JEE Main 1 February 2023 Shift 1 question paper with solutions
JEE Main 1 February 2023 Shift 1: all 90 questions in paper order (Physics, Chemistry, Maths) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.
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Physics
Question 1
Physics · Mechanical Properties of Solids · Single correct
( P + $\frac{a}{V^2}$) (V - b) = RT represents the equation of state of some gases. Where P is the pressure, V is the volume, T is the temperature and a, b, R are the constants. The physical quantity, which has dimensional formula as that of $\frac{b^2}{a}$, will be:
Bulk modulus
Modulus of rigidity
Compressibility
Energy density
Answer: (c)
Solution
Given $[b] = [V]$ and $\left[ \frac{a}{b^2} \right] = [P]$. Therefore, $\left[ \frac{b^2}{a} \right] = \frac{1}{[P]} = \frac{1}{[B]} = [K]$.
Question 2
Physics · Motion in a Straight Line · Single correct
An object moves with speed $v_1$, $v_2$, and $v_3$ along a line segment $AB$, $BC$ and $CD$ respectively as shown in figure. Where $AB = BC$ and $AD = 3 \, AB$, then average speed of the object will be:
Given $AB = x$, $BC = x$, and $2x + CD = 3x$. Therefore, $CD = x$. The average velocity $ $ is given by: $$ = \frac{3x}{\frac{x}{v_1} + \frac{x}{v_2} + \frac{x}{v_3}} = \frac{3v_1 v_2 v_3}{v_2 v_3 + v_1 v_3 + v_1 v_2}.$$
Question 3
Physics · Motion in a Plane · Single correct
A child stands on the edge of the cliff 10 m above the ground and throws a stone horizontally with an initial speed of 5 $\mathrm{ms^{-1}}$. Neglecting the air resistance, the speed with which the stone hits the ground will be _____ $\mathrm{ms^{-1}}$ (given, g = 10 $\mathrm{ms^{-2}}$).
A block of mass $5 \, \mathrm{kg}$ is placed at rest on a table of rough surface. Now, if a force of $30 \, \mathrm{N}$ is applied in the direction parallel to surface of the table, the block slides through a distance of $50 \, \mathrm{m}$ in an interval of time $10 \, \mathrm{s}$. Coefficient of kinetic friction is (given, $g = 10 \, \mathrm{ms^{-2}}$):
0.60
0.75
0.50
0.25
Answer: (c)
Solution
Given the equation for displacement: $$S = ut + \frac{1}{2} at^2$$ Substitute the values: $$50 = 0 + \frac{1}{2} \times a \times 100$$ Solve for $a$: $$a = 1 \, \mathrm{m/s^2}$$ Using the equation of motion: $$F - \mu mg = ma$$ Substitute the values: $$30 - \mu \times 50 = 5 \times 1$$ Solve for $\mu$: $$50\mu = 25$$ Therefore, $$\mu = \frac{1}{2}$$
Question 5
Physics · Gravitation · Single correct
If earth has a mass nine times and radius twice to the of a planet P. Then $\frac{v_e}{3} \sqrt{x} \, \mathrm{ms^{-1}}$ will be the minimum velocity required by a rocket to pull out of gravitational force of P, where $v_e$ is escape velocity on earth. The value of $x$ is
2
3
18
1
Answer: (a)
Solution
The escape velocity for the planet is given by $$v_{(escape) plant} = \sqrt{\frac{2GM_P}{R_P}}$$ Substituting the given values, we have $$= \sqrt{\frac{2G \left( \frac{M_e}{9} \right)}{\left( \frac{R_e}{2} \right)}} = \frac{v_e \sqrt{2}}{3} \therefore x = 2$$
Question 6
Physics · Gravitation · Single correct
Given below are two statements: Statement-I: Acceleration due to gravity is different at different places on the surface of earth. Statement-II: Acceleration due to gravity increases as we go down below the earth's surface. In the light of the above statements, choose the correct answer from the options given below
Both Statement I and Statement II are true
Both Statement I and Statement II are false
Statement I is true but Statement II is false
Statement I is false but Statement II is true
Answer: (c)
Solution
The effective gravity $g_{eff}$ is given by the equation: $$g_{eff} = g - \omega^2 R_e \sin^2 \theta,$$ where $\theta$ is the co-latitude angle. Another expression for effective gravity is: $$g_{eff} = g \left( 1 - \frac{d}{R_e} \right),$$ where $d$ is the depth.
Question 7
Physics · Mechanical Properties of Fluids · Single correct
A mercury drop of radius $10^{-3} \, \mathrm{m}$ is broken into 125 equal size droplets. Surface tension of mercury is $0.45 \, \mathrm{Nm}^{-1}$. The gain in surface energy is:
A sample of gas at temperature $T$ is adiabatically expanded to double its volume. The work done by the gas in the process is ( given, $\gamma$ = $\frac{3}{2}$):
The average kinetic energy of a molecule of the gas is
proportional to absolute temperature
proportional to volume
proportional to pressure
dependent on the nature of the gas
Answer: (a)
Solution
Basic theory Translational K.E on average of a molecule is $\frac{3}{2} KT$ which is independent of nature, pressure and volume.
Question 10
Physics · Waves · Single correct
A steel wire with mass per unit length $7.0 \times 10^{-3} \, \mathrm{kg \, m^{-1}}$ is under tension of $70 \, \mathrm{N}$. The speed of transverse waves in the wire will be:
$200 \, \pi \, \mathrm{m/s}$
$100 \, \mathrm{m/s}$
$10 \, \mathrm{m/s}$
$50 \, \mathrm{m/s}$
Answer: (b)
Solution
The velocity $v$ is given by the formula $$v = \sqrt{\frac{T}{\mu}} = \sqrt{\frac{70}{70 \times 10^{-3}}} = 100 \, \mathrm{m/s}$$
Question 11
Physics · Electric Charges and Fields · Single correct
Let $\sigma$ be the uniform surface charge density of two infinite thin plane sheets shown in figure. Then the electric fields in three different region $E_I$, $E_{II}$ and $E_{III}$ are:
The expression for the magnetic field at point P is given by: $$B_P = \left( \frac{\mu_0 i}{4r} + \frac{\mu_0 i}{4\pi r} \right) = \frac{\mu_0 i}{2r} \left( \frac{1}{2} + \frac{1}{2\pi} \right)$$
Question 14
Physics · Current Electricity · Single correct
Match the List-I with List-II \begin{tabular}{|c|l|c|l|} \hline & \text{List I} & & \text{List II}\\ \hline \text{A.} & \text{AC generator} & \text{I.} & \text{Presence of both L and C}\\ \hline \text{B.} & \text{Transformer} & \text{II.} & \text{Electromagnetic Induction}\\ \hline \text{C.} & \text{Resonance phenomenon to occur} & \text{III.} & \text{Quality factor}\\ \hline \text{D.} & \text{Sharpness of resonance} & \text{IV.} & \text{Mutual Inductance}\\ \hline \end{tabular}
A-IV, B-II, C-I, D-III
A-II, B-I, C-III, D-IV
A-II, B-IV, C-I, D-III
A-IV, B-III, C-I, D-II
Answer: (c)
Solution
Based on theory
Question 15
Physics · Current Electricity · Single correct
Match the List-I with List-II: Choose the correct answer from the options given below: \begin{tabular}{|c|l|c|l|} \hline & \text{List I} & & \text{List II}\\ \hline \text{A.} & \text{Microwaves} & \text{I.} & \text{Radio active decay of the nucleus}\\ \hline \text{B.} & \text{Gamma rays} & \text{II.} & \text{Rapid acceleration and deceleration of electron in aerials}\\ \hline \text{C.} & \text{Radio waves} & \text{III.} & \text{Inner shell electrons}\\ \hline \text{D.} & \text{X-rays} & \text{IV.} & \text{Klystron valve}\\ \hline \end{tabular}
A-I, B-II, C-III, D-IV
A-IV, B-I, C-II, D-III
A-I, B-III, C-IV, D-II
A-IV, B-III, C-II, D-I
Answer: (b)
Solution
Based on theory
Question 16
Physics · Wave Optics · Single correct
'n' polarizing sheets are arranged such that each makes an angle $45^\circ$ with the proceeding sheet. An unpolarized light of intensity I is incident into this arrangement. The output intensity is found to be $\frac{I}{64}$. The value of n will be:
3
6
5
4
Answer: (b)
Solution
After passing through first sheet $$I_1 = \frac{I}{2}$$ After passing through second sheet $$I_2 = I_1 \cos^2(45^\circ) = \frac{I}{4}$$ After passing through $n^{th}$ sheet $$I_n = \frac{I}{2^n} = \frac{I}{64}$$ $$n = 6$$
Question 17
Physics · Dual Nature of Radiation and Matter · Single correct
A proton moving with one tenth of velocity of light has a certain de Broglie wavelength of $\lambda$. An alpha particle having certain kinetic energy has the same de-Broglie wavelength $\lambda$. The ratio of kinetic energy of proton and that of alpha particle is:
2 : 1
4 : 1
1 : 2
1 : 4
Answer: (b)
Solution
The kinetic energy is given by $$KE = \frac{p^2}{2m} = \frac{h^2}{2m \lambda^2}$$. The ratio of kinetic energies is $$\frac{KE_p}{KE_\alpha} = \frac{m_\alpha}{m_p} = 4:1$$.
Question 18
Physics · Nuclei · Single correct
The mass of proton, neutron and helium nucleus are respectively $1.0073$ $\mathrm{u}$, 1.0087 $\mathrm{u}$ and 4.0015 $\mathrm{u}$. The binding energy of helium nucleus is:
14.2 $\mathrm{MeV}$
28.4 $\mathrm{MeV}$
56.8 $\mathrm{MeV}$
7.1 $\mathrm{MeV}$
Answer: (b)
Solution
The binding energy (B.E) of Helium is given by the equation: $$B.E of Helium = (2m_p + 2m_N - m_{He}) c^2$$ This evaluates to: $$= 28.4 \, MeV$$
Question 19
Physics · Physical World, Units and Measurements · Single correct
Match the List I with List II Choose the correct answer from the options given below: \begin{tabular}{|c|l|c|l|} \hline & \text{List I} & & \text{List II}\\ \hline \text{A.} & \text{Intrinsic Semiconductor} & \text{I.} & \text{Fermi-level near conduction band}\\ \hline \text{B.} & \text{n-type semiconductor} & \text{II.} & \text{Fermi-level at middle}\\ \hline \text{C.} & \text{p-type semiconductor} & \text{III.} & \text{Fermi-level near valence band}\\ \hline \text{D.} & \text{Metals} & \text{IV.} & \text{Fermi-level inside conduction band}\\ \hline \end{tabular}
(A) $\rightarrow$ I, (B) $\rightarrow$ II, (C) $\rightarrow$ III, (D) $\rightarrow$ IV
(A) $\rightarrow$ II, (B) $\rightarrow$ I, (C) $\rightarrow$ III, (D) $\rightarrow$ IV
(A) $\rightarrow$ II, (B) $\rightarrow$ III, (C) $\rightarrow$ I, (D) $\rightarrow$ IV
(A) $\rightarrow$ III, (B) $\rightarrow$ I, (C) $\rightarrow$ II, (D) $\rightarrow$ IV
Answer: (c)
Solution
Based on theory
Question 20
Physics · Communication Systems · Single correct
Which of the following frequencies does not belong to FM broadcast.
106 $\mathrm{MHz}$
64 $\mathrm{MHz}$
99 $\mathrm{MHz}$
89 $\mathrm{MHz}$
Answer: (b)
Solution
FM broadcast range is $88 \, \mathrm{MHz}$ to $108 \, \mathrm{MHz}$.
Question 21
Physics · Work, Energy and Power · Numerical
A small particle moves to position $5\hat{i} - 2\hat{j} + \hat{k}$ from its initial position $2\hat{i} + 3\hat{j} - 4\hat{k}$ under the action of force $5\hat{i} + 2\hat{j} + 7\hat{k} \, \mathrm{N}$. The value of work done will be
Physics · System of Particles and Rotational Motion · Numerical
A solid cylinder is released from rest from the top of an inclined plane of inclination $30^\circ$ and length $60 \, \mathrm{cm}$. If the cylinder rolls without slipping, its speed upon reaching the bottom of the inclined plane is _________ $\mathrm{ms^{-1}}$. (Given $g = 10 \, \mathrm{ms^{-2}}$)
Answer: 2
Solution
The velocity is given by the equation $$v = \sqrt{\frac{2gh}{1 + \frac{k^2}{R^2}}}$$ where $h = 60 \sin 30^\circ = 30 \, \mathrm{cm}$. Also, $$k^2 = \frac{R^2}{2}.$$
Question 23
Physics · Mechanical Properties of Solids · Numerical
A certain pressure $P$ is applied to 1 litre of water and 2 litre of a liquid separately. Water gets compressed to 0.01$\%$ whereas the liquid gets compressed to 0.03$\%$. The ratio of Bulk modulus of water to that of the liquid is $\frac{3}{x}$. The value of $x$ is
The amplitude of a particle executing SHM is 3 cm. The displacement at which its kinetic energy will be 25$\%$ more than the potential energy is:
Answer: 2
Solution
Given $KE = PE + \frac{PE}{4}$. Therefore, $KE = \frac{5}{4} PE$. Now, $\frac{1}{2} m \omega^2 \left(A^2 - x^2\right) = \frac{5}{4} \times \frac{1}{2} m \omega^2 x^2$. This implies $A^2 - x^2 = \frac{5}{4} x^2$. Rearranging gives $\frac{9x^2}{4} = A^2$. Thus, $x = \frac{2}{3} A$. Therefore, $x = \frac{2}{3} \times 3 cm$, which gives $x = 2 cm$.
Question 25
Physics · Electric Charges and Fields · Numerical
Two equal positive point charges are separated by a distance $2a$. The distance of a point from the centre of the line joining two charges on the equatorial line (perpendicular bisector) at which force experienced by a test charge $q_0$ becomes maximum is $\frac{a}{\sqrt{x}}$. The value of $x$ is __________.
Answer: 2
Solution
The force is given by the equation $$F = \frac{2Kqq_0x}{(x^2 + a^2)^{3/2}}.$$ For $F$ to be maximum, $$\frac{dF}{dx} = 0.$$ Solving for $x$, we find $$x = \frac{a}{\sqrt{2}}.$$
Question 26
Physics · Experimental Physics · Numerical
In an experiment to find emf of a cell using potentiometer, the length of null point for a cell of emf 1.5 V is found to be 60 cm. If this cell is replaced by another cell of emf E, the length of null point increases by 40 cm. The value of E is $\frac{x}{10} \, \mathrm{V}$. The value of x is .
Physics · Electrostatic Potential and Capacitance · Numerical
A charge particle of 2 $\mu \mathrm{C}$ accelerated by a potential difference of 100 $\mathrm{V}$ enters a region of uniform magnetic field of magnitude 4 $\mathrm{mT}$ at right angle to the direction of field. The charge particle completes semicircle of radius 3 $\mathrm{cm}$ inside magnetic field. The mass of the charge particle is _____ $\times 10^{-18} \mathrm{kg}$.
A series LCR circuit is connected to an ac source of 220V, 50Hz. The circuit contain a resistance $R = 100\Omega$ and an inductor of inductive reactance $X_L = 79.6\Omega$. The capacitance of the capacitor needed to maximize the average rate at which energy is supplied will be _________ $\mu$ F.
Answer: 40
Solution
To maximize the average rate at which energy supplied i.e. power will be maximum. So in LCR circuit power will be maximum at the condition of resonance and in resonance condition $$X_L = X_C$$ $$79.6 = \frac{1}{\omega C}$$ $$\therefore C = \frac{1}{2\pi \times 50 \times 79.6}$$ $$\therefore C = 40 \mu \mathrm{F}$$
Question 29
Physics · Ray Optics and Optical Instruments · Numerical
A thin cylindrical rod of length 10 cm is placed horizontally on the principle axis of a concave mirror of focal length 20 cm. The rod is placed in a such a way that mid point of the rod is at 40 cm from the pole of mirror. The length of the image formed by the mirror will be $\frac{x}{3}$ cm. The value of $x$ is
A light of energy 12.75 eV is incident on a hydrogen atom in its ground state. The atom absorbs the radiation and reaches to one of its excited states. The angular momentum of the atom in the excited state is $\frac{x}{\pi} \times 10^{-17}$ eVs. The value of $x$ is _______ (use $h = 4.14 \times 10^{-15}$ eVs, $c = 3 \times 10^{8}$ ms$^{-1}$).
Answer: 828
Solution
In the ground state energy $= -13.6 \, \mathrm{eV}$. So energy $$\frac{-13.6 \, \mathrm{eV}}{n^2} = -13.6 + 12.75$$ $$\frac{-13.6 \, \mathrm{eV}}{n^2} = -0.85$$ $$n = \sqrt{16}$$ $$n = 4$$ Angular momentum $$= \frac{nh}{2\pi} = \frac{4h}{2\pi} = \frac{2h}{\pi}$$ Angular momentum $$= \frac{2}{\pi} \times 4.14 \times 10^{-15}$$ $$= \frac{828 \times 10^{-17}}{\pi} \, \mathrm{eVs}$$
Chemistry
Question 31
Chemistry · Hydrogen · Single correct
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Assertion A: Hydrogen is an environment friendly fuel. Reason R: Atomic number of hydrogen is 1 and it is a very light element. In the light of the above statements, choose the correct answer from the options given below
A is true but R is false
Both A and R are true but R is NOT the correct explanation of A
A is false but R is true
Both A and R are true and R is the correct explanation of A
Answer: (b)
Solution
No pollution occurs by combustion of hydrogen and very low density of hydrogen.
Question 32
Chemistry · The s-Block Elements · Single correct
Match List I with List II \begin{tabular}{|c|l|c|c|} \hline \text{List-I} & & \text{List-II} & \\ \hline \text{(A)} & \text{Slaked lime} & \text{(I)} & $\mathrm{NaOH}$ \\ \hline \text{(B)} & \text{Dead burnt plaster} & \text{(II)} & $\mathrm{Ca(OH)_2}$ \\ \hline \text{(C)} & \text{Caustic soda} & \text{(III)} & $\mathrm{Na_2CO_3\cdot10H_2O}$ \\ \hline \text{(D)} & \text{Washing soda} & \text{(IV)} & $\mathrm{CaSO_4}$ \\ \hline \end{tabular} Choose the correct answer form the options given below:
(A) – I, (B) – IV, (C ) – II, (D) – III
(A) – III, (B) – I, (C ) – II, (D) – IV
(A) – II, (B) – IV, (C ) – I, (D) – III
(A) – III, (B) – II, (C ) – IV, (D) – I
Answer: (c)
Solution
From S-block NCERT
Question 33
Chemistry · The s-Block Elements · Multiple correct
Choose the correct statement(s): A. Beryllium oxide is purely acidic in nature. B. Beryllium carbonate is kept in the atmosphere of $\mathrm{CO}_2$. C. Beryllium sulphate is readily soluble in water. D. Beryllium shows anomalous behavior. Choose the correct answer from the options given below:
A, B and C only
B, C and D only
A and B only
A only
Answer: (b)
Solution
A. Beryllium oxide is amphoteric in nature. B. Beryllium carbonate is kept in the atmosphere of $\mathrm{CO_2}$ because it is thermally less stable. C. Beryllium sulphate is readily soluble in water due to high degree of hydration. D. Beryllium shows anomalous behaviour due to small size, high ionization energy and high value of $\phi$ (polarising power).
Question 34
Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct
Resonance in carbonate ion ($\mathrm{CO}_3^{2-}$) is Which of the following is true?
It is possible to identify each structure individually by some physical or chemical method.
All these structures are in dynamic equilibrium with each other.
Each structure exists for equal amount of time.
$\mathrm{CO}_3^{2-}$ has a single structure i.e., resonance hybrid of the above three structures.
Answer: (d)
Solution
Resonating structures are hypothetical and resonance hybrid is a real structure which is the weighted average of all the resonating structures.
Question 35
Chemistry · Hydrocarbons · Multiple correct
But-2-yne is reacted separately with one mole of Hydrogen as shown below: Identify the incorrect statements from the options given below: \text{A. A is more soluble than B.} \text{B. The boiling point \& melting point of A are higher and lower than B respectively.} \text{C. A is more polar than B because dipole moment of A is zero.} \text{D. }$Br_2$ \text{ adds easily to B than A.}
B and C only
B, C and D only
A, C and D only
A and B only
Answer: (b)
Solution
Incorrect statements are C and D only, correct choice is not available.
Question 36
Chemistry · Environmental Chemistry · Single correct
How can photochemical smog be controlled?
By using tall chimneys
By complete combustion of fuel
By using catalytic converters in the automobiles/industry
By using catalyst
Answer: (c)
Solution
NCERT (Environmental chemistry)
Question 37
Chemistry · The Solid State · Single correct
Which of the following represents the lattice structure of $A_{0.95}O$ containing $A^{2+}$, $A^{3+}$ and $O^{2-}$ ions? $A^{2+}$ $A^{3+}$ $O^{2-}$
B and C only
B only
A and B only
A only
Answer: (d)
Solution
Applying electrical neutrality principle in metal deficiency defect. $3A^{2+}$ are replaced by $2A^{3+}$; thus one vacant site per pair of $A^{3+}$ is created.
Question 38
Chemistry · Surface Chemistry · Single correct
Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R. Assertion A: Amongst He, Ne, Ar and Kr; 1 g of activated charcoal adsorbs more of Kr. Reason R : The critical volume $V_c$ (cm$^3$ mol$^{-1}$) and critical pressure $P_c$ (atm) is highest for Krypton but the compressibility factor at critical point $Z_c$ is lowest for Krypton. In the light of the above statements, choose the correct answer from the options given below.
A is true but R is false
A is false but R is true
Both A and R are true but R is NOT the correct explanation of A
Both A and R are true and R is the correct explanation A
Answer: (a)
Solution
Adsorption is proportional to van der Waals attraction forces. $$Z_c = \frac{3}{8}$$ for all real gases.
Question 39
Chemistry · General Principles and Processes of Isolation of Elements · Single correct
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Assertion A: In an Ellingham diagram, the oxidation of carbon to carbon monoxide shows a negative slope with respect to temperature. Reason R: CO tends to get decomposed at higher temperature. In the light of the above statements, choose the correct answer from the options given below
Both A and R are correct and R is the correct explanation of A
A is not correct but R is correct
Both A and R are correct but R is NOT the correct explanation of A
A is correct but R is not correct
Answer: (d)
Solution
The reaction is given by: $$2\mathrm{C}(s) + \mathrm{O_2}(g) \rightarrow 2\mathrm{CO}(g)$$ $\Delta_r S^\circ$ is positive, $\Delta_r G^\circ = \Delta_r H^\circ - T \Delta_r S^\circ$; thus the slope is negative. As temperature increases, $\Delta_r G^\circ$ becomes more negative, thus it has a lower tendency to get decomposed.
Question 40
Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct
Given below are two statements: Statement I: Chlorine can easily combine with oxygen to form oxides; and the product has a tendency to explode. Statement II: Chemical reactivity of an element can be determined by its reaction with oxygen and halogens. In the light of the above statements, choose the correct answer from the options given below.
Both the statements I and II are true
Statement I is true but Statement II is false
Statement I is false but Statement II is true
Both the Statements I and II are false
Answer: (a)
Solution
Chlorine oxides, $\mathrm{Cl_2O}$, $\mathrm{ClO_2}$, $\mathrm{Cl_2O_6}$, and $\mathrm{Cl_2O_7}$ are
Question 41
Chemistry · Co-ordination Compounds · Single correct
A solution of $\mathrm{FeCl_3}$, when treated with $\mathrm{K_4[Fe(CN)_6]}$, gives a Prussian blue precipitate due to the formation of:
K[Fe_2(CN)_6]
$\mathrm{Fe[Fe(CN)_6]}$
Fe_3[Fe(CN)_6]_2
Fe_4[Fe(CN)_6]_3
Answer: (d)
Solution
Formation of Prussian blue complex takes place.
Question 42
Chemistry · The d-and f-Block Elements · Single correct
Highest oxidation state of Mn is exhibited in $\mathrm{Mn_2O_7}$. The correct statements about $\mathrm{Mn_2O_7}$ are
A and C only
A and D only
B and D only
B and C only
Answer: (a)
Solution
Question 43
Chemistry · Co-ordination Compounds · Single correct
Which of the following complex will show largest splitting of d-orbitals?
$[\mathrm{Fe(C_2O_4)_3}]^{3-}$
$[\mathrm{FeF_6}]^{3-}$
$[\mathrm{Fe(CN)_6}]^{3-}$
$[\mathrm{Fe(NH_3)_6}]^{3+}$
Answer: (c)
Solution
$\overline{\mathrm{CN}}$ is a strong field ligand so maximum splitting in $d$ orbitals take place.
Question 44
Chemistry · Co-ordination Compounds · Single correct
Which of the following are examples of double salts? (A) $\mathrm{FeSO_4\cdot(NH_4)_2SO_4\cdot6H_2O}$ (B) $\mathrm{CuSO_4\cdot4NH_3\cdot H_2O}$ (C) $\mathrm{K_2SO_4\cdot Al_2(SO_4)_3\cdot24H_2O}$ (D) $\mathrm{Fe(CN)_2\cdot4KCN}$ Choose the correct answer.
A and C only
A and B only
A, B and D only
B and D only
Answer: (a)
Solution
Double salt contains two or more types of salts. $\mathrm{CuSO_4.4NH_3.H_2O}$ and $\mathrm{Fe(CN)_2.4KCN}$ are complex compounds.
Question 45
Chemistry · Analytical Chemistry · Single correct
Identify the incorrect option from the following:
Answer: (b)
Solution
In alcoholic KOH, elimination reaction takes place
Question 46
Chemistry · Alcohols, Phenols and Ethers · Single correct
Decreasing order of dehydration of the following alcohols is
a > d > b > c
b > d > c > a
b > a > d > c
d > b > c > a
Answer: (b)
Solution
Dehydration of alcohol is directly proportional to the stability of carbocation.
Question 47
Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct
In the following reaction, 'A' is 'A' Major product.
Answer: (b)
Solution
Initially lone pair electron of $-\mathrm{NH_2}$ attack on electrophilic carbon, after then lone pair electron of oxygen attacks leading to formation of cyclic compound.
Question 48
Chemistry · Co-ordination Compounds · Single correct
Match List I with List II \begin{tabular}{|c|l|c|l|} \hline \text{List-I} & & \text{List-II} & \\ \hline \text{(A) Tranquilizers} & & \text{(I) Anti blood clotting} & \\ \hline \text{(B) Aspirin} & & \text{(II) Salvarsan} & \\ \hline \text{(C) Antibiotic} & & \text{(III) Antidepressant drugs} & \\ \hline \text{(D) Antiseptic} & & \text{(IV) Soframicine} & \\ \hline \end{tabular} Choose the correct answer from the options given below:
$(A) - IV, (B) - II, (C) - I, (D) - III$
$(A) - II, (B) - I, (C) - III, (D) - IV$
$(A) - II, (B) - I, (C) - IV, (D) - IV$
$(A) - II, (B) - IV, (C) - I, (D) - III$
Answer: (c)
Solution
NCERT (Chemistry in every day life)
Question 49
Chemistry · Biomolecules · Single correct
The correct representation in six-membered pyranose form for the following sugar [X] is
Answer: (b)
Solution
By Howorth structure of mannose
Question 50
Chemistry · Co-ordination Compounds · Single correct
Match List I and List II \begin{tabular}{|c|l|c|l|} \hline \text{List I} & & \text{List II} & \\ \hline \text{Test} & & \text{Functional group / Class of Compound} & \\ \hline \text{(A) Molisch's Test} & & \text{(I) Peptide} & \\ \hline \text{(B) Biuret Test} & & \text{(II) Carbohydrate} & \\ \hline \text{(C) Carbylamine Test} & & \text{(III) Primary amine} & \\ \hline \text{(D) Schiff's Test} & & \text{(IV) Aldehyde} & \\ \hline \end{tabular} Choose the correct answer from the options given below:
(A) - I, (B) - II, (C ) - III, (D) - IV
(A) - III, (B) - IV, (C ) -I, (D) - II
(A) - II, (B) - I, (C ) - III, (D) - IV
(A) - III, (B) - IV, (C ) -II, (D) - I
Answer: (c)
Solution
Match the tests in List I with the functional groups or class of compounds in List II. Molisch's Test is used for detecting carbohydrates. Biuret Test is used for detecting peptides. Carbylamine Test is used for detecting primary amines. Schiff's Test is used for detecting aldehydes.
Question 51
Chemistry · Solutions · Numerical
The density of $3 \, \mathrm{M}$ solution of NaCl is $1.0 \, \mathrm{g \, mL^{-1}}$. Molality of the solution is _______ $\times 10^{-2} \, \mathrm{m}$. (Nearest integer). Given: Molar mass of Na and Cl is $23$ and $35.5 \, \mathrm{g \, mol^{-1}}$ respectively.
Answer: 364
Solution
The molality $m$ is calculated as follows: $$m = \frac{1000 \times M}{1000 \times d - M \times M.W of solute}$$ Substituting the given values: $$= \frac{1000 \times 3}{1000 \times 1 - (3 \times 58.5)} = 3.64$$ Therefore, $$= 364 \times 10^{-2}$$
Question 52
Chemistry · Structure of Atom · Single correct
Electrons in a cathode ray tube have been emitted with a velocity of $1000 \, \mathrm{ms^{-1}}$. The number of following statements which is/are true about the emitted radiation is ________ . Given: $h = 6 \times 10^{-34} \, \mathrm{Js}$, $m_e = 9 \times 10^{-31} \, \mathrm{kg}$.
The deBroglie wavelength of the electron emitted is $666.67 \, \mathrm{nm}$.
The characteristic of electrons emitted depend upon the material of the electrodes of the cathode ray tube.
The cathode rays start from cathode and move towards anode.
The nature of the emitted electrons depends on the nature of the gas present in cathode ray tube.
Answer: (b)
Solution
$(A)$ $V_e = 1000 \, \mathrm{m/s}$; $h = 6 \times 10^{-34} \, \mathrm{Js}$; $m_e = 9 \times 10^{-31} \, \mathrm{kg}$ $$\lambda = \frac{h}{mv} = \frac{6 \times 10^{-34}}{9 \times 10^{-31} \times 1000} = 666.67 \times 10^{-9} \, \mathrm{m}$$ $$= 666.67 \, \mathrm{nm}$$ $(B)$ The characteristic of electrons emitted is independent of the material of the electrodes of the cathode ray tube. $(C)$ The cathode rays start from cathode and move towards anode. $(D)$ The nature of the emitted electrons is independent on the nature of the gas present in cathode ray tube.
Question 53
Chemistry · Thermodynamics · Numerical
At 25°C, the enthalpy of the following processes are given: $$\mathrm{H_2(g) + O_2(g) \rightarrow 2OH(g)} \Delta H^\circ = 78 \, \mathrm{kJ \, mol^{-1}}$$ $$\mathrm{H_2(g) + \frac{1}{2}O_2(g) \rightarrow H_2O(g)} \Delta H^\circ = -242 \, \mathrm{kJ \, mol^{-1}}$$ $$\mathrm{H_2(g) \rightarrow 2H(g)} \Delta H^\circ = 436 \, \mathrm{kJ \, mol^{-1}}$$ $$\mathrm{\frac{1}{2}O_2(g) \rightarrow O(g)} \Delta H^\circ = 249 \, \mathrm{kJ \, mol^{-1}}$$ What would be the value of $X$ for the following reaction? (Nearest integer) $$\mathrm{H_2O(g) \rightarrow H(g) + OH(g)} \Delta H^\circ = X \, \mathrm{kJ \, mol^{-1}}$$
Answer: 499
Solution
The reaction sequence is as follows: $$\mathrm{2H_2O(g) \rightarrow 2H_2(g) + O_2(g)} +(242 \times 2) \, \mathrm{kJ \, mol^{-1}}$$ $$\mathrm{H_2(g) + O_2(g) \rightarrow 2OH} +78 \, \mathrm{kJ \, mol^{-1}}$$ $$\mathrm{H_2(g) \rightarrow 2H} +436 \, \mathrm{kJ \, mol^{-1}}$$ Adding these reactions gives: $$\mathrm{2H_2O \rightarrow 2H + 2OH} +998 \, \mathrm{kJ \, mol^{-1}}$$ For the reaction: $$\mathrm{H_2O \rightarrow H + OH}$$ The enthalpy change is: $$998 \times \frac{1}{2} = +499 \, \mathrm{kJ \, mol^{-1}}$$
Question 54
Chemistry · Equilibrium · Numerical
(i) $X(g) \rightleftharpoons Y(g) + Z(g)$ \quad $K_{p1} = 3$ (ii) $A(g) \rightleftharpoons 2B(g)$ \quad $K_{p2} = 1$ If the degree of dissociation and initial concentration of both the reactants $X(g)$ and $A(g)$ are equal, then the ratio of the total pressure at equilibrium $\left(\dfrac{P_1}{P_2}\right)$ is equal to $x : 1$. The value of $x$ is \underline{\hspace{1.5cm}} (Nearest integer)
Answer: 12
Solution
For the reaction $\mathrm{x(g) \rightleftharpoons y(g) + z(g)}$, $k_{p_1} = 3$. Initial moles at equilibrium are $n$, $n - \alpha n$, $\alpha n$, and $-\alpha n$. The expression for $k_{p_1}$ is given by: $$k_{p_1} = \frac{\left( \frac{\alpha}{1 + \alpha} \times p_1 \right)^2}{\frac{1 - \alpha}{1 + \alpha} \times p_1}$$ Simplifying, we have: $$3 = \frac{\alpha^2 \times p_1}{1 - \alpha^2}$$ For the reaction $\mathrm{A(g) \rightleftharpoons 2B(g)}$, $k_{p_2} = 1$. Initial moles at equilibrium are $n$, $x - \alpha n$, $2 \alpha n$, and $p_{total} = p_2$. The expression for $k_{p_2}$ is: $$k_{p_2} = \frac{\left( \frac{2\alpha}{1 + \alpha} \times p_2 \right)^2}{\frac{1 - \alpha}{1 + \alpha} \times p_2}$$ Simplifying, we have: $$1 = \frac{4\alpha^2 \times p_2}{1 - \alpha^2}$$ The ratio of $k_{p_1}$ to $k_{p_2}$ is: $$\frac{k_{p_1}}{k_{p_2}} = \frac{p_1}{4p_2}$$ Thus, we have: $$\frac{3}{1} = \frac{p_1}{4p_2}$$ Therefore, $p_1 : p_2 = 12 : 1$ and $x = 12$.
The total number of chiral compound/s from the following is ________.
Answer: 2
Solution
The molecule has a chiral center indicated by the asterisk. There is no plane of symmetry (POS) or center of symmetry (COS), making it chiral. The first structure is achiral due to the presence of a plane of symmetry. The second structure is also achiral due to the presence of a plane of symmetry.
Question 56
Chemistry · Solutions · Numerical
25 $\mathrm{mL}$ of an aqueous solution of $\mathrm{KCl}$ was found to require 20 $\mathrm{mL}$ of 1 $\mathrm{M}$ $\mathrm{AgNO_3}$ solution when titrated using $\mathrm{K_2CrO_4}$ as an indicator. What is the depression in freezing point of $\mathrm{KCl}$ solution of the given concentration? (Nearest integer). (Given: $K_f$ = 2.0 $\mathrm{K \, kg \, mol^{-1}}$) Assume 1) 100$\%$ ionization and 2) density of the aqueous solution as 1 $\mathrm{g \, mL^{-1}}$
Answer: 3
Solution
At equivalence point, mmol of KCl = mmol of AgNO_3. = 20 mmole Volume of solution = 25 ml Mass of solution = 25 gm Mass of solvent = 25 - mass of solute = 25 - [20 $\times$ 10^{-3} $\times$ 74.5] = 23.51 gm Molality of KCl = $\frac{mole of KCl}{mass of solvent in kg}$ = $\frac{20 \times 10^{-3}}{23.51 \times 10^{-3}}$ = 0.85 i of KCl = 2 $\;$ (100$\%$ ionisation) $\Delta$ $T_f$ = i $\times$ $K_f$ $\times$ m = 2 $\times$ 2 $\times$ 0.85 = 3.4 $\approx$ 3
Question 57
Chemistry · Electrochemistry · Numerical
At what pH, given half cell $\mathrm{MnO_4^-} \ (0.1 \, \mathrm{M}) \mid \mathrm{Mn^{2+}} \ (0.001 \, \mathrm{M})$ will have electrode potential of $1.282 \, \mathrm{V}$? __________ (Nearest Integer) Given $E^o_{\mathrm{MnO_4^-/Mn^{2+}}} = 1.54 \, \mathrm{V}$, $\frac{2.303RT}{F} = 0.059 \, \mathrm{V}$
Answer: 3
Solution
The balanced chemical equation is: $$\mathrm{MnO_4^- + 8H^+ + 5e^- \rightleftharpoons Mn^{2+} + 4H_2O}$$ The Nernst equation is given by: $$E = E^\circ - \frac{0.059}{5} \log \frac{[\mathrm{Mn^{2+}}]}{[\mathrm{MnO_4^-}][\mathrm{H^+}]^8}$$ Substituting the given values: $$1.282 = 1.54 - \frac{0.059}{5} \log \frac{10^{-3}}{10^{-1} \times [\mathrm{H^+}]^8}$$ Simplifying further: $$0.258 \times 5 = \frac{0.059}{[\mathrm{H^+}]^8} \log 10^{-2}$$ This implies: $$21.86 = -2 + 8 \mathrm{pH}$$ Therefore, $$\mathrm{pH} = 2.98$$ Approximately, $$\approx 3$$
Question 58
Chemistry · Chemical Kinetics and Nuclear Chemistry · Numerical
A and B are two substances undergoing radioactive decay in a container. The half life of A is $15 \, \mathrm{min}$ and that of B is $5 \, \mathrm{min}$. If the initial concentration of B is 4 times that of A and they both start decaying at the same time, how much time will it take for the concentration of both of them to be same?
Sum of oxidation states of bromine in bromic acid and perbromic acid is _______.
Answer: 12
Solution
$\mathrm{HBrO_3}$ (Bromic acid) Ox. State of Br = $+5$ $\mathrm{HBrO_4}$ (Perbromic acid) Ox. State of Br = $+7$ Sum of Ox. State = $12$
Question 60
Chemistry · Aldehydes, Ketones and Carboxylic Acids · Numerical
Number of isomeric compounds with molecular formula $\mathrm{C_9H_{10}O}$ which (i) do not dissolve in $\mathrm{NaOH}$ (ii) do not dissolve in $\mathrm{HCl}$. (iii) do not give orange precipitate with $2, 4 - \mathrm{DNP}$ (iv) on hydrogenation give identical compound with molecular formula $\mathrm{C_9H_{12}O}$ is
Answer: 2
Solution
As per the language of given question, the best possible isomeric structure is Ph - CH = CH - O - $CH_3$ (cis and trans). So, the answer is 2.
Maths
Question 61
Maths · Basics Of Mathematics · Single correct
Let $$S = \left\{ x : x \in \mathbb{R} and \left( \sqrt{3} + \sqrt{2} \right)^{x^2 - 4} + \left( \sqrt{3} - \sqrt{2} \right)^{x^2 - 4} = 10 \right\}$$ Then n (S) is equal to
Maths · Complex Numbers and Quadratic Equations · Single correct
If the center and radius of the circle $|\frac{z-2}{z-3}|$ = 2 are respectively $\alpha, \beta$ and $\gamma$, then $3\alpha + \beta + \gamma$ is equal to
The sum to 10 terms of the series \[\frac{1}{1+1^2+1^4} + \frac{2}{1+2^2+2^4} + \frac{3}{1+3^2+3^4} + \ldots is: \]
$\frac{59}{111}$
$\frac{55}{111}$
$\frac{56}{111}$
$\frac{58}{111}$
Answer: (b)
Solution
Given $$T_r = \frac{(r^2 + r + 1) - (r^2 - r + 1)}{2(r^4 + r^2 + 1)}$$ This simplifies to $$T_r = \frac{1}{2} \left[ \frac{1}{r^2 - r + 1} - \frac{1}{r^2 + r + 1} \right]$$ Calculating for specific values: $$T_1 = \frac{1}{2} \left[ \frac{1}{1} - \frac{1}{3} \right]$$ $$T_2 = \frac{1}{2} \left[ \frac{1}{3} - \frac{1}{7} \right]$$ $$T_3 = \frac{1}{2} \left[ \frac{1}{7} - \frac{1}{13} \right]$$ $\vdots$ $$T_{10} = \frac{1}{2} \left[ \frac{1}{91} - \frac{1}{111} \right]$$ Summing up the series: $$\Rightarrow \sum_{r=1}^{10} T_r = \frac{1}{2} \left[ 1 - \frac{1}{111} \right] = \frac{55}{111}$$
Question 64
Maths · Binomial Theorem · Single correct
The value of $\frac{1}{1!50!}$ + $\frac{1}{3!48!}$ + $\frac{1}{5!46!}$ + $\ldots$ + $\frac{1}{49!2!}$ + $\frac{1}{51!1!}$ is
$\frac{2^{50}}{50!}$
$\frac{2^{50}}{51!}$
$\frac{2^{51}}{51!}$
$\frac{2^{51}}{50!}$
Answer: (b)
Solution
The given expression is $$\sum_{r=1}^{26} \frac{1}{(2r-1)!(51-(2r-1))!} = \sum_{r=1}^{26} {}^{51}C_{2r-1} \frac{1}{51!}$$ which simplifies to $$= \frac{1}{51!} \left\{ {}^{51}C_{1} + {}^{51}C_{3} + \ldots + {}^{51}C_{51} \right\} = \frac{1}{51!} (2^{50}).$$
Question 65
Maths · Straight Lines and Pair of Straight Lines · Single correct
The combined equation of the two lines $ax + by + c = 0$ and $a'x + b'y + c' = 0$ can be written as $(ax + by + c) (a'x + b'y + c') = 0$ The equation of the angle bisectors of the lines represented by the equation $2x^2 + xy - 3y^2 = 0$ is
$3x^2 + 5xy + 2y^2 = 0$
$x^2 - y^2 + 10xy = 0$
$3x^2 + xy - 2y^2 = 0$
$x^2 - y^2 - 10xy = 0$
Answer: (d)
Solution
Equation of the pair of angle bisector for the homogenous equation $ax^2 + 2hxy + by^2 = 0$ is given as $$\frac{x^2 - y^2}{a - b} = \frac{xy}{h}$$ Here $a = 2$, $h = \frac{1}{2}$ and $b = -3$. Equation will become $$\frac{x^2 - y^2}{2 - (-3)} = \frac{xy}{1/2}$$ $$x^2 - y^2 = 10xy$$ $$x^2 - y^2 - 10xy = 0$$
Question 66
Maths · Properties of Triangles · Single correct
If the orthocentre of the triangle, whose vertices are $(1, 2)$, $(2, 3)$ and $(3, 1)$ is $(\alpha, \beta)$, then the quadratic equation whose roots are $\alpha + 4\beta$ and $4\alpha + \beta$, is
The negation of the expression $q \lor ((\sim q) \land p)$ is equivalent to
$(\sim p) \land (\sim q)$
$p \land (\sim q)$
$(\sim p) \lor (\sim q)$
$(\sim p) \lor q$
Answer: (a)
Solution
The expression is given as: $$\sim (q \lor ((\sim q) \land p))$$ This can be rewritten as: $$= \sim q \land \sim ((\sim q) \land p)$$ Applying distribution: $$= \sim q \land (q \lor \sim p)$$ Using distribution again: $$= (\sim q \land q) \lor (\sim q \land \sim p)$$ Simplifying further: $$= (\sim q \land \sim p)$$
Question 68
Maths · Statistics · Single correct
The mean and variance of 5 observations are 5 and 8 respectively. If 3 observations are 1, 3, 5, then the sum of cubes of the remaining two observations is
1072
1792
1216
1456
Answer: (a)
Solution
Given $\($ $\frac{1 + 3 + 5 + a + b}{5}$ = 5 $\)$ $\($ a + b = 16 $\)$ ......(1) $\($ $\sigma$^2 = $\frac{\sum x_1^2}{5}$ - $\left$( $\frac{\sum x}{5}$ $\right$)^2 $\)$ $\($ 8 = $\frac{1^2 + 3^2 + 5^2 + a^2 + b^2}{5}$ - 25 $\)$ $\($ a^2 + b^2 = 130 $\)$ ......(2) By (1), (2) $\($ a = 7, b = 9 $\)$
Question 69
Maths · Properties of Triangles · Single correct
For a triangle ABC, the value of $\cos 2A + \cos 2B + \cos 2C$ is least. If its inradius is 3 and incentre is M, then which of the following is NOT correct?
Perimeter of $\triangle ABC$ is $18\sqrt{3}$
$\sin 2A + \sin 2B + \sin 2C = \sin A + \sin B + \sin C$
$\overline{MA} \cdot \overline{MB} = -18$
area of $\triangle ABC$ is $\frac{27\sqrt{3}}{2}$
Answer: (d)
Solution
If $\cos 2A + \cos 2B + \cos 2C$ is minimum then $A = B = C = 60^\circ$. So $\triangle ABC$ is equilateral. Now in-radius $r = 3$. So in $\triangle MBD$ we have $$\tan 30^\circ = \frac{MD}{BD} = \frac{r}{a/2} = \frac{6}{a}$$ $$\frac{1}{\sqrt{3}} = \frac{1}{a} = a = 6\sqrt{3}$$ Perimeter of $\triangle ABC = 18\sqrt{3}$. Area of $\triangle ABC = \frac{\sqrt{3}}{4} a^2 = 27\sqrt{3}$.
Question 70
Maths · Relations and Functions · Single correct
Let R be a relation on $\mathbb{R}$, given by $$R = \{(a, b) : 3a - 3b + \sqrt{7} \text{ is an irrational number}\}.$$ Then R is
Reflexive but neither symmetric nor transitive
Reflexive and transitive but not symmetric
Reflexive and symmetric but not transitive
An equivalence relation
Answer: (a)
Solution
Check for reflexivity: As $3(a - a) + \sqrt{7} = \sqrt{7}$ which belongs to relation so relation is reflexive. Check for symmetric: Take $a = \frac{\sqrt{7}}{3}, b = 0$. Now $(a, b) \in R$ but $(b, a) \notin R$. As $3(b - a) + \sqrt{7} = 0$ which is rational so relation is not symmetric. Check for Transitivity: Take $(a, b)$ as $\left( \frac{\sqrt{7}}{3}, 1 \right)$ and $(b, c)$ as $\left( 1, \frac{2\sqrt{7}}{3} \right)$. So now $(a, b) \in R$ and $(b, c) \in R$ but $(a, c) \notin R$ which means relation is not transitive.
Question 71
Maths · Determinants · Single correct
Let S denote the set of all real values of $\lambda$ such that the system of equations $$\lambda x + y + z = 1$$ $$x + \lambda y + z = 1$$ $$x + y + \lambda z = 1$$ is inconsistent, then $\sum_{\lambda \in S} (|\lambda|^2 + |\lambda|)$ is equal to
Maths · Inverse Trigonometric Functions · Single correct
Let S be the set of all solutions of the equation $$\cos^{-1}(2x) - 2\cos^{-1}\left(\sqrt{1-x^2}\right) = \pi, \ x \in \left[-\frac{1}{2}, \frac{1}{2}\right].$$ Then $$\sum_{x \in S} 2\sin^{-1}(x^2 - 1)$$ is equal to
Maths · Applications of Derivatives · Single correct
Let $f(x) = 2x + \tan^{-1} x$ and $g(x) = \log_e \left( \sqrt{1 + x^2} + x \right)$, $x \in [0, 3]$. Then
There exists $\hat{x} \in [0,3]$ such that $f'(\hat{x}) < g'(\hat{x})$
max $f(x) >$ max $g(x)$
There exist $0 < x_1 < x_2 < 3$ such that $f(x) < g(x)$, $\forall x \in (x_1, x_2)$
min $f'(x) = 1 +$ max $g'(x)$
Answer: (b)
Solution
Given $f(x) = 2x + \tan^{-1}x$ and $g(x) = \ln \left( \sqrt{1+x^2} + x \right)$ and $x \in [0, 3]$. $g'(x) = \frac{1}{\sqrt{1+x^2}}$. Now, $0 \leq x \leq 3$. $0 \leq x^2 \leq 9$ $1 \leq 1+x^2 \leq 10$. So, $$2 + \frac{1}{10} \leq f'(x) \leq 3$$ $$\frac{21}{10} \leq f'(x) \leq 3 and \frac{1}{\sqrt{10}} \leq g'(x) \leq 1$$ Option (4) is incorrect. From above, $g'(x) \ln (3 + \sqrt{10})$ Option (2) is correct.
Question 74
Maths · Applications of Derivatives · Single correct
Let $f(x) = \begin{vmatrix} 1 + \sin^2 x & \cos^2 x & \sin 2x \\ \sin^2 x & 1 + \cos^2 x & \sin 2x \\ \sin^2 x & \cos^2 x & 1 + \sin 2x \end{vmatrix}$, $x \in \left[ \frac{\pi}{6}, \frac{\pi}{3} \right]$. If $\alpha$ and $\beta$ respectively are the maximum and the minimum values of $f$, then
$\lim_{{n \to \infty}}$ ($\frac{1}{1+n}$ + $\frac{1}{2+n}$ + $\frac{1}{3+n}$ + $\ldots$ + $\frac{1}{2n}$) is equal to :-
0
$\\log_e$ 2
$\\log_e(\\frac{3}{2})$
$\\log_e(\\frac{2}{3})$
Answer: (b)
Solution
The limit is given by $$\lim_{{n \to \infty}} \left( \frac{1}{1+n} + \ldots + \frac{1}{n+n} \right) = \lim_{{n \to \infty}} \sum_{{r=1}}^{n} \frac{1}{n+r}$$ which can be rewritten as $$= \lim_{{n \to \infty}} \sum_{{r=1}}^{n} \frac{1}{n} \left( \frac{1}{1+\frac{r}{n}} \right)$$ This is equivalent to the integral $$= \int_{0}^{1} \frac{1}{1+x} \, dx = [\ln(1+x)]_{0}^{1} = \ln 2$$
Question 76
Maths · Differential Equations · Single correct
The area enclosed by the closed curve C given by the differential equation $\frac{dy}{dx} + \frac{x+a}{y-2} = 0, \ y(1) = 0$ is $4\pi$. Let P and Q be the points of intersection of the curve C and the y-axis. If normals at P and Q on the curve C intersect x-axis at points R and S respectively, then the length of the line segment RS is
If y = y(x) is the solution curve of the differential equation $\($ $\frac{dy}{dx}$ + y $\tan$ x = x $\sec$ x $\)$, $\($ 0 $\leq$ x $\leq$ $\frac{\pi}{3}$ $\)$, y(0) = 1, then $\($ y( $\frac{\pi}{6}$ ) $\)$ is equal to
The number of words, with or without meaning, that can be formed using all the letters of the word ASSASSINATION so that the vowels occur together, is _____.
Answer: 50400
Solution
Vowels: A, A, A, I, I, O Consonants: S, S, S, S, N, N, T Therefore, the total number of ways in which vowels come together $$= \frac{8!}{4!2!} \times \frac{6!}{3!2!} = 50400$$
Question 82
Maths · Sequences and Series · Fill in the blank
Let $a_1 = 8$, $a_2$, $a_3$, $\ldots$, $a_n$ be an A.P. If the sum of its first four terms is 50 and the sum of its last four terms is 170, then the product of its middle two terms is ______.
The number of 3-digit numbers, that are divisible by either 2 or 3 but not divisible by 7 is ____.
Answer: 514
Solution
Divisible by 2 gives 450. Divisible by 3 gives 300. Divisible by 7 gives 128. Divisible by 2 and 7 gives 64. Divisible by 3 and 7 gives 43. Divisible by 2 and 3 gives 150. Divisible by 2, 3, and 7 gives 21. Therefore, the total numbers are calculated as follows: $$450 + 300 - 150 - 64 - 43 + 21 = 514.$$
Question 84
Maths · Binomial Theorem · Fill in the blank
The remainder when $19^{200} + 23^{200}$ is divided by 49, is ____.
If \[ \int_0^1 (x^{21} + x^{14} + x^7)(2x^{14} + 3x^7 + 6)^{1/7} \, dx = \frac{1}{l}(11)^{m/n} \] where $l$, $m$, $n \in \mathbb{N}$, $m$ and $n$ are coprime then $l + m + n$ is equal to ____.
Answer: 63
Solution
Given the integral $$\int \left( x^{20} + x^{13} + x^6 \right) \left( 2x^{21} + 3x^{14} + 6x^7 \right)^{1/7} \, dx$$ Let $$2x^{21} + 3x^{14} + 6x^7 = t$$ Then, $$42(x^{20} + x^{13} + x^6) \, dx = dt$$ Thus, $$\frac{1}{42} \int_0^{11} t^{1/7} \, dt = \left( \frac{t^{8/7}}{8/7} \times \frac{1}{42} \right) \bigg|_0^{11}$$ This simplifies to $$= \frac{1}{48} \left( t^{8/7} \right) \bigg|_0^{11} = \frac{1}{48} (11)^{8/7}$$ Let $$l = 48, \ m = 8, \ n = 7$$ Therefore, $$l + m + n = 63$$
Question 87
Maths · Applications of Integrals · Numerical
Let A be the area bounded by the curve $y = x |x - 3|$, the x-axis and the ordinates $x = -1$ and $x = 2$. Then $12A$ is equal to _____.
Let f : ℝ → ℝ be a differentiable function such that f'(x) + f(x) = ∫₀² f(t) dt. If f(0) = e⁻², then 2f(0) − f(2) is equal to _____.
Answer: 1
Solution
dy/dx + y = k y·$e^x$ = k·$e^x$ + c f(0) = $e^{-2}$ ⇒ c = $e^{-2}$ - k ∴ y = k + $(e^{-2} - k)e^{-x}$ Now, k = ∫₀² [k + $(e^{-2} - k)e^{-x}]$ dx ⇒ k = $e^{-2}$ - 1 ∴ y = $(e^{-2} - 1) + e^{-x}$ f(2) = 2$e^{-2}$ - 1, f(0) = $e^{-2}$ 2f(0) - f(2) = 1
Question 89
Maths · Vector Algebra · Numerical
Let $\vec{v} = \alpha \hat{i} + 2 \hat{j} - 3 \hat{k}$, $\vec{w} = 2 \alpha \hat{i} + \hat{j} - \hat{k}$, and $\vec{u}$ be a vector such that $|\vec{u}| = \alpha > 0$. If the minimum value of the scalar triple product $[\vec{u} \vec{v} \vec{w}]$ is $-\alpha \sqrt{3401}$, and $|\vec{u} \cdot \hat{i}|^2 = \frac{m}{n}$ where m and n are coprime natural numbers, then m + n is equal to ______.
Maths · Three Dimensional Geometry · Fill in the blank
$A(2,6,2)$, $B(-4,0,\lambda)$, $C(2,3,-1)$ and $D(4,5,0)$, $|\lambda|\leq5$, are the vertices of a quadrilateral $ABCD$. If its area is $18$ square units, then $5-6\lambda$ is equal to $\underline{\hspace{2cm}}$.
Answer: 11
Solution
Given points A(2, 6, 2), B(-4, 0, $\lambda$), C(2, 3, -1), D(4, 5, 0). The area is given by $$Area = \frac{1}{2} \left| \overrightarrow{BD} \times \overrightarrow{AC} \right| = 18$$ The cross product is calculated as $$\overrightarrow{AC} \times \overrightarrow{BD} = \begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ 0 & -3 & -3 \\ 8 & 5 & -\lambda \end{vmatrix}$$ This results in $$(3\lambda + 15) \hat{i} - \hat{j} (-24) + \hat{k} (-24)$$ Thus, $$\overrightarrow{AC} \times \overrightarrow{BD} = (3\lambda + 15) \hat{i} + 24 \hat{j} - 24 \hat{k}$$ The magnitude is $$\sqrt{(3\lambda + 15)^2 + (24)^2 + (24)^2} = 36$$ Solving gives $$\lambda^2 + 10\lambda + 9 = 0$$ The solutions are $$\lambda = -1, -9$$ Given $|\lambda| \leq 5$, we have $\lambda = -1$. Finally, $$5 - 6\lambda = 5 - 6(-1) = 11$$