JEE Main 30 January 2023 Shift 1 question paper with solutions
JEE Main 30 January 2023 Shift 1: all 90 questions in paper order (Physics, Chemistry, Maths) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.
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Physics
Question 1
Physics · Electric Charges and Fields · Single correct
Electric field in a certain region is given by $$\vec{E} = \left( \frac{A}{x^2} \hat{i} + \frac{B}{y^3} \hat{j} \right).$$ The SI unit of $A$ and $B$ are:
Nm$^3$C$^{-1}$; Nm$^2$C$^{-1}$
Nm$^2$C$^{-1}$; Nm$^3$C$^{-1}$
Nm$^3$C; Nm$^2$C
Nm$^2$C; Nm$^3$C
Answer: (b)
Solution
The electric field vector is given by $$\vec{E} = \frac{A}{x^2} \hat{i} + \frac{B}{y^3} \hat{j}$$. The dimensional analysis for the term $$\left[ \frac{A}{x^2} \right] = \mathrm{NC^{-1}}$$ implies that $$[A] = \mathrm{Nm^2C^{-1}}$$.
Question 2
Physics · Motion in a Straight Line · Single correct
Match Column-I with Column-II :
A- II B-IV, C-III, D-I
A- I, B-II, C-III, D-IV
A- II B-III, C-IV, D-I
A- I, B-III. C-IV, D-II
Answer: (a)
Solution
Given $\($ $\frac{dx}{dt}$ = slope $\geq$ 0 $\)$ always increasing. (A - II) $\($ $\frac{dx}{dt}$ 0 $\)$ for first half, $\($ $\frac{dx}{dt}$ < 0 $\)$ for second half. (C - III) $\($ $\frac{dx}{dt}$ = constant $\)$
Question 3
Physics · Laws of Motion · Single correct
The figure represents the momentum time (p-t) curve for a particle moving along an axis under the influence of the force. Identify the regions on the graph where the magnitude of the force is maximum and minimum respectively? If $(t_3 - t_2) < t_1$.
c and a
b and c
c and b
a and b
Answer: (c)
Solution
Given $\left| \frac{d\vec{p}}{dt} \right| = \left| \vec{F} \right|$, it implies $\frac{d\vec{p}}{dt} = Slope of curve$. Max slope (c) min slope (b)
Question 4
Physics · Work, Energy and Power · Single correct
As per the given figure, a small ball P slides down the quadrant of a circle and hits the other ball Q of equal mass which is initially at rest. Neglecting the effect of friction and assume the collision to be elastic, the velocity of ball Q after collision will be : (g = 10 $\mathrm{m/s^2}$)
0
0.25 $\mathrm{m/s}$
2 $\mathrm{m/s}$
4 $\mathrm{m/s}$
Answer: (c)
Solution
The velocities will be interchanged after collision. Speed of P just before collision = $\sqrt{2gh}$ $$= \sqrt{2 \times 10 \times 0.2} = 2 \, \mathrm{m/s}$$
Question 5
Physics · System of Particles and Rotational Motion · Single correct
A ball of mass 200 g rests on a vertical post of height 20 m. A bullet of mass 10 g, travelling in horizontal direction, hits the centre of the ball. After collision both travels independently. The ball hits the ground at a distance 30 m and the bullet at a distance of 120 m from the foot of the post. The value of initial velocity of the bullet will be (if $g = 10 \, \mathrm{m/s^2}$):
If the gravitational field in the space is given as $\left( -\frac{K}{r^2} \right)$. Taking the reference point to be at $r = 2 \, \mathrm{cm}$ with gravitational potential $V = 10 \, \mathrm{J/kg}$. Find the gravitational potential at $r = 3 \, \mathrm{cm}$ in SI unit (Given, that $K = 6 \, \mathrm{J \, cm/kg}$)
9
11
12
10
Answer: (b)
Solution
Given $\($-$\frac{dV}{dr}$ = -$\frac{k}{r^2}$$\)$, we have $\($$\int$_{10}^{V} dV = $\int$_{2}^{3} $\frac{k}{r^2}$ $\,$ dr$\)$. This implies $\($V - 10 = k $\left$[ $\frac{1}{2}$ - $\frac{1}{3}$ $\right$]$\)$. Simplifying, $\($V - 10 = $\frac{k}{6}$ $\Rightarrow$ V = 11$\)$ volts.
Question 7
Physics · Mechanical Properties of Solids · Single correct
Choose the correct relationship between Poisson ratio $\sigma$, bulk modulus $(K)$ and modulus of rigidity $(\eta)$ of a given solid object:
Physics · Mechanical Properties of Fluids · Single correct
The height of liquid column raised in a capillary tube of certain radius when dipped in liquid A vertically is, 5 cm. If the tube is dipped in a similar manner in another liquid B of surface tension and density double the values of liquid A, the height of liquid column raised in liquid B would be ______ m.
0.20
0.5
0.05
0.10
Answer: (c)
Solution
Given $$h = \frac{2S \cos \theta}{r \rho g}$$ Therefore, $$\frac{h_1}{h_2} = \frac{S_1}{S_2} \frac{\rho_2}{\rho_1}$$ $$\frac{5}{h_2} = \left[ \frac{1}{2} \right] \left[ \frac{2}{1} \right] \implies h_2 = 5 \, \mathrm{cm} = 0.05 \, \mathrm{m}$$ {Info about angle of contact not there so most}
Question 9
Physics · Thermodynamics · Single correct
Heat is given to an ideal gas in an isothermal process. A. Internal energy of the gas will decrease. B. Internal energy of the gas will increase. C. Internal energy of the gas will not change. D. The gas will do positive work. E. The gas will do negative work. Choose the correct answer from the options given below:
A and E only
B and D only
C and E only
C and D only
Answer: (d)
Solution
Given $dQ = dU + dW$. Therefore, $dU = nC_V \, dT$. Since $dU = 0$ for isothermal processes, $U$ is constant. Also, $dQ > 0$ (supplied). Hence, $dW > 0$.
Question 10
Physics · Kinetic Theory · Single correct
The pressure (P) and temperature (T) relationship of an ideal gas obeys the equation $PT^2 = constant$. The volume expansion coefficient of the gas will be:
$3T^2$
$\frac{3}{T^2}$
$\frac{3}{T^3}$
$\frac{3}{T}$
Answer: (d)
Question 11
Physics · Electric Charges and Fields · Single correct
Two isolated metallic solid spheres of radii $R$ and $2R$ are charged such that both have same charge density $\sigma$. The spheres are then connected by a thin conducting wire. If the new charge density of the bigger sphere is $\sigma'$. The ratio $\frac{\sigma'}{\sigma}$ is:
The charge flowing in a conductor changes with time as $Q(t) = \alpha t - \beta t^2 + \gamma t^3$. Where $\alpha, \beta$ and $\gamma$ are constants. Minimum value of current is :
$\alpha - \frac{3\beta^2}{\gamma}$
$\alpha - \frac{\gamma^2}{3\beta}$
$\beta - \frac{\alpha^2}{3\gamma}$
$\alpha - \frac{\beta^2}{3\gamma}$
Answer: (d)
Solution
Given $Q = \left( \alpha t - \beta t^2 + \gamma t^3 \right)$. The current $i = \frac{dQ}{dt} = \left( \alpha - 2 \beta t + 3 \gamma t^2 \right)$. Differentiating $i$ with respect to $t$, we have: $$\frac{di}{dt} = \left( 3 \gamma t - 2 \beta \right) = 0$$ Solving for $t$, we get: $$t = \frac{\beta}{3 \gamma}$$ Substituting back, we find: $$i = \left( \alpha - 2 \beta t + 3 \gamma t^2 \right) = \left( \alpha - \frac{\beta^2}{3 \gamma} \right)$$
Question 13
Physics · Moving Charges and Magnetism · Single correct
A massless square loop, of wire of resistance $10 \, \Omega$, supporting a mass of $1 \, \mathrm{g}$, hangs vertically with one of its sides in a uniform magnetic field of $10^3 \, \mathrm{G}$, directed outwards in the shaded region. A dc voltage $V$ is applied to the loop. For what value of $V$, the magnetic force will exactly balance the weight of the supporting mass of $1 \, \mathrm{g}$? (If sides of the loop $= 10 \, \mathrm{cm}$, $g = 10 \, \mathrm{ms}^{-2}$)
Physics · Moving Charges and Magnetism · Single correct
The magnetic moments associated with two closely wound circular coils A and B of radius $r_A = 10 \, \mathrm{cm}$ and $r_B = 20 \, \mathrm{cm}$ respectively are equal if: (Where $N_A$, $I_A$ and $N_B$, $I_B$ are number of turn and current of A and B respectively)
$2N_A I_A = N_B I_B$
$N_A = 2N_B$
$N_A I_A = 4N_B I_B$
$4N_A I_A = N_B I_B$
Answer: (c)
Solution
Given $M = N I A$. Since $M_A = M_B$, therefore $N_A I_A A_A = N_B I_B A_B$. Thus, $N_A I_A \pi (0.1)^2 = N_B I_B \pi (0.2)^2$. Therefore, $N_A I_A = 4 N_B I_B$.
Question 15
Physics · Alternating Current · Single correct
In a series LR circuit with $X_L = R$, power factor is $P_1$. If a capacitor of capacitance $C$ with $X_C = X_L$ is added to the circuit the power factor becomes $P_2$. The ratio of $P_1$ to $P_2$ will be:
1:3
1:$\sqrt{2}$
1:1
1:2
Answer: (b)
Solution
Given $P = \frac{R}{Z}$, we have $P_1 = \frac{R}{\sqrt{R^2 + X_L^2}} = \frac{R}{R\sqrt{2}}$ (as $X_L = R$). Therefore, $P_1 = \frac{1}{\sqrt{2}}$. For $P_2$, we have $P_2 = \frac{R}{\sqrt{R^2 + (X_L - X_L)^2}} = P_2 = 1$. Thus, $P_1 = \frac{1}{\sqrt{2}}$.
Question 16
Physics · Ray Optics and Optical Instruments · Single correct
A person has been using spectacles of power $-1.0$ diopter for distant vision and a separate reading glass of power $2.0$ diopters. What is the least distance of distinct vision for this person:
Physics · Dual Nature of Radiation and Matter · Single correct
A small object at rest, absorbs a light pulse of power 20 $\mathrm{mW}$ and duration 300 $\mathrm{ns}$. Assuming speed of light as $3 \times 10^8 \, \mathrm{m/s}$, the momentum of the object becomes equal to:
0.5 $\times$ 10^{-17} $\mathrm{kg \, m/s}$
2 $\times$ 10^{-17} $\mathrm{kg \, m/s}$
3 $\times$ 10^{-17} $\mathrm{kg \, m/s}$
1 $\times$ 10^{-17} $\mathrm{kg \, m/s}$
Answer: (b)
Solution
Momentum is given by the formula $$Momentum = \frac{Energy}{C}$$ which can also be expressed as $$= \frac{Power \times time}{C}$$ Substituting the given values, we have $$= \frac{(20 \times 10^{-3} \, \mathrm{W})(300 \times 10^{-9} \, \mathrm{s})}{3 \times 10^8 \, \mathrm{m/s}}$$ Simplifying this expression, we get $$= 2 \times 10^{-17} \, \mathrm{kg \cdot m/s}$$
Question 18
Physics · Atoms · Single correct
Speed of an electron in Bohr's $7^{th}$ orbit for Hydrogen atom is $3.6 \times 10^6 \, \mathrm{m/s}$. The corresponding speed of the electron in $3^{rd}$ orbit, in m/s is:
Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct
The output waveform of the given logical circuit for the following inputs A and B as shown below, is: Inputs
Answer: (d)
Solution
Given the expressions: $$(A \cdot A) = A$$ $$\overline{B \cdot B} = \overline{B}$$ $$\overline{\overline{A \cdot B}} = A + B$$ This represents an OR Gate.
Question 20
Physics · Alternating Current · Single correct
A sinusoidal carrier voltage is amplitude modulated. The resultant amplitude modulated wave has maximum and minimum amplitude of 120 V and 80 V respectively. The amplitude of each sideband is :
15 V
10 V
20 V
5 V
Answer: (b)
Solution
Given $A_c + A_m = 120$ and $A_c - A_m = 80$. Therefore, $$A_c = 100$$ $$A_m = 20$$ Modulation index is given by $$\frac{20}{100} = \frac{1}{5}$$ Amplitude of each sideband is $$= \frac{A_c \times (modulation index)}{2}$$ $$= 100 \times \frac{1}{10} = 10 volt$$
Question 21
Physics · Motion in a Straight Line · Numerical
A horse rider covers half the distance with $5 \, \mathrm{m/s}$ speed. The remaining part of the distance was travelled with speed $10 \, \mathrm{m/s}$ for half the time and with speed $15 \, \mathrm{m/s}$ for other half of the time. The mean speed of the rider averaged over the whole time of motion is $x/7 \, \mathrm{m/s}$. The value of $x$ is
Answer: 50
Solution
Given $t_{AB} = \frac{x}{5 \, \mathrm{m/s}}$. In motion BC, $x = d_1 + d_2$ where $d_1$ and $d_2$ are the distances travelled with $10 \, \mathrm{m/s}$ and $15 \, \mathrm{m/s}$ respectively in equal time intervals $\frac{t}{2}$ each. $$d_1 = \frac{10t}{2}, d_2 = \frac{15t}{2}$$ $$d_1 + d_2 = x = \frac{t}{2}(10 + 15) = \frac{25t}{2}$$ $$\langle v \rangle = \frac{2x}{\frac{x}{5} + \frac{2x}{25}} = \frac{2 \times 25}{5 + 2} = \frac{50}{7} \, \mathrm{m/s}$$ Ans.: 50
Question 22
Physics · System of Particles and Rotational Motion · Fill in the blank
A thin uniform rod of length $2\,\mathrm{m}$, cross-sectional area $A$ and density $d$ is rotated about an axis passing through the centre and perpendicular to its length with angular velocity $\omega$. If value of $\omega$ in terms of the rotational kinetic energy $E$ is \[ \sqrt{\frac{\alpha E}{A d}}, \] then the value of $\alpha$ is .
The general displacement of a simple harmonic oscillator is $x = A \sin \omega t$. Let $T$ be its time period. The slope of its potential energy $(U)$ – time $(t)$ curve will be maximum when $t = \frac{T}{\beta}$. The value of $\beta$ is
Answer: 8
Solution
Given $x = A \sin(\omega t)$. The potential energy $U_{(x)} = \frac{1}{2} k x^2$, Differentiating with respect to $t$, $$\frac{dU}{dt} = \frac{1}{2} k 2x \frac{dx}{dt}$$ Substituting $x = A \sin(\omega t)$, $$= k A^2 \omega \sin \omega t \cos \omega t \times \frac{2}{2}$$ The maximum rate of change of potential energy is $$\left( \frac{dU}{dt} \right)_{max} = \frac{k A^2 \omega}{2} (\sin 2\omega t)_{max}$$ Solving for $\omega t$, $$2\omega t = \frac{\pi}{2} \Rightarrow t = \frac{\pi}{4} \omega = \frac{T}{8} \Rightarrow \beta = 8$$
Question 24
Physics · Electrostatic Potential and Capacitance · Numerical
A capacitor of capacitance $900 \, \mu \mathrm{F}$ is charged by a $100 \, \mathrm{V}$ battery. The capacitor is disconnected from the battery and connected to another uncharged identical capacitor such that one plate of uncharged capacitor connected to positive plate and another plate of uncharged capacitor connected to negative plate of the charged capacitor. The loss of energy in this process is measured as $x \times 10^{-2} \, \mathrm{J}$. The value of $x$ is
Answer: 225
Solution
Given $C = 900 \, \mu \mathrm{F}$. $Q = CV = 900 \times 10^{-6} \times 100 = 9 \times 10^{-2} = 90 \, \mathrm{MC}$. Now, $$\begin{array}{c} At t = 0 \\ \begin{array}{c|c} 90 \, \mathrm{mc} & -90 \, \mathrm{mc} \\ C & C \\ Q = 0 & \\ \end{array} \end{array}$$ Common potential will be developed across both capacitors by KVL. Total charge on left plates of capacitors should be conserved. $$90 \, \mathrm{mc} + 0 = 2C V_0$$ $$C V_0 = 45 \, \mathrm{mc}$$ $$\begin{array}{c|c} 45 \, \mathrm{mc} & -45 \, \mathrm{mc} \\ C & C \\ \end{array}$$ $$\frac{1}{2} (90 \, \mathrm{mc})^2 + \frac{1}{2} (45 \, \mathrm{mc})^2 = \frac{1}{2} \left[ \frac{Q^2}{C} \right]$$
Question 25
Physics · Current Electricity · Fill in the blank
In the following circuit, the magnitude of current $I_1$, is $\_$$\_$$\_$ A.
Answer: 1
Solution
Junction law at A, $$\frac{x - (y + 5)}{1} + \frac{x - 2}{2} + \frac{x - 0}{2} = 0 \ldots(1)$$ Junction law at B, $$\frac{y + 5 - x}{1} + \frac{y - 0}{1} + \frac{y - 2}{1} = 0 \ldots(2)$$ On solving equation (1) and Equation (2) $$x = 3$$ and $$y = 0$$ At D junction $$I_1 = i_1 + i_2$$ $$I_1 = \frac{y - 0}{1} + \frac{x - 0}{2}$$ $$= \frac{0 - 0}{1} + \frac{3 - 0}{2}$$
Question 26
Physics · Electromagnetic Induction · Numerical
As per the given figure, if $\frac{dI}{dt} = -1 \, \mathrm{A/s}$ then the value of $V_{AB}$ at this instant will be _____ V.
Physics · Ray Optics and Optical Instruments · Numerical
In an experiment for estimating the value of focal length of converging mirror, image of an object placed at 40 cm from the pole of the mirror is formed at distance 120 cm from the pole of the mirror. These distances are measured with a modified scale in which there are 20 small divisions in 1 cm. The value of error in measurement of focal length of the mirror is $1/K$ cm. The value of $K$ is _______.
Answer: 32
Solution
Given $\frac{1}{v} + \frac{1}{u} = \frac{1}{f}$. \[ -\frac{1}{120} - \frac{1}{40} = \frac{1}{f}, \quad f = -30\,\mathrm{cm} \] Now, \[ -\frac{1}{v^2}\,dv - \frac{1}{u^2}\,du = -\frac{1}{f^2}\,df \] Also $(dv = du = \frac{1}{20}\,\mathrm{cm})$ \[ \frac{1}{20}\left(\frac{1}{120}\right)^2 + \frac{1}{20}\left(\frac{1}{40}\right)^2 = \frac{df}{(30)^2} \] On solving \[ df = \frac{1}{32}\,\mathrm{cm} \] Therefore, $k = 32$
Question 28
Physics · Wave Optics · Numerical
In Young's double slit experiment, two slits $S_1$ and $S_2$ are 'd' distance apart and the separation from slits to screen is $D$ (as shown in figure). Now if two transparent slabs of equal thickness $0.1 \, \mathrm{mm}$ but refractive index $1.51$ and $1.55$ are introduced in the path of beam ($\lambda = 4000\, \mathrm{\AA}$) from $S_1$ and $S_2$ respectively. The central bright fringe spot will shift by number of fringes.
Answer: 10
Solution
Path difference at P be $\Delta x$. $$\Delta x = (\mu_2 - \mu_1)t$$ $$= (1.55 - 1.51) \times 0.1 \, \mathrm{mm}$$ $$= 0.04 \times 10^{-4}$$ $$\Delta x = 4 \times 10^{-6} = 4 \, \mu \mathrm{m}$$ $$y = \frac{\Delta x D}{d} = 4 \times 10^{-6} \frac{D}{d}$$ { $y$ is the distance of central maxima from geometric center } Fringe width $= \frac{\lambda D}{d} = 4 \times 10^{-6} \, \mathrm{m} \frac{D}{d} = 4 \, \mu \mathrm{m} \frac{D}{d}$ Therefore, central bright fringe spot will shift by $x$. Number of shift $= \frac{y}{\beta}$ $$= \frac{4 \times 10^{-6} \, D/d}{4 \times 10^{-7} \, D/d} = 10$$ Ans
Question 29
Physics · Dual Nature of Radiation and Matter · Numerical
A point source of light is placed at the centre of curvature of a hemispherical surface. The source emits a power of 24 W. The radius of curvature of hemisphere is 10 cm and the inner surface is completely reflecting. The force on the hemisphere due to the light falling on it is _______ $\times 10^{-8} \, \mathrm{N}$.
In a screw gauge, there are 100 divisions on the circular scale and the main scale moves by 0.5 mm on a complete rotation of the circular scale. The zero of circular scale lies 6 divisions below the line of graduation when two studs are brought in contact with each other. When a wire is placed between the studs, 4 linear scale divisions are clearly visible while $46^{th}$ division the circular scale coincide with the reference line. The diameter of the wire is _________ $\times$ $10^{-2}$ mm.
Chemistry · Classification of Elements and Periodicity in Properties · Single correct
Match List-I with List-II Choose the correct answer from the options given below:
A – II, B – IV, C – I, D – III
A – I, B – III, C – IV, D – II
A – IV, B – III, C – II, D – I
A – IV, B – II, C – I, D – III
Answer: (d)
Solution
The table shows the atomic numbers and corresponding blocks for different elements. Atomic number 37 (K) belongs to the s-block. Atomic number 78 (Pt) belongs to the d-block. Atomic number 52 (Te) belongs to the p-block. Atomic number 65 (Tb) belongs to the f-block.
Question 32
Chemistry · Chemical Bonding and Molecular Structure · Multiple correct
For OF$_2$ molecule consider the following: (A) Number of lone pairs on oxygen is 2. (B) FOF angle is less than 104.5$^\circ$. (C) Oxidation state of O is $-2$. (D) Molecule is bent 'V' shaped. (E) Molecular geometry is linear. Correct options are:
C, D, E only
B, E, A only
A, C, D only
A, B, D only
Answer: (d)
Solution
Two lone pair one oxygen. Molecule is 'v' shaped. Bond angle is less than $104.5^\circ$ ($102^\circ$). O.S. of 'O' is $+2$.
Question 33
Chemistry · Co-ordination Compounds · Single correct
Match List I with List II Choose the correct answer from the options given below:
A – II, B – III, C – IV, D – I
A – IV, B – III, C – II, D – I
A – II, B – I, C – IV, D – III
A – IV, B – I, C – II, D – III
Answer: (b)
Solution
$\mathrm{IF_7}$ has zero lone pair. $\mathrm{ICl_4^-}$ has two lone pairs. $\mathrm{XeF_6}$ has one lone pair. $\mathrm{XeF_2}$ has three lone pairs.
Question 34
Chemistry · The s-Block Elements · Single correct
The alkaline earth metal sulphate(s) which are readily soluble in water is/are:
BeSO_4
MgSO_4
CaSO_4
SrSO_4
Answer: (c)
Solution
Due to high hydration energy $\mathrm{Be^{2+}}$ and $\mathrm{Mg^{2+}}$, $\mathrm{BeSO_4}$ and $\mathrm{MgSO_4}$ are readily soluble in water.
Question 35
Chemistry · The s-Block Elements · Single correct
Lithium aluminium hydride can be prepared from the reaction of
$LiCl$ and $Al_2H_6$
$LiH$ and $Al_2Cl_6$
$LiCl$, $Al$ and $H_2$
LiH and $Al(OH)_3$
Answer: (b)
Solution
The balanced chemical equation is given by: $$8 \mathrm{LiH} + \mathrm{Al_2Cl_6} \rightarrow 2 \mathrm{LiAlH_4} + 6 \mathrm{LiCl}$$
Question 36
Chemistry · Surface Chemistry · Single correct
Given below are two statements: one is labelled as Assertion $(A)$ and the other is labelled as Reason $(R)$. Assertion $(A)$: In expensive scientific instruments, silica gel is kept in watch-glasses or in semipermeable membrane bags. Reason $(R)$: Silica gel adsorbs moisture from air via adsorption, thus protects the instrument from water corrosion (rusting) and / or prevents malfunctioning. In the light of the above statements, choose the correct answer from the options given below:
$(A)$ is false but $(R)$ is true
$(A)$ is true but $(R)$ is false
Both $(A)$ and $(R)$ are true and $(R)$ is the correct explanation of $(A)$
Both $(A)$ and $(R)$ are true but $(R)$ is not the correct explanation of $(A)$
Answer: (c)
Solution
Silica gel prevents water corrosion (rusting) and instrument malfunction by adsorbing moisture from the air.
Question 37
Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct
What is the correct order of acidity of the protons marked A–D in the given compounds ?
$H_C > H_D > H_B > H_A$
$H_C > H_D > H_A > H_B$
$H_D > H_C > H_B > H_A$
$H_C > H_A > H_D > H_B$
Answer: (b)
Solution
The acidity of an acid depends upon the stability of its conjugate base. The given structures show the relative stability of the conjugate bases. The stability order is as follows: $$Structure 1 > Structure 2 > Structure 3 > Structure 4$$
Question 38
Chemistry · Hydrocarbons · Single correct
The major products 'A' and 'B', respectively, are
Answer: (a)
Solution
The reaction starts with the addition of $\mathrm{H^+}$ to the alkene $\mathrm{H_3C - C = CH_2}$, forming a carbocation $\mathrm{H_3C - \overset{+}{C} - CH_3}$. Under the conditions of $\mathrm{H_2SO_4}$ at $80^\circ \mathrm{C}$, the carbocation rearranges to form $\mathrm{CH_3 - C = CH - CH_3}$ (B). The $\mathrm{O^- - SO_3H}$ group then attacks the carbocation, resulting in the formation of $\mathrm{CH_3 - C - CH_3}$ with $\mathrm{OSO_3H}$ attached (A).
Question 39
Chemistry · Environmental Chemistry · Single correct
Formation of photochemical smog involves the following reaction in which A, B and C are respectively. (i) $\mathrm{NO_2} \xrightarrow{h\nu} \mathrm{A + B}$ (ii) $\mathrm{B + O_2 \rightarrow C}$ (iii) $\mathrm{A + C \rightarrow NO_2 + O_2}$ Choose the correct answer from the options given below:
$\mathrm{O, NO \& NO_3^-}$
$\mathrm{O, N_2O \& NO}$
$\mathrm{N, O_2 \& O_3}$
$\mathrm{NO, O \& O_2}$
Answer: (d)
Solution
The reactions are as follows: $$\mathrm{NO_{2(g)} \xrightarrow{h\nu} NO_{(g)} + O_{(g)}}$$ This is reaction (A) and (B). $$\mathrm{O_{(g)} + O_{2(g)} \rightleftharpoons O_{3(g)}}$$ This is reaction (B) and (C). $$\mathrm{NO_{(g)} + O_{3(g)} \rightarrow NO_{2(g)} + O_{2(g)}}$$ This is reaction (A) and (C).
Question 40
Chemistry · General Principles and Processes of Isolation of Elements · Single correct
In the extraction of copper, its sulphide ore is heated in a reverberatory furnace after mixing with silica to:
separate $CuO$ as $CuSiO_3$
remove calcium as $CaSiO_3$
decrease the temperature needed for roasting of $Cu_2S$
remove $FeO$ as $FeSiO_3$
Answer: (d)
Solution
The copper ore contains iron, it is mixed with silica before heating in reverberatory furnace. FeO slags off as $\mathrm{FeSiO_3}$. $$\mathrm{FeO} + \mathrm{SiO_2} \rightarrow \mathrm{FeSiO_3}$$
Question 41
Chemistry · The d-and f-Block Elements · Single correct
During the qualitative analysis of $\mathrm{SO}_3^{2-}$ using dilute $\mathrm{H}_2\mathrm{SO}_4$, $\mathrm{SO}_2$ gas is evolved which turns $\mathrm{K}_2\mathrm{Cr}_2\mathrm{O}_7$ solution (acidified with dilute $\mathrm{H}_2\mathrm{SO}_4$):
Black
Red
Green
Blue
Answer: (c)
Solution
The reaction is given by: $$\mathrm{Cr_2O_7^{2-} + SO_2^{2-} \xrightarrow{H^+} Cr^{3+} + SO_4^{2-}}$$
Question 42
Chemistry · Co-ordination Compounds · Single correct
Which of the following is correct order of ligand field strength?
CO < en < NH_3 < C_2O_4^{2-} < S^{2-}
S^{2-} < C_2O_4^{2-} < NH_3 < en < CO
NH_3 < en < CO < S^{2-} < C_2O_4^{2-}
S^{2-} < NH_3 < en < CO < C_2O_4^{2-}
Answer: (b)
Solution
The increasing order of field strength of ligands (according to spectrochemical series) is $\mathrm{S^{2-} < C_2O_4^{2-} < NH_3 < en < CO}$.
Question 43
Chemistry · Chemistry in Everyday Life · Single correct
To inhibit the growth of tumours, identify the compounds used from the following: \begin{enumerate} \item[(A)] EDTA \item[(B)] Coordination compounds of Pt \item[(C)] D-Penicillamine \item[(D)] Cis-Platin \end{enumerate} Choose the correct answer from the option given below:
B and D Only
C and D Only
A and B Only
A and C Only
Answer: (a)
Solution
Cis-Platin is used in chemotherapy to inhibit the growth of tumors. (cis[$\mathrm{Pt(NH_3)_2Cl_2}$])
Question 44
Chemistry · Co-ordination Compounds · Single correct
Match List I with List II
A – II, B – I, C – III, D – IV
A – III, B – II, C – IV, D – I
A – IV, B – II, C – III, D – I
A – II, B – I, C – IV, D – III
Answer: (d)
Solution
A corresponds to the Wurtz-fitting reaction. B corresponds to the Fitting reaction. C corresponds to the Sandmeyer reaction. D corresponds to the Finkelstein reaction.
Question 45
Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct
Which of the following compounds would give the following set of qualitative analysis ? (i) Fehling's Test : Positive (ii) Na fusion extract upon treatment with sodium nitroprusside gives a blood red colour but not prussian blue.
Answer: (d)
Solution
Aromatic aldehydes do not give Fehling's test. Both nitrogen and sulfur must be present to obtain blood red colour. Sodium nitroprusside gives blood red colour with S & N.
Question 46
Chemistry · Amines · Single correct
Benzyl isocyanide can be obtained by: Choose the correct answer from the options given below :
A and D
Only B
A and B
B and C
Answer: (c)
Solution
The reaction of benzyl bromide with silver cyanide $(\mathrm{AgCN})$ gives benzyl isocyanide. The reaction of benzylamine with chloroform $(\mathrm{CHCl_3})$ and aqueous $\mathrm{KOH}$ gives benzyl isocyanide through the carbylamine reaction. The reaction of $\mathrm{N}$-methylbenzylamine with chloroform and aqueous solution gives no reaction. The reaction of benzyl tosylate with potassium cyanide $(\mathrm{KCN})$ gives benzyl cyanide.
Question 47
Chemistry · Polymers · Single correct
Caprolactam when heated at high temperature in presence of water, gives
Teflon
Dacron
Nylon 6, 6
Nylon 6
Answer: (d)
Solution
Caprolactam is converted to Nylon-6 in the presence of $\mathrm{H_2O}$ and heat $\Delta$. The reaction involves the opening of the lactam ring to form the polymer chain.
Question 48
Chemistry · Chemistry in Everyday Life · Single correct
Amongst the following compounds, which one is an antacid?
In the wet tests for identification of various cations by precipitation, which transition element cation doesn’t belong to group IV in qualitative inorganic analysis?
$\mathrm{Fe}^{3+}$
$\mathrm{Zn}^{2+}$
$\mathrm{Co}^{2+}$
$\mathrm{Ni}^{2+}$
Answer: (a)
Solution
Zn^{2+}, Co^{2+}, Ni^{2+} = $\mathrm{IV^{th}}$ Group Fe^{3+} = $\mathrm{III^{rd}}$ Group
Question 50
Chemistry · Biomolecules · Single correct
Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Ketoses give Seliwanoff's test faster than Aldoses. Reason (R): Ketoses undergo $\beta$-elimination followed by formation of furfural. In the light of the above statements, choose the correct answer from the options given below:
is false but (R) is true
Both (A) and (R) are true and (R) is the correct explanation of (A)
is true but (R) is false
Both (A) and (R) are true but (R) is not the correct explanation of (A)
Answer: (c)
Solution
Seliwanoff's test is a differentiating test for ketose and aldose. This test relies on the principle that the keto hexose are more rapidly dehydrated to form 5-hydroxy methyl furfural when heated in acidic medium which on condensation with resorcinol, cherry red or brown red coloured complex is formed rapidly indicating a positive test.
Question 51
Chemistry · Structure of Atom · Numerical
The energy of one mole of photons of radiation of frequency $2 \times 10^{12} \, \mathrm{Hz}$ in $\mathrm{J \, mol^{-1}}$ is _______. (Nearest integer) (Given: $h = 6.626 \times 10^{-34} \, \mathrm{Js}$ $N_A = 6.022 \times 10^{23} \, \mathrm{mol^{-1}}$)
Answer: 798
Solution
For one photon $E = h \nu$. For one mole photon, $$E = 6.023 \times 10^{23} \times 6.626 \times 10^{-34} \times 2 \times 10^{12}$$ $$= 798.16 \, \mathrm{J}$$ $$\approx 798 \, \mathrm{J}$$
Question 52
Chemistry · Thermodynamics · Numerical
When 2 litre of ideal gas expands isothermally into vacuum to a total volume of 6 litre, the change in internal energy is _____ J. (Nearest integer)
Answer: 0
Solution
For ideal gas $U = f(T)$ and for isothermal process, $\Delta U = 0$
Question 53
Chemistry · Equilibrium · Numerical
600 $\mathrm{mL}$ of 0.01 $\mathrm{M}$ HCl is mixed with 400 $\mathrm{mL}$ of 0.01 $\mathrm{M}$ $\mathrm{H_2SO_4}$ . The pH of the mixture is $\_$$\_$$\_$$\_$$\_$$\_$ $\times$ $10^{-2}$. (Nearest integer) [Given $\log$ 2 = 0.30, $\log$ 3 = 0.48 $\log$ 5 = 0.69 $\log$ 7 = 0.84 $\log$ 11 = 1.04]
A 300 mL bottle of soft drink has 0.2 M $\mathrm{CO_2}$ dissolved in it. Assuming $\mathrm{CO_2}$ behaves as an ideal gas, the volume of the dissolved $\mathrm{CO_2}$ at STP is _________ mL. (Nearest integer) Given: At STP, molar volume of an ideal gas is 22.7 L mol$^{-1}$
A solution containing 2 g of a non-volatile solute in 20 g of water boils at 373.52 $\mathrm{K}$. The molecular mass of the solute is _____ $\mathrm{g\,mol^{-1}}$. (Nearest integer) Given, water boils at 373 $\mathrm{K}$, K_b for water = 0.52 $\mathrm{K\,kg\,mol^{-1}}$
Answer: 100
Solution
Given $\Delta T_b = 373.52 - 373$. This equals $0.52$. We have $\Delta T_b = K_b \cdot m$. Thus, $0.52 = 0.52 \times \frac{2}{Molar Mass} \times \frac{1}{20 \times 10^{-3}}$. Therefore, the Molar Mass is $100 \, \mathrm{g/mol}$.
Question 56
Chemistry · Some Basic Concepts of Chemistry · Numerical
Some amount of dichloromethane ($\mathrm{CH_2Cl_2}$) is added to $671.141 \, \mathrm{mL}$ of chloroform ($\mathrm{CHCl_3}$) to prepare $2.6 \times 10^{-3} \, \mathrm{M}$ solution of $\mathrm{CH_2Cl_2}$ (DCM). The concentration of DCM is _____ ppm (by mass). Given: Atomic mass: $\mathrm{C} = 12$; $\mathrm{H} : 1$; $\mathrm{Cl} = 35.5$ density of $\mathrm{CHCl_3} = 1.49 \, \mathrm{g \, cm^{-3}}$
Consider the cell $$\mathrm{Pt}_{(s)}\mid\mathrm{H}_2\,(g,1\,\mathrm{atm})\mid\mathrm{H}^+\,(\mathrm{aq},1\,\mathrm{M})\mid\mid\mathrm{Fe}^{3+}\,(\mathrm{aq}),\mathrm{Fe}^{2+}\,(\mathrm{aq})\mid\mathrm{Pt}_{(s)}$$ When the potential of the cell is 0.712 V at 298 K, the ratio $\left[\mathrm{Fe}^{2+}\right]/\left[\mathrm{Fe}^{3+}\right]$ is _______. (Nearest integer) Given: $\mathrm{Fe}^{3+} + e^- = \mathrm{Fe}^{2+}$, $\mathrm{E}^\circ\mathrm{Fe}^{3+},\mathrm{Fe}^{2+}\mid\mathrm{Pt} = 0.771$ $$\frac{2.303RT}{F} = 0.06\,\mathrm{V}$$
Answer: 10
Solution
$Pt(s)|H_2(g,1\,atm)|H^+(aq,1M)\parallel Fe^{3+}(aq),Fe^{2+}(aq)|Pt(s)$ At anode $H_2\rightarrow2H^++2e^-$ At cathode $Fe^{3+}+e^-\rightarrow Fe^{2+}$ $E^\circ=E^\circ_{H_2|H^+}+E^\circ_{Fe^{3+}|Fe^{2+}}=0.771\,V$ $E=E^\circ-\dfrac{0.06}{1}\log\left(\dfrac{Fe^{2+}}{Fe^{3+}}\right)$ $0.712=(0+0.771)-\dfrac{0.06}{1}\log\left(\dfrac{Fe^{2+}}{Fe^{3+}}\right)$ $\log\left(\dfrac{Fe^{2+}}{Fe^{3+}}\right)=\dfrac{0.059}{0.06}\approx1$ $\therefore\ \dfrac{Fe^{2+}}{Fe^{3+}}=10$
Question 58
Chemistry · Chemical Kinetics and Nuclear Chemistry · Numerical
If compound A reacts with B following first order kinetics with rate constant $2.011 \times 10^{-3} \, \mathrm{s}^{-1}$. The time taken by A (in seconds) to reduce from $7 \, \mathrm{g}$ to $2 \, \mathrm{g}$ will be _______. (Nearest Integer) $[\log 5 = 0.698, \log 7 = 0.845, \log 2 = 0.301]$
Answer: 623
Solution
The reaction is given by $\mathrm{A + B \rightarrow P}$. Initially, at $t = 0$, the concentration is $7 \, \mathrm{g}$, and at $t = t$, the concentration is $2 \, \mathrm{g}$. At constant volume, the time $t$ is calculated as follows: $$t = \frac{2.303}{K} \log \frac{[\mathrm{A}]_0}{[\mathrm{A}]_t}$$ Substituting the given values: $$= \frac{2 \cdot 303}{2 \cdot 011 \times 10^{-3}} \log \frac{7}{2}$$ $$= \frac{2 \cdot 303 \times 0 \cdot 544}{2 \cdot 011 \times 10^{-3}}$$ $$= 622.989$$ Therefore, $t \approx 623$.
Question 59
Chemistry · Redox Reactions · Numerical
The number of electrons involved in the reduction of permanganate to manganese dioxide in acidic medium is .
Answer: 3
Solution
The balanced redox reaction is given by: $$\mathrm{MnO_4^- + 4H^+ + 3e^- \rightarrow MnO_2 + 2H_2O}$$
Question 60
Chemistry · Aldehydes, Ketones and Carboxylic Acids · Numerical
A trisubstituted compound 'A', $\mathrm{C}_{10}\mathrm{H}_{12}\mathrm{O}_2$ gives neutral $\mathrm{FeCl}_3$ test positive. Treatment of compound 'A' with $\mathrm{NaOH}$ and $\mathrm{CH}_3\mathrm{Br}$ gives $\mathrm{C}_{11}\mathrm{H}_{14}\mathrm{O}_2$, with hydroiodic acid gives methyl iodide and with hot conc. $\mathrm{NaOH}$ gives a compound B, $\mathrm{C}_{10}\mathrm{H}_{12}\mathrm{O}_2$. Compound 'A' also decolorises alkaline $\mathrm{KMnO}_4$. The number of $\pi$ bond/s present in the compound 'A' is _______.
Answer: 4
Solution
The compound with the structure $\mathrm{C_{10}H_{12}O_2}$ can have the following groups present: $\mathrm{CH=O}$ and $\mathrm{C_3H_7}$ (both groups can be present). Alternatively, the compound can have $\mathrm{CH_2OH}$ and $\mathrm{C=CH_3}$ (both groups can be present). The reaction with $\mathrm{NaOH}$ and $\mathrm{CH_3I}$ converts the compound to have $\mathrm{OCH_3}$, resulting in $\mathrm{CH=O + C_3H_7}$.
Maths
Question 61
Maths · Trigonometric Functions · Single correct
If the solution of the equation $\log_{\cos x} \cot x + 4 \log_{\sin x} \tan x = 1$, $x \in \left(0, \frac{\pi}{2}\right)$, is $\sin^{-1}\left(\frac{\alpha + \sqrt{\beta}}{2}\right)$, where $\alpha$, $\beta$ are integers, then $\alpha + \beta$ is equal to:
3
5
6
4
Answer: (d)
Solution
Given $\log_{\cos x} \cot x + 4 \log_{\sin x} \tan x = 1$. This implies $$\frac{\ln \cos x - \ln \sin x}{\ln \cos x} + 4 \frac{\ln \sin x - \ln \cos x}{\ln \sin x} = 1$$ which simplifies to $$\left( \ln \sin x \right)^2 - 4 \left( \ln \sin x \right) \left( \ln \cos x \right) + 4 \left( \ln \cos x \right)^2 =$$ $$\ln \sin x = 2 \ln \cos x$$ Therefore, $$\sin^2 x + \sin x - 1 = 0 \implies \sin x = \frac{-1 + \sqrt{5}}{2}$$ Thus, $\alpha + \beta = 4$.
Question 62
Maths · Sequences and Series · Single correct
If $a_n = \frac{-2}{4n^2 - 16n + 15}$, then $a_1 + a_2 + \ldots + a_{25}$ is equal to :
If the coefficient of $x^{15}$ in the expansion of $$ \left(ax^3+\frac{1}{bx^{\frac{1}{3}}}\right)^{15} $$ is equal to the coefficient of $x^{-15}$ in the expansion of $$ \left(ax^{\frac{1}{3}}-\frac{1}{bx^3}\right)^{15}, $$ where $a$ and $b$ are positive real numbers, then for each such ordered pair a,b :
Maths · Straight Lines and Pair of Straight Lines · Single correct
A straight line cuts off the intercepts $OA = a$ and $OB = b$ on the positive directions of $x$-axis and $y$-axis respectively. If the perpendicular from origin $O$ to this line makes an angle of $\frac{\pi}{6}$ with positive direction of $y$-axis and the area of $\triangle OAB$ is $\frac{98}{3} \sqrt{3}$, then $a^2 - b^2$ is equal to:
$\frac{392}{3}$
196
$\frac{196}{3}$
98
Answer: (a)
Solution
Equation of straight line: $\($ $\frac{x}{a}$ + $\frac{y}{b}$ = 1 $\)$ Or $\($ x $\cos$ $\frac{\pi}{3}$ + y $\sin$ $\frac{\pi}{3}$ = p $\)$ $\[$ $\frac{x}{2}$ + $\frac{y \sqrt{3}}{2}$ = p $\]$ $\[$ $\frac{x}{3p}$ + $\frac{y}{2p}$ = 1 $\]$ Comparing both: $\($ a = 2p, b = $\frac{2p}{\sqrt{3}}$ $\)$ Now area of $\($ $\triangle$ OAB = $\frac{1}{2}$ $\cdot$ ab = $\frac{98}{3}$ $\cdot$ $\sqrt{3}$ $\)$ $\[$ $\frac{1}{2}$ $\cdot$ 2p $\cdot$ $\frac{2p}{\sqrt{3}}$ = $\frac{98}{3}$ $\cdot$ $\sqrt{3}$ $\]$ $\[$ p^2 = 49 $\]$ $\[$ $\frac{p^2 \cdot 49}{2}$ = 2 $\]$
Question 67
Maths · Conic Sections · Single correct
Let $y = x + 2$, $4y = 3x + 6$ and $3y = 4x + 1$ be three tangent lines to the circle $(x-h)^2 + (y-k)^2 = r^2$. Then $h + k$ is equal to:
5
5(1+$\sqrt{2}$)
6
5$\sqrt{2}$
Answer: (a)
Solution
Given $L_1: y = x + 2$, $L_2: 4y = 3x + 6$, $L_3: 3y = 4x + 1$. Bisector of lines $L_2$ and $L_3$ is given by: $$\frac{4x - 3y + 1}{5} = \pm \left( \frac{3x - 4y + 6}{5} \right)$$ For the positive case: $$4x - 3y + 1 = 3x - 4y + 6$$ Simplifying gives: $$x + y = 5$$ The center lies on the bisector of $4x - 3y + 1 = 0$ and $$3x - 4y + 6 = 0$$ Therefore, $h + k = 5$.
Question 68
Maths · Conic Sections · Single correct
If P(h,k) be point on the parabola $x = 4y^2$, which is nearest to the point Q(0,33), then the distance of P from the directrix of the parabola $y^2 = 4(x+y)$ is equal to :
For $S_1 \equiv ((p \lor q) \Rightarrow r) \Leftrightarrow (p \Rightarrow r)$, the truth table is as follows: \begin{tabular}{|l|l|l|l|l|l|} \hline p & q & r & (p \lor q) & (p \lor q) \Rightarrow r & ((p \lor q) \Rightarrow r) \Leftrightarrow (p \Rightarrow r) \\ \hline T & T & T & T & T & T \\ \hline T & T & F & T & F & F \\ \hline T & F & T & T & T & T \\ \hline T & F & F & T & F & F \\ \hline F & T & T & T & T & T \\ \hline F & T & F & T & F & T \\ \hline F & F & T & F & T & T \\ \hline F & F & F & F & T & T \\ \hline \end{tabular} $_$ For $S_2 \equiv (p \lor q) \Rightarrow r \Leftrightarrow ((p \Rightarrow r) \lor (q \Rightarrow r))$, the truth table is as follows: \begin{tabular}{|l|l|l|l|l|l|} \hline p & q & r & (p \lor q) & (p \lor q) \Rightarrow r & (p \Rightarrow r) \lor (q \Rightarrow r) & S_2 \\ \hline T & T & T & T & T & T & T \\ \hline T & T & F & T & F & T & F \\ \hline T & F & T & T & T & T & T \\ \hline T & F & F & T & F & T & F \\ \hline F & T & T & T & T & T & T \\ \hline F & T & F & T & F & T & F \\ \hline F & F & T & F & T & T & T \\ \hline F & F & F & F & T & T & T \\ \hline \end{tabular}
Question 70
Maths · Relations and Functions · Single correct
The minimum number of elements that must be added to the relation $R = \{(a,b), (b,c)\}$ on the set $\{a,b,c\}$ so that it becomes symmetric and transitive is:
4
7
5
3
Answer: (b)
Solution
For symmetric $(a, b), (b, c) \in R$ implies $(b, a), (c, b) \in R$. For transitive $(a, b), (b, c) \in R$ implies $(a, c) \in R$. Now 1. Symmetric $\therefore (a, c) \in R \implies (c, a) \in R$ 2. Transitive $\therefore (a, b), (b, a) \in R$ implies $(a, a) \in R \& (b, c), (c, b) \in R$ implies $(b, b) \& (c, c) \in R$ $\therefore$ Elements to be added $$\left\{ (b, a), (c, b), (a, c), (c, a), (a, a), (b, b), (c, c) \right\}$$ Number of elements to be added $= 7$
Question 71
Maths · Determinants · Single correct
Let $A = \begin{pmatrix}m & n \\ p & q \end{pmatrix}$, $d = |A| \neq 0$ $|A - d(Adj A)| = 0$. Then
$(1 + d)^2 = (m + q)^2$
$1 + d^2 = (m + q)^2$
$(1 + d)^2 = m^2 + q^2$
$1 + d^2 = m^2 + q^2$
Answer: (a)
Solution
Given $$A = \begin{bmatrix} m & n \\ p & q \end{bmatrix}, |A - d(adj A)| = 0$$ We have $$|A - d(adj A)| = \left| \begin{bmatrix} m & n \\ p & q \end{bmatrix} - d \begin{bmatrix} q & -n \\ -p & m \end{bmatrix} \right|$$ This simplifies to $$= \left| \begin{bmatrix} m - qd & n(1 + d) \\ p(1 + d) & q - md \end{bmatrix} \right| = 0$$ Thus, $$(m - qd)(q - md) - np(1 + d)^2 = 0$$ Expanding, we get $$mq - m^2d - q^2d + mqd^2 - np(1 + d)^2 = 0$$ Rearranging terms, $$(mq - np) + d^2(mq - np) - d(m^2 + q^2 + 2np) = 0$$ This leads to $$d + d^3 - d((m + q)^2 - 2d) = 0$$ Simplifying further, $$1 + d^2 = (m + q)^2 - 2d$$ Finally, $$(1 + d)^2 = (m + q)^2$$ Therefore, Option (1) is correct.
Question 72
Maths · Determinants · Single correct
Let the system of linear equations $$x + y + kz = 2$$ $$2x + 3y - z = 1$$ $$3x + 4y + 2z = k$$ have infinitely many solutions. Then the system $$(k+1)x + (2k-1)y = 7$$ $$(2k+1)x + (k+5)y = 10$$ has :
infinitely many solutions
unique solution satisfying $x - y = 1$
no solution
unique solution satisfying $x + y = 1$
Answer: (d)
Solution
Given the matrix equation: $$\begin{vmatrix} 1 & 1 & k \\ 2 & 3 & -1 \\ 3 & 4 & 2 \end{vmatrix} = 0$$ We have: $$1(10) - 1(7) + k(-1) - 0$$ This simplifies to: $$k = 3$$ For $k = 3$, the second system is: $$4x + 5y = 7 .....(1)$$ and $$7x + 8y = 10 .....(2)$$ Clearly, they have a unique solution. Subtracting equation (1) from equation (2): $$(2) - (1) \Rightarrow 3x + 3y = 3$$ This implies: $$x + y = 1$$
Question 73
Maths · Relations and Functions · Single correct
Suppose $f:\mathbb{R}\to(0,\infty)$ be a differentiable function such that $5f(x+y)=f(x)\cdot f(y),\ \forall x,y\in\mathbb{R}$. If $f(3)=320$, then $\displaystyle\sum_{n=0}^{5}f(n)$ is equal to:
Maths · Applications of Derivatives · Single correct
The number of points on the curve $y = 54x^3 - 135x^4 - 70x^3 + 180x^2 + 210x$ at which the normal lines are parallel to $x + 90y + 2 = 0$ is:
2
3
4
0
Answer: (c)
Solution
Normal of line is parallel to line $x + 90y + 2 = 0$ $$m_N = -\frac{1}{90}$$ $$-\left(\frac{dx}{dy}\right)_{(x_1, y_1)} = -\frac{1}{90} \implies \left(\frac{dy}{dx}\right)_{(x_1, y_1)} = 90$$ Now, $$\frac{dy}{dx} = 270x^4 - 540x^3 - 210x^2 + 360x + 210 = 90$$ $$\implies x = 1, 2, -\frac{2}{3}, -\frac{1}{3}$$ (4) normals
Question 75
Maths · Integrals · Single correct
If $[t$ denotes the greatest integer $\leq 1$, then the value of $$\frac{3(e-1)^2}{e} \int_{1}^{2} x^2 e^{[x]+[x^3]} \, dx$$ is:
$e^9 - e$
$e^8 - e$
$e^7 - 1$
$e^8 - 1$
Answer: (b)
Solution
Given the integral $$\int_1^2 x^2 e^{[x^3]+1} \, dx$$. Let $x^3 = t$, then $3x^2 \, dx = dt$. The integral becomes $$= \frac{e}{3} \int_1^8 e^{[t]} \, dt$$. This can be expanded as $$= \frac{e}{3} \left( \int_1^2 e \, dt + \int_2^3 e^2 \, dt + \ldots + \int_7^8 e^7 \, dt \right)$$. Evaluating the integrals, we have $$= \frac{e}{3} (e + e^2 + \ldots + e^7)$$. Simplifying further, $$= \frac{e^2}{3} (1 + e + \ldots + e^6) = \frac{e^2 (e^7 - 1)}{3 (e - 1)}$$. Therefore, $$\frac{3(e-1)}{e} \int_1^2 x^2 \times e^{[x]+[x^3]} \, dx = \frac{3}{e} (e-1) \times \frac{e^2 (e^7 - 1)}{3 (e-1)}$$. This simplifies to $$= e(e^7 - 1)$$ which equals $$= e^8 - e$$.
Question 76
Maths · Differential Equations · Single correct
Let the solution curve $y = y(x)$ of the differential equation $$\frac{\mathrm{d}y}{\mathrm{d}x} - \frac{3x^5 \tan^{-1}(x^3)}{(1+x^6)^{\frac{3}{2}}} y = 2x$$ $$\exp\left(\frac{x^3 - \tan^{-1} x^3}{\sqrt{(1+x)^6}}\right)$$ pass through the origin. Then $y(1)$ is equal to:
If $\vec{a}$, $\vec{b}$, $\vec{c}$ are three non-zero vectors and $\hat{n}$ is a unit vector perpendicular to $\vec{c}$ such that $\vec{a} = \alpha \vec{b} - \hat{n}$, $(\alpha \neq 0)$ and $\vec{b} \cdot \vec{c} = 12$, then $\left| \vec{c} \times (\vec{a} \times \vec{b}) \right|$ is equal to :
Maths · Three Dimensional Geometry · Single correct
The line $l_1$ passes through the point $(2,6,2)$ and is perpendicular to the plane $2x + y - 2z = 10$. Then the shortest distance between the line $l_1$ and the line \[\frac{x+1}{2} = \frac{y+4}{-3} = \frac{z}{2}\] is:
Maths · Three Dimensional Geometry · Single correct
Let a unit vector $\overline{OP}$ make angles $\alpha$, $\beta$, and $\gamma$ with the positive directions of the coordinate axes $OX$, $OY$, and $OZ$, respectively, where $\beta \in \left(0,\frac{\pi}{2}\right)$ $\overline{OP}$ is perpendicular to the plane through the points $(1,2,3)$, $(2,3,4)$, and $(1,5,7)$, then which one of the following is true?
If an unbiased die, marked with $-2, -1, 0, 1, 2, 3$ on its faces, is thrown five times, then the probability that the product of the outcomes is positive, is:
$\frac{881}{2592}$
$\frac{521}{2592}$
$\frac{440}{2592}$
$\frac{27}{288}$
Answer: (b)
Solution
Either all outcomes are positive or any two are negative. Now, $p = P(positive) = \frac{3}{6} = \frac{1}{2}$ $q = p(negative) = \frac{2}{6} = \frac{1}{3}$ Required probability $$= \binom{5}{5} \left( \frac{1}{2} \right)^5 + \binom{5}{2} \left( \frac{1}{3} \right)^2 \left( \frac{1}{2} \right)^3 + \binom{5}{4} \left( \frac{1}{3} \right)^4 \left( \frac{1}{2} \right)^1$$ $$= \frac{521}{2592}$$ Therefore, Option (2) is correct.
Question 81
Maths · Complex Numbers and Quadratic Equations · Numerical
Let $z = 1 + i$ and $z_1 = \frac{1 + i \bar{z}}{\bar{z}(1 - z) + \frac{1}{z}}$. Then $\frac{12}{\pi}$ $\arg(z_1)$ is equal to _______.
Answer: 9
Solution
Given $z = 1 + i$. $$z_1 = \frac{1 + i \bar{z}}{\bar{z}(1-z) + \frac{1}{z}}$$ Substituting $z = 1 + i$, we have: $$z_1 = \frac{1 + i(1-i)}{(1-i)(1-1-i) + \frac{1}{1+i}}$$ Simplifying further: $$= \frac{1 + i - i^2}{(1-i)(-i) + \frac{1-i}{2}}$$ $$= \frac{2 + i}{-3i - 1} = \frac{4 + 2i}{-3i - 1}$$ Multiplying numerator and denominator by the conjugate: $$= \frac{-(4 + 2i)(3i - 1)}{(3i)^2 - (1)^2}$$ The argument of $z_1$ is: $$Arg(z_1) = \frac{3\pi}{4}$$ Therefore: $$\frac{12}{\pi} arg(z_1) = \frac{12}{\pi} \times \frac{3\pi}{4} = 9$$
Question 82
Maths · Permutations and Combinations · Numerical
Number of 4-digit numbers (the repetition of digits is allowed) which are made using the digits 1, 2, 3 and 5, and are divisible by 15, is equal to
Answer: 21
Solution
For a number to be divisible by 15, the last digit should be 5 and the sum of digits must be divisible by 3. Possible combinations are 1 2 1 5 Numbers = 3 2 2 3 5 Numbers = 3 3 3 1 5 Numbers = 3 1 1 5 5 Numbers = 3 2 3 5 5 Numbers = 6 3 5 5 5 Numbers = 3 Total Numbers = 21
Question 83
Maths · Sequences and Series · Fill in the blank
Let $$\sum_{n=0}^{\infty} \frac{n^3 ((2n)!) + (2n-1)(n!)}{(n!)((2n)!) } = ae + \frac{b}{e} + c,$$ where $a, b, c \in \mathbb{Z}$ and $e = \sum_{n=0}^{\infty} \frac{1}{n!}$. Then $a^2 - b + c$ is equal to ________.
Answer: 26
Solution
The given expression is $$\sum_{n=0}^{\infty} \frac{n^3 \left( (2n)! \right) + (2n-1)(n!)}{(n!)((2n)!)}$$ which simplifies to $$\sum_{n=0}^{\infty} \frac{1}{(n-3)!} + \sum_{n=0}^{\infty} \frac{3}{(n-2)!} + \sum_{n=0}^{\infty} \frac{1}{(n-1)!} + \sum_{n=0}^{\infty} \frac{1}{(2n-1)!} - \sum_{n=0}^{\infty} \frac{1}{(2n)!}.$$ This further simplifies to $$= e + 3e + e + \frac{1}{2} \left( e - \frac{1}{e} \right) - \frac{1}{2} \left( e + \frac{1}{e} \right).$$ Therefore, $$= 5e - \frac{1}{e}.$$ Finally, $$a^2 - b + c = 26.$$
Question 84
Maths · Statistics · Numerical
The mean and variance of 7 observations are 8 and 16 respectively. If one observation 14 is omitted a and b are respectively mean and variance of remaining 6 observation, then $a + 3b - 5$ is equal to .
Let $S = \{1, 2, 3, 4, 5, 6\}$. Then the number of one-one functions $f: S \to P(S)$, where $P(S)$ denote the power set of $S$, such that $f(n) \subseteq f(m)$ where $n < m$ is
Answer: 3240
Solution
Let $S = \{1, 2, 3, 4, 5, 6\}$, then the number of one-one functions, $f: S \to P(S)$, where $P(S)$ denotes the power set of $S$, such that $f(n) < f(m)$ where $n < m$ is $$n(S) = 6$$ $$P(S) = \left\{ \emptyset, \{1\}, \ldots, \{6\}, \{1, 2\}, \ldots, \{5, 6\}, \ldots, \{1, 2, 3, 4, 5, 6\} \right\}$$ - 64 elements case - 1 $f(6) = S$ i.e. 1 option, $f(5) = any 5 element subset A of S$ i.e. 6 options, $f(4) = any 4 element subset B of A$ i.e. 5 options, $f(3) = any 3 element subset C of B$ i.e. 4 options, $f(2) = any 2 element subset D of C$ i.e. 3 options, $f(1) = any 1 element subset E of D or empty subset i.e. 3 options,$ Total functions = 1080 Case - 2 $f(6) = any 5 element subset A of S$ i.e. 6 options, $f(5) = any 4 element subset B of A$ i.e. 5 options, $f'(4) = any 3 element subset C of B$ i.e. 4 options, $f(3) = any 2 element subset D of C$ i.e. 3 options, $f'(2) = any 1 element subset E of D$ i.e. 2 options, $f(1) = empty subset i.e. 1 option$ Total functions = 720 Case - 3 $f(6) = S$ $f(5) = any 4 element subset A of S$ i.e. 15 options, $f(4) = any 3 element subset B of A$ i.e. 4 options, $f(3) = any 2 element subset C of B$ i.e. 3 options, $f(2) = any 1 element subset D of C$ i.e. 2 options, $f(1) = empty subset i.e. 1 option$ Total functions = 360 Case - 4 $f(6) = S$ $f(5) = any 5 element subset A of S$ i.e. 6 options, $f(4) = any 3 element subset B of A$ i.e. 10 options, $f(3) = any 2 element subset C of B$ i.e. 3 options, $f(2) = any 1 element subset D of C$ i.e. 2 options, $f(1) = empty subset i.e. 1 option$
Question 86
Maths · Relations and Functions · Numerical
Let $f^1(x) = \frac{3x + 2}{2x + 3}, \ x \in \mathbb{R} - \left\{ -\frac{3}{2} \right\}$ For $n \geq 2$, define $f^n(x) = f^1 \circ f^{n-1}(x)$. If $f^5(x) = \frac{ax + b}{bx + a}$, $\gcd(a, b) = 1$, then $a + b$ is equal to ________.
Answer: 3125
Solution
Given $$f^1(x) = \frac{3x+2}{2x+3}$$ Then $$f^2(x) = \frac{13x+12}{12x+13}$$ Then $$f^3(x) = \frac{63x+62}{62x+63}$$ Therefore, $$f^5(x) = \frac{1563x+1562}{1562x+1563}$$ Finally, $$a + b = 3125$$
Question 87
Maths · Integrals · Numerical
$$ \lim_{{x \to 0}} \frac{{48}}{{x^4}} \int_0^x \frac{{t^3}}{{t^6 + 1}} \, dt is equal to $$
Answer: 12
Solution
Given the limit expression: $$48 \lim_{x \to 0} \frac{\int_0^x \frac{t^3}{t^6 + 1} \, dt}{x^4}$$ This is an indeterminate form $\($ $\frac{0}{0}$ $\)$. Applying L'Hôpital's Rule: $$48 \lim_{x \to 0} \frac{x^3}{x^6 + 1} \times \frac{1}{4x^3}$$ The result is: $$= 12$$
Question 88
Maths · Applications of Integrals · Numerical
Let $\alpha$ be the area of the larger region bounded by the curve $y^2 = 8x$ and the lines $y = x$ and $x = 2$, which lies in the first quadrant. Then the value of $3\alpha$ is equal to _________.
Answer: 22
Solution
Given $y = x$ and $y^2 = 8x$. Solving it, $x^2 = 8x$. Therefore, $x = 0, 8$. Thus, $y = 0, 8$. The intersection at $x = 2$ will occur at $y^2 = 16 \Rightarrow y = \pm 4$. Therefore, the area of the shaded region is $$\int_{2}^{8} (\sqrt{8x - x}) \, dx = \int_{2}^{8} (2\sqrt{2} \sqrt{x} - x) \, dx$$ $$= \left[ 2\sqrt{2} \cdot \frac{x^{3/2}}{3/2} - \frac{x^2}{2} \right]_{0}^{8}$$ $$= \left( \frac{4\sqrt{2}}{2} \cdot 2^{9/2} - 32 \right) - \left( \frac{4\sqrt{2}}{2} \cdot 2^{9/2} - 2 \right)$$ Therefore, $3A = 22$.
Question 89
Maths · Three Dimensional Geometry · Numerical
If the equation of the plane passing through the point $(1,1,2)$ and perpendicular to the line $x - 3y + 2z - 1 = 0$ $4x - y + z$ is $Ax + By + Cz = 1$, then $140(C - B + A)$ is equal to _____.
Answer: 15
Solution
Given the equations of the planes: $$x - 3y + 2z - 1 = 0$$ $$4x - y + z = 0$$ The cross product of the normals $\vec{n}_1 \times \vec{n}_2$ is: $$\begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ 1 & -3 & 2 \\ 4 & -1 & 1 \end{vmatrix}$$ This results in: $$=-\hat{i} + 7\hat{j} + 11\hat{k}$$ The direction ratios of the normal to the plane are $-1, 7, 11$. Equation of the plane: $$-1(x - 1) + 7(y - 1) + 11(z - 2) = 0$$ Simplifying gives: $$-x + 7y + 11z = 28$$ Dividing throughout by 28: $$\frac{-1}{28}x + \frac{7y}{28} + \frac{11z}{28} = 1$$ This is in the form $Ax + By + Cz = 1$. Calculating $140(C - B + A)$: $$140 \left( \frac{11}{28} - \frac{7}{28} - \frac{1}{28} \right)$$ This simplifies to: $$= 140 \times \frac{3}{28} = 15$$
Question 90
Maths · Three Dimensional Geometry · Numerical
If $\lambda_1 < \lambda_2$ are two values of $\lambda$ such that the angle between the planes $P_1 : \mathbf{r} \cdot (3\hat{i} - 5\hat{j} + \hat{k}) = 7$ and $P_2 : \mathbf{r} \cdot (\lambda \hat{i} + \hat{j} - 3\hat{k}) = 9$ is $\sin^{-1}\left(\frac{2\sqrt{6}}{5}\right)$, then the square of the length of perpendicular from the point $(38\lambda_1, 10\lambda_2, 2)$ to the plane $P_1$ is _____.