, $\angle A = \frac{2\pi}{3}$, $AB = AC$ and $B$ is on the positive $x$-axis. If $BC = 4\sqrt{3}$ and the line $BC$ intersects the line $y = x + 3$ at $(\alpha, \beta)$, then $\frac{\beta^4}{\alpha^2}$ is :

Answer: 36

Solution

Using the sine rule, we have $\($ $\frac{c}{\sin 30^\circ}$ = $\frac{4\sqrt{3}}{\sin 120^\circ}$ $\)$. Solving for $\($ c $\)$, we get $\($ 2c = 8 $\Rightarrow$ c = 4 $\)$. The length $\($ AB = |(b + 1)| = 4 $\)$. Given $\($ b = 3 $\)$, the slope $\($ m_{AB} = 0 $\)$. The slope $\($ m_{BC} = $\frac{-1}{\sqrt{3}}$ $\)$. For line $\($ BC $\)$, we have $\($ -y = $\frac{-1}{\sqrt{3}}$(x - 3) $\)$ which simplifies to $\($ $\sqrt{3}$y + x = 3 $\)$. The point of intersection is given by the equations $\($ y = x + 3 $\)$ and $\($ $\sqrt{3}$y + x = 3 $\)$. Solving these, $\($ ($\sqrt{3}$ + 1)y = 6 $\)$ gives $\($ y = $\frac{6}{\sqrt{3} + 1}$ $\)$. For $\($ x $\)$, $\($ x = $\frac{6}{\sqrt{3} + 1}$ - 3 = $\frac{6 - 3\sqrt{3} - 3}{\sqrt{3} + 1}$ = 3$\left$($\frac{1 - \sqrt{3}}{1 + \sqrt{3}}$$\right$) = $\frac{-6}{(1 + \sqrt{3})^2}$ $\)$. Finally, $\($ $\frac{\beta^4}{\alpha^2}$ = 36 $\)$.

Physics

Question 31

Physics · Current Electricity · Single correct

In an ammeter, 5$\%$ of the main current passes through the galvanometer. If resistance of the galvanometer is $G$, the resistance of ammeter will be :

  1. $\frac{G}{20}$
  2. $\frac{G}{199}$
  3. $199G$
  4. $200G$

Answer: (a)

Solution

Given the circuit, we have the equation $I_S S = I_g G$. Substituting the given values, we get $$\frac{95}{100} I S = \frac{5I}{100} G.$$ Solving for $S$, we find $$S = \frac{G}{19}.$$ The resistance $R_A$ is given by $$R_A = \frac{S G}{S + G} = \frac{\frac{G^2}{19}}{\frac{20G}{19}}.$$ Simplifying, we get $$R_A = \frac{G}{20}.$$

Question 32

Physics · Current Electricity · Single correct

To measure the temperature coefficient of resistivity $\alpha$ of a semiconductor, an electrical arrangement shown in the figure is prepared. The arm BC is made up of the semiconductor. The experiment is being conducted at $25^\circ \mathrm{C}$ and resistance of the semiconductor arm is $3 \, \mathrm{m}\Omega$. Arm BC is cooled at a constant rate of $2^\circ \mathrm{C/s}$. If the galvanometer $G$ shows no deflection after $10 \, \mathrm{s}$, then $\alpha$ is:

  1. $-2 \times 10^{-2} \, \mathrm{C}^{-1}$
  2. $-1.5 \times 10^{-2} \, \mathrm{C}^{-1}$
  3. $-1 \times 10^{-2} \, \mathrm{C}^{-1}$
  4. $-2.5 \times 10^{-2} \, \mathrm{C}^{-1}$

Answer: (c)

Solution

For no deflection $\frac{0.8}{1} = \frac{R}{3}$. Therefore, $R = 2.4 \, \mathrm{m\Omega}$. Temperature fall in 10 s $= 20^\circ \mathrm{C}$. $$\Delta R = R \alpha \Delta t$$ $$\alpha = \frac{\Delta R}{R \Delta t} = \frac{-0.6}{3 \times 20}$$ $$= -10^{-2} \, \mathrm{C^{-1}}$$

Question 33

Physics · Nuclei · Single correct

From the statements given below : (A) The angular momentum of an electron in $n^{th}$ orbit is an integral multiple of $h$. (B) Nuclear forces do not obey inverse square law. (C) Nuclear forces are spin dependent. (D) Nuclear forces are central and charge independent. (E) Stability of nucleus is inversely proportional to the value of packing fraction. Choose the correct answer from the options given below :

  1. , (B), (C), (D) only
  2. , (C), (D), (E) only
  3. , (B), (C), (E) only
  4. , (C), (D), (E) only

Answer: (c)

Solution

Part of Theory

Question 34

Physics · Thermodynamics · Single correct

A diatomic gas ($\gamma = 1.4$) does 200 J of work when it is expanded isobarically. The heat given to the gas in the process is:

  1. 850 J
  2. 800 J
  3. 600 J
  4. 700 J

Answer: (d)

Solution

Given $\gamma = 1 + \frac{2}{f} = 1.4 \Rightarrow \frac{2}{f} = 0.4$. Therefore, $f = 5$. The work done $W = nR\Delta T = 200 \, \mathrm{J}$. The heat $Q$ is given by $$Q = \left(\frac{f + 2}{2}\right) nR\Delta T$$ $$= \frac{7}{2} \times 200 = 700 \, \mathrm{J}$$

Question 35

Physics · System of Particles and Rotational Motion · Single correct

A disc of radius $R$ and mass $M$ is rolling horizontally without slipping with speed $v$. It then moves up an inclined smooth surface as shown in figure. The maximum height that the disc can go up the incline is :

  1. $\frac{v^2}{g}$
  2. $\frac{3}{4} \frac{v^2}{g}$
  3. $\frac{1}{2} \frac{v^2}{g}$
  4. $\frac{2}{3} \frac{v^2}{g}$

Answer: (c)

Solution

Only the translational kinetic energy of the disc changes into gravitational potential energy. And rotational KE remains unchanged as there is no friction. $$\frac{1}{2}mv^2 = mgh$$ $$h = \frac{v^2}{2g}$$

Question 36

Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct

Conductivity of a photodiode starts changing only if the wavelength of incident light is less than 660 nm. The band gap of photodiode is found to be $\left( \frac{X}{8} \right)$ eV. The value of X is ; (Given, $h = 6.6 \times 10^{-34}$ Js, $e = 1.6 \times 10^{-19}$ C)

  1. 15
  2. 11
  3. 13
  4. 21

Answer: (a)

Solution

Given $E_g = \frac{hc}{\lambda} = \frac{6.6 \times 10^{-34} \times 3 \times 10^8}{660 \times 10^{-9}} J$. $$= \frac{6.6 \times 10^{-34} \times 3 \times 10^8}{660 \times 10^{-9} \times 1.6 \times 10^{-19}} eV$$ $$= \frac{15}{8} eV$$ So $x = 15$

Question 37

Physics · Mechanical Properties of Fluids · Single correct

A big drop is formed by coalescing 1000 small droplets of water. The surface energy will become:

  1. 100 times
  2. 10 times
  3. $\frac{1}{100}$th
  4. $\frac{1}{10}$th

Answer: (d)

Solution

Let's say the radius of small droplets is $r$ and that of the big drop is $R$. $$\frac{4}{3} \pi R^3 = 1000 \frac{4}{3} \pi r^3$$ $$R = 10r$$ $$U_i = 1000 \left(4 \pi r^2 S\right)$$ $$U_f = 4 \pi R^2 S$$ $$= 100 \left(4 \pi r^2 S\right)$$ $$U_f = \frac{1}{10} U_i$$

Question 38

Physics · Electromagnetic Waves · Single correct

If frequency of electromagnetic wave is $60 \, \mathrm{MHz}$ and it travels in air along $z$ direction then the corresponding electric and magnetic field vectors will be mutually perpendicular to each other and the wavelength of the wave (in m) is:

  1. 2.5
  2. 10
  3. 5
  4. 2

Answer: (c)

Solution

Given the formula for wavelength, we have: $$\lambda = \frac{c}{f} = \frac{3 \times 10^8}{60 \times 10^6} = 5 \, \mathrm{m}$$

Question 39

Physics · Laws of Motion · Single correct

A cricket player catches a ball of mass $120 \, \mathrm{g}$ moving with $25 \, \mathrm{m/s}$ speed. If the catching process is completed in $0.1 \, \mathrm{s}$ then the magnitude of force exerted by the ball on the hand of player will be (in SI unit):

  1. 24
  2. 12
  3. 25
  4. 30

Answer: (d)

Solution

The average force is given by the change in momentum over the change in time. $$F_{av} = \frac{\Delta p}{\Delta t}$$ Substituting the given values: $$= \frac{0.12 \times 25}{0.1} = 30 \, \mathrm{N}$$

Question 40

Physics · Dual Nature of Radiation and Matter · Single correct

Monochromatic light of frequency $6 \times 10^{14} \, \mathrm{Hz}$ is produced by a laser. The power emitted is $2 \times 10^{-3} \, \mathrm{W}$. How many photons per second on an average, are emitted by the source? (Given $h = 6.63 \times 10^{-34} \, \mathrm{Js}$)

  1. $9 \times 10^{18}$
  2. $6 \times 10^{15}$
  3. $5 \times 10^{15}$
  4. $7 \times 10^{16}$

Answer: (c)

Solution

Given $P = nh\nu$. $$n = \frac{P}{h\nu} = \frac{2 \times 10^{-3}}{6.63 \times 10^{-34} \times 6 \times 10^{14}}$$ $$= 5 \times 10^{15}$$

Question 41

Physics · Wave Optics · Single correct

A microwave of wavelength 2.0 $\mathrm{\ cm}$ falls normally on a slit of width 4.0 $\mathrm{\ cm}$. The angular spread of the central maxima of the diffraction pattern obtained on a screen 1.5 $\mathrm{\ m}$ away from the slit, will be:

  1. $30^\circ$
  2. $15^\circ$
  3. $60^\circ$
  4. $45^\circ$

Answer: (c)

Solution

For first minima $a \sin \theta = \lambda$ $$\sin \theta = \frac{\lambda}{a} = \frac{1}{2}$$ $$\theta = 30^\circ$$ Angular spread $= 60^\circ$

Question 42

Physics · Electric Charges and Fields · Single correct

$C_1$ and $C_2$ are two hollow concentric cubes enclosing charges 2Q and 3Q respectively as shown in figure. The ratio of electric flux passing through $C_1$ and $C_2$ is$:$

  1. 2 : 5
  2. 5 : 2
  3. 2 : 3
  4. 3 : 2

Answer: (a)

Solution

Given $\($ $\phi$_{smaller cube} = $\frac{2Q}{\epsilon_0}$ $\)$ and $\($ $\phi$_{bigger cube} = $\frac{5Q}{\epsilon_0}$ $\)$. Therefore, $\($ $\frac{\phi_{smaller cube}}{\phi_{bigger cube}}$ = $\frac{2}{5}$ $\)$.

Question 43

Physics · Kinetic Theory · Single correct

If the root mean square velocity of hydrogen molecule at a given temperature and pressure is $2 \, \mathrm{km/s}$, the root mean square velocity of oxygen at the same condition in $\mathrm{km/s}$ is :

  1. 2.0
  2. 0.5
  3. 1.5
  4. 1.0

Answer: (b)

Solution

The root mean square velocity $V_{rms}$ is given by $$V_{rms} = \sqrt{\frac{3RT}{M}}.$$ The ratio of velocities is $$\frac{V_1}{V_2} = \sqrt{\frac{M_2}{M_1}} \Rightarrow \frac{2}{V_2} = \sqrt{\frac{32}{2}}.$$ Solving for $V_2$, we find $$V_2 = 0.5 \, km/s.$$

Question 44

Physics · Motion in a Straight Line · Single correct

Train A is moving along two parallel rail tracks towards north with speed $72 \, \mathrm{km/h}$ and train B is moving towards south with speed $108 \, \mathrm{km/h}$. Velocity of train B with respect to A and velocity of ground with respect to B are (in $\mathrm{ms^{-1}}$):

  1. -30 and 50
  2. -50 and -30
  3. -50 and 30
  4. 50 and -30

Answer: (c)

Solution

Given $V_A = 20 \, \mathrm{m/s}$ and $V_B = -30 \, \mathrm{m/s}$. Velocity of B with respect to A is given by $$V_{B/A} = -50 \, \mathrm{m/s}$$ Velocity of ground with respect to B is $$V_{G/B} = 30 \, \mathrm{m/s}$$

Question 45

Physics · Electrostatic Potential and Capacitance · Single correct

A galvanometer (G) of $2\,\Omega$ resistance is connected in the given circuit. The ratio of charge stored in $C_1$ and $C_2$ is:

  1. $\frac{2}{3}$
  2. $\frac{3}{2}$
  3. 1
  4. $\frac{1}{2}$

Answer: (d)

Solution

In steady state, Req = 12$\,$ $\Omega$. I = $\frac{6}{12}$ = 0.5$\,$ A. P.D across C_1 = 3$\,$ V. P.D across C_2 = 4$\,$ V. q_1 = C_1 V_1 = 12$\,$ $\muC$. q_2 = C_2 V_2 = 24$\,$ $\muC$. $\frac{q_1}{q_2}$ = $\frac{1}{2}$.

Question 46

Physics · Current Electricity · Single correct

In a metre-bridge when a resistance in the left gap is $2\,\Omega$ and unknown resistance in the right gap, the balance length is found to be $40\,\mathrm{cm}$. On shunting the unknown resistance with $2\,\Omega$, the balance length changes by:

  1. $22.5\,\mathrm{cm}$
  2. $20\,\mathrm{cm}$
  3. $62.5\,\mathrm{cm}$
  4. $65\,\mathrm{cm}$

Answer: (a)

Solution

First case $\frac{2}{40} = \frac{X}{60} \implies X = 3\, \Omega$. In second case $X' = \frac{2 \times 3}{2 + 3} = 1.2\, \Omega$. $$\frac{2}{\ell} = \frac{1.2}{100 - \ell}$$ $$200 - 2\ell = 1.2\ell$$ $$\ell = \frac{200}{3.2} = 62.5\, cm$$ Balance length changes by $22.5\, cm$.

Question 47

Physics · Physical World, Units and Measurements · Single correct

Match List - I with List - II. \begin{tabular}{ll} \textbf{List - I} & \textbf{List - II} \\ \text{(Number)} & \text{(Significant figure)} \\ \text{(A) 1001} & \text{(I) 3} \\ \text{(B) 010.1} & \text{(II) 4} \\ \text{(C) 100.100} & \text{(III) 5} \\ \text{(D) 0.0010010} & \text{(IV) 6} \\ \end{tabular} Choose the correct answer from the options given below:

  1. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
  2. (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
  3. (A)-(II), (B)-(I), (C)-(IV), (D)-(III)
  4. (A)-(I), (B)-(II), (C)-(III), (D)-(IV)

Answer: (c)

Solution

Theoretical

Question 48

Physics · Alternating Current · Single correct

A transformer has an efficiency of 80$\%$ and works at 10 $\,$ $\mathrm{V}$ and 4 $\,$ $\mathrm{kW}$. If the secondary voltage is 240 $\,$ $\mathrm{V}$, then the current in the secondary coil is :

  1. $1.59\,\mathrm{A}$
  2. $13.33\,\mathrm{A}$
  3. $1.33\,\mathrm{A}$
  4. $15.1\,\mathrm{A}$

Answer: (b)

Solution

Efficiency is given by $$\frac{E_s I_s}{E_p I_p}$$. Given $$0.8 = \frac{240 I_s}{4000}$$, we have $$3200 = 240 I_s$$. Solving for $I_s$, we get $$I_s = \frac{3200}{240} = 13.33 \, \mathrm{A}$$.

Question 49

Physics · Gravitation · Single correct

A light planet is revolving around a massive star in a circular orbit of radius $R$ with a period of revolution $T$. If the force of attraction between planet and star is proportional to $R^{-3/2}$ then choose the correct option:

  1. $T^2 \propto R^{5/2}$
  2. $T^2 \propto R^{7/2}$
  3. $T^2 \propto R^{3/2}$
  4. $T^2 \propto R^3$

Answer: (a)

Solution

Given the equation for force, $$F = \frac{GMm}{R^{3/2}} = m\omega^2 R$$. We have $$\omega^2 \propto \frac{1}{R^{5/2}}$$, therefore, $$T = \frac{2\pi}{\omega}$$ so $$T^2 \propto R^{5/2}$$.

Question 50

Physics · Laws of Motion · Single correct

A body of mass 4 kg experiences two forces $\vec{F}_1 = 5\hat{i} + 8\hat{j} + 7\hat{k}$ and $\vec{F}_2 = 3\hat{i} - 4\hat{j} - 3\hat{k}$. The acceleration acting on the body is :

  1. $-2\hat{i} - \hat{j} - \hat{k}$
  2. $4\hat{i} + 2\hat{j} + 2\hat{k}$
  3. $2\hat{i} + \hat{j} + \hat{k}$
  4. $2\hat{i} + 3\hat{j} + 3\hat{k}$

Answer: (c)

Solution

Net force $= 8\hat{i} + 4\hat{j} + 4\hat{k}$ $$\vec{a} = \frac{\vec{F}}{m} = 2\hat{i} + \hat{j} + \hat{k}$$

Question 51

Physics · Oscillations · Numerical

A mass $m$ is suspended from a spring of negligible mass and the system oscillates with a frequency $f_1$. The frequency of oscillations if a mass $9m$ is suspended from the same spring is $f_2$. The value of $\frac{f_1}{f_2}$ is _____.

Answer: 3

Solution

Given the equations for $f_1$ and $f_2$: $$f_1 = \frac{1}{2\pi} \sqrt{\frac{k}{m}}$$ $$f_2 = \frac{1}{2\pi} \sqrt{\frac{k}{9m}}$$ We find the ratio: $$\frac{f_1}{f_2} = \sqrt{\frac{9}{1}} = \frac{3}{1}$$

Question 52

Physics · Motion in a Straight Line · Numerical

A particle initially at rest starts moving from reference point. $x = 0$ along x-axis, with velocity $v$ that varies as $v = 4\sqrt{x} \, \mathrm{m/s}$. The acceleration of the particle is _____ $\mathrm{ms^{-2}}$.

Answer: 8

Solution

Given $V = 4\sqrt{x}$. Acceleration $a$ is given by $a = V \frac{dv}{dx}$. Substituting the values, we have: $$a = 4\sqrt{x} \times 4 \times \frac{1}{2} x^{-1/2} = 8 \, \mathrm{m/s^2}$$

Question 53

Physics · Moving Charges and Magnetism · Numerical

A moving coil galvanometer has 100 turns and each turn has an area of 2.0 $\mathrm{cm}^2$. The magnetic field produced by the magnet is 0.01 $\mathrm{T}$ and the deflection in the coil is 0.05 $\mathrm{radian}$ when a current of 10 $\mathrm{mA}$ is passed through it. The torsional constant of the suspension wire is $x \times 10^{-5}$ $\mathrm{N} - \mathrm{m/rad}$. The value of $x$ is _____

Answer: 4

Solution

Given $\tau = \mathrm{BINA} \sin \theta$. $C \theta = \mathrm{BINA} \sin 90^\circ$. $C = \frac{\mathrm{BINA}}{\theta} = \frac{0.01 \times 10 \times 10^{-3} \times 100 \times 2 \times 10^{-4}}{0.05} = 4 \times 10^{-5} \, \mathrm{N} - \mathrm{m/rad}$. $x = 4$

Question 54

Physics · Mechanical Properties of Solids · Numerical

One end of a metal wire is fixed to a ceiling and a load of 2 $\mathrm{kg}$ hangs from the other end. A similar wire is attached to the bottom of the load and another load of 1 $\mathrm{kg}$ hangs from this lower wire. Then the ratio of longitudinal strain of upper wire to that of the lower wire will be _____ [Area of cross section of wire = $0.005 \, \mathrm{cm^2}$, $Y = 2 \times 10^{11} \, \mathrm{Nm^{-2}}$ and $g = 10 \, \mathrm{ms^{-2}}$]

Answer: 3

Solution

The change in length $\Delta L$ is given by the formula: $$\Delta L = \frac{FL}{AY}$$ where $F$ is the force, $L$ is the original length, $A$ is the cross-sectional area, and $Y$ is Young's modulus. The ratio of change in length to the original length is: $$\frac{\Delta L}{L} = \frac{F}{AY}$$ For two different forces $F_1$ and $F_2$, the ratio of their changes in length is: $$\frac{\Delta L_1}{L_1} \Big/ \frac{\Delta L_2}{L_2} = \frac{F_1}{F_2} = \frac{30}{10} = 3$$

Question 55

Physics · Atoms · Numerical

A particular hydrogen - like ion emits the radiation of frequency $3 \times 10^{15} \, \mathrm{Hz}$ when it makes transition from $n = 2$ to $n = 1$. The frequency of radiation emitted in transition from $n = 3$ to $n = 1$ is $\frac{x}{9} \times 10^{15} \, \mathrm{Hz}$, when x =

Answer: 32

Solution

Given the energy equation: $$E = -13.6 z^2 \left( \frac{1}{n_i^2} - \frac{1}{n_f^2} \right)$$ We have $$E = C \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right)$$ Thus, $$h\nu = C \left[ \frac{1}{n_f^2} - \frac{1}{n_i^2} \right]$$ The ratio of frequencies is given by: $$\frac{\nu_1}{\nu_2} = \frac{\left[ \frac{1}{n_f^2} - \frac{1}{n_i^2} \right]_{2 \to 1}}{\left[ \frac{1}{n_f^2} - \frac{1}{n_i^2} \right]_{3 \to 1}}$$ Substituting the values, we get: $$= \frac{\left[ \frac{1}{1} - \frac{1}{4} \right]}{\left[ \frac{1}{1} - \frac{1}{9} \right]} = \frac{3/4}{8/9}$$ Simplifying further: $$= \frac{3}{4} \times \frac{9}{8}$$ Thus, $$\frac{\nu_1}{\nu_2} = \frac{27}{32}$$ Therefore, $$\nu_2 = \frac{32}{27} \nu_1 = \frac{32}{27} \times 3 \times 10^{15} \, \mathrm{Hz} = \frac{32}{9} \times 10^{15} \, \mathrm{Hz}$$

Question 56

Physics · Electrostatic Potential and Capacitance · Fill in the blank

In an electrical circuit drawn below the amount of charge stored in the capacitor is _____ $\mu C$.

Answer: 60

Solution

In steady state there will be no current in branch of capacitor, so no voltage drop across $R_2 = 5 \Omega$. $I_2 = 0$ $I_1 = I_3 = \frac{10}{4 + 6} = 1 \, \mathrm{A}$ $V_{R_3} = V_c + V_{R_2}$, $V_{R_2} = 0$ $I_3 R_3 = V_c$ $V_c = 1 \times 6 = 6 \, \mathrm{volt}$ $q_c = CV_c = 10 \times 6 = 60 \, \mu \mathrm{C}$

Question 57

Physics · Electromagnetic Induction · Numerical

A coil of 200 turns and area 0.20 $\mathrm{m^2}$ is rotated at half a revolution per second and is placed in uniform magnetic field of 0.01 $\mathrm{T}$ perpendicular to axis of rotation of the coil. The maximum voltage generated in the coil is $\frac{2\pi}{\beta}$ volt. The value of $\beta$ is _____.

Answer: 5

Solution

Given $\phi = NAB \cos(\omega t)$. The electromotive force $\varepsilon$ is given by $$\varepsilon = -\frac{d\phi}{dt} = NAB \omega \sin(\omega t).$$ The maximum electromotive force $\varepsilon_{max}$ is $$\varepsilon_{max} = NAB \omega$$ $$= 200 \times 0.2 \times 0.01 \times \pi$$ $$= \frac{4\pi}{10} = \frac{2\pi}{5} volt.$$

Question 58

Physics · Wave Optics · Numerical

In Young's double slit experiment, monochromatic light of wavelength $5000\,\mathrm{\AA}$ is used. The slits are $1.0\,\mathrm{mm}$ apart and screen is placed at $1.0\,\mathrm{m}$ away from slits. The distance from the centre of the screen where intensity becomes half of the maximum intensity for the first time is _______$\times 10^{-6}\,\mathrm{m}$.

Answer: 125

Solution

Let intensity of light on screen due to each slit is $I_0$. So intensity at centre of screen is $4I_0$. Intensity at distance $y$ from centre: $$I = I_0 + I_0 + 2\sqrt{I_0 I_0} \cos \phi$$ $$I_{max} = 4I_0$$ $$\frac{I_{max}}{2} = 2I_0 = 2I_0 + 2I_0 \cos \phi$$ $$\cos \phi = 0$$ $$\phi = \frac{\pi}{2}$$ $$K \Delta x = \frac{\pi}{2}$$ $$\frac{2\pi}{\lambda} d \sin \theta = \frac{\pi}{2}$$ $$\frac{2}{\lambda} d \times \frac{y}{D} = \frac{1}{2}$$ $$y = \frac{\lambda D}{4d} = \frac{5 \times 10^{-7} \times 1}{4 \times 10^{-3}}$$ $$= 125 \times 10^{-6}$$ $$= 125$$

Question 59

Physics · System of Particles and Rotational Motion · Numerical

A uniform rod $AB$ of mass $2 \, \mathrm{kg}$ and Length $30 \, \mathrm{cm}$ at rest on a smooth horizontal surface. An impulse of force $0.2 \, \mathrm{Ns}$ is applied to end $B$. The time taken by the rod to turn through at right angles will be $\frac{\pi}{x} \, \mathrm{s}$, where $x =$ ______

Answer: 4

Solution

Impulse $J = 0.2 \, \mathrm{N} - \mathrm{S}$ $J = \int F \, dt = 0.2 \, \mathrm{N} - \mathrm{s}$ Angular impulse $\vec{M}$ $$\vec{M}_c = \int \tau \, dt$$ $$= \int F \frac{L}{2} \, dt$$ $$= \frac{L}{2} \int F \, dt = \frac{L}{2} \times J$$ $$= \frac{0.3}{2} \times 0.2$$ $$= 0.03$$ $$I_{cm} = \frac{L^2}{12} = \frac{2 \times (0.3)^2}{12} = \frac{0.09}{6}$$ $$M = I_{cm} (\omega_f - \omega_i)$$ $$0.03 = \frac{0.09}{6} (\omega_f)$$ $$\omega_f = 2 \, \mathrm{rad/s}$$ $$\theta = \omega t$$ $$t = \frac{\theta}{\omega} = \frac{\pi}{2 \times 2} = \frac{\pi}{4} \, \mathrm{sec.}$$ $X = 4$

Question 60

Physics · Electric Charges and Fields · Numerical

Suppose a uniformly charged wall provides a uniform electric field of $2 \times 10^4 \, \mathrm{N/C}$ normally. A charged particle of mass $2 \, \mathrm{g}$ being suspended through a silk thread of length $20 \, \mathrm{cm}$ and remain stayed at a distance of $10 \, \mathrm{cm}$ from the wall. Then the charge on the particle will be $\frac{1}{\sqrt{x}} \, \mu \mathrm{C}$ where $x=$____. [use $g = 10 \, \mathrm{m/s^2}$ ]

Answer: 3

Solution

Given $\sin \theta = \frac{10}{20} = \frac{1}{2}$. Therefore, $\theta = 30^\circ$. We have $\tan \theta = \frac{qE}{mg}$. Substituting the values, $\tan 30^\circ = \frac{q \times 2 \times 10^4}{1 \times 10^{-3} \times 10}$. This simplifies to $\frac{1}{\sqrt{3}} = q \times 10^6$. Solving for $q$, we get $q = \frac{1}{\sqrt{3}} \times 10^{-6} \, \mathrm{C}$. Therefore, $x = 3$.

Chemistry

Question 61

Chemistry · The d-and f-Block Elements · Single correct

The transition metal having highest $3^{rd}$ ionisation enthalpy is :

  1. Cr
  2. Mn
  3. V
  4. Fe

Answer: (b)

Solution

3rd Ionisation energy: [NCERT Data] V: $2833 \, \mathrm{KJ/mol}$ Cr: $2990 \, \mathrm{KJ/mol}$ Mn: $3260 \, \mathrm{KJ/mol}$ Fe: $2962 \, \mathrm{KJ/mol}$ Alternative Mn: $3d^5 4s^2$ Fe: $3d^6 4s^2$ Cr: $3d^5 4s^1$ V: $3d^3 4s^2$ So Mn has highest 3rd IE among all the given elements due to $d^5$ configuration.

Question 62

Chemistry · Chemical Bonding and Molecular Structure · Single correct

Given below are two statements: Statement (I): A $\pi$ bonding MO has lower electron density above and below the inter-nuclear axis. Statement (II): The $\pi^*$ antibonding MO has a node between the nuclei. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both Statement I and Statement II are false
  2. Both Statement I and Statement II are true
  3. Statement I is false but Statement II is true
  4. Statement I is true but Statement II is false

Answer: (c)

Solution

A $\pi$ bonding molecular orbital has higher electron density above and below the inter nuclear axis.

Question 63

Chemistry · The d-and f-Block Elements · Single correct

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason ( R ). Assertion (A) : In aqueous solutions $\mathrm{Cr}^{2+}$ is reducing while $\mathrm{Mn}^{3+}$ is oxidising in nature. Reason ( R ) : Extra stability to half filled electronic configuration is observed than incompletely filled electronic configuration. In the light of the above statement, choose the most appropriate answer from the options given below:

  1. Both (A) and ( R ) are true and ( R ) is the correct explanation of (A)
  2. Both (A) and ( R ) are true but ( R ) is not the correct explanation of (A)
  3. is false but ( R ) is true
  4. is true but ( R ) is false

Answer: (a)

Solution

$\mathrm{Cr}^{2+}$ is reducing as its configuration changes from $d^4$ to $d^3$ due to formation of $\mathrm{Cr}^{3+}$, which has half-filled $t_{2g}$ level. On the other hand, the change $\mathrm{Mn}^{3+}$ to $\mathrm{Mn}^{2+}$ results in half-filled $d^5$ configuration, which has extra stability.

Question 64

Chemistry · Co-ordination Compounds · Single correct

Match List - I with List - II. Choose the correct answer from the options given below.

  1. (A)-(IV), (B)-(II), (C)-(I), (D)-(III)
  2. (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
  3. (A)-(III), (B)-(I), (C)-(II), (D)-(IV)
  4. (A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Answer: (c)

Solution

The given reactions involve phenol as the starting compound. 1. When phenol is treated with zinc dust and heated, it forms benzene. 2. When phenol is treated with chloroform and sodium hydroxide, followed by acidification with hydrochloric acid, it forms salicylaldehyde. 3. When phenol is treated with carbon dioxide and sodium hydroxide, followed by acidification with hydrochloric acid, it forms salicylic acid. 4. When phenol is treated with concentrated nitric acid, it forms picric acid.

Question 65

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

Given below are two statements: Statement (I): Both metal and non-metal exist in p and d-block elements. Statement (II): Non-metals have higher ionisation enthalpy and higher electronegativity than the metals. In the light of the above statements, choose the most appropriate answer from the option given below:

  1. Both Statement I and Statement II are false
  2. Statement I is false but Statement II is true
  3. Statement I is true but Statement II is false
  4. Both Statement I and Statement II are true

Answer: (b)

Solution

I. In p-Block both metals and non-metals are present but in d-Block only metals are present. II. EN and IE of non-metals are greater than that of metals. I - False, II - True

Question 66

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

The strongest reducing agent among the following is:

  1. NH_3
  2. SbH_3
  3. BiH_3
  4. PH_3

Answer: (c)

Solution

Strongest reducing agent: $\mathrm{BiH_3}$, explained by its low bond dissociation energy.

Question 67

Chemistry · Co-ordination Compounds · Single correct

Which of the following compounds show colour due to d-d transition?

  1. $\mathrm{CuSO_4 \cdot 5H_2O}$
  2. $\mathrm{K_2Cr_2O_7}$
  3. $\mathrm{K_2CrO_4}$
  4. $\mathrm{KMnO_4}$

Answer: (a)

Solution

$\mathrm{CuSO_4\cdot 5H_2O}$ $\mathrm{Cu}^{2+} : 3d^9\,4s^0$ Unpaired electron is present, so it shows colour due to $d$-$d$ transition.

Question 68

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

The set of meta directing functional groups from the following sets is:

  1. -CN, -NH_2, -NHR, -OCH_3
  2. -NO_2, -NH_2, -COOH, -COOR
  3. -NO_2, -CHO, -SO_3H, -COR
  4. -CN, -CHO, -NHCOCH_3, -COOR

Answer: (c)

Solution

All are $-M$, hence meta directing groups.

Question 69

Chemistry · Chemical Bonding and Molecular Structure · Single correct

Select the compound from the following that will show intramolecular hydrogen bonding.

  1. $\mathrm{H_2O}$
  2. $\mathrm{NH_3}$
  3. $\mathrm{C_2H_5OH}$

Answer: (d)

Solution

For $\mathrm{H_2O}$, $\mathrm{NH_3}$, $\mathrm{C_2H_5OH}$, there is intermolecular H-bonding. The given structure shows intramolecular H-bonding.

Question 70

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

Lassaigne's test is used for detection of:

  1. Nitrogen and Sulphur only
  2. Nitrogen, Sulphur and Phosphorous Only
  3. Phosphorous and halogens only
  4. Nitrogen, Sulphur, phosphorous and halogens

Answer: (d)

Solution

Lassaigne's test is used for detection of all elements N, S, P, X.

Question 71

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

Which among the following has highest boiling point?

  1. $\mathrm{CH_3CH_2CH_2CH_3}$
  2. $\mathrm{CH_3CH_2CH_2CH_2 - OH}$
  3. $\mathrm{CH_3CH_2CH_2CHO}$
  4. $\mathrm{H_5C_2 - O - C_2H_5}$

Answer: (b)

Solution

Due to H-bonding, the boiling point of alcohol is high.

Question 72

Chemistry · Hydrocarbons · Single correct

In the given reactions identify $A$ and $B$.

  1. $A$: 2-Pentyne; $B$: trans-2-butene
  2. $A$: n-Pentane; $B$: trans-2-butene
  3. $A$: 2-Pentyne; $B$: Cis-2-butene
  4. $A$: n-Pentane; $B$: Cis-2-butene

Answer: (a)

Solution

The reaction of 2-pentyne with hydrogen in the presence of Pd/C catalyst results in the formation of a fully saturated alkane. The reaction of 2-pentyne with sodium in liquid ammonia results in the formation of trans-2-butene.

Question 73

Chemistry · Structure of Atom · Single correct

The number of radial node/s for $3p$ orbital is:

  1. 1
  2. 4
  3. 2
  4. 3

Answer: (a)

Solution

For 3p: $n = 3$, $\ell = 1$. Number of radial nodes $= n - \ell - 1$. $$= 3 - 1 - 1 = 1$$

Question 74

Chemistry · Co-ordination Compounds · Single correct

Match List - I with List - II. Choose the correct answer from the options given below :

  1. (A)-(I), (B)-(II), $(C)$-(III), (D)-(IV)
  2. (A)-(III), (B)-(I), $(C)$-(IV), (D)-(II)
  3. (A)-(IV), (B)-(III), $(C)$-(II), (D)-(I)
  4. (A)-(II), (B)-(III), $(C)$-(I), (D)-(IV)

Answer: (b)

Solution

$CCl_4$ used in fire extinguisher. $CH_2Cl_2$ used as paint remover. Freons used in refrigerator and AC. DDT used as non Biodegradable insecticide.

Question 75

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

The functional group that shows negative resonance effect is:

  1. --NH$_2$
  2. --OH
  3. --COOH
  4. --OR

Answer: (c)

Solution

The group shown exhibits a $-R$ effect, while the remaining three groups show a $+R$ effect via lone pair.

Question 76

Chemistry · Co-ordination Compounds · Single correct

$[Co(NH_3)_6]^{3+}$ and $[CoF_6]^{3-}$ are respectively known as:

  1. Spin free Complex, Spin paired Complex
  2. Spin paired Complex, Spin free Complex
  3. Outer orbital Complex, Inner orbital Complex
  4. Inner orbital Complex, Spin paired Complex

Answer: (b)

Solution

For $[\mathrm{Co(NH_3)_6}]^{3+}$, $\mathrm{Co^{3+}}$ (strong field ligand) $\Rightarrow 3\, d^6 \left(t_{2g}^6, e_g^0\right)$, Hybridisation: $d^2sp^3$. Inner orbital complex (spin paired complex). Pairing will take place. For $[\mathrm{CoF_6}]^{3-}$, $\mathrm{Co^{3+}}$ (weak field ligand) $\Rightarrow 3\, d^6 \left(t_{2g}^4, e_g^2\right)$. Hybridisation: $sp^3d^2$. Outer orbital complex (spin free complex) no pairing will take place.

Question 77

Chemistry · The p-Block Elements (Group-13 and 14) · Single correct

Given below are two statements: Statement (I): SiO$_2$ and GeO$_2$ are acidic while SnO and PbO are amphoteric in nature. Statement (II): Allotropic forms of carbon are due to property of catenation and $p\pi - d\pi$ bond formation. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both Statement I and Statement II are false
  2. Both Statement I and Statement II are true
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true

Answer: (c)

Solution

SiO$_2$ and GeO$_2$ are acidic and SnO, PbO are amphoteric. Carbon does not have d-orbitals so can not form p$\pi$ - d$\pi$ bond with itself. Due to properties of catenation and p$\pi$ - p$\pi$ bond formation, carbon is able to show allotropic forms.

Question 78

Chemistry · Haloalkanes and Haloarenes · Single correct

Acid D formed in above reaction is :

  1. Gluconic acid
  2. Succinic acid
  3. Oxalic acid
  4. Malonic acid

Answer: (b)

Solution

The reaction sequence starts with $\mathrm{C_2H_5Br}$ treated with alcoholic $\mathrm{KOH}$ to form $\mathrm{CH_2=CH_2}$ (A). Next, $\mathrm{Br_2}$ in $\mathrm{CCl_4}$ is added to form $\mathrm{CH_2Br-CH_2Br}$ (B). This compound is then treated with excess $\mathrm{KCN}$ to form $\mathrm{CH_2CN-CH_2CN}$ (C). Finally, hydrolysis with $\mathrm{H_3O^+}$ converts it to succinic acid, $\mathrm{CH_2(COOH)-CH_2(COOH)}$ (D).

Question 79

Chemistry · Equilibrium · Single correct

Solubility of calcium phosphate (molecular mass, M) in water is $W \, \mathrm{g}$ per $100 \, \mathrm{mL}$ at $25^\circ \mathrm{C}$. Its solubility product at $25^\circ \mathrm{C}$ will be approximately.

  1. $10^7 \left( \frac{W}{M} \right)^3$
  2. $10^7 \left( \frac{W}{M} \right)^5$
  3. $10^3 \left( \frac{W}{M} \right)^5$
  4. $10^5 \left( \frac{W}{M} \right)^5$

Answer: (b)

Solution

Given the solubility equation: $$S = \frac{W \times 10}{M}$$ The dissociation of $\mathrm{Ca_3(PO_4)_2(s)}$ is given by: $$\mathrm{Ca_3(PO_4)_2(s) \rightleftharpoons 3Ca^{2+}(aq.) + 2PO_4^{3-}(aq.)}$$ Let $3s$ and $2s$ be the concentrations of $\mathrm{Ca^{2+}}$ and $\mathrm{PO_4^{3-}}$ respectively. The solubility $S$ is: $$S = \frac{W \times 1000}{M \times 100} = \frac{W \times 10}{M}$$ The solubility product $K_{sp}$ is: $$K_{sp} = (3s)^3 (2s)^2$$ $$= 108 \, s^5$$ Substituting $s$: $$= 108 \times 10^5 \times \left(\frac{W}{M}\right)^5$$ $$= 1.08 \times 10^7 \left(\frac{W}{M}\right)^5$$

Question 80

Chemistry · Co-ordination Compounds · Single correct

Given below are two statements: Statement (I): Dimethyl glyoxime forms a sixmembered covalent chelate when treated with $\mathrm{NiCl_2}$ solution in presence of $\mathrm{NH_4OH}$. Statement (II): Prussian blue precipitate contains iron both in (+2) and (+3) oxidation states. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Statement I is false but Statement II is true
  2. Both Statement I and Statement II are true
  3. Both Statement I and Statement II are false
  4. Statement I is true but Statement II is false

Answer: (a)

Solution

The reaction of $\mathrm{Ni^{2+}}$ with $\mathrm{NH_4OH}$ and dmg forms a complex with a five-membered ring structure. The structure shown is a coordination complex where $\mathrm{Ni^{2+}}$ is coordinated with dmg ligands forming a stable chelate. This complex is characterized by the presence of two five-membered rings.

Question 81

Chemistry · Hydrocarbons · Numerical

Total number of isomeric compounds (including stereoisomers) formed by monochlorination of 2-methylbutane is _______.

Answer: 6

Solution

The question shows four different chlorinated compounds. The correct answer is determined by identifying the compound with the correct structural feature or position of chlorine.

Question 82

Chemistry · Chemical Kinetics and Nuclear Chemistry · Numerical

The following data were obtained during the first order thermal decomposition of a gas A at constant volume: \[ \mathrm{A(g) \rightarrow 2B(g) + C(g)} \] \[ \begin{array}{c|c|c} \mathrm{S.No} & \mathrm{Time/s} & \mathrm{Total\ pressure/(atm)}\\ 1 & 0 & 0.10\\ 2 & 115 & 0.28 \end{array} \] The rate constant of the reaction is \[ \underline{\hspace{2cm}}\times 10^{-2}\,\mathrm{s}^{-1} \] (nearest integer).

Answer: 2

Solution

For the reaction $\mathrm{A(g)} \rightarrow 2\mathrm{B(g)} + \mathrm{C(g)}$, at $t = 0$, the concentration of $\mathrm{A}$ is $0.1$. At $t = 115 \, \mathrm{sec}$, the concentration of $\mathrm{A}$ is $0.1 - x$ and the concentration of $\mathrm{B}$ is $2x$. Given $0.1 + 2x = 0.28$, we solve for $x$: $$2x = 0.18$$ $$x = 0.09$$ The rate constant $K$ is calculated as: $$K = \frac{1}{115} \ln \frac{0.1}{0.1 - 0.09}$$ $$= 0.0200 \, \mathrm{sec^{-1}}$$ $$= 2 \times 10^{-2} \, \mathrm{sec^{-1}}$$

Question 83

Chemistry · Biomolecules · Numerical

The number of tripeptides formed by three different amino acids using each amino acid once is _________.

Answer: 6

Solution

Let 3 different amino acids be A, B, C. Then the following combinations of tripeptides can be formed: ABC, ACB, BAC, BCA, CAB, CBA.

Question 84

Chemistry · Amines · Numerical

Number of compounds which give reaction with Hinsberg's reagent is .

Answer: 5

Solution

Question 85

Chemistry · Solutions · Numerical

Mass of ethylene glycol (antifreeze) to be added to 18.6 kg of water to protect the freezing point at $-24^\circ \mathrm{C}$ is _______ kg (Molar mass in gmol$^{-1}$ for ethylene glycol 62, $K_f$ of water $= 1.86 \mathrm{K \ kg \ mol}^{-1}$)

Answer: 15

Solution

Given $\Delta T_f = i K_f \times molality$. $$24 = (1) \times 1.86 \times \frac{W}{62 \times 18.6}$$ $W = 14880 \, gm$ $= 14.880 \, kg$

Question 86

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Numerical

Following Kjeldahl's method, 1 g of organic compound released ammonia, that neutralised 10 $\mathrm{mL}$ of 2$MH_2S0_4$. The percentage of nitrogen in the compound is ______ $\%$.

Answer: 56

Solution

Given the reaction: $\mathrm{H_2SO_4} + 2\mathrm{NH_3} \rightarrow (\mathrm{NH_4})_2\mathrm{SO_4}$. Millimole of $\mathrm{H_2SO_4} \rightarrow 10 \times 2$. So millimole of $\mathrm{NH_3} = 20 \times 2 = 40$. Organic compound $\rightarrow \mathrm{NH_3}$, 40 millimole. Therefore, mole of $N = \frac{40}{1000}$. Weight of $N = \frac{40}{1000} \times 14$. Percentage composition of $N$ in organic compound: $$\frac{40 \times 14}{1000 \times 1} \times 100$$ $$= 56\%$$

Question 87

Chemistry · Electrochemistry · Numerical

The amount of electricity in Coulomb required for the oxidation of 1 mol of $H_2O$ to $O_2$ is _______ $\times 10^5 \mathrm{C}$.

Answer: 2

Solution

The reaction is given by $2\mathrm{H_2O} \rightarrow \mathrm{O_2} + 4\mathrm{H^+} + 4e^-$. The equation for work done is $\frac{W}{E} = \frac{Q}{96500}$. The moles multiplied by the n-factor is equal to $\frac{Q}{96500}$. Therefore, $1 \times 2 = \frac{Q}{96500}$. Solving for $Q$, we get $Q = 2 \times 96500\, \mathrm{C} = 1.93 \times 10^5\, \mathrm{C}$.

Question 88

Chemistry · Thermodynamics · Fill in the blank

For a certain reaction at 300 \, $\mathrm{K}$, $\mathrm{K} = 10$, then $\Delta G^\circ$ for the same reaction is _________ $\times 10^{-1}$ $\mathrm{kJ}$ $\mathrm{mol}^{-1}$. (Given $R$ = 8.314 $\mathrm{J}$ $\mathrm{K}^{-1}$ $\mathrm{mol}^{-1})$

Answer: 57

Solution

Given $\Delta G^\circ = -RT \ln K$. $$= -8.314 \times 300 \ln(10)$$ $$= 5744.14 \, \mathrm{J/mole}$$ $$= 57.44 \times 10^{-1} \, \mathrm{kJ/mole}$$

Question 89

Chemistry · Redox Reactions · Numerical

Consider the following redox reaction : $\mathrm{MnO_4^-} + \mathrm{H^+} + \mathrm{H_2C_2O_4} \rightleftharpoons \mathrm{Mn^{2+}} + \mathrm{H_2O} + \mathrm{CO_2}$ The standard reduction potentials are given as below ($E^\circ_{red}$) $E^\circ_{\mathrm{MnO_4^-/Mn^{2+}}} = +1.51 \, \mathrm{V}$ $E^\circ_{\mathrm{CO_2/H_2C_2O_4}} = -0.49 \, \mathrm{V}$ If the equilibrium constant of the above reaction is given as $K_{\mathrm{eq}} = 10^x$, then the value of x = ________ (nearest integer)

Answer: 339

Solution

CellRx; $\mathrm{MnO_4^- + H_2C_2O_4 \rightarrow Mn^{2+} + CO_2}$ $E^\circ_{cell} = E^\circ_{op}$ of anode $+ E^\circ_{RP}$ of cathode $$= 0.49 + 1.51 = 2.00 \, \mathrm{V}$$ At equilibrium $E_{cell} = 0,$ $E^\circ_{cell} = \frac{0.059}{n} \log K$ (As per NCERT $\frac{RT}{F} = 0.059$ But $\frac{RT}{F} = 0.0591$ can also be taken.) $$2 = \frac{0.059}{10} \log K$$ $$\log K = 338.98$$

Question 90

Chemistry · Hydrocarbons · Numerical

10 $\mathrm{mL}$ of gaseous hydrocarbon on combustion gives 40 $\mathrm{mL}$ of $\mathrm{CO_2(g)}$ and 50 $\mathrm{mL}$ of water vapour. Total number of carbon and hydrogen atoms in the hydrocarbon is .

Answer: 14

Solution

The reaction is given as: $$\mathrm{CxHy} + \mathrm{O_2} \rightarrow \mathrm{CO_2} + \mathrm{H_2O}$$ The balanced equation is: $$\mathrm{CxHy} + \left( x + \frac{y}{4} \right) \mathrm{O_2} \rightarrow x\mathrm{CO_2} + \frac{y}{2}\mathrm{H_2O}$$ Given: $$10x = 40$$ Solving for $x$ gives: $$x = 4$$ Next, solve for $y$: $$5y = 50$$ This gives: $$y = 10$$ Thus, the compound is $\mathrm{C_4H_{10}}$.