JEE Main 4 April 2024 Shift 2 question paper with solutions

JEE Main 4 April 2024 Shift 2: all 90 questions in paper order (Maths, Physics, Chemistry) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.

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Maths

Question 1

Maths · Continuity and Differentiability · Single correct

If the function $$f(x) = \begin{cases} \frac{72^x - 9^x - 8^x + 1}{\sqrt{2} - \sqrt{1 + \cos x}}, & x \neq 0 \\ a \log_e 2 \log_e 3, & x = 0 \end{cases}$$ is continuous at $x = 0$, then the value of $a^2$ is equal to

  1. 968
  2. 1152
  3. 746
  4. 1250

Answer: (b)

Solution

Given $\lim_{x \to 0} f(x) = a \ln 2 \ln 3$. $$\lim_{n \to 0} \frac{72^x - 9^x - 8^x + 1}{\sqrt{2} - \sqrt{1 + \cos x}} = \lim_{x \to 0} \frac{(8^x - 1)(9^x - 1)}{\sqrt{2} - \sqrt{1 + \cos x}}$$ $$\lim_{n \to 0} \left( \frac{8^x - 1}{x} \right) \left( \frac{9^x - 1}{x} \right) \left( \frac{x^2}{1 - \cos x} \right) (\sqrt{2} + \sqrt{1 + \cos x})$$ Therefore, $\ln 8 \times \ln 9 \times 2 \times 2\sqrt{2} = 24\sqrt{2} \ln 2 \ln 3$. Thus, $a = 24\sqrt{2}, a^2 = 576 \times 2 = 1152$

Question 2

Maths · Vector Algebra · Single correct

If $\lambda > 0$, let $\theta$ be the angle between the vectors $\vec{a} = \hat{i} + \lambda \hat{j} - 3 \hat{k}$ and $\vec{b} = 3 \hat{i} - \hat{j} + 2 \hat{k}$. If the vectors $\vec{a} + \vec{b}$ and $\vec{a} - \vec{b}$ are mutually perpendicular, then the value of $(14 \cos \theta)^2$ is equal to

  1. 50
  2. 40
  3. 25
  4. 20

Answer: (c)

Solution

Given $ (\vec{a} + \vec{b}) \cdot (\vec{a} - \vec{b}) = 0, \lambda > 0 $. $|\vec{a}|^2 - |\vec{b}|^2 = 0 \rightarrow 1 + \lambda^2 + 9 = 9 + 1 + 4$. Therefore, $\lambda = 2$, $\cos \theta = \frac{\vec{a} - \vec{b}}{|\vec{a}| \cdot |\vec{b}|} = \frac{3 - \lambda - 6}{\sqrt{14} \cdot \sqrt{14}}$. $14 \cos \theta = 3 - 8 = -5$. Thus, $(14 \cos \theta)^2 = 25$.

Question 3

Maths · Conic Sections · Single correct

Let $C$ be a circle with radius $\sqrt{10}$ units and centre at the origin. Let the line $x + y = 2$ intersects the circle $C$ at the points $P$ and $Q$. Let $MN$ be a chord of $C$ of length $2$ unit and slope $-1$. Then, a distance (in units) between the chord $PQ$ and the chord $MN$ is

  1. $3 - \sqrt{2}$
  2. $\sqrt{2} + 1$
  3. $\sqrt{2} - 1$
  4. $2 - \sqrt{3}$

Answer: (a)

Solution

Given $C: x^2 + y^2 = 10$. $AN = \frac{MN}{2} = 1$. Therefore, in $\triangle OAN \rightarrow (ON)^2 = (OA)^2 + (AN)^2$. $10 = (OA)^2 + 1 \rightarrow OA = 3$. Perpendicular distance of center from $$PQ = \frac{|0 + 0 - 2|}{\sqrt{2}} = \sqrt{2}$$ Perpendicular distance between $MN$ and $$PQ = OA + \sqrt{2} or |OA - \sqrt{2}|$$ $$= 3 + \sqrt{2} or 3 - \sqrt{2}$$

Question 4

Maths · Relations and Functions · Single correct

Let a relation $R$ on $N \times N$ be defined as: $(x_1, y_1) \, R \, (x_2, y_2)$ if and only if $x_1 \leq x_2$ or $y_1 \leq y_2$. Consider the two statements: (I) $R$ is reflexive but not symmetric. (II) $R$ is transitive Then which one of the following is true?

  1. Both (I) and (II) are correct.
  2. Only (II) is correct.
  3. Neither (I) nor (II) is correct.
  4. Only (I) is correct.

Answer: (d)

Solution

All $((x_1 y_1), (x_1, y_1))$ are in $R$ where $x_1, y_1 \in \mathbb{N}$. Therefore, $R$ is reflexive. $((1, 1), (2, 3)) \in R$ but $((2, 3), (1, 1)) \notin R$. Therefore, $R$ is not symmetric. $((2, 4), (3, 3)) \in R$ and $((3, 3), (1, 3)) \in R$ but $((2, 4), (1, 3)) \notin R$. Therefore, $R$ is not transitive.

Question 5

Maths · Sequences and Series · Single correct

Let three real numbers $a, b, c$ be in arithmetic progression and $a + 1, b, c + 3$ be in geometric progression. If $a > 10$ and the arithmetic mean of $a, b$ and $c$ is 8, then the cube of the geometric mean of $a, b$ and $c$ is

  1. 128
  2. 316
  3. 120
  4. 312

Answer: (c)

Solution

Given $2b = a + c$, $b^2 = (a + 1)(c + 3)$. $$\frac{a + b + c}{3} = 8 \rightarrow b = 8, a + c = 16$$ $$64 = (a + 1)(19 - a) = 19 + 18a - a^2$$ $$a^2 - 18a - 45 = 0 \rightarrow (a - 15)(a + 3) = 0, (a > 10)$$ $a = 15, c = 1, b = 8$ $$\left((abc)^{1/3}\right)^3 = abc = 120$$

Question 6

Maths · Matrices · Single correct

Let $A = \begin{bmatrix} 1 & 2 \\ 0 & 1 \end{bmatrix}$ and $B = I + adj(A) + (adj A)^2 + \ldots + (adj A)^{10}$. Then, the sum of all the elements of the matrix $B$ is:

  1. -124
  2. 22
  3. -88
  4. -110

Answer: (c)

Solution

Given $$Adj(A) = \begin{bmatrix} 1 & -2 \\ 0 & 1 \end{bmatrix}$$ Then $$(AdjA)^2 = \begin{bmatrix} 1 & -4 \\ 0 & 1 \end{bmatrix}$$ Continuing this pattern, $$(AdjA)^{10} = \begin{bmatrix} 1 & -20 \\ 0 & 1 \end{bmatrix}$$ Now, calculate matrix $B$: $$B = \begin{bmatrix} 1 & 0 \\ 0 & 1 \end{bmatrix} + \begin{bmatrix} 1 & -2 \\ 0 & 1 \end{bmatrix} + \begin{bmatrix} 1 & -4 \\ 0 & 1 \end{bmatrix} + \cdots + \begin{bmatrix} 1 & -20 \\ 0 & 1 \end{bmatrix}$$ This results in $$B = \begin{bmatrix} 11 & -110 \\ 0 & 11 \end{bmatrix} \Rightarrow$$ sum of elements of B $$= -88$$

Question 7

Maths · Sequences and Series · Single correct

The value of $$\frac{1 \times 2^2 + 2 \times 3^2 + \ldots + 100 \times (101)^2}{1^2 \times 2 + 2^2 \times 3 + \ldots + 100^2 \times 101}$$ is

  1. $\frac{32}{31}$
  2. $\frac{31}{30}$
  3. $\frac{306}{305}$
  4. $\frac{305}{301}$

Answer: (d)

Solution

The given expression is $$\frac{1 \times 2^2 + 2 \times 3^2 + \ldots + 100 \times (101)^2}{1^2 \times 2 + 2^2 \times 3 + \ldots + 100^2 \times 101} = \frac{\sum_{r=1}^{100} r(r+1)^2}{\sum_{r=1}^{100} r^2(r+1)}$$ This can be rewritten as $$\frac{\sum_{r=1}^{100} \left( r^3 + 2r^2 + r \right)}{\sum_{r=1}^{100} \left( r^3 + r^2 \right)} = \frac{\left( \frac{n(n+1)}{2} \right)^2 + \frac{n(n+1)(2n+1)}{6} + \frac{n(n+1)}{2}}{\left( \frac{n(n+1)}{2} \right)^2 + \frac{n(n+1)(2n+1)}{6}}$$ Substituting $n = 100$, we have $$= \frac{\frac{100(101)}{2} \left[ \frac{n(n+1)}{2} + \frac{2}{3} \cdot (2n+1) + 1 \right]}{\frac{100(101)}{2} + \frac{2}{3}(201) + 1}$$ Simplifying further, $$= \frac{\frac{100 \times 101}{2} + \frac{2}{3} \times 201 + 1}{\frac{100 \times 101}{2} + \frac{201}{3}} = \frac{5185}{5117} = \frac{305}{301}$$

Question 8

Maths · Limits and Derivatives · Single correct

Let $f(x) = \int_{0}^{x} \left( t + \sin(1 - e^t) \right) \, dt, \ x \in \mathbb{R}$. Then, $\lim_{x \to 0} \frac{f(x)}{x^3}$ is equal to

  1. $-\frac{1}{6}$
  2. $\frac{2}{3}$
  3. $-\frac{2}{3}$
  4. $\frac{1}{6}$

Answer: (a)

Solution

$\lim_{x\to0}\frac{f(x)}{3x^3}$ Using L'Hospital Rule, $\lim_{x\to0}\frac{f'(x)}{3x^2}$ $= \lim_{x\to0} \frac{x+\sin(1-e^x)} {3x^2}$ (Again L'Hospital) Using L'Hospital Rule, $=\lim_{x\to0}-\frac{\left[\sin(1-e^x)-(-e^x)e^x+\cos(1-e^x)e^x\right]}{6}$ $=-\frac16$

Question 9

Maths · Applications of Integrals · Single correct

The area (in sq. units) of the region described by $\{(x, y) : y^2 \leq 2x, and y \geq 4x - 1\}$ is

  1. $\frac{11}{32}$
  2. $\frac{8}{9}$
  3. $\frac{11}{12}$
  4. $\frac{9}{32}$

Answer: (d)

Solution

Shaded area is given by the integral from $-\frac{1}{2}$ to $1$ of $(x_{Right} - x_{Left}) \, dy$. Given $y^2 = 2x$ and $y = 4x - 1$. Solve for $y = 1$ and $y = -\frac{1}{2}$. The shaded area is $$ \int_{-\frac{1}{2}}^{1} \left( \frac{y + 1}{4} - \frac{y^2}{2} \right) \, dy $$ This evaluates to $$ \left( \frac{1}{4} \left( \frac{y^2}{2} + y \right) - \frac{y^3}{6} \right) \bigg|_{-\frac{1}{2}}^{1} = \frac{9}{32}. $$

Question 10

Maths · Complex Numbers and Quadratic Equations · Single correct

The area (in sq. units) of the region $S = \{ z \in \mathbb{C} : |z - 1| \leq 2; (z + \bar{z}) + i(z - \bar{z}) \leq 2, \mathrm{Im}(z) \geq 0 \}$ is

  1. $\frac{7\pi}{3}$
  2. $\frac{7\pi}{4}$
  3. $\frac{17\pi}{8}$
  4. $\frac{3\pi}{2}$

Answer: (d)

Solution

Put $z = x + iy$. $|z - 1| \leq 2 \Rightarrow (x - 1)^2 + y^2 \leq 4 \ldots (i)$ $\Rightarrow x - y \leq 1 \ldots (ii)$ $Im(z) \geq 0 \Rightarrow y \geq 0 \ldots (iii)$ Required area $= Area of semi-circle - area of sector A$ $$\frac{1}{2} \pi (2)^2 - \frac{\pi}{2}$$ $$= \frac{3\pi}{2}$$

Question 11

Maths · Integrals · Single correct

If the value of the integral $\int_{-1}^{1} \frac{\cos \alpha x}{1+3x} \, dx$ is $\frac{2}{\pi}$. Then, a value of $\alpha$ is

  1. $\frac{\pi}{3}$
  2. $\frac{\pi}{6}$
  3. $\frac{\pi}{4}$
  4. $\frac{\pi}{2}$

Answer: (d)

Solution

Let $I = \int_{-1}^{+1} \frac{\cos \alpha x}{1+3^x} \, dx$ ...(I) $I = \int_{-1}^{+1} \frac{\cos \alpha x}{1+3^{-x}} \, dx$ Using $\int_a^b f(x) \, dx = \int_a^b f(a+b-x) \, dx$ ...(II) Add (I) and (II) $$2I = \int_{-1}^{+1} \cos(\alpha x) \, dx = 2 \int_0^1 \cos(\alpha x) \, dx$$ $$I = \frac{\sin \alpha}{\alpha} = \frac{2}{\pi} (given)$$ Therefore, $\alpha = \frac{\pi}{2}$

Question 12

Maths · Applications of Derivatives · Single correct

Let $f(x) = 3\sqrt{x - 2} + \sqrt{4 - x}$ be a real valued function. If $\alpha$ and $\beta$ are respectively the minimum and the maximum values of $f$, then $\alpha^2 + 2\beta^2$ is equal to

  1. 42
  2. 38
  3. 24
  4. 44

Answer: (a)

Solution

Given $f(x) = 3\sqrt{x-2} + \sqrt{4-x}$. $x - 2 \geq 0$ and $4 - x \geq 0$. Therefore, $x \in [2, 4]$. Let $x = 2 \sin^2 \theta + 4 \cos^2 \theta$. Therefore, $f(x) = 3\sqrt{2} \cos \theta + \sqrt{2} \sin \theta$. Thus, $\sqrt{2} \leq 3\sqrt{2} \cos \theta + \sqrt{2} \sin \theta \leq \sqrt{9 \times 2 + 2}$. $\sqrt{2} \leq 3\sqrt{2} \cos \theta + \sqrt{2} \sin \theta \leq \sqrt{20}$. Therefore, $\alpha = \sqrt{2}$ and $\beta = \sqrt{20}$. $\alpha^2 + 2\beta^2 = 2 + 40 = 42$

Question 13

Maths · Binomial Theorem · Single correct

If the coefficients of $x^4$, $x^5$ and $x^6$ in the expansion of $(1 + x)^n$ are in the arithmetic progression, then the maximum value of $n$ is:

  1. 7
  2. 21
  3. 28
  4. 14

Answer: (d)

Solution

Coeff. of $x^4 = {}^nC_4$ Coeff. of $x^5 = {}^nC_5$ Coeff. of $x^6 = {}^nC_6$ ${}^nC_4,\ {}^nC_5,\ {}^nC_6 \ldots$ AP $2C_5 = {}^nC_4 + {}^nC_6$ $$2 = \frac{{}^nC_4}{{}^nC_5} + \frac{{}^nC_6}{{}^nC_5} \qquad \left\{\frac{{}^nC_r}{{}^nC_r} = \frac{n-r+1}{r}\right\}$$ $$2 = \frac{5}{n-4} + \frac{n-5}{6}$$ $$12(n-4) = 30 + n^2 - 9n + 20$$ $$n^2 - 21n + 98 = 0$$ $$(n-14)(n-7) = 0$$ $n_{\max} = 14 \qquad n_{\min} = 7$

Question 14

Maths · Conic Sections · Single correct

Consider a hyperbola H having centre at the origin and foci on the x-axis. Let $C_1$ be the circle touching the hyperbola H and having the centre at the origin. Let $C_2$ be the circle touching the hyperbola H at its vertex and having the centre at one of its foci. If areas (in sq units) of $C_1$ and $C_2$ are $36\pi$ and $4\pi$, respectively, then the length (in units) of latus rectum of H is

  1. $\frac{14}{3}$
  2. $\frac{28}{3}$
  3. $\frac{11}{3}$
  4. $\frac{10}{3}$

Answer: (b)

Solution

Let $H : \frac{x^2}{a^2} - \frac{y^2}{b^2} = 1 \left( b^2 = a^2 \left( e^2 - 1 \right) \right)$. Therefore, equation of $C_1$ is $\mathrm{Ar.} = 36\pi$. $$\pi a^2 = 36\pi$$ $$a = 6$$ Therefore, equation of $C_1$ is $x^2 + y^2 = a^2$. Now radius of $C_2$ can be $a(e - 1)$ or $a(e + 1)$ for $r = a(e - 1)$ for $r = a(e + 1)$. $$\mathrm{Ar.} = 4\pi \pi r^2 = 4\pi$$ $$\pi a^2 (e - 1)^2 = 4\pi$$ $$a^2 (e + 1)^2 = 4$$ $$36\pi (e - 1)^2 = 4\pi$$ $$36(e + 1)^2 = 4$$ $$e - 1 = \frac{1}{3}$$ $$e + 1 = \frac{1}{3}$$ $$e = \frac{4}{3}$$ $$-\frac{2}{3}$$ Not possible. Therefore, $b^2 = 36 \left( \frac{16}{9} - 1 \right) = 28$. Therefore, $LR = \frac{2\, b^2}{a} = \frac{2 \times 28}{6} = \frac{28}{3}$.

Question 15

Maths · Probability (Advanced) · Single correct

If the mean of the following probability distribution of a random variable $X$: \begin{tabular}{|c|c|c|c|c|c|} \hline X & 0 & 2 & 4 & 6 & 8\\ \hline P(X) & $a$ & $2a$ & $a+b$ & $2b$ & $3b$\\ \hline \end{tabular} is $\dfrac{46}{9}$, then the variance of the distribution is

  1. $\frac{173}{27}$
  2. $\frac{566}{81}$
  3. $\frac{151}{27}$
  4. $\frac{581}{81}$

Answer: (b)

Solution

$\sum P_i = 1$ $a + 2a + a + b + 2b + 3b = 1$ $$4a + 6b = 1 \tag{I}$$ $E(x) = \text{mean} = \dfrac{46}{9}$ $\displaystyle\sum P_i X_i = \dfrac{46}{9} \Rightarrow 4a + 4a + 4b + 12b + 24b = \dfrac{46}{9}$ $8a + 40b = \dfrac{46}{9}$ $$4a + 20b = \dfrac{23}{9} \tag{II}$$ Subtract (I) from (II) we get $b = \dfrac{1}{9}$ \& $a = \dfrac{1}{12}$ $\text{Variance} = E(x_i^2) - E(x_i)^2$ $E(x_i)^2 = 0^2 \times 9^2 + 2^2 \times 2a + 4^2(a+b) + 6^2(2b) + 8^2(3b)$ $= 24a + 280b$ Put $a = \dfrac{1}{12},\quad b = \dfrac{1}{9}$ $E(x_i^2) = 2 + \dfrac{280}{9} = \dfrac{298}{9}$ $\therefore\ \sigma^2 = E(x_i^2) - E(x_i)^2$ $= \dfrac{298}{9} - \left(\dfrac{46}{9}\right)^2$ $\sigma^2 = \dfrac{298}{9} - \dfrac{2116}{81}$ $= \dfrac{566}{81}$

Question 16

Maths · Conic Sections · Single correct

Let PQ be a chord of the parabola $y^2 = 12x$ and the midpoint of PQ be at $(4, 1)$. Then, which of the following point lies on the line passing through the points P and Q?

  1. (3, -3)
  2. (2, -9)
  3. ($\frac{3}{2}$, -16)
  4. ( $\frac{1}{2}$, -20 )

Answer: (d)

Solution

Given $T = S_1$. The equation is $y - 6(x + 4) = 1 - 48$. Simplifying, we get $6x - y = 23$. Option 4 $\left( \frac{1}{2}, -20 \right)$ will satisfy.

Question 17

Maths · Inverse Trigonometric Functions · Single correct

Given that the inverse trigonometric function assumes principal values only. Let $x, y$ be any two real numbers in $[-1, 1]$ such that $\cos^{-1} x - \sin^{-1} y = \alpha$, $-\frac{\pi}{2} \leq \alpha \leq \pi$. Then, the minimum value of $x^2 + y^2 + 2xy \sin \alpha$ is

  1. 0
  2. -1
  3. $\frac{1}{2}$
  4. -$\frac{1}{2}$

Answer: (a)

Solution

Given $\cos^{-1} x - \left( \frac{\pi}{2} - \cos^{-1} y \right) = \alpha$. Then $\cos^{-1} x + \cos^{-1} y = \frac{\pi}{2} + \alpha$. $\alpha \in \left[ -\frac{\pi}{2}, \pi \right], \frac{\pi}{2} + \alpha \in \left[ 0, \frac{3\pi}{2} \right]$. $\cos^{-1} \left( xy - \sqrt{1-x^2} \sqrt{1-y^2} \right) = \frac{\pi}{2} + \alpha$. $xy - \sqrt{1-x^2} \sqrt{1-y^2} = -\sin \alpha$. $(xy + \sin \alpha) = (1-x^2)(1-y^2)$. $x^2 y^2 + 2xy \sin \alpha + \sin^2 \alpha = 1 - x^2 - y^2 + x^2 y^2$. $x^2 + y^2 + 2xy \sin \alpha = 1 - \sin^2 \alpha$. $x^2 + y^2 + 2xy \sin \alpha = \cos^2 \alpha$. The minimum value of $\cos^2 \alpha = 0$. At $\alpha = \frac{\pi}{2}$.

Question 18

Maths · Differential Equations · Single correct

Let $y = y(x)$ be the solution of the differential equation $(x^2 + 4)^2 \, dy + (2x^3 y + 8xy - 2) \, dx = 0$. If $y(0) = 0$, then $y(2)$ is equal to

  1. $\frac{\pi}{32}$
  2. $2\pi$
  3. $\frac{\pi}{8}$
  4. $\frac{\pi}{16}$

Answer: (a)

Solution

Given $\dfrac{dy}{dx}+y\left(\dfrac{2x^3+8x}{(x^2+4)^2}\right)=\dfrac{2}{(x^2+4)^2}$. $\dfrac{dy}{dx}+y\left(\dfrac{2x}{x^2+4}\right)=\dfrac{2}{(x^2+4)^2}$. $\mathrm{I.F.}=e^{\int \frac{2x}{x^2+4}\,dx}$. $\mathrm{I.F.}=x^2+4$. $y(x^2+4)=\int \dfrac{2}{(x^2+4)^2}(x^2+4)\,dx$. $y(x^2+4)=2\int \dfrac{dx}{x^2+2^2}$. $y(x^2+4)=\dfrac{2}{2}\tan^{-1}\left(\dfrac{x}{2}\right)+c$. Given $y(0)=0$, $0=0+c$. $\Rightarrow c=0$. $\therefore\ y(x^2+4)=\tan^{-1}\left(\dfrac{x}{2}\right)$. At $x=2$, $y(4+4)=\tan^{-1}(1)$. $8y=\dfrac{\pi}{4}$. $\therefore\ y(2)=\dfrac{\pi}{32}$.

Question 19

Maths · Vector Algebra · Single correct

Let $\vec{a} = \hat{i} + \hat{j} + \hat{k}$, $\vec{b} = 2\hat{i} + 4\hat{j} - 5\hat{k}$ and $\vec{c} = x\hat{i} + 2\hat{j} + 3\hat{k}$, $x \in \mathbb{R}$. If $\vec{d}$ is the unit vector in the direction of $\vec{b} + \vec{c}$ such that $\vec{a} \cdot \vec{d} = 1$, then $(\vec{a} \times \vec{b}) \cdot \vec{c}$ is equal to

  1. 11
  2. 3
  3. 9
  4. 6

Answer: (a)

Solution

Given $\($ $\vec{d}$ = $\lambda$ ($\vec{b}$ + $\vec{c}$) $\)$ and $\($ $\vec{a}$ $\cdot$ $\vec{d}$ = $\lambda$ ($\vec{b}$ $\cdot$ $\vec{a}$ + $\vec{c}$ $\cdot$ $\vec{a}$) $\)$. We have $\($ 1 = $\lambda$ (1 + x + 5) $\)$. Therefore, $\($ 1 = $\lambda$ (x + 6) $\)$ ...(1). The magnitude $\($ |$\vec{d}$| = 1 $\)$ implies $\($ |$\lambda$ ($\vec{b}$ + $\vec{c}$)| = 1 $\)$. Thus, $\($ |$\lambda$ ((x + 2) $\hat{i}$ + 6 $\hat{j}$ - 2 $\hat{k}$)| = 1 $\)$. This gives $\($ $\lambda$^2 ((x + 2)^2 + 6^2 + 2^2) = 1 $\)$. Expanding, $\($ x^2 + 4x + 4 + 36 + 4 = (x + 6)^2 $\)$. Simplifying, $\($ x^2 + 4x + 44 = x^2 + 12x + 36 $\)$. Solving for $\($ x $\)$, we get $\($ 8x = 8 $\)$, hence $\($ x = 1 $\)$. The determinant $\($ $\begin{vmatrix}$ 1 & 1 & 1 $\\$ 2 & 4 & -5 $\\$ x & 2 & 3 $\end{vmatrix}$ = ($\vec{a}$ $\times$ $\vec{b}$) $\cdot$ $\vec{c}$ $\)$ is calculated as $\($ $\begin{vmatrix}$ 0 & 0 & 1 $\\$ -2 & 9 & -4 $\\$ x - 2 & -1 & 3 $\end{vmatrix}$ = 2 - 9(x - 2) $\)$. Therefore, $\($ = 20 - 9x $\)$. At $\($ x = 1 $\)$, $\($ 20 - 9 = 11 $\)$.

Question 20

Maths · Three Dimensional Geometry · Single correct

Let P be the point of intersection of the lines $\frac{x-2}{1} = \frac{y-4}{5} = \frac{z-2}{1}$ and $\frac{x-3}{2} = \frac{y-2}{3} = \frac{z-3}{2}$. Then, the shortest distance of P from the line $4x = 2y = z$ is

  1. $\frac{5\sqrt{14}}{7}$
  2. $\frac{3\sqrt{14}}{7}$
  3. $\frac{\sqrt{14}}{7}$
  4. $\frac{6\sqrt{14}}{7}$

Answer: (b)

Solution

Line $L_1$ is given by $\($ $\frac{x-2}{1}$ = $\frac{y-4}{5}$ = $\frac{z-2}{1}$ = $\lambda$ $\)$. Point $P(\lambda + 2, 5\lambda + 4, \lambda + 2)$. Line $L_2$ is given by $\($ $\frac{x-3}{2}$ = $\frac{y-2}{3}$ = $\frac{z-3}{2}$ $\)$. Point $P(2\mu + 3, 3\mu + 2, 2\mu + 3)$. $\($ $\lambda$ + 2 = 2$\mu$ + 3 $\)$, $\($ 3$\mu$ + 2 = 5$\lambda$ + 4 $\)$. Solving these equations: $\($ $\lambda$ = 2$\mu$ + 1 $\)$, $\($ 3$\mu$ = 5$\lambda$ + 2 $\)$. $\($ 3$\mu$ = 5(2$\mu$ + 1) + 2 $\)$. $\($ 3$\mu$ = 10$\mu$ + 7 $\)$. $\($ $\mu$ = -1 $\)$, $\($ $\lambda$ = -1 $\)$. Both satisfy $P$. $P(1, -1, 1)$. Line $L_3$ is given by $\($ $\frac{x}{1/4}$ = $\frac{y}{1/2}$ = $\frac{z}{1}$ $\)$. $\($ L_3 = $\frac{x}{1}$ = $\frac{y}{2}$ = $\frac{z}{4}$ = k $\)$. Coordinates of $Q(k, 2k, 4k)$. Direction ratios of $PQ = \langle k-1, 2k+1, 4k-1 \rangle$. $PQ \perp L_3$. $\($ (k-1) + 2(2k+1) + 4(4k-1) = 0 $\)$. $\($ k - 1 + 4k + 2 + 16k - 4 = 0 $\)$. $\($ k = $\frac{1}{7}$ $\)$. $Q\left( \frac{1}{7}, \frac{2}{7}, \frac{4}{7} \right)$. $\($ PQ = $\sqrt{\left( 1 - \frac{1}{7} \right)^2 + \left( -1 - \frac{2}{7} \right)^2 + \left( 1 - \frac{4}{7} \right)^2}$ $\)$. $\($ = $\sqrt{\frac{36}{49} + \frac{81}{49} + \frac{9}{49}}$ = $\frac{\sqrt{126}}{7}$ $\)$. $\($ PQ = $\frac{3\sqrt{14}}{7}$ $\)$.

Question 21

Maths · Complex Numbers and Quadratic Equations · Numerical

Let $S=\left\{\sin^2 2\theta:\left(\sin^4\theta+\cos^4\theta\right)x^2+\left(\sin2\theta\right)x+\left(\sin^6\theta+\cos^6\theta\right)=0\text{ has real roots}\right\}$. If $\alpha$ and $\beta$ be the smallest and largest elements of the set S, respectively, Then \[ 3\left((\alpha-2)^2+(\beta-1)^2\right) \] equals

Answer: 4

Solution

Given $$D = (\sin 2\theta)^2 - 4 \left( 1 - \frac{\sin^2 2\theta}{2} \right) \left( 1 - \frac{3}{4} \sin^2 2\theta \right)$$ Simplifying, we have $$= (\sin 2\theta)^2 - 4 \left( 1 - \frac{5}{4} \sin^2 2\theta + \frac{3}{8} \sin^4 2\theta \right)$$ This gives $$D = -\frac{3}{2} \sin^4 2\theta + 6 \sin^2 2\theta - 4 > 0$$ Rearranging, $$3 \sin^4 2\theta - 12 \sin^2 2\theta + 8 < 0$$ Solving for $\sin^2 2\theta$, $$\sin^2 2\theta = \frac{12 \pm \sqrt{12^2 - 12 \cdot 8}}{6} = \frac{12 \pm 4\sqrt{3}}{6} = \frac{6 \pm 2\sqrt{3}}{3}$$ Thus, $$\sin^2 2\theta = 2 \pm \frac{2}{\sqrt{3}}, but \sin^2 2\theta \in [0,1]$$ Therefore, $$\alpha = 2 - \frac{2}{\sqrt{3}}, \beta = 1 \rightarrow (\alpha - 2)^2 = \frac{4}{3}, (\beta - 1)^2 = 0$$ Finally, $$3(\alpha - 2)^2 + (\beta - 1)^2 = 4$$

Question 22

Maths · Integrals · Numerical

If $\int \csc^{5}x\,dx=\alpha\cot x\,\csc x\left(\csc^{2}x+\frac{3}{2}\right)+\beta\log_{e}\left|\tan\frac{x}{2}\right|+C$, where $\alpha,\beta\in\mathbb{R}$ and $C$ is the constant of integration, then the value of $8(\alpha+\beta)$ equals:

Answer: 1

Solution

Given $$\int \csc^3 x \cdot \csc^2 x \, dx = I$$ By applying integration by parts $$I = - \cot x \csc^3 x + \int \cot x \left(-3 \csc^2 x \cot x \csc x \right) \, dx$$ $$I = - \cot x \csc^3 x - 3 \int \csc^3 x \left(\csc^2 x - 1\right) \, dx$$ $$I = - \cot x \csc^3 x - 3I + 3 \int \csc^3 x \, dx$$ Let $$I_1 = \int \csc^3 x \, dx = - \csc x \cot x - \int \cot^2 x \csc x \, dx$$ $$I_1 = - \csc x \cot x - \int \left(\csc^2 x - 1\right) \csc x \, dx$$ $$2I_1 = - \csc x \cot x + \ln \left| \tan \frac{x}{2} \right|$$ $$I_1 = -\frac{1}{2} \csc x \cot x + \frac{1}{2} \ln \left| \tan \frac{x}{2} \right|$$ $$4I = - \cot x \csc^3 x - \frac{3}{2} \csc x \cot x + \frac{3}{2} \ln \left| \tan \frac{x}{2} \right| + 4c$$ $$I = -\frac{1}{4} \csc x \cot x \left(\csc^2 x + \frac{3}{2}\right) + \frac{3}{8} \ln \left| \tan \frac{x}{2} \right| + c$$ Therefore, $$\alpha = -\frac{1}{4}, \beta = \frac{3}{8} \rightarrow 8(\alpha + \beta) = 1$$

Question 23

Maths · Applications of Derivatives · Numerical

Let $f : \mathbb{R} \to \mathbb{R}$ be a thrice differentiable function such that $f(0) = 0$, $f(1) = 1$, $f(2) = -1$, $f(3) = 2$ and $f(4) = -2$. Then, the minimum number of zeros of $(3f'f'' + ff''')(x)$ is

Answer: 5

Solution

Given $$ (3f'f'' + ff''')(x) = \left((ff'' + (f')^2)(x)\right)' $$ $$ (fff'' + (f')^2)(x) = \left((ff')(x)\right)' $$ Therefore, $$ (3f'f'' + f''')(x) = (f(x) \cdot f'(x))'' $$ From the graph: Minimum roots of $f(x) \to 4$ Therefore, minimum roots of $f'(x) \to 3$ Therefore, minimum roots of $(f(x) \cdot f'(x)) \to 7$ Therefore, minimum roots of $(f(x) \cdot f'(x))'' \to 5$

Question 24

Maths · Relations and Functions (Advanced) · Fill in the blank

Consider the function $f:\mathbb{R}\to\mathbb{R}$ defined by $f(x)=\frac{2x}{\sqrt{1+9x^2}}$. If the composition of $f$, $\underset{\text{10 times}}{(f\circ f\circ f\circ\cdots\circ f)}(x)$ = $\frac{2^{10}x}{\sqrt{1+9\alpha x^2}}$, then the value of $\sqrt{3\alpha+1}$ is equal to ______.

Answer: 1024

Solution

Given $$f(f(x)) = \frac{2f(x)}{\sqrt{1 + 9f^2(x)}} = \frac{4x}{\sqrt{1 + 9x^2 + 9 \cdot 2^2 x^2}}$$ $$f(f(f(x))) = \frac{2^3 x / \sqrt{1 + 9x^2}}{\sqrt{1 + 9 \left(1 + 2^2\right) \frac{2^2 x^2}{1 + 9x^2}}} = \frac{2^3 x}{\sqrt{1 + 9x^2 \left(1 + 2^2 + 2^4\right)}}$$ Therefore, by observation $$\alpha = 1 + 2^2 + 2^4 + \ldots + 2^{18} = 1 \left(\frac{(2^2)^{10} - 1}{2^2 - 1}\right) = \frac{2^{20} - 1}{3}$$ $$3\alpha + 1 = 2^{20} \rightarrow \sqrt{3\alpha + 1} = 2^{10} = 1024$$

Question 25

Maths · Matrices · Numerical

Let $A$ be a $2 \times 2$ symmetric matrix such that $A \begin{bmatrix} 1 \\ 1 \end{bmatrix} = \begin{bmatrix} 3 \\ 7 \end{bmatrix}$ and the determinant of $A$ be $1$. If $A^{-1} = \alpha A + \beta I$, where $I$ is an identity matrix of order $2 \times 2$, then $\alpha + \beta$ equals

Answer: 5

Solution

Let $A = \begin{bmatrix} a & b \\ b & d \end{bmatrix}$. $$\begin{bmatrix} a & b \\ b & d \end{bmatrix} \begin{bmatrix} 1 \\ 1 \end{bmatrix} = \begin{bmatrix} 3 \\ 7 \end{bmatrix}, ad - b^2 = 1$$ $a + b = 3, b + d = 7, (3 - b)(7 - b) - b^2 = 1$ $21 - 10b = 1 \rightarrow b = 2, a = 1, d = 5$ $$A = \begin{bmatrix} 1 & 2 \\ 2 & 5 \end{bmatrix}, A^{-1} = \begin{bmatrix} 5 & -2 \\ -2 & 1 \end{bmatrix}$$ $A^{-1} = \alpha A + \beta I$ $$\begin{bmatrix} 5 & -2 \\ -2 & 1 \end{bmatrix} = \begin{bmatrix} \alpha + \beta & 2\alpha \\ 2\alpha & 5\alpha + \beta \end{bmatrix}$$ $\alpha = -1, \beta = 6 \rightarrow \alpha + \beta = 5$

Question 26

Maths · Permutations and Combinations · Numerical

There are 4 men and 5 women in Group A, and 5 men and 4 women in Group B. If 4 persons are selected from each group, then the number of ways of selecting 4 men and 4 women is

Answer: 5626

Solution

\begin{tabular}{|c|c|c|} \hline From Group A & From Group B & Ways of selection \\ \hline 4M & 4W & ${}^{4}C_{4}\times{}^{4}C_{4}=1$ \\ \hline 3M1W & 1M3W & ${}^{4}C_{3}\times{}^{5}C_{1}\times{}^{5}C_{1}\times{}^{4}C_{3}=400$ \\ \hline 2M2W & 2M2W & ${}^{4}C_{2}\times{}^{5}C_{2}\times{}^{5}C_{2}\times{}^{4}C_{2}=3600$ \\ \hline 1M3W & 3M1W & ${}^{4}C_{1}\times{}^{5}C_{3}\times{}^{5}C_{3}\times{}^{4}C_{1}=1600$ \\ \hline 4W & 4M & ${}^{5}C_{4}\times{}^{5}C_{4}=25$ \\ \hline Total & & 5626 \\ \hline \end{tabular}

Question 27

Maths · Probability · Numerical

In a tournament, a team plays 10 matches with probabilities of winning and losing each match as $\frac{1}{3}$ and $\frac{2}{3}$ respectively. Let $x$ be the number of matches that the team wins, and $y$ be the number of matches that team loses. If the probability $\mathbb{P}(|x - y| \leq 2)$ is $p$, then $3^9 p$ equals

Answer: 8288

Solution

Given $P(W) = \frac{1}{3}$ and $P(L) = \frac{2}{3}$. Let $x$ be the number of matches that the team wins and $y$ be the number of matches that the team loses. We have $|x - y| \leq 2$ and $x + y = 10$. Also, $|x - y| = 0, 1, 2$ and $x, y \in \mathbb{N}$. Case-I: $-I : |x - y| = 0 \Rightarrow x = y$ Therefore, $x + y = 10 \Rightarrow x = 5 = y$ $$P(|x - y| = 0) = \binom{10}{5} \left(\frac{1}{3}\right)^5 \left(\frac{2}{3}\right)^5$$ Case-II: $|x - y| = 1 \Rightarrow x - y = \pm 1$ \begin{tabular}{|c|c|} \hline $x=y+1$ & $x=y-1$ \\ \hline $\because\ x+y=10$ & $\because\ x+y=10$ \\ \hline $2y=9$ & $2y=11$ \\ \hline Not possible & Not possible \\ \hline \end{tabular} Case-III: $|x - y| = 2 \Rightarrow x - y = \pm 2$ $x - y = 2$ OR $x - y = -2$ Therefore, $x + y = 10$ $x = 6, y = 4$ $x = 4, y = 6$ $$P(|x - y| = 2) = \binom{10}{6} \left(\frac{1}{3}\right)^6 \left(\frac{2}{3}\right)^4 + \binom{10}{4} \left(\frac{1}{3}\right)^4 \left(\frac{2}{3}\right)^6$$ $p = \frac{1}{3} \left(\binom{10}{5} \frac{2^5}{3^{10}} + \binom{10}{6} \frac{2^4}{3^{10}} + \binom{10}{4} \frac{2^6}{3^{10}}\right)$ $3^9 p = \frac{1}{3} \left(\binom{10}{5} 2^5 + \binom{10}{6} 2^4 + \binom{10}{4} 2^6\right)$ $= 8288$

Question 28

Maths · Properties of Triangles · Numerical

Consider a triangle ABC having the vertices A(1, 2), B($\alpha$, $\beta$) and C($\gamma$, $\delta$) and angles $\angle$ ABC = $\frac{\pi}{6}$ and $\angle$ BAC = $\frac{2\pi}{3}$. If the points B and C lie on the line y = x + 4, then $\alpha^2$ + $\gamma^2$ is equal to

Answer: 14

Solution

Equation of line passes through point $A(1, 2)$ which makes angle $\dfrac{\pi}{6}$ from $y = x + 4$ is $$y - 2 = \frac{1 \pm \tan\frac{\pi}{6}}{1 \mp \tan\frac{\pi}{6}}(x-1)$$ $$y - 2 = \frac{\sqrt{3} \pm 1}{\sqrt{3} \mp 1}(x-1)$$ $$\oplus \hspace{6cm} \oplus$$ $y - 2 = (2+\sqrt{3})(x-1)$ $\quad\Big|\quad$ $y - 2 = (2-\sqrt{3})(x-1)$ solve with $y = x + 4$ $\hspace{2cm}$ solve with $y = x + 4$ $x + 2 = (2+\sqrt{3})x - 2 - \sqrt{3}$ $\quad$ $x + 2 = (2-\sqrt{3})x - 2 + \sqrt{3}$ $$x = \frac{4+\sqrt{3}}{1+\sqrt{3}} \qquad x = \frac{4-\sqrt{3}}{1-\sqrt{3}}$$ $$\alpha^2 + \gamma^2 = \left(\frac{4+\sqrt{3}}{1+\sqrt{3}}\right)^2 + \left(\frac{4-\sqrt{3}}{1-\sqrt{3}}\right)^2$$ $$\alpha^2 + \gamma^2 = 14$$

Question 29

Maths · Three Dimensional Geometry · Numerical

Consider a line L passing through the points P(1, 2, 1) and Q(2, 1, -1). If the mirror image of the point A(2, 2, 2) in the line L is $(\alpha, \beta, \gamma)$, then $\alpha + \beta + 6\gamma$ is equal to

Answer: 6

Solution

Direction ratios of line $L$ are $-1 : 1 : 2$. Direction ratios of $AB$ are $\alpha - 2 : \beta - 2 : \gamma - 2$. Since $AB \perp L$, we have $2 - \alpha + \beta - 2 + 2\gamma - 4 = 0$. Simplifying gives $2\gamma + \beta - \alpha = 4$. Let $C$ be the midpoint of $AB$. Then $C \left( \frac{\alpha + 2}{2}, \frac{\beta + 2}{2}, \frac{\gamma + 2}{2} \right)$. The direction ratios of $PC$ are $\frac{\alpha}{2} : \frac{\beta - 2}{2} : \frac{\gamma}{2}$. Since line $L \parallel PC$, we have $\frac{-\alpha}{2} = \frac{\beta - 2}{2} = \frac{\gamma}{4} = K$ (let). Solving gives $\alpha = -2K$, $\beta = 2K + 2$, $\gamma = 4K$. Using in (1) gives $K = \frac{1}{6}$. Therefore, the value of $\alpha + \beta + 6\gamma = 24K + 2 = 6$.

Question 30

Maths · Differential Equations · Numerical

Let $y = y(x)$ be the solution of the differential equation $(x + y + 2)^2 dx = dy, y(0) = -2$. Let the maximum and minimum values of the function $y = y(x)$ in $\left[0, \frac{\pi}{3}\right]$ be $\alpha$ and $\beta$, respectively. If $(3\alpha + \pi)^2 + \beta^2 = \gamma + \delta \sqrt{3}, \gamma, \delta \in \mathbb{Z}$, then $\gamma + \delta$ equals _____

Answer: 31

Solution

Given $\dfrac{dy}{dx}=(x+y+2)^2$ ...(1) and $y(0)=-2$. Let $x+y+2=v$. Then $1+\dfrac{dy}{dx}=\dfrac{dv}{dx}$. From (1), $\dfrac{dv}{dx}=1+v^2$. $\int \dfrac{dv}{1+v^2}=\int dx$ $\tan^{-1}(v)=x+C$ $\tan^{-1}(x+y+2)=x+C$ At $x=0,\ y=-2 \Rightarrow C=0$. $\Rightarrow \tan^{-1}(x+y+2)=x$ $y=\tan x-x-2$ $f(x)=\tan x-x-2,\quad x\in\left[0,\dfrac{\pi}{3}\right]$ $f'(x)=\sec^2x-1>0 \Rightarrow f(x)\uparrow$ $f_{\min}=f(0)=-2=\beta$ $f_{\max}=f\left(\dfrac{\pi}{3}\right)=\sqrt{3}-\dfrac{\pi}{3}-2=\alpha$ Now $(3\alpha+\pi)^2+\beta^2=\gamma+\delta\sqrt{3}$. $\Rightarrow (3\alpha+\pi)^2+\beta^2=(3\sqrt{3}-6)^2+4$ $\Rightarrow \gamma+\delta\sqrt{3}=67-36\sqrt{3}$ $\Rightarrow \gamma=67$ $\delta=-36$ $\Rightarrow \gamma+\delta=31$

Physics

Question 31

Physics · Kinetic Theory · Single correct

The translational degrees of freedom ($f_t$) and rotational degrees of freedom ($f_r$) of $\mathrm{CH}_4$ molecule are:

  1. $f_t = 2$ and $f_r = 2$
  2. $f_t = 3$ and $f_r = 3$
  3. $f_t = 3$ and $f_r = 2$
  4. $f_t = 2$ and $f_r = 3$

Answer: (b)

Solution

Since $\mathrm{CH_4}$ is polyatomic non-linear. D.O.F of $\mathrm{CH_4}$ T. DOF = 3 RDOF = 3

Question 32

Physics · Motion in a Straight Line · Single correct

A cyclist starts from the point P of a circular ground of radius 2 km and travels along its circumference to the point S. The displacement of a cyclist is :

  1. 6 km
  2. $\sqrt{8}$ km
  3. 4 km
  4. 8 km

Answer: (b)

Solution

Question 33

Physics · Magnetism and Matter · Single correct

The magnetic moment of a bar magnet is $0.5 \, \mathrm{Am}^2$. It is suspended in a uniform magnetic field of $8 \times 10^{-2} \, \mathrm{T}$. The work done in rotating it from its most stable to most unstable position is:

  1. $8 \times 10^{-2} \, \mathrm{J}$
  2. $4 \times 10^{-2} \, \mathrm{J}$
  3. Zero
  4. $16 \times 10^{-2} \, \mathrm{J}$

Answer: (a)

Solution

At stable equilibrium $$U = -mB \cos 0^\circ = -mB$$ At unstable equilibrium $$U = -mB \cos 180^\circ = +mB$$ $$W = \Delta U$$ $$W.D. = 2mB$$ $$= 2(0.5)8 \times 10^{-2} = 8 \times 10^{-2} \, J$$

Question 34

Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct

Which of the diode circuit shows correct biasing used for the measurement of dynamic resistance of p-n junction diode :

Answer: (c)

Solution

Diode should be in forward biased to calculate dynamic resistance.

Question 35

Physics · Electromagnetic Waves · Single correct

Arrange the following in the ascending order of wavelength: A. Gamma rays ($\lambda_1$) B. $x$ - rays ($\lambda_2$) C. Infrared waves ($\lambda_3$) D. Microwaves ($\lambda_4$) Choose the most appropriate answer from the options given below

  1. $\lambda_4 < \lambda_3 < \lambda_1 < \lambda_2$
  2. $\lambda_2 < \lambda_1 < \lambda_4 < \lambda_3$
  3. $\lambda_1 < \lambda_2 < \lambda_3 < \lambda_4$
  4. $\lambda_4 < \lambda_3 < \lambda_2 < \lambda_1$

Answer: (c)

Solution

Given the inequality $\lambda_1 < \lambda_2 < \lambda_3 < \lambda_4$.

Question 36

Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct

Identify the logic gate given in the circuit:

  1. NAND-gate
  2. AND gate
  3. NOR gate
  4. OR- gate

Answer: (d)

Solution

Given $$\overline{\overline{Y}} = \overline{A} \cdot \overline{B}$$ By De-Morgan Law $$\overline{Y} = A + B$$ $$Y = A + B$$ Hence OR gate

Question 37

Physics · Wave Optics · Single correct

The width of one of the two slits in a Young's double slit experiment is 4 times that of the other slit. The ratio of the maximum of the minimum intensity in the interference pattern is:

  1. 1 : 1
  2. 4 : 1
  3. 9 : 1
  4. 16 : 1

Answer: (c)

Solution

Since, Intensity is proportional to the width of slit ($\omega$) so, $I_1 = I, I_2 = 4I$. $$I_{\min} = \left( \sqrt{I_1} - \sqrt{I_2} \right)^2 = I$$ $$I_{\max} = \left( \sqrt{I_1} + \sqrt{I_2} \right)^2 = 9I$$ $$\frac{I_{\max}}{I_{\min}} = \frac{9I}{I} = \frac{9}{1}$$

Question 38

Physics · Gravitation · Single correct

Correct formula for height of a satellite from earths surface is:

  1. $\left( \frac{T^2 R^2}{4 \pi^2 g} \right)^{1/3} - R$
  2. $\left( \frac{T^2 R^2 g}{4 \pi^2} \right)^{1/3} - R$
  3. $\left( \frac{T^2 R^2 g}{4 \pi^2} \right)^{-1/3} + R$
  4. $\left( \frac{T^2 R^2 g}{4 \pi} \right)^{1/2} - R$

Answer: (b)

Solution

Given $\($ $\frac{GMm}{(R+h)^2}$ = $\frac{mv^2}{(R+h)}$ $\)$ $\($ $\Rightarrow$ $\frac{GM}{(R+h)}$ = v^2 $\)$ ....(1) $\($ $\Rightarrow$ v = (R+h)$\omega$ $\)$ $\($ $\Rightarrow$ v = (R+h)$\frac{2\pi}{T}$ $\)$ ....(2) $\($ $\Rightarrow$ $\frac{GM}{R^2}$ = g $\)$ $\($ $\Rightarrow$ GM = gR^2 $\)$ ....(3) Put value from (2) $\&$ (3) in eq. (1) $\($ $\Rightarrow$ $\frac{gR^2}{(R+h)}$ = (R+h)^2 $\left$( $\frac{2\pi}{T}$ $\right$)^2 $\)$ $\($ $\Rightarrow$ $\frac{T^2 R^2 \, g}{(2\pi)^2}$ = (R+h)^3 $\)$ $\($ $\Rightarrow$ $\left$[ $\frac{T^2 R^2 \, g}{(2\pi)^2}$ $\right$]^{1/3} - R = h $\)$

Question 39

Physics · Current Electricity · Single correct

Match List I with List II

  1. A-I. B-IV. C-II. D-III
  2. A-IV. B-I. C-II. D-III
  3. A-IV. B-I. C-III. D-II
  4. A-I. B-IV. C-III. D-II

Answer: (a)

Solution

A - V lags by 90^$\circ$ from I hence option (I) is correct. B - V lead by 90^$\circ$ from I hence option (IV) is correct C - In LCR resonance $X_L = X_C$. Hence circuit is purely resistive so option (II) is correct D - In LCR series V is at some angle from I hence (III) is correct.

Question 40

Physics · Mechanical Properties of Fluids · Single correct

Given below are two statements : Statement I : The contact angle between a solid and a liquid is a property of the material of the solid and liquid as well. Statement II : The rise of a liquid in a capillary tube does not depend on the inner radius of the tube. In the light of the above statements, choose the correct answer from the options given below:

  1. Statement I is true but Statement II is false.
  2. Statement I is false but Statement II is true.
  3. Both Statement I and Statement II are false.
  4. Both Statement I and Statement II are true.

Answer: (a)

Solution

Statement I is correct as we know contact angle depends on cohesive and adhesive forces. Statement II is incorrect because height of liquid is given by $$h = \frac{2T \cos \theta_c}{\rho g r}$$ where $r$ is radius of Tube (assuming length of capillary is sufficient).

Question 41

Physics · Work, Energy and Power · Single correct

A body of $m$ kg slides from rest along the curve of vertical circle from point $A$ to $B$ in friction less path. The velocity of the body at $B$ is:

  1. 16.7 m/s
  2. 19.8 m/s
  3. 10.6 m/s
  4. 21.9 m/s

Answer: (d)

Solution

Apply W.E.T. from $A$ to $B$ $$\Rightarrow W_{mg} = K_B - K_A$$ $$\Rightarrow mg\left(\frac{R}{\sqrt{2}} + R\right) = \frac{1}{2}mv_B^2 - 0 \quad \{v_A = 0 \text{ rest}\}$$ $$\Rightarrow mgR\,\frac{(\sqrt{2}+1)}{\sqrt{2}} = \frac{1}{2}mv_B^2$$ $$\Rightarrow \sqrt{gR\,\frac{2(\sqrt{2}+1)}{\sqrt{2}}} = v_B$$ $$\Rightarrow \sqrt{\frac{10 \times 14 \times 2(2.4)}{1.4}} = v_B$$ $$\Rightarrow 21.9 = v_B$$

Question 42

Physics · Current Electricity · Single correct

An electric bulb rated $50 \, \mathrm{W} - 200 \, \mathrm{V}$ is connected across a $100 \, \mathrm{V}$ supply. The power dissipation of the bulb is:

  1. 25 $\mathrm{W}$
  2. 12.5 $\mathrm{W}$
  3. 50 $\mathrm{W}$
  4. 100 $\mathrm{W}$

Answer: (b)

Solution

Rated power and voltage gives resistance $$R = \frac{V^2}{P} = \frac{(200)^2}{50} = \frac{40000}{50}$$ $$R = 800$$ $$P = \frac{(V_{applied})^2}{R} = \frac{(100)^2}{800}$$ $$P = 12.5 watt$$

Question 43

Physics · Laws of Motion · Single correct

A 2 kg brick begins to slide over a surface which is inclined at an angle of $45^\circ$ with respect to horizontal axis. The co-efficient of static friction between their surfaces is:

  1. 1.7
  2. $\frac{1}{\sqrt{3}}$
  3. 0.5
  4. 1

Answer: (d)

Solution

Given the forces acting on the inclined plane, we have: $$mg \sin 45 = f_L$$ $$mg \cos 45 = N$$ The frictional force is given by: $$f_L = \mu_s N$$ The coefficient of static friction is: $$\mu_s = \tan 45 = 1$$ Alternatively, using the angle of repose: $$\tan \theta = \mu_s (\theta is angle of repose)$$ Thus: $$\tan 45 = \mu_s = 1$$

Question 44

Physics · Oscillations · Single correct

In simple harmonic motion, the total mechanical energy of given system is $E$. If mass of oscillating particle $P$ is doubled then the new energy of the system for same amplitude is:

  1. $E$
  2. $\frac{E}{\sqrt{2}}$
  3. $2E$
  4. $E\sqrt{2}$

Answer: (a)

Solution

T.E. = $\frac{1}{2}$ k A^2 since A is same T.E. will be same.

Question 45

Physics · Dual Nature of Radiation and Matter · Single correct

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R. Assertion A: Number of photons increases with increase in frequency of light. Reason R: Maximum kinetic energy of emitted electrons increases with the frequency of incident radiation. In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both A and R are correct and R is the correct explanation of A.
  2. Both A and R are correct and R is NOT the correct explanation of A.
  3. A is not correct but R is correct.
  4. A is correct but R is not correct.

Answer: (c)

Solution

Intensity of light $I = \frac{n h \nu}{A}$. Here $n$ is the number of photons per unit time. $$n = \frac{I A}{h \nu}$$ so on increasing frequency $\nu$, $n$ decreases taking intensity constant. $$k_{max} = h \nu - \phi$$ So on increasing $\nu$, kinetic energy increases.

Question 46

Physics · Atoms · Single correct

According to Bohr's theory, the moment of momentum of an electron revolving in $4^{th}$ orbit of hydrogen atom is:

  1. $\frac{h}{\pi}$
  2. $\frac{h}{2\pi}$
  3. $8\frac{h}{\pi}$
  4. $2\frac{h}{\pi}$

Answer: (d)

Solution

Moment of momentum is $\vec{r} \times \vec{P}$ $$\vec{L} = \vec{r} \times m \vec{v}$$ $$L = mvr = \frac{nh}{2\pi} = \frac{4h}{2\pi} = \frac{2h}{\pi}$$

Question 47

Physics · Thermodynamics · Single correct

A sample of gas at temperature $T$ is adiabatically expanded to double its volume. Adiabatic constant for the gas is $\gamma = 3/2$. The work done by the gas in the process is: ($\mu = 1 mole$)

  1. $RT[1 - 2\sqrt{2}]$
  2. $RT[\sqrt{2} - 2]$
  3. $RT[2 - \sqrt{2}]$
  4. $RT[2\sqrt{2} - 1]$

Answer: (c)

Solution

Given $$W = \frac{nR \Delta T}{1 - \gamma}$$ $$TV^{\gamma - 1} = constant = T_f (2V)^{\gamma - 1}$$ $$T_f = T \left( \frac{1}{2} \right)^{1/2} = \frac{T}{\sqrt{2}}$$ $$W = \frac{R \left( \frac{T}{\sqrt{2}} - T \right)}{1 - \frac{3}{2}} = 2RT \left( \frac{\sqrt{2} - 1}{\sqrt{2}} \right)$$ $$= RT(2 - \sqrt{2})$$

Question 48

Physics · Electric Charges and Fields · Single correct

A charge $q$ is placed at the center of one of the surface of a cube. The flux linked with the cube is:

  1. $\frac{q}{2\epsilon_0}$
  2. $\frac{q}{8\epsilon_0}$
  3. Zero
  4. $\frac{q}{4\epsilon_0}$

Answer: (a)

Solution

From $$2\phi = \frac{q}{\epsilon_0}$$ $$\phi = \frac{q}{2\epsilon_0}$$

Question 49

Physics · Physical World, Units and Measurements · Single correct

Applying the principle of homogeneity of dimensions, determine which one is correct, where $T$ is time period, $G$ is gravitational constant, $M$ is mass, $r$ is radius of orbit.

  1. $T^2 = \frac{4\pi^2 r^2}{GM}$
  2. $T^2 = \frac{4\pi^2 r}{GM^2}$
  3. $T^2 = \frac{4\pi^2 r^3}{GM}$
  4. $T^2 = 4\pi^2 r^3$

Answer: (c)

Solution

According to the principle of homogeneity, the dimension of LHS should be equal to the dimensions of RHS, so option (3) is correct. $$T^2 = \frac{4\pi^2 r^3}{GM}$$ $$[T^2] = \frac{[L^3]}{[M^{-1} L^3 T^{-2}][M]}$$ (Dimension of G is $[M^{-1} L^3 T^{-2}]$) $$[T^2] = \frac{[L^3]}{[L^3 T^{-2}]} = [T^2]$$

Question 50

Physics · Gravitation · Single correct

A 90 kg body placed at $2R$ distance from surface of earth experiences gravitational pull of: ($R$ = Radius of earth, $g = 10 \, \mathrm{m} \, \mathrm{s}^{-2}$)

  1. 100 N
  2. 300 N
  3. 225 N
  4. 120 N

Answer: (a)

Solution

Here $g_s$ is the gravitational acceleration at the surface. Value of $g = g_5 \left(1 + \frac{h}{R}\right)^{-2}$ $$= g_5 (1 + 2)^{-2} = \frac{g_5}{9}$$ Force $= mg = 90 \times \frac{g_5}{9} = 100 \, \mathrm{N}$

Question 51

Physics · Oscillations · Numerical

The displacement of a particle executing SHM is given by $x = 10 \sin \left( wt + \frac{\pi}{3} \right) \, \mathrm{m}$. The time period of motion is $3.14 \, \mathrm{s}$. The velocity of the particle at $t = 0$ is ______ m/s.

Answer: 10

Solution

Given, $$T = 3.14 = \frac{2\pi}{\omega}$$ $$\omega = 2 \, \mathrm{rad/s}$$ $$x = 10 \sin \left( \omega t + \frac{\pi}{3} \right)$$ $$v = \frac{dx}{dt} = 10 \omega \cos \left( \omega t + \frac{\pi}{3} \right)$$ at $t = 0$ $$v = 10 \omega \cos \left( \frac{\pi}{3} \right) = 10 \times 2 \times \frac{1}{2} \ [using \omega = 2 \, \mathrm{rad/s}]$$ $$v = 10 \, \mathrm{m/s}$$

Question 52

Physics · Motion in a Straight Line · Numerical

A bus moving along a straight highway with speed of $72 \, \mathrm{km/h}$ is brought to halt within $4 \, \mathrm{s}$ after applying the brakes. The distance travelled by the bus during this time (Assume the retardation is uniform) is $\ldots$ m.

Answer: 40

Solution

Question 53

Physics · Electrostatic Potential and Capacitance · Numerical

A parallel plate capacitor of capacitance $12.5 \, \mathrm{pF}$ is charged by a battery connected between its plates to potential difference of $12.0 \, \mathrm{V}$. The battery is now disconnected and a dielectric slab $(\epsilon_r = 6)$ is inserted between the plates. The change in its potential energy after inserting the dielectric slab is _____ $10^{-12} \, \mathrm{J}$.

Answer: 750

Solution

Before inserting dielectric capacitance is given $C_0 = 12.5 \, \mathrm{pF}$ and charge on the capacitor $Q = C_0 \, V$. After inserting dielectric capacitance will become $\epsilon_r C_0$. Change in potential energy of the capacitor $$= E_i - E_f$$ $$= \frac{Q^2}{2C_i} - \frac{Q^2}{2C_f} = \frac{Q^2}{2C_0} \left[ 1 - \frac{1}{\epsilon_r} \right]$$ $$= \frac{(C_0 \, V)^2}{2C_0} \left[ 1 - \frac{1}{\epsilon_r} \right] = \frac{1}{2} C_0 \, V^2 \left[ 1 - \frac{1}{\epsilon_r} \right]$$ Using $C_0 = 12.5 \, \mathrm{pF}$, $V = 12 \, \mathrm{V}$, $\epsilon_r = 6$ $$= \frac{1}{2} (12.5) \times 12^2 \left[ 1 - \frac{1}{6} \right] = \frac{1}{2} (12.5) \times 12^2 \times \frac{5}{6}$$ $$= 750 \, \mathrm{pJ} = 750 \times 10^{-12} \, \mathrm{J}$$

Question 54

Physics · System of Particles and Rotational Motion · Numerical

In a system two particles of masses $m_1 = 3 \, \mathrm{kg}$ and $m_2 = 2 \, \mathrm{kg}$ are placed at certain distance from each other. The particle of mass $m_1$ is moved towards the center of mass of the system through a distance $2 \, \mathrm{cm}$. In order to keep the center of mass of the system at the original position, the particle of mass $m_2$ should move towards the center of mass by the distance ____ cm.

Answer: 3

Solution

Given $$\Delta X_{C.O.M.} = \frac{m_1 \Delta x_1 + m_2 \Delta x_2}{m_1 + m_2}$$ $$\Rightarrow 0 = \frac{3 \times 2 + 2(-x)}{3 + 2}$$ $$\Rightarrow x = 3 \, cm$$

Question 55

Physics · Nuclei · Numerical

The disintegration energy $Q$ for the nuclear fission of $^{235}\mathrm{U} \rightarrow ^{140}\mathrm{Ce} + ^{94}\mathrm{Zr} + n$ is ____ MeV. Given atomic masses of $^{235}\mathrm{U} : 235.0439u; \, ^{140}\mathrm{Ce} : 139.9054u, \, ^{94}\mathrm{Zr} : 93.9063u; \, n : 1.0086u,$ Value of $c^2 = 931\mathrm{MeV}/u$

Answer: 208

Solution

The reaction is given by $$^{235}\mathrm{U} \rightarrow ^{140}\mathrm{Ce} + ^{94}\mathrm{Zr} + \mathrm{n}$$ Disintegration energy $$Q = (m_R - m_p) \, c^2$$ $$m_R = 235.0439 \, \mathrm{u}$$ $$m_p = 139.9054 \, \mathrm{u} + 93.9063 \, \mathrm{u} + 1.0086 \, \mathrm{u}$$ $$= 234.8203 \, \mathrm{u}$$ $$Q = (235.0439 \, \mathrm{u} - 234.8203 \, \mathrm{u}) c^2$$ $$= 0.2236 \, c^2$$ $$= 0.2236 \times 931$$ $$Q = 208.1716$$

Question 56

Physics · Ray Optics and Optical Instruments · Numerical

A light ray is incident on a glass slab of thickness $4\sqrt{3}$ cm and refractive index $\sqrt{2}$. The angle of incidence is equal to the critical angle for the glass slab with air. The lateral displacement of ray after passing through glass slab is _____ cm. ( Given $\sin 15^\circ = 0.25$)

Answer: 2

Solution

Given $i = \theta_c$. Therefore, $i = \sin^{-1}\left(\frac{1}{\mu}\right)$. Hence, $i = 45^\circ$. According to Snell's law, $1 \sin 45^\circ = \sqrt{2} \sin r$. Therefore, $r = 30^\circ$. The lateral displacement $\Delta = \frac{t \sin(i - r)}{\cos r}$. Thus, $\Delta = \frac{4 \sqrt{3} \times \sin 15^\circ}{\cos 30^\circ}$. Therefore, $\Delta = 2 \, \mathrm{cm}$.

Question 57

Physics · Electromagnetic Induction · Numerical

A rod of length 60 $\mathrm{\ cm}$ rotates with a uniform angular velocity 20 $\mathrm{\ rads^{-1}}$ about its perpendicular bisector, in a uniform magnetic field 0.5 $\mathrm{\ T}$. The direction of magnetic field is parallel to the axis of rotation. The potential difference between the two ends of the rod is _____ $\mathrm{V}$.

Answer: 0

Solution

Therefore, $V_0 - V_A = \frac{B \omega \ell^2}{2}$. $V_0 - V_B = \frac{B \omega \ell^2}{2}$. Therefore, $V_A = V_B$. Thus, $V_A - V_B = 0$.

Question 58

Physics · Current Electricity · Numerical

Two wires $A$ and $B$ are made up of the same material and have the same mass. Wire $A$ has radius of $2.0 \, \mathrm{mm}$ and wire $B$ has radius of $4.0 \, \mathrm{mm}$. The resistance of wire $B$ is $2 \, \Omega$. The resistance of wire $A$ is _____ $\Omega$.

Answer: 32

Solution

$R=\dfrac{\rho l}{A}$ $=\dfrac{\rho V}{A^2}$ $\therefore\ \dfrac{R_A}{R_B}$ $=\dfrac{A_B^2}{A_A^2}$ $=\dfrac{r_B^4}{r_A^4}$ $\Rightarrow\ \dfrac{R_A}{R_B}$ $=\left(\dfrac{4\times10^{-3}}{2\times10^{-3}}\right)^4$ $=16$ $\Rightarrow\ R_A=32\Omega$

Question 59

Physics · Moving Charges and Magnetism · Numerical

Two parallel long current carrying wire separated by a distance $2r$ are shown in the figure. The ratio of magnetic field at $A$ to the magnetic field produced at $C$ is $\frac{x}{7}$. The value of $x$ is _____

Answer: 5

Solution

Given $$B_A = \frac{\mu_0 i}{2 \pi r} + \frac{\mu_0 (2i)}{2 \pi (3r)} = \frac{5 \mu_0 i}{6 \pi r}$$ $$B_C = \frac{\mu_0 (2i)}{2 \pi r} + \frac{\mu_0 i}{2 \pi (3r)} = \frac{7 \mu_0 i}{6 \pi r}$$ Therefore, $$\frac{B_A}{B_C} = \frac{5}{7}$$ Thus, $x = 5$

Question 60

Physics · Mechanical Properties of Fluids · Numerical

Mercury is filled in a tube of radius 2 cm up to a height of 30 cm. The force exerted by mercury on the bottom of the tube is _____ N. (Given, atmospheric pressure = $10^5 \, \mathrm{Nm}^{-2}$, density of mercury = $1.36 \times 10^4 \, \mathrm{kg \, m}^{-3}$, $g = 10 \, \mathrm{m \, s}^{-2}$, $\pi = \frac{22}{7}$)

Answer: 177

Solution

F = P_0 A + $\rho$ mghA $$= 10^5 \times \frac{22}{7} \times \left(2 \times 10^{-2}\right)^2$$ $$+ 1.36 \times 10^4 \times 10 \times \left(30 \times 10^{-2}\right) \left(\frac{22}{7} \times \left(2 \times 10^{-2}\right)^2\right)$$ F = 51.29 + 125.71 = 177 $\mathrm{N}$

Chemistry

Question 61

Chemistry · Equilibrium · Single correct

The equilibrium constant for the reaction $$\mathrm{SO_3(g) \rightleftharpoons SO_2(g) + \frac{1}{2}O_2(g)}$$ is $K_c = 4.9 \times 10^{-2}$. The value of $K_c$ for the reaction given below is $$2\mathrm{SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g)}$$ is :

  1. 4.9
  2. 49
  3. 41.6
  4. 416

Answer: (d)

Solution

Given $$K'_C = \left( \frac{1}{K_C} \right)^2 = \left( \frac{1}{4.9 \times 10^{-2}} \right)^2$$ Therefore, $$K'_C = 416.49$$

Question 62

Chemistry · Amines · Single correct

Find out the major product formed from the following reaction. $[Me : -CH_3]$

Answer: (c)

Solution

The above mechanism is valid for both cis and trans isomers. So the products are the same for both cis and trans isomers.

Question 63

Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct

When $\mathrm{MnO_2}$ and $\mathrm{H_2SO_4}$ are added to a salt (A), the greenish yellow gas liberated as salt (A) is:

  1. CaI_2
  2. NaBr
  3. KNO_3
  4. NH_4Cl

Answer: (d)

Solution

The reaction is as follows: $$2 \mathrm{NH_4Cl} + \mathrm{MnO_2} + 2 \mathrm{H_2SO_4} \xrightarrow{\Delta} \mathrm{MnSO_4} + (\mathrm{NH_4})_2\mathrm{SO_4} + 2 \mathrm{H_2O} + \mathrm{Cl_2} \uparrow$$ This results in a greenish yellow solution.

Question 64

Chemistry · Chemical Bonding and Molecular Structure · Single correct

The correct statement/s about Hydrogen bonding is/are A. Hydrogen bonding exists when H is covalently bonded to the highly electro negative atom. B. Intermolecular H bonding is present in o-nitro phenol C. Intramolecular H bonding is present in HF. D. The magnitude of H bonding depends on the physical state of the compound. E. H-bonding has powerful effect on the structure and properties of compounds Choose the correct answer from the options given below:

  1. A, B, D only
  2. A, D, E only
  3. A only
  4. A, B, C only

Answer: (b)

Solution

(A) Generally hydrogen bonding exists when H is covalently bonded to the highly electronegative atom like F, O, N. (B) Intramolecular H bonding is present in (C) Intermolecular Hydrogen bonding is present in HF (D) The magnitude has Hydrogen bonding in solid state is greater than liquid state. (E) Hydrogen bonding has powerful effect on the structure & properties of compound like melting point, boiling point, density etc.

Question 65

Chemistry · Hydrocarbons · Single correct

In the above chemical reaction sequence "A" and "B" respectively are

  1. $\mathrm{H_2O, \ H^+ \ and \ KMnO_4}$
  2. $\mathrm{O_3, \ Zn/H_2O \ and \ NaOH_{(alc)} / I_2}$
  3. $\mathrm{O_3, \ Zn/H_2O \ and \ KMnO_4}$
  4. $\mathrm{H_2O, \ H^+ \ and \ NaOH_{(alc)}/I_2}$

Answer: (b)

Solution

The reaction sequence involves the following steps: Step 1: The cyclohexene undergoes ozonolysis in the presence of $\mathrm{Zn/H_2O}$ to form a diketone. This is represented as compound "A". Step 2: The diketone "A" is treated with $\mathrm{NaOH}$ and $\mathrm{I_2}$, which is a haloform reaction. This results in the formation of a carboxylate ion and chloroform ($\mathrm{CHCl_3}$). The carboxylate ion is represented as compound "B". The final products are the sodium salt of the carboxylic acid and chloroform.

Question 66

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

Common name of Benzene - 1, 2 - diol is -

  1. catechol
  2. o-cresol
  3. quinol
  4. resorcinol

Answer: (a)

Solution

IUPAC name: Benzene-1,2-diol Common name: catechol

Question 67

Chemistry · Alcohols, Phenols and Ethers · Single correct

Consider the above reactions, identify product $B$ and product $C$.

  1. B = 1-Propanol C = 2-Propanol
  2. B = C = 2-Propanol
  3. B = 2-Propanol C = 1-Propanol
  4. B = C = 1-Propanol

Answer: (c)

Solution

The reaction starts with $\mathrm{CH_3-CH_2-CH_2-Br} + \mathrm{NaOH}$, which converts to $\mathrm{CH_3-CH_2-CH_2-OH}$ in the presence of $\mathrm{C_2H_5OH}$. This is 1-Propanol, labeled as [C]. Alternatively, $\mathrm{CH_3-CH=CH_2}$ is formed as a product, which can further react with $\mathrm{H_2O/H^+}$ to form $\mathrm{CH_3-CH(OH)-CH_3}$, which is 2-Propanol, labeled as [B].

Question 68

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

The adsorbent used in adsorption chromatography is/are: A. Silica Gel B. Alumina C. Quick lime D. Magnesia Choose the most appropriate answer from the options given below:

  1. A only
  2. B only
  3. C and D only
  4. A and B only

Answer: (d)

Solution

The most common polar and acidic support used in adsorption chromatography is silica. The surface silanol groups on their support adsorb polar compounds and work particularly well for basic substances. Alumina is an example of a polar and basic adsorbent that is used in adsorption chromatography.

Question 69

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

Product P is

Answer: (c)

Solution

The reaction involves the elimination of HBr from the given alkyl bromide in the presence of alcoholic KOH. This is an example of a dehydrohalogenation reaction, which typically follows the E2 mechanism. The major product is the more substituted alkene, which is formed according to Zaitsev's rule.

Question 70

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

Correct order of stability of carbanion is -

  1. $d > a > c > b$
  2. $a > b > c > d$
  3. $d > c > b > a$
  4. $c > b > d > a$

Answer: (c)

Solution

As we know compound (d) is aromatic and the compound (a) is anti-aromatic. Hence compound (d) is most stable and compound (a) is least stable among these in compound (b) and (c) carbon atom of that positive charge is $sp^3$ hybridised they on the basis of angle strain theory compound (c) is more stable than compound (b).

Question 71

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

The correct order of the first ionization enthalpy is

  1. $\mathrm{Al} > \mathrm{Ga} > \mathrm{Tl}$
  2. $\mathrm{Ga} > \mathrm{Al} > \mathrm{B}$
  3. $\mathrm{Tl} > \mathrm{Ga} > \mathrm{Al}$
  4. $\mathrm{B} > \mathrm{Al} > \mathrm{Ga}$

Answer: (c)

Solution

Q3 (i) due to lanthanide contraction Tl has more I.E. as compared to Ga and Al. (ii) due to scandide contraction Ga has more I.E. as compared to Al.

Question 72

Chemistry · Co-ordination Compounds · Single correct

If an iron (III) complex with the formula $[\mathrm{Fe(NH_3)}_x(\mathrm{CN})_y]^-$ has no electron in its $e_g$ orbital, then the value of $x + y$ is

  1. 4
  2. 5
  3. 6
  4. 3

Answer: (c)

Solution

Complex is $\left[ \mathrm{Fe(NH_3)_2(CN)_4} \right]^\ominus$. $x = 2$ $y = 4$ so $x + y = 6$

Question 73

Chemistry · Electrochemistry · Single correct

Fuel cell, using hydrogen and oxygen as fuels, A. has been used in spaceship B. has as efficiency of 40$\%$ to produce electricity C. uses aluminum as catalysts D. is eco-friendry E. is actually a type of Galvanic cell only Choose the correct answer from the options given below:

  1. A, B, D, E only
  2. A, D, E only
  3. A, B, D only
  4. A, B, C only

Answer: (b)

Solution

Fuel cell is used in spaceship and it is type of galvanic cell.

Question 74

Chemistry · Structure of Atom · Single correct

Choose the Incorrect Statement about Dalton's Atomic Theory

  1. chemical reactions involve reorganization of atoms
  2. Matter consists of indivisible atoms.
  3. Compounds are formed when atoms of different elements combine in any ratio.
  4. Compounds are formed when atoms of different elements combine in any ratio. All the atoms of a given element have identical properties including identical mass.

Answer: (c)

Solution

In compound atoms of different elements combine in fixed ratio by mass.

Question 75

Chemistry · Biomolecules · Single correct

Match List I with List II \begin{tabular}{|c|l|c|l|} \hline & List - I & & List - II \\ \hline A. & $\alpha$-Glucose and $\alpha$-Galactose & I. & Functional isomers \\ \hline B. & $\alpha$-Glucose and $\beta$-Glucose & II. & Homologous \\ \hline C. & $\alpha$-Glucose and $\alpha$-Fructose & III. & Anomers \\ \hline D. & $\alpha$-Glucose and $\alpha$-Ribose & IV. & Epimers \\ \hline \end{tabular} Choose the correct answer from the options given below:

  1. A-IV, B-III, C-I, D-II
  2. A-III, B-IV, C-I, D-II
  3. A-IV, B-III, C-II, D-I
  4. A-III, B-IV, C-II, D-I

Answer: (a)

Solution

Based on biomolecules theory and structure of these named compounds - (A) $\alpha$-Glucose and $\alpha$-Galactose (IV) Epimers. (B) $\alpha$-Glucose and $\beta$-Glucose (III) Anomers (C) $\alpha$-Glucose and $\alpha$-Fructose (I) Functional isomers (D) $\alpha$-Glucose and $\alpha$-Ribose (II) Homologous

Question 76

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

Given below are two statements : Statement I : The correct order of first ionization enthalpy values of Li, Na, F and Cl is Na < Li < Cl < F. Statement II : The correct order of negative electron gain enthalpy values of Li, Na, F and Cl is Na < Li < F < Cl In the light of the above statements, choose the correct answer from the options given below :

  1. Statement I is true but Statement II is false
  2. Statement I is false but Statement II is true
  3. Both Statement I and Statement II are false
  4. Both Statement I and Statement II are true

Answer: (d)

Solution

Q4 (i) $\mathrm{Na} < \mathrm{Li} < \mathrm{Cl} < \mathrm{F}$ I.E$_1$ in kJ/mol $\downarrow$ $496 520 1256 1681$ (ii) $\mathrm{Na} < \mathrm{Li} < \mathrm{F} < \mathrm{Cl}$ $\Delta_{eg} \mathrm{H}$ in kJ/mol $\downarrow$ $-53 -60 -328 -349$

Question 77

Chemistry · Electrochemistry · Single correct

For a strong electrolyte, a plot of molar conductivity against (concentration) $^{1/2}$ is a straight line, with a negative slope, the correct unit for the slope is

  1. $\mathrm{Scm}^{2}\ \mathrm{mol}^{-3/2}\ \mathrm{L}^{-1/2}$
  2. $\mathrm{Scm}^{2}\ \mathrm{mol}^{-3/2}\ \mathrm{L}^{1/2}$
  3. $\mathrm{Scm}^{2}\ \mathrm{mol}^{-3/2}\ \mathrm{L}$
  4. $\mathrm{Scm}^{2}\ \mathrm{mol}^{-1}\ \mathrm{L}^{1/2}$

Answer: (b)

Solution

$\Lambda_m=\Lambda_m^{\circ}-A\sqrt{C}$ Units of $A\sqrt{C}= \mathrm{Scm}^{2}\ \mathrm{mole}^{-1}$ Units of $A=\mathrm{Scm}^{2}\ \mathrm{mole}^{-3/2}\ \mathrm{L}^{1/2}$

Question 78

Chemistry · The d-and f-Block Elements · Single correct

A first row transition metal in its +2 oxidation state has a spin-only magnetic moment value of 3.86BM. The atomic number of the metal is

  1. 26
  2. 25
  3. 23
  4. 22

Answer: (c)

Solution

For $\mathrm{Ti}^{+2}$ with atomic number 22, the electron configuration is $[\mathrm{Ar}] 3d^2$. For $\mathrm{V}^{+2}$ with atomic number 23, the electron configuration is $[\mathrm{Ar}] 3d^3$. For $\mathrm{Mn}^{+2}$ with atomic number 25, the electron configuration is $[\mathrm{Ar}] 3d^5$. For $\mathrm{Fe}^{+2}$ with atomic number 26, the electron configuration is $[\mathrm{Ar}] 3d^6$.

Question 79

Chemistry · Co-ordination Compounds · Single correct

The number of unpaired d-electrons in $[\mathrm{Co}(\mathrm{H}_2\mathrm{O})_6]^{3+}$ is

  1. 2
  2. 1
  3. 0
  4. 4

Answer: (c)

Solution

Given $[\mathrm{Co(H_2O)_6}]^{+3}$. The electron configuration for $\mathrm{Co^{+3}}$ is $d^6$. The $t_{2g}$ orbitals are fully filled with paired electrons. There are no unpaired electrons.

Question 80

Chemistry · Chemical Bonding and Molecular Structure · Single correct

The number of species from the following that have pyramidal geometry around the central atom is _______. $\mathrm{S_2O_3^{2-}}$, $\mathrm{SO_4^{2-}}$, $\mathrm{SO_3^{2-}}$, $\mathrm{S_2O_7^{2-}}$

  1. 4
  2. 3
  3. 2
  4. 1

Answer: (d)

Solution

The first structure is pyramidal. The remaining structures are tetrahedral with respect to the central atom.

Question 81

Chemistry · Structure of Atom · Numerical

The maximum number of orbitals which can be identified with $n = 4$ and $m_l = 0$ is ______

Answer: 4

Solution

Given $n = 4$, the orbitals are $4s$, $4p$, $4d$, and $4f$. For $m_l$, each orbital can have $1$ value. So answer is 4.

Question 82

Chemistry · Chemical Bonding and Molecular Structure · Numerical

Number of compounds / species from the following with non-zero dipole moment is $BeCl_2, BCl_3, NF_3, XeF_4, CCl_4, H_2O, H_2 S, HBr, CO_2, H_2, HCl$

Answer: 5

Solution

Polar molecule: $\mathrm{NF_3}$, $\mathrm{H_2O}$, $\mathrm{H_2S}$, $\mathrm{HBr}$, $\mathrm{HCl}$ $\mu \neq 0$ Non Polar molecule: $\mathrm{BeCl_2}$, $\mathrm{BCl_3}$, $\mathrm{XeF_4}$, $\mathrm{CCl_4}$, $\mathrm{CO_2}$, $\mathrm{H_2}$ $\mu = 0$ So answer is 5.

Question 83

Chemistry · Thermodynamics · Numerical

Three moles of an ideal gas are compressed isothermally from 60 $\mathrm{L}$ to 20 $\mathrm{L}$ using constant pressure of 5 $\mathrm{atm}$. Heat exchange Q for the compression is -

Answer: 200

Solution

As isothermal $\Delta U = 0$ and process is irreversible. $Q = -W = -[-P_{ext} (V_2 - V_1)]$. $Q = 5(20 - 60) = -200 \, atm - L$

Question 84

Chemistry · Amines · Numerical

From 6.55 g of aniline, the maximum amount of acetanilide that can be prepared will be ___ $\times 10^{-1}$ $\mathrm{g}$.

Answer: 95

Solution

93 g aniline form 135 g acetanilide. So 6.55 g aniline form $$\frac{135}{93} \times 6.55 = 9.5$$. $$95 \times 10^{-1}$$

Question 85

Chemistry · Chemical Kinetics and Nuclear Chemistry · Numerical

Consider the following reaction, the rate expression of which is given below $\mathrm{A + B \rightarrow C}$ $\text{rate} = k[\mathrm{A}]^{1/2}[\mathrm{B}]^{1/2}$ The reaction is initiated by taking $1\,\mathrm{M}$ concentration of A and B each. If the rate constant $(k)$ is $4.6 \times 10^{-2}\,\mathrm{s^{-1}}$, then the time taken for A to become $0.1\,\mathrm{M}$ is _____ sec. (nearest integer)

Answer: 50

Solution

Given $\($ K = $\frac{2.303}{t}$ $\log$ $\frac{1}{0.1}$ $\)$. $\($ 4.6 $\times$ 10^{-2} = $\frac{2.303}{t}$ $\)$. $\($ t = 50 sec. $\)$

Question 86

Chemistry · Amines · Numerical

Phthalimide is made to undergo following sequence of reactions. Total number of $\pi$ bonds present in product 'P' is/are

Answer: 8

Solution

Total number of $\pi$-bonds present in product $P$ is 8.

Question 87

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Numerical

The total number of 'sigma' and 'Pi' bonds in 2-oxohex-4-ynoic acid is

Answer: 18

Solution

Number of $\sigma$-bonds $= 14$ Number of $\pi$-bonds $= 4$ $= 18$

Question 88

Chemistry · The d-and f-Block Elements · Numerical

A first row transition metal with highest enthalpy of atomisation, upon reaction with oxygen at high temperature forms oxides of formula $M_2O_n$ (where $n = 3, 4, 5$). The 'spin-only' magnetic moment value of the amphoteric oxide from the above oxides is ______ BM (near integer) (Given atomic number: Sc : 21, Ti : 22, V : 23, Cr : 24, Mn : 25, Fe : 26, Co : 27, Ni : 28, Cu : 29, Zn : 30)

Answer: 0

Solution

V has the highest enthalpy of atomisation ($515 \, \mathrm{kJ/mol}$) among first row transition elements. $\mathrm{V_2O_5}$ Here V is in $+5$ oxidation state. $\mathrm{V^{+5}} \Rightarrow 1s^2 2s^2 2p^6 3s^2 3p^6$ (no unpaired electrons)

Question 89

Chemistry · Solutions · Numerical

$2.7\ \mathrm{kg}$ of each of water and acetic acid are mixed. The freezing point of the solution will be $-x^\circ\mathrm{C}$. Consider the acetic acid does not dimerise in water, nor dissociates in water. $x=$ (nearest integer) Given: Molar mass of water $=18\ \mathrm{g\,mol^{-1}}$ Molar mass of acetic acid $=60\ \mathrm{g\,mol^{-1}}$ $K_f$ of $\mathrm{H_2O}$ $=1.86\ \mathrm{K\,kg\,mol^{-1}}$ $K_f$ of acetic acid $=3.90\ \mathrm{K\,kg\,mol^{-1}}$ Freezing point of$\mathrm{H_2O}$ $=273\ \mathrm{K}$ Freezing point of acetic acid $=290\ \mathrm{K}$

Answer: 31

Solution

As moles of water > moles of $\mathrm{CH_3COOH}$ water is solvent. $$T_F^\circ - (T_F)_S = K_F \times M$$ $$0 - (T_F)_S = 1.86 \times \frac{2700/60}{2700/1000}$$ $$(T_F)_S = -31^\circ \mathrm{C}.$$

Question 90

Chemistry · Biomolecules · Numerical

Vanillin compound obtained from vanilla beans, has total sum of oxygen atoms and $\pi$ electrons is

Answer: 11

Solution

Vanillin compound is an organic compound molecular formula $\mathrm{C_8H_8O_3}$. It is a phenolic aldehyde. Its functional compounds include aldehyde, hydroxyl and ether. It is the primary component of the extract of the vanilla beans. Total sum of oxygen atoms and $\pi$-electrons is $3 + 8 = 11$ Total number of oxygen atoms $= 3$ Total number of $\pi$-bonds $= 4$ Therefore, total number of $\pi$-electrons $= 8$