JEE Main 6 April 2023 Shift 2 question paper with solutions

JEE Main 6 April 2023 Shift 2: all 90 questions in paper order (Maths, Physics, Chemistry) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.

Register free to attempt this shift as a timed 180-minute test with instant scoring and chapter-wise analysis.

Maths

Question 1

Maths · Probability · Single correct

Three dice are rolled. If the probability of getting different numbers on the three dice is $\frac{p}{q}$, where $p$ and $q$ are co-prime, then $q - p$ is equal to

  1. 2
  2. 1
  3. 3
  4. 4

Answer: (d)

Solution

Given that three dice are thrown. The total number of outcomes when three dice are thrown together is $6^3 = 6 \times 6 \times 6$. The number of outcomes such that all the outcomes are different is $6 \times 5 \times 4$. For example: If the outcome in dice 1 is "6" then the number of outcomes for dice 2 should be 5 (1, 2, 3, 4, 5) which excludes the outcome "6". Hence, the required probability is $$= \frac{6 \times 5 \times 4}{6 \times 6 \times 6}$$ $$= \frac{20}{36} = \frac{5}{9} = \frac{p}{q}$$ $$\Rightarrow q - p = 9 - 5 = 4$$ Therefore, the required answer is 4.

Question 2

Maths · Binomial Theorem · Single correct

Among the statements : $\mathrm{(S_1)}$ : $2023^{2022} - 1999^{2022}$ is divisible by 8. $\mathrm{(S_2)}$ : $13(13)^n - 11n - 13$ is divisible by 144 for infinitely many $n \in \mathbb{N}$

  1. Only $(S_2)$ is correct
  2. Only $(S_1)$ is correct
  3. Both $(S_1)$ and $(S_2)$ are correct
  4. Both $(S_1)$ and $(S_2)$ are incorrect

Answer: (b)

Solution

Given, (S1) : $(2023)^{2022}$ - $(1999)^{2022}$ is divisible by 8 Now we know that (x - y) divides $(x^n - y^n)$ $\forall$ n $\in$ $\mathbb{N}$ So, (2023 - 1999) divides $(2023)^{2022}$ - $(1999)^{2022}$ $\Rightarrow$ 24 divides $(2023)^{2022}$ - $(1999)^{2002}$ $\Rightarrow$ 8 will divide $(2023)^{2022}$ - $(1999)^{2002}$ As 8 divides 24 Hence, (S1) is correct Now solving, (S2) : $13(13)^n - 11n - 13$ is divisible by 144 for n $\in$ $\mathbb{N}$ So using binomial theorem in $(1+12)^{n}$ we get, $13(1+12)^{n}-11n-13$ $=13\left({}^{n}C_{0}+{}^{n}C_{1}12+{}^{n}C_{2}12^{2}+\cdots+{}^{n}C_{n}12^{n}\right)-11n-13$ $=12\times13n-11n+12\lambda$ $=145n+144\lambda$ which is not divisible by $144$. Hence, $(S2)$ is incorrect.

Question 3

Maths · Sequences and Series · Single correct

\[ \lim_{n\to\infty} \left[ \left(2^{-\frac{1}{2}}-2^{-\frac{3}{2}}\right) \left(2^{-\frac{1}{2}}-2^{-\frac{5}{2}}\right) \cdots \left(2^{-\frac{1}{2}}-2^{-\frac{(2n+1)}{2}}\right) \right] \] is equal to

  1. 1
  2. 0
  3. $\sqrt{2}$
  4. $\frac{1}{\sqrt{2}}$

Answer: (b)

Solution

Let, $$L = \lim_{n \to \infty} \left\{ \left( 2^{\frac{1}{2}} - 2^{\frac{1}{3}} \right) \left( 2^{\frac{1}{2}} - 2^{\frac{1}{5}} \right) \cdots \left( 2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} \right) \right\}$$ Now, $$2^{\frac{1}{2}} - 2^{\frac{1}{3}} < 1$$ $$2^{\frac{1}{2}} - 2^{\frac{1}{5}} < 1$$ ------------------ $$2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} < 1 \forall n \in \mathbb{N}$$ And $$\left( 2^{\frac{1}{2}} - 2^{\frac{1}{3}} \right)^n < \left( 2^{\frac{1}{2}} - 2^{\frac{1}{3}} \right) \left( 2^{\frac{1}{2}} - 2^{\frac{1}{5}} \right) \cdots \left( 2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} \right) < \left( 2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} \right)^n$$ $$\Rightarrow \lim_{n \to \infty} \left( 2^{\frac{1}{2}} - 2^{\frac{1}{3}} \right)^n < \lim_{n \to \infty} \left( \left( 2^{\frac{1}{2}} - 2^{\frac{1}{3}} \right) \left( 2^{\frac{1}{2}} - 2^{\frac{1}{5}} \right) \cdots \left( 2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} \right) \right) < \lim_{n \to \infty} \left( 2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} \right)^n$$ $$\Rightarrow \lim_{n \to \infty} \left( 2^{\frac{1}{2}} - 2^{\frac{1}{3}} \right)^n < L < \lim_{n \to \infty} \left( 2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} \right)^n$$ And $$\lim_{n \to \infty} \left( 2^{\frac{1}{2}} - 2^{\frac{1}{3}} \right)^n = 0 \& \lim_{n \to \infty} \left( 2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} \right)^n = 0$$ $$\left\{ as 2^{\frac{1}{2}} - 2^{\frac{1}{3}} < 1 \& 2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} < 1 \right\}$$ Hence, $$\lim_{n \to \infty} \left\{ \left( 2^{\frac{1}{2}} - 2^{\frac{1}{3}} \right) \left( 2^{\frac{1}{2}} - 2^{\frac{1}{5}} \right) \cdots \left( 2^{\frac{1}{2}} - 2^{\frac{1}{2n+1}} \right) \right\} = 0$$

Question 4

Maths · Complex Numbers and Quadratic Equations · Single correct

Let $a \neq b$ be two non-zero real numbers. Then the number of elements in the set $X = \{ z \in \mathbb{C} : \mathrm{Re}(az^2 + bz) = a \text{ and } \mathrm{Re}(bz^2 + az) = b \}$ is equal to

  1. 0
  2. 1
  3. 3
  4. 2

Answer: (a)

Solution

Given, $$X = \{ z \in \mathbb{C} : \Re(az^2 + bz) = a and \Re(bz^2 + az) = b \}$$ Now, let $z = x + iy$. So, $\Re(az^2 + bz) = a$ $$\Rightarrow \Re\left(a(x + iy)^2 + b(x + iy)\right) = a$$ $$\Rightarrow \Re\left(a(x^2 - y^2 + 2ixy) + b(x + iy)\right) = a$$ $$\Rightarrow a(x^2 - y^2) + bx = a \ldots (i)$$ And, $\Re(bz^2 + az) = b$ $$\Rightarrow \Re\left(b(x + iy)^2 + a(x + iy)\right) = b$$ $$\Rightarrow \Re\left(b(x^2 - y^2 + 2ixy) + a(x + iy)\right) = b$$ $$\Rightarrow b(x^2 - y^2) + ax = b \ldots (ii)$$ From (i) and (ii), (i) - (ii) we get, $$(x^2 - y^2)(a - b) - x(a - b) = a - b$$ $$\Rightarrow x^2 - y^2 - x = 1 \ldots (iii)$$ From (i) and (ii), (i) + (ii) $$((x^2 - y^2) + x - 1)(a + b) = 0 (Note: here a + b \neq 0 is considered but it is not clear from the question)$$ $$\Rightarrow x^2 - y^2 + x - 1 = 0 \ldots (iv)$$ Now from (iii) and (iv) we get, $$x = 0, \; y^2 = -1 (No solution)$$

Question 5

Maths · Relations and Functions · Single correct

Let the sets $A$ and $B$ denote the domain and range respectively of the function $f(x) = \frac{1}{\sqrt{\lceil x \rceil - x}}$, where $\lceil x \rceil$ denotes the smallest integer greater than or equal to $x$. Then among the statements (S1): $A \cap B = (1, \infty) - \mathbb{N}$ and (S2): $A \cup B = (1, \infty)$

  1. Only (S2) is true
  2. Only (S1) is true
  3. Neither (S1) nor (S2) is true
  4. Both (S1) and (S2) are true

Answer: (c)

Solution

Given, $$f(x) = \frac{1}{\sqrt{[x] - x}}$$ We know that, $x = [x] + \{x\}$ where $\{x\}$ is the fractional part of $x$ whose value is $0 0$, but $-\{x\} \in (-1, 0)$ Hence, $\sqrt{-\{x\}}$ is not defined Hence, Domain and Range will be $= \emptyset$

Question 6

Maths · Differential Equations · Single correct

If the solution curve $f(x, y) = 0$ of the differential equation $\left(1 + \log_e x\right) \frac{dx}{dy} - x \log_e x = e^y$, $x > 0$, passes through the points $(1, 0)$ and $(a, 2)$, then $a^a$ is equal to

  1. $e^{e^2}$
  2. $e^{e}$
  3. $e^{\sqrt{2e^2}}$
  4. $e^{2e\sqrt{2}}$

Answer: (a)

Solution

The given differential equation is $\left(1 + \ln(x)\right) \frac{dx}{dy} - x \ln(x) = e^y$. Put $x \ln(x) = t$. $$\Rightarrow (1 + \ln(x)) dx = dt$$ $$\Rightarrow \frac{dt}{dy} - t = e^y$$ which is a linear differential equation. Integrating factor $= e^{-\int dy} = e^{-y}$. The solution of the differential equation is $$\Rightarrow t \times e^{-y} = \int e^y \times e^{-y} dy + c$$ $$\Rightarrow t \times e^{-y} = y + c$$ $$\Rightarrow x \ln(x) = y \, e^y + c \, e^y$$ Put $x = 1$, $y = 0$ $$\Rightarrow c = 0$$ Put $x = a$, $y = 2$ $$a \ln(a) = 2e^2$$ $$\therefore a^a = e^{2e^2}$$ Hence this is the correct option.

Question 7

Maths · Vector Algebra · Single correct

The sum of all values of $\alpha$, for which the points whose position vectors are $\hat{i} - 2\hat{j} + 3\hat{k}$, $2\hat{i} - 3\hat{j} + 4\hat{k}$, $(\alpha + 1)\hat{i} + 2\hat{k}$ and $9\hat{i} + (\alpha - 8)\hat{j} + 6\hat{k}$ are coplanar, is equal to

  1. $-2$
  2. $2$
  3. $6$
  4. $4$

Answer: (b)

Solution

Let the given vectors be $\vec{A} = \hat{i} - 2\hat{j} + 3\hat{k}$, $\vec{B} = 2\hat{i} - 3\hat{j} + 4\hat{k}$, $\vec{C} = (\alpha + 1)\hat{i} + 2\hat{k}$ and $\vec{D} = 9\hat{i} + (\alpha - 8)\hat{j} + 6\hat{k}$. We know that if the vectors are coplanar then $$\begin{vmatrix} \vec{AB} & \vec{AC} & \vec{AD} \end{vmatrix} = 0$$ $$\Rightarrow \vec{AB} = (2\hat{i} - 3\hat{j} + 4\hat{k}) - (\hat{i} - 2\hat{j} + 3\hat{k}) = \hat{i} - \hat{j} + \hat{k}$$ $$\Rightarrow \vec{AC} = ((\alpha + 1)\hat{i} + 2\hat{k}) - (\hat{i} - 2\hat{j} + 3\hat{k}) = \alpha \hat{i} + 2\hat{j} - \hat{k}$$ $$\Rightarrow \vec{AD} = (9\hat{i} + (\alpha - 8)\hat{j} + 6\hat{k}) - (\hat{i} - 2\hat{j} + 3\hat{k}) = 8\hat{i} + (\alpha - 6)\hat{j} + 3\hat{k}$$ Now, $$\begin{vmatrix} 1 & -1 & 1 \\ \alpha & 2 & -1 \\ 8 & \alpha - 6 & 3 \end{vmatrix} = 0$$ $$\Rightarrow 1(6 + \alpha - 6) + (3\alpha + 8) + (\alpha^2 - 6\alpha - 16) = 0$$ On simplifying we get, $$\Rightarrow \alpha^2 - 2\alpha - 8 = 0$$ Therefore, sum of the roots is $(-2) = 2$.

Question 8

Maths · Determinants · Single correct

For the system of equations $$ \begin{aligned} x + y + z &= 6 \\ x + 2y + \alpha z &= 10 \\ x + 3y + 5z &= \beta, \end{aligned} $$ which one of the following is NOT true?

  1. System has no solution for $\alpha = 3$, $\beta = 24$
  2. System has a unique solution for $\alpha = -3$, $\beta = 14$
  3. System has infinitely many solutions for $\alpha = 3$, $\beta = 14$
  4. System has a unique solution for $\alpha = 3$, $\beta \neq 14$

Answer: (d)

Solution

Given, the system of equations $$x + y + z = 6$$ $$x + 2y + \alpha z = 10$$ $$x + 3y + 5z = \beta$$ Now finding, $$\Delta = \begin{vmatrix} 1 & 1 & 1 \\ 1 & 2 & \alpha \\ 1 & 3 & 5 \end{vmatrix}$$ $$\Rightarrow \Delta = 1(10 - 3\alpha) - (5 - \alpha) + (3 - 2)$$ $$\Rightarrow \Delta = 6 - 2\alpha$$ Now for unique solution, $\Delta \neq 0 \Rightarrow \alpha \neq 3$ So, for unique solution $\Rightarrow \alpha \neq 3$ But in option $(D)$, system has unique solution for $\alpha = 3$ which is completely wrong.

Question 9

Maths · Applications of Integrals · Single correct

The area bounded by the curves $y = |x - 1| + |x - 2|$ and $y = 3$ is equal to

  1. 4
  2. 6
  3. 3
  4. 5

Answer: (a)

Solution

Given: $$y = f(x) = |x - 1| + |x - 2|$$ $$\Rightarrow f(x) = \begin{cases} 3 - 2x; & x < 1 \\ 1; & 1 \leq x < 2 \\ 2x - 3; & x \geq 2 \end{cases}$$ Let us draw diagram of $y = f(x)$ and $y = 3$ we get, Required area is the area of trapezium which is Area $= \frac{1}{2} [1 + 3] \times 2$ $= 4$ sq. units

Question 10

Maths · Matrices · Single correct

Let $P$ be a square matrix such that $P^2 = I - P$. For $\alpha, \beta, \gamma, \delta \in \mathbb{N}$, if $P^\alpha + P^\beta = \gamma I - 29P$ and $P^\alpha - P^\beta = \delta I - 13P$, then $\alpha + \beta + \gamma - \delta$ is equal to

  1. 18
  2. 40
  3. 22
  4. 24

Answer: (d)

Solution

Given, $P$ be a square matrix such that $P^2 = I - P$. Now solving $P^2 = I - P$ we get, $$P^4 = (I - P)(I - P)$$ $$P^4 = I + P^2 - 2P$$ $$P^4 = I + I - P - 2P = 2I - 3P$$ Now solving, $P^4 \cdot P^2 = P^6 = 2I - 5P + 3P^2$ $$P^6 = 2I - 5P + 3(I - P) = 5I - 8P \ldots (i)$$ Similarly $P^8 = 13I - 21P \ldots (ii)$ Now adding (ii) + (i) we get, $$P^8 + P^6 = 18I - 29P$$ Now subtracting (ii) - (i) we get, $$P^8 - P^6 = 8I - 13P$$ Now comparing with $P^\alpha - P^\beta = \delta I$ and $P^\alpha + P^\beta = \gamma I - 29P$ we get, $\alpha = 8$, $\beta = 6$, $\gamma = 18$, $\delta = 8$ Hence, $\alpha + \beta + \gamma - \delta = 8 + 6 + 18 - 8 = 24$

Question 11

Maths · Permutations and Combinations · Single correct

All the letters of the word PUBLIC are written in all possible orders and these words are written as in a dictionary with serial numbers. Then the serial number of the word PUBLIC is

  1. 576
  2. 578
  3. 580
  4. 582

Answer: (d)

Solution

The given word is PUBLIC. Arranging the letters alphabetically, we get BCILPU. When the word starts with any of the letters B/C/I/L, the number of possibilities is $5! \times 4 = 480$. Now when the word starts with PB, then the number of possibilities is $4! = 24$. Now when the word starts with PC, then the number of possibilities is $4! = 24$. Now when the word starts with PI, then the number of possibilities is $4! = 24$. Now when the word starts with PL, then the number of possibilities is $4! = 24$. Now when the word starts with PUBC, then the number of possibilities is $2! = 2$. Now when the word starts with PUBI, then the number of possibilities is $2! = 2$. Now when the word starts with PUBLC, then the number of possibilities is $1$. Now when the word starts with PUBLIC, then the number of possibilities is $1$. Rank $= 480 + 24 \times 4 + 2 \times 2 + 1 \times 2 = 582$. Hence, rank of the word PUBLIC is 582.

Question 12

Maths · Three Dimensional Geometry · Single correct

Let the line $L$ pass through the point $(0, 1, 2)$, intersect the line $\frac{x-1}{2} = \frac{y-2}{3} = \frac{z-3}{4}$ and be parallel to the plane $2x + y - 3z = 4$. Then the distance of the point $P(1, -9, 2)$ from the line $L$ is

  1. $\sqrt{74}$
  2. $\sqrt{69}$
  3. $\sqrt{54}$
  4. 9

Answer: (a)

Solution

Given, the line $L$ pass through the point $(0, 1, 2)$, intersect the line $\frac{x-1}{2} = \frac{y-2}{3} = \frac{z-3}{4}$ and be parallel to the plane $2x + y - 3z = 4$. Now plotting the diagram of above data we have, let the direction of line which passes through $(0, 1, 2)$ be $(a, b, c)$. Now the line $L$ and $L_1$ are coplanar, so coplanar condition we get, $$\begin{vmatrix} a & b & c \\ 2 & 3 & 4 \\ 2 & 3 & 4 \end{vmatrix} = 0$$ $$\Rightarrow \begin{vmatrix} 1 & 1 & 1 \\ 2 & 3 & 4 \end{vmatrix} = 0$$ $$\Rightarrow a - 2b + c = 0 \ldots (1)$$ And the line $L$ is perpendicular to the normal vector of the plane, so by perpendicular condition we get, $$2a + b - 3c = 0 \ldots (2)$$ So, from equation (1) and (2) we get, $$a = b = c$$ So, equation of line $L$ will be, $$L = \frac{x-1}{a} = \frac{y-1}{a} = \frac{z-2}{a} = \lambda$$ So any point on $L$ can be taken as $A(\lambda, 1 + \lambda, 2 + \lambda)$. Now $\overrightarrow{AP}$ will be perpendicular to the direction ratio of the line $L$, so, again by perpendicular condition we get, $$\overrightarrow{AP} \cdot (\hat{i} + \hat{j} + \hat{k}) = 0$$ $$\Rightarrow \lambda - 1 + \lambda + 10 + \lambda = 0$$ $$\Rightarrow 3\lambda = 0$$ $$\Rightarrow \lambda = -3$$ Hence, $A(-3, -2, -1)$ and $P(1, -9, 2)$ So, by distance formula we get, $AP = \sqrt{74}$

Question 13

Maths · Three Dimensional Geometry · Single correct

A plane P contains the line of intersection of the plane $\vec{r} \cdot (\hat{i} + \hat{j} + \hat{k}) = 6$ and $\vec{r} \cdot (2\hat{i} + 3\hat{j} + 4\hat{k}) = -5$. If P passes through the point (0, 2, -2), then the square of distance of the point (12, 12, 18) from the plane P is

  1. 620
  2. 155
  3. 310
  4. 1240

Answer: (a)

Solution

Given, a plane $P$ contains the line of intersection of the plane $\vec{r} \cdot (\hat{i} + \hat{j} + \hat{k}) = 6$ and $\vec{r} \cdot (2\hat{i} + 3\hat{j} + 4\hat{k}) = -5$. Now let, $P_1 : x + y + z - 6 = 0$ and $P_2 : 2x + 3y + 4z + 5 = 0$. So, by family of planes concept we get, $$P : (x + y + z - 6) + \lambda (2x + 3y + 4z + 5) = 0$$ Also given plane $P$ passes through $(0, 2, -2)$. So, $(0 + 2 - 2 - 6) + \lambda (4 + 6 - 8 + 5) = 0$ $$\Rightarrow -6 + \lambda (3) = 0$$ $$\Rightarrow \lambda = 2$$ Hence, equation of plane will be, $$P : 5x + 7y + 9z + 4 = 0$$ Now distance of point $(12, 12, 18)$ from plane will be, $$\left( \frac{5(12) + 7(12) + 9(18) + 4}{\sqrt{25 + 49 + 81}} \right)$$ And square of distance will be, $$= \left( \frac{310}{155} \right)^2$$ $$= 620$$

Question 14

Maths · Integrals · Single correct

Let $f(x)$ be a function satisfying $f(x) + f(\pi - x) = \pi^2$, $\forall x \in \mathbb{R}$. Then $\int_0^\pi f(x) \sin x \, dx$ is equal to

  1. $\frac{\pi^2}{4}$
  2. $2\pi^2$
  3. $\pi^2$
  4. $\frac{\pi^2}{2}$

Answer: (c)

Solution

Let $$I = \int_0^\pi f(x) \sin x \, dx \cdots (1)$$ Now using the property $$\int_a^b f(x) \, dx = \int_a^b f(a+b-x) \, dx$$ we get, $$\Rightarrow I = \int_0^\pi f(\pi - x) \sin (\pi - x) \, dx$$ $$\Rightarrow I = \int_0^\pi f(\pi - x) \sin x \, dx \cdots (2)$$ Adding (1) and (2), we get $$2I = \int_0^\pi [f(x) + f(\pi - x)] \sin x \, dx$$ $$\Rightarrow 2I = \pi^2 \int_0^\pi \sin x \, dx \{as given f(x) + f(\pi - x) = \pi^2\}$$ $$\Rightarrow 2I = \pi^2 [-\cos x]_0^\pi$$ $$\Rightarrow 2I = 2\pi^2$$ $$\Rightarrow I = \pi^2$$ Hence this is the correct option.

Question 15

Maths · Binomial Theorem · Single correct

If the coefficients of $x^7$ in $\left(ax^2 + \frac{1}{2bx}\right)^{11}$ and $x^{-7}$ in $\left(ax - \frac{1}{3bx^2}\right)^{11}$ are equal, then

  1. 729ab = 32
  2. 32ab = 729
  3. 64ab = 243
  4. 243ab = 64

Answer: (a)

Solution

The coefficient of $x^7$ in $\left(ax^2 + \frac{1}{2bx}\right)^{11}$ and $\left(ax - \frac{1}{3bx^2}\right)^{11}$ are equal, then $$T_{r+1} = {}^{11}C_{r} (ax^2)^{11-r} \left(\frac{1}{2bx}\right)^r$$ $$= {}^{11}C_{r} a^{11-r} \left(\frac{1}{2b}\right)^r x^{22-3r}$$ Now solving $22 - 3r = 7 \Rightarrow r = 5$ Coefficient of $x^{-7}$ in $\left(ax - \frac{1}{3bx^2}\right)^{11}$ $$T_{r+1} = {}^{11}C_{r} (ax)^{11-r} \left(-\frac{1}{3bx^2}\right)^r$$ $$= {}^{11}C_{r} a^{11-r} \left(-\frac{1}{3b}\right)^r x^{11-3r}$$ Now solving $11 - 3r = -7 \Rightarrow r = 6$ Now equating coefficient of $x^7$ and $x^{-7}$ we get, $$\therefore {}^{11}C_{5} (a)^6 \left(\frac{1}{2b}\right)^5 = {}^{11}C_{6} a^5 \left(-\frac{1}{3b}\right)^6$$ $$\Rightarrow 3^6 ab = 32$$ $$\Rightarrow 729ab = 32$$ Hence this is the correct option.

Question 16

Maths · Mathematical Reasoning · Single correct

Among the statements $(S1): \ (p \Rightarrow q) \lor ((\sim p) \land q)$ is a tautology $(S2): \ (q \Rightarrow p) \Rightarrow ((\sim p) \land q)$ is a contradiction

  1. Neither $(S1)$ and $(S2)$ is True
  2. Both $(S1)$ and $(S2)$ are True
  3. Only $(S2)$ is True
  4. Only $(S1)$ is True

Answer: (a)

Solution

Plotting the Truth table of the given expression we get, $$ \begin{array}{|c|c|c|c|c|c|c|} \hline p & q & \neg p & \neg p \land q & p \Rightarrow q & q \Rightarrow p & (p \Rightarrow q) \lor (\neg p \land q) & (q \Rightarrow p) \lor (\neg p \land q) \\ \hline \mathrm{T} & \mathrm{T} & \mathrm{F} & \mathrm{F} & \mathrm{T} & \mathrm{T} & \mathrm{T} & \mathrm{T} \\ \mathrm{T} & \mathrm{F} & \mathrm{F} & \mathrm{F} & \mathrm{F} & \mathrm{T} & \mathrm{T} & \mathrm{T} \\ \mathrm{F} & \mathrm{T} & \mathrm{T} & \mathrm{T} & \mathrm{T} & \mathrm{F} & \mathrm{T} & \mathrm{T} \\ \mathrm{F} & \mathrm{F} & \mathrm{T} & \mathrm{F} & \mathrm{T} & \mathrm{T} & \mathrm{T} & \mathrm{T} \\ \hline \end{array} $$ Hence, $(q \Rightarrow p) \lor (\neg p \land q)$ is a tautology, and $(p \Rightarrow q) \lor (\neg p \land q)$ is neither tautology and contradiction. So both statements are false.

Question 17

Maths · Conic Sections · Single correct

If the tangents at the points $P$ and $Q$ on the circle $x^2 + y^2 - 2x + y = 5$ meet at the point $R\left(\frac{9}{4}, 2\right)$, then the area of the triangle $PQR$ is

  1. $\frac{5}{4}$
  2. $\frac{13}{8}$
  3. $\frac{5}{8}$
  4. $\frac{13}{4}$

Answer: (c)

Solution

Given, the tangents at the points $P$ and $Q$ on the circle $x^2 + y^2 - 2x + y = 5$ meet at the point $R\left(\frac{9}{4}, 2\right)$. Now plotting the diagram of the above data we have, Now we know that, length of tangent is given by, $PR = QR = \sqrt{S_1}$. So, $L = \sqrt{S_1} = \sqrt{\left(\frac{9}{4}\right)^2 + (2)^2 - 2 \times \frac{9}{4} + 2 - 5}$ $$\Rightarrow L = \frac{5}{4}$$ Now distance between $CR$ will be, $$CR = \sqrt{\left(\frac{9}{4} - 1\right)^2 + \left(2 + \frac{1}{2}\right)^2} = \sqrt{\frac{25}{16} + \frac{25}{4}} = \sqrt{\frac{125}{16}} = \frac{5\sqrt{5}}{4}$$ Now finding $PQ$ by equating area, we get $$\frac{1}{2} \times \frac{5}{2} \times L = \frac{1}{2} \times PQ \times \frac{CR}{2}$$ $$\Rightarrow \frac{1}{2} \times \frac{5}{4} = \frac{1}{2} \times PQ \times \frac{5\sqrt{5}}{4}$$ $$\Rightarrow PQ = \sqrt{5}$$ Now finding area of triangle $PQR$ by Heron's formula, $$s = \frac{2\sqrt{5} + 5}{4}$$ So, area will be $$\Delta = \sqrt{s(s-a)(s-b)(s-c)}$$ $$\Rightarrow \Delta = \sqrt{\frac{2\sqrt{5} + 5}{4} \left(\frac{2\sqrt{5} + 5}{4} - \frac{5}{4}\right) \left(\frac{2\sqrt{5} + 5}{4} - \sqrt{5}\right) \left(\frac{5}{4}\right)}$$ $$\Rightarrow \Delta = \sqrt{\frac{2\sqrt{5} + 5}{4} \left(\frac{2\sqrt{5}}{4}\right) \left(\frac{2\sqrt{5}}{4}\right) \left(\frac{5 - 2\sqrt{5}}{4}\right)}$$ $$\Rightarrow \Delta = \sqrt{\left(\frac{5}{4}\right) \left(\frac{5}{4}\right) \left(\frac{25 - 20}{16}\right)} = \frac{5}{8}$$

Question 18

Maths · Vector Algebra · Single correct

Let the vectors $\vec{a}$, $\vec{b}$, $\vec{c}$ represent three coterminous edges of a parallelopiped of volume $V$. Then the volume of the parallelopiped, whose coterminous edges are represented by $\vec{a}$, $\vec{b} + \vec{c}$ and $\vec{a} + 2\vec{b} + 3\vec{c}$ is equal to

  1. $2V$
  2. $6V$
  3. $V$
  4. $3V$

Answer: (c)

Solution

We know that, Volume of parallelepiped whose edges determined by vectors $\vec{a}, \vec{b}, \vec{c}$ is $\left[ \vec{a} \vec{b} \vec{c} \right]$. Now it is given that $V$ is volume of parallelepiped $\vec{a}, \vec{b}, \vec{c}$, so required volume of parallelepiped with new edges will be $$= \left[ \vec{a} \vec{b} + \vec{c} \vec{a} + 2\vec{b} + 3\vec{c} \right]$$ $$= \begin{vmatrix} 1 & 0 & 0 \\ 0 & 1 & 1 \\ 1 & 2 & 3 \end{vmatrix} \begin{vmatrix} \vec{a} \vec{b} \vec{c} \end{vmatrix}$$ $$= \{(1)(3 - 2) - 0 + 0\} \begin{vmatrix} \vec{a} \vec{b} \vec{c} \end{vmatrix}$$ $$= \left[ \vec{a} \vec{b} \vec{c} \right]$$ $$= V$$ Hence this is the correct option.

Question 19

Maths · Sequences and Series · Single correct

If $\gcd(m, n) = 1$ and $1^2 - 2^2 + 3^2 - 4^2 + \ldots + (2021)^2 - (2022)^2 + (2023)^2 = 1012m^2n$ then $m^2 - n^2$ is equal to

  1. 240
  2. 200
  3. 220
  4. 180

Answer: (a)

Solution

Let $S=1^2-2^2+3^2-4^2+\cdots+(2021)^2-(2022)^2+(2023)^2$ $\Rightarrow S=(1-2)(1+2)+(3-4)(3+4)+\cdots+(2021-2022)(2021+2022)+(2023)^2$ $\Rightarrow S=-[3+7+11+15+\cdots+4043]+(2023)^2$ The number of terms in the bracket are $\frac{2022}{2}=1011$ $\Rightarrow S=-\frac{1011}{2}(6+1010\times4)+(2023)^2$ $\Rightarrow S=-1011\times2023+(2023)^2$ $\Rightarrow S=2023\times1012$ $\Rightarrow S=17^2\times7\times1012$ So, $m=17,\ n=7$ and $gcd(17,7)=1$ Hence, $m^2-n^2=17^2-7^2=240$ Hence this is the correct option.

Question 20

Maths · Conic Sections · Single correct

In a group of 100 persons 75 speak English and 40 speak Hindi. Each person speaks at least one of the two languages. If the number of persons who speak only English is $\alpha$ and the number of persons who speaks only Hindi is $\beta$, then the eccentricity of the ellipse $25\left(\beta^2 x^2 + \alpha^2 y^2\right) = \alpha^2 \beta^2$ is

  1. $\frac{\sqrt{119}}{12}$
  2. $\frac{\sqrt{117}}{12}$
  3. $\frac{3\sqrt{15}}{12}$
  4. $\frac{\sqrt{129}}{12}$

Answer: (a)

Solution

Given, in a group of 100 persons 75 speak English and 40 speak Hindi, and each person speaks at least one of the two languages. And the number of persons who speak only English is $\alpha$ and the number of persons who speaks only Hindi is $\beta$. Now from above diagram we can see that, $$\beta = 100 - 75 = 25$$ So, $$\alpha = 75 - (40 - 25) = 60$$ Hence, number of people who speak English only is $\alpha = 60$ and Hindi is $\beta = 25$. Now putting the value in given equation of ellipse we get, $$25 \left[ \frac{x^2}{60^2} + \frac{y^2}{25^2} \right] = 1$$ $$\Rightarrow \frac{x^2}{36 \times 4} + \frac{y^2}{25} = 1$$ Now comparing with $\frac{x^2}{a^2} + \frac{y^2}{b^2} = 1$ we get, $a = 12$ and $b = 5$. Now we know that, eccentricity of ellipse is given by $e = \sqrt{1 - \frac{b^2}{a^2}}$. $$\Rightarrow e = \sqrt{1 - \frac{25}{36 \times 4}} = \frac{\sqrt{119}}{12}$$

Question 21

Maths · Integrals · Numerical

Let $f(x) = \frac{x}{\left(1 + x^n\right)^{\frac{1}{n}}}, \ x \in \mathbb{R} - \{-1\}, \ n \in \mathbb{N}, \ n > 2$. If $f^n(x) = (f \circ f \circ f \ldots upto n times)(x)$, then $\lim_{n \to \infty} \int_0^1 x^{n-2} (f^n(x)) \, dx$ is equal to

Answer: 0

Solution

Given, $f(x) = \frac{x}{(1+x^n)^n}$, $x \in \mathbb{R} - \{-1\}$, $n \in \mathbb{N}$, $n > 2$, $f^n(x) = (f \circ f \circ \ldots up to n times ) (x)$. Now finding $f(f(x)) = \frac{f(x)}{\left[ 1 + (f(x))^n \right]^{\frac{1}{n}}}$. $$\Rightarrow f(f(x)) = \frac{\frac{x}{(1+x^n)^n}}{\left[ 1 + \left( \frac{x}{(1+x^n)^n} \right)^n \right]^{\frac{1}{n}}}$$ $$\Rightarrow f(f(x)) = \frac{x}{\left[ 1 + 2x^n \right]^{\frac{1}{n}}}$$ Similarly, $f^n(x) = \frac{x}{(1+n \cdot x)^n}$. Now solving the integral we get, $$I = \int_0^1 \frac{x^{n-1}}{(1+n x)^{\frac{1}{n}}} \, dx$$ Now let, $1 + n x = t^n$ $$\Rightarrow n^2 x^{n-1} \, dx = n t^{n-1} \, dt$$ $$I = \int_1^{(1+n)^n} \frac{1}{n} \cdot \frac{1}{t} \, dt$$ $$\Rightarrow I = \left[ \frac{1}{n} \ln t \right]_1^{(1+n)^n}$$ $$\Rightarrow I = \frac{1}{n} \left[ n \ln (1+n) - 0 \right]$$ $$\Rightarrow I = n (n-1) \left( (1+n)^{1-\frac{1}{n}} - 1 \right)$$ Now solving the limit we get, $$\lim_{n \to \infty} \frac{(1+n)^{1-\frac{1}{n}} - 1}{n(n-1)}$$ Now let $n = \frac{1}{h}$ so the limit changes to, $$\lim_{h \to 0} \frac{\left( 1 + \frac{1}{h} \right)^{h-1} - 1}{\frac{1}{h} \left( \frac{1}{h} - 1 \right)}$$ $$= \lim_{h \to 0} \frac{h \left( 1 + \frac{1}{h} \right)^{h-1} - h}{1-h}$$ $$= \lim_{h \to 0} \frac{h \left( 1 - h \right)}{1-h}$$ $$= \lim_{h \to 0} h (1-h)$$ $$= \lim_{h \to 0} h = 0$$

Question 22

Maths · Trigonometric Functions · Fill in the blank

The value of $\tan 9^\circ - \tan 27^\circ - \tan 63^\circ + \tan 81^\circ$ is _____.

Answer: 4

Solution

Given, $$\tan 9^\circ - \tan 27^\circ - \tan 63^\circ + \tan 81^\circ$$ $$= (\cot 81^\circ + \tan 81^\circ) - (\tan 27^\circ + \cot 27^\circ)$$ $$= (\tan 9^\circ + \cot 9^\circ) - (\tan 27^\circ + \cot 27^\circ)$$ $$= \left( \frac{\sin 9^\circ}{\cos 9^\circ} + \frac{\cos 9^\circ}{\sin 9^\circ} \right) - \left( \frac{\sin 27^\circ}{\cos 27^\circ} + \frac{\cos 27^\circ}{\sin 27^\circ} \right)$$ $$= \frac{2}{\sin 18^\circ} - \frac{2}{\sin 54^\circ}$$ $$= \frac{2 \times 4}{\sqrt{5} - 1} - \frac{2 \times 4}{\sqrt{5} + 1}$$ $$= 8 \left( \frac{1}{\sqrt{5} - 1} - \frac{1}{\sqrt{5} + 1} \right)$$ $$= 8 \left( \frac{\sqrt{5} + 1 - (\sqrt{5} - 1)}{(\sqrt{5} - 1)(\sqrt{5} + 1)} \right)$$ $$= 8 \left( \frac{2}{5 - 1} \right) = 4$$

Question 23

Maths · Three Dimensional Geometry · Numerical

If the lines $\($ $\frac{x-1}{2}$ = $\frac{2-y}{-3}$ = $\frac{z-3}{\alpha}$ $\)$ and $\($ $\frac{x-4}{5}$ = $\frac{y-1}{2}$ = $\frac{z}{\beta}$ $\)$ intersect, then the magnitude of the minimum value of $\($ 8$\alpha$$\beta$ $\)$ is .

Answer: 18

Solution

Let, $$L_1 = \frac{x-1}{2} = \frac{y-2}{3} = \frac{z-3}{\alpha} = \lambda$$ $$L_2 = \frac{x-4}{5} = \frac{y-1}{2} = \frac{z-0}{\beta} = \mu$$ For point of intersection $$2\lambda + 1 = 5\mu + 4 \ldots \ (i)$$ $$3\lambda + 2 = 2\mu + 1 \ldots \ (ii)$$ $$\alpha \lambda + 3 = \beta \mu + 0 \ldots \ (iii)$$ From (i) and (ii), we get $\lambda = \mu = -1$. Now, from (iii), we get $\alpha - \beta = 3$. Let $y = 8\alpha \beta$. $$\Rightarrow y = 8\alpha (\alpha - 3)$$ $$\Rightarrow y = 8 \left( \alpha^2 - 3\alpha + \frac{9}{4} \right) - 18$$ $$\Rightarrow y = 8 \left( \alpha - \frac{3}{2} \right)^2 - 18$$ So, Minimum value of $y = -18$ at $\alpha = \frac{3}{2}$.

Question 24

Maths · Sequences and Series · Numerical

If $(20)^{19} + 2(21)(20)^{18} + 3(21)^2(20)^{17} + \ldots + 20(21)^{19} = k(20)^{19}$, then $k$ is equal to _____.

Answer: 400

Solution

Let, $$S = (20)^{19} + 2(21)(20)^{18} + 3(21)^{2}(20)^{17} + \ldots + 20(21)^{19}$$ Thus, $$S = 20^{19} + 2 \cdot (20)^{19} \cdot \left( \frac{21}{20} \right) + 3(20)^{19} \cdot \left( \frac{21}{20} \right)^{2} + \ldots + 20(20)^{19} \cdot \left( \frac{21}{20} \right)^{19}$$ $$\Rightarrow S = 20^{19} \left( 1 + 2 \cdot \frac{21}{20} + 3 \left( \frac{21}{20} \right)^{2} + \ldots + 20 \left( \frac{21}{20} \right)^{19} \right)$$ Now on comparing with $S = k \cdot (20)^{19}$ we get, $$\Rightarrow k = 1 + 2 \cdot \left( \frac{21}{20} \right) + 3 \left( \frac{21}{20} \right)^{2} + \ldots + 20 \left( \frac{21}{20} \right)^{19} \ldots (1)$$ $$\Rightarrow \frac{21}{20} k = \frac{21}{20} + 2 \left( \frac{21}{20} \right)^{2} + \ldots + 19 \left( \frac{21}{20} \right)^{19} + 20 \left( \frac{21}{20} \right)^{20} \ldots (2)$$ Now on subtracting above equations we get, $$\Rightarrow k - \frac{21}{20} k = 1 + \frac{21}{20} + \left( \frac{21}{20} \right)^{2} + \ldots + \left( \frac{21}{20} \right)^{19} - 20 \left( \frac{21}{20} \right)^{20}$$ $$\Rightarrow \frac{-k}{20} = \left( \frac{21}{20} \right)^{20 - 1} - 20 \left( \frac{21}{20} \right)^{20}$$ $$\Rightarrow \frac{-k}{20} = \left( \left( \frac{21}{20} \right)^{20} - 1 \right) \times 20 - 20 \left( \frac{21}{20} \right)^{20}$$ $$\Rightarrow \frac{-k}{20} = -20$$ $$\Rightarrow k = 400$$

Question 25

Maths · Permutations and Combinations · Numerical

The number of 4-letter words, with or without meaning, each consisting of 2 vowels and 2 consonants, which can be formed from the letters of the word UNIVERSE without repetition is _____.

Answer: 432

Solution

Given, we have to make four letter word from UNIVERSE each consisting 2 vowels and 2 consonants. Now in UNIVERSE, we have, E, E, I, U, (Vowels) + N, R, S, V (Consonants). 2 different vowels + 2 consonants can be arrange in $^3C_2 \cdot ^4C_2 \cdot 4! = 3 \times 6 \times 24 = 432$ ways. $^3C_2$ is taken because of repetition of letter E.

Question 26

Maths · Applications of Derivatives · Fill in the blank

The number of points, where the curve $y = x^5 - 20x^3 + 50x + 2$ crosses the $x$-axis, is _____.

Answer: 5

Solution

Let, $f(x) = x^5 - 20x^3 + 50x + 2$. Now differentiating the function $f(x)$ with respect to $x$, we get, $$f'(x) = 5x^4 - 60x^2 + 50$$ $$\Rightarrow f'(x) = 5(x^4 - 12x^2 + 10)$$ Now equating $f'(x) = 0$ we get, $$x^4 - 12x^2 + 10 = 0$$ $$\Rightarrow x^2 = \frac{12 \pm \sqrt{144 - 40}}{2}$$ $$\Rightarrow x^2 = 6 \pm \sqrt{26}$$ $$\Rightarrow x^2 \approx 11.1, \ 0.9$$ $$\Rightarrow x \approx \pm 3.31, \ \pm 0.95$$ Now finding the nature of function at integer value near by above value we get, $f(0) = 2$, $f(1) > 0$, $f(2) 0$. Now plotting the graph by observing above values, we get, Hence, it will cross $x$-axis 5 times.

Question 27

Maths · Complex Numbers and Quadratic Equations · Fill in the blank

For $\alpha$, $\beta$, $z \in \mathbb{C}$ and $\lambda > 1$, if $\sqrt{\lambda - 1}$ is the radius of the circle $|z - \alpha|^2 + |z - \beta|^2 = 2\lambda$, then $|\alpha - \beta|$ is equal to _____.

Answer: 2

Solution

Given, $\alpha$, $\beta$, $z \in \mathbb{C}$ and $\lambda > 1$. And $\sqrt{\lambda - 1}$ is the radius of the circle $|z - \alpha|^2 + |z - \beta|^2 = 2\lambda$. Now we know that equation of circle is given by, $$|z - z_1|^2 + |z - z_2|^2 = |z_1 - z_2|^2,$$ where radius is given by $r = \frac{|z_1 - z_2|}{2}$, On comparing with $|z - \alpha|^2 + |z - \beta|^2 = 2\lambda$, we get $$\frac{|z_1 - z_2|}{2} = \frac{|\alpha - \beta|}{2}$$ and $|\alpha - \beta|^2 = 2\lambda$. $$\Rightarrow \frac{|\alpha - \beta|}{2} = \sqrt{\lambda - 1} (given)$$ $$\Rightarrow |\alpha - \beta| = 2\sqrt{\lambda - 1}$$ $$\Rightarrow |\alpha - \beta|^2 = 4(\lambda - 1)$$ $$\Rightarrow 2\lambda = 4(\lambda - 1)$$ $$\Rightarrow \lambda = 2$$ Hence, $|\alpha - \beta|^2 = 4 = |\alpha - \beta| = 2$

Question 28

Maths · Applications of Derivatives · Numerical

Let a curve $y = f(x)$, $x \in (0, \infty)$ pass through the points $P\left(1, \frac{3}{2}\right)$ and $Q\left(a, \frac{1}{2}\right)$. If the tangent at any point $R(b, f(b))$ to the given curve cuts the $y$-axis at the point $S(0, c)$ such that $bc = 3$, then $(PQ)^2$ is equal to .

Answer: 5

Solution

Given, a curve $y = f(x)$, $x \in (0, \infty)$ pass through the points $P \left( 1, \frac{3}{2} \right)$ and $Q \left( a, \frac{1}{2} \right)$, and the tangent at any point $R(b, f(b))$ to the given curve cuts the $y$-axis at the point $S(0, c)$ such that $bc = 3$. Now tangent to the curve is given by, $$Y - y = m(X - x), m = \frac{dy}{dx}$$ Now at $Y$-axis, put $X = 0$ we get, $$Y = y - mx or c = y - mx as point S(0, c) given,$$ Now given $bc = 3$ $$\Rightarrow x(y - mx) = 3 \{here b = x on the curve\}$$ $$\Rightarrow y - \frac{xdy}{dx} = \frac{3}{x}$$ $$\Rightarrow ydx - xdy = \frac{3dx}{x} \cdot \frac{1}{x^2}$$ $$\Rightarrow d \left( \frac{y}{x} \right) = 3d \left( \frac{x^{-2}}{-2} \right)$$ Now integrating both side we get, $$\Rightarrow \frac{y}{x} = \frac{3}{2x^2} + C,$$ Now given curve passes through $P \left( 1, \frac{3}{2} \right)$, so $C = 0$. So, equation of curve will be $2xy = 3$. Now curve also passes through the point $Q \left( a, \frac{1}{2} \right)$. So, $a = 3$. Hence, $P \left( 1, \frac{3}{2} \right), Q \left( 3, \frac{1}{2} \right)$. So, by distance formula we get, $(PQ)^2 = 4 + 1 = 5$.

Question 29

Maths · Conic Sections · Numerical

Let the eccentricity of the ellipse \[ \frac{x^2}{a^2}+\frac{y^2}{b^2}=1 \] be the reciprocal of that of the hyperbola \[ 2x^2-2y^2=1. \] If the ellipse intersects the hyperbola at right angles, then the square of the length of the latus rectum of the ellipse is

Answer: 2

Solution

Given, the eccentricity of an ellipse $\frac{x^2}{a^2} + \frac{y^2}{b^2} = 1$ is reciprocal to that of the hyperbola $2x^2 - 2y^2 = 1$. Now eccentricity of rectangular hyperbola $2x^2 - 2y^2 = 1$ is $e_H = \sqrt{2}$. So, $e_e = \frac{1}{\sqrt{2}}$. Now, focus of hyperbola $=(\pm 1, 0)$. Now given that both curve intersect orthogonally, so ellipse and hyperbola are confocal. So, for ellipse $ae_e = 1 \Rightarrow a = \sqrt{2}$. Now length of latus rectum L. R. $= \frac{2b^2}{a} = 2a(1 - e_e^2) = 2\sqrt{2} \cdot \frac{1}{2} = \sqrt{2}$.

Question 30

Maths · Statistics · Numerical

If the mean and variance of the frequency distribution are 9 and 15.08 respectively, then the value of $\alpha^2 + \beta^2 - \alpha \beta$ is

Answer: 25

Solution

Given, the mean and variance of the frequency distribution are 9 and 15.08 respectively. Now mean is given by, $$Mean = \frac{8 + 16 + 120 + 80 + 56 + 80 + 6\alpha + 12\beta}{40 + \alpha + \beta} = 9$$ $$\Rightarrow 360 + 9\alpha + 9\beta = 360 + 6\alpha + 12\beta$$ $$\Rightarrow 3\alpha - 3\beta = 0$$ $$\Rightarrow \alpha = \beta \ldots\ldots(1)$$ Now variance is given by, $$15.08 = \frac{16 + 64 + 36\alpha + 960 + 800 + 144\alpha + 784 + 1280}{40 + 2\alpha} - 9^2$$ $$\Rightarrow 96.08 = \frac{3904 + 180\alpha}{40 + 2\alpha}$$ $$\Rightarrow (40 + 2\alpha)(96.08) = 3904 + 180\alpha$$ $$\Rightarrow 3843.20 + (192.16)\alpha = 3904 + 180\alpha$$ $$\Rightarrow (12.16)\alpha = 60.80$$ $$\Rightarrow \alpha = 5 = \beta$$ Hence, $$\alpha^2 + \beta^2 - \alpha\beta = 25 + 25 - 25 = 25$$

Physics

Question 31

Physics · Ray Optics and Optical Instruments · Single correct

A 2 meter long scale with least count of 0.2 cm is used to measure the locations of objects on an optical bench. While measuring the focal length of a convex lens, the object pin and the convex lens are placed at 80 cm mark and 1 m mark, respectively. The image of the object pin on the other side of lens coincides with image pin that is kept at 180 cm mark. The % error in the estimation of focal length is:

  1. 0.85
  2. 1.70
  3. 1.02
  4. 0.51

Answer: (b)

Solution

The formula for a lens is given by $\frac{1}{f} = \frac{1}{v} - \frac{1}{u}$ $\ldots$ (i) $u = (100 \pm 0.2) \, \mathrm{cm} - (80 \pm 0.2) \, \mathrm{cm} = (20 \pm 0.4) \, \mathrm{cm}$ $v = (180 \pm 0.2) \, \mathrm{cm} - (100 \pm 0.2) \, \mathrm{cm} = (80 \pm 0.4) \, \mathrm{cm}$ Substituting the values in the equation of focal length, $$\frac{1}{f} = \frac{1}{v} - \frac{1}{u} = \frac{1}{80} - \left(-\frac{1}{20}\right) = \frac{5}{80}$$ $$\Rightarrow \; f = 16 \, \mathrm{cm}$$ Differentiating the equation (i) $$\frac{df}{f^2} = \frac{dv}{v^2} + \frac{du}{u^2}$$ (Only positive sign is considered for error calculation) $$= \frac{0.4}{6400} + \frac{0.4}{400} = 0.4 \times \frac{17}{6400}$$ $$\Rightarrow df = 0.4 \times \frac{17}{6400} \times 16^2 = 0.272$$ The percentage error is $$\frac{df}{f} \times 100 = \frac{0.272}{16} \times 100 = 1.70\%$$

Question 32

Physics · Alternating Current · Single correct

A capacitor of capacitance $150.0 \, \mu \mathrm{F}$ is connected to an alternating source of emf given by $E = 36 \sin(120 \pi t) \, \mathrm{V}$. The maximum value of current in the circuit is approximately equal to:

  1. $2 \, \mathrm{A}$
  2. $\sqrt{2} \, \mathrm{A}$
  3. $2\sqrt{2} \, \mathrm{A}$
  4. $\frac{1}{\sqrt{2}} \, \mathrm{A}$

Answer: (a)

Solution

The formula for maximum current is given by $I_{max} = \omega C V_m \ldots (i)$ The given data is $\omega = 120 \pi$ $V_m = 36 \, \mathrm{V}$ $C = 150 \, \mu \mathrm{F}$ Substituting the values in equation (i) $$I_{max} = (120 \pi) \times (150 \times 10^{-6}) \times 36$$ $$= 2.036 \, \mathrm{A}$$ $$\approx 2 \, \mathrm{A}$$

Question 33

Physics · Mechanical Properties of Fluids · Single correct

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Assertion A: When you squeeze one end of a tube to get toothpaste out from the other end, Pascal’s principle is observed. Reason R: A change in the pressure applied to an enclosed incompressible fluid is transmitted undiminished to every portion of the fluid and to the walls of its container. In the light of the above statements, choose the most appropriate answer from the options given below.

  1. Both A and R are correct but R is NOT the correct explanation of A
  2. A is not correct but R is correct
  3. A is correct but R is not correct
  4. Both A and R is correct and R is the correct explanation of A

Answer: (d)

Solution

Pascal's law states that the pressure in a closed incompressible fluid is transmitted equally in all directions. The formula for pressure is given by $$P = \frac{F}{A}$$ When a toothpaste is squeezed let the pressure transmitted by $P$. At the mouth of the toothpaste the pressure will also be equal to $P$ due to Pascal's law. The pressure applied to the tube is transmitted equally throughout the toothpaste. When the pressure reaches the open end, it forces toothpaste out through the opening. Hence, both $A$ & $R$ is correct and $R$ is correct explanation for $A$.

Question 34

Physics · Ray Optics and Optical Instruments · Single correct

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Assertion A: The phase difference of two light waves change if they travel through different media having same thickness, but different indices of refraction. Reason R: The wavelengths of waves are different in different media. In the light of the above statements, choose the most appropriate answer from the options given below

  1. Both A and R are correct but R is NOT the correct explanation of A
  2. A is not correct but R is correct
  3. A is correct but R is not correct
  4. Both A and R are correct and R is the correct explanation of A

Answer: (d)

Solution

When light travels through a medium, its velocity depends on the density of the medium. The formula to calculate the speed of light can be written as $$v = \nu \lambda \ldots (1)$$ From equation (1), it can be concluded that higher the speed, higher is the wavelength. Hence, the wavelength of light depends on the refractive index of the medium. Because of changed wavelength the phase difference changes while the two waves travel the same distance. Thus, both A and R are correct and R is the correct explanation of A.

Question 35

Physics · Current Electricity · Single correct

Figure shows a part of an electric circuit. The potentials at points $a$, $b$ and $c$ are $30 \, \mathrm{V}$, $12 \, \mathrm{V}$ and $2 \, \mathrm{V}$ respectively. The current through the $20 \, \Omega$ resistor will be,

  1. $1.0 \, \mathrm{A}$
  2. $0.4 \, \mathrm{A}$
  3. $0.6 \, \mathrm{A}$
  4. $0.2 \, \mathrm{A}$

Answer: (b)

Solution

Let the potential be $x \, \mathrm{V}$ at the junction. By using $V = IR$ we get, $$30 - x = 10i_1$$ $$x - 12 = 20i_2$$ $$x - 2 = 30i_3$$ By using Kirchhoff's law, $$i_1 = i_2 + i_3$$ $$\Rightarrow \frac{30-x}{10} + \frac{12-x}{20} + \frac{2-x}{30} = 0$$ $$\Rightarrow \frac{90 - 3x + 18 - 1.5x + 2 - x}{30} = 0$$ $$\Rightarrow x = 20 \, \mathrm{V}$$ The current through the $20 \, \Omega$ resistor is $$i_2 = \left( \frac{30 - 12}{20} \right) \, \mathrm{A}$$ $$\Rightarrow i_2 = \frac{8}{20} \, \mathrm{A} = 0.4 \, \mathrm{A}$$

Question 36

Physics · Motion in a Straight Line · Single correct

As shown in the figure, a particle is moving with constant speed $\pi \, \mathrm{m} \, \mathrm{s}^{-1}$. Considering its motion from $A$ to $B$, the magnitude of the average velocity is:

  1. $\sqrt{3} \, \mathrm{m} \, \mathrm{s}^{-1}$
  2. $\pi \, \mathrm{m} \, \mathrm{s}^{-1}$
  3. $1.5 \sqrt{3} \, \mathrm{m} \, \mathrm{s}^{-1}$
  4. $2 \sqrt{3} \, \mathrm{m} \, \mathrm{s}^{-1}$

Answer: (c)

Solution

The given data is $v = \pi \, \mathrm{m \, s^{-1}}$ By using trigonometric ratios in the triangle shown above the displacement can be found out by $$\sin 60^\circ = \frac{AB}{2R}$$ $$\Rightarrow AB = R\sqrt{3}$$ The formula for distance is $$d = vt$$ $$\Rightarrow t = \frac{d}{v}$$ $$\Rightarrow t = \frac{120^\circ}{360^\circ} \times \frac{2\pi R}{\pi} = \frac{2R}{3}$$ So, the average velocity is $$v_{avg} = \frac{\sqrt{3}R}{\frac{2R}{3}} = \frac{3\sqrt{3}}{2}$$ $$= 1.5\sqrt{3} \, \mathrm{m \, s^{-1}}$$

Question 37

Physics · Dual Nature of Radiation and Matter · Single correct

The work functions of Aluminium and Gold are $4.1 \, \mathrm{eV}$ and $5.1 \, \mathrm{eV}$ respectively. The ratio of the slope of the stopping potential versus frequency plot for Gold to that of Aluminium is

  1. 1.24
  2. 2
  3. 1
  4. 1.5

Answer: (c)

Solution

The data given is $\phi_{Al} = 4.1 \, \mathrm{eV}$ and $\phi_{Au} = 5.1 \, \mathrm{eV}$. The energy is given by $$h\nu = \phi + KE$$ $$\Rightarrow h\nu = \phi + eV_0$$ where $V_0$ is the stopping potential and $K = eV_0$. Thus, the above equation can be written as $$eV_0 = h\nu - \phi$$ $$\Rightarrow V_0 = \frac{h\nu}{e} - \frac{\phi}{e}$$ The equation is of the form of $y = mx + c$. The slope is $$m = \frac{h}{e}.$$ Since the Planck constant $h$ and charge of an electron is a constant $e$, the slope does not depend on the work function. Hence the ratio of the slope of the plot of stopping potential and frequency for both the given metals is 1.

Question 38

Physics · Waves · Single correct

The ratio of speed of sound in hydrogen gas to the speed of sound in oxygen gas at the same temperature is:

  1. 1 : 2
  2. 4 : 1
  3. 1 : 4
  4. 1 : 1

Answer: (b)

Solution

The formula to calculate the speed of sound in hydrogen gas is given by $$v_{H_2} = \sqrt{\frac{\gamma RT}{M_{H_2}}} \ldots (1)$$ The formula to calculate the speed of sound in oxygen is given by $$v_{O_2} = \sqrt{\frac{\gamma RT}{M_{O_2}}} \ldots (2)$$ Divide equation (1) by (2) and simplify to obtain the required ratio. $$\frac{v_{H_2}}{v_{O_2}} = \sqrt{\frac{M_{O_2}}{M_{H_2}}} \ldots (3)$$ Substitute the values of the known parameters into equation (3) to calculate the required ratio. $$\frac{v_{H_2}}{v_{O_2}} = \sqrt{\frac{32}{2}}$$ $$= 4 : 1$$

Question 39

Physics · Motion in a Plane · Single correct

A child of mass $5 \, \mathrm{kg}$ is going round a merry-go-round that makes 1 rotation in $3.14 \, \mathrm{s}$. The radius of the merry-go-round is $2 \, \mathrm{m}$. The centrifugal force on the child will be

  1. 80 N
  2. 40 N
  3. 100 N
  4. 50 N

Answer: (b)

Solution

The angular speed ($\omega$) of the child can be calculated as follows: $$\omega = \frac{2\pi}{3.14}$$ $$= 2 \, \mathrm{rad} \, \mathrm{s}^{-1}$$ The formula to calculate the centrifugal force on the child is given by $$F_r = m\omega^2 r \ldots (1)$$ Substitute the values of the known parameters into equation (1) to calculate the required centrifugal force. $$F_r = 5 \, \mathrm{kg} \times (2 \, \mathrm{rad} \, \mathrm{s}^{-1})^2 \times 2 \, \mathrm{m}$$ $$= 40 \, \mathrm{N}$$

Question 40

Physics · Motion in a Straight Line · Single correct

A particle starts with an initial velocity of $10.0 \, \mathrm{ms}^{-1}$ along $x$-direction and accelerates uniformly at the rate of $2.0 \, \mathrm{m\,s}^{-2}$. The time taken by the particle to reach the velocity of $60.0 \, \mathrm{m\,s}^{-1}$ is _____.

  1. 25 s
  2. 3 s
  3. 6 s
  4. 30 s

Answer: (a)

Solution

The given data is $v = 60 \, \mathrm{m \, s^{-1}}$ $u = 10 \, \mathrm{m \, s^{-1}}$ $a = 2 \, \mathrm{m \, s^{-2}}$ Using the equation $v = u + at$, we get $$60 = 10 + 2t$$ $$\Rightarrow t = \frac{(60 - 10)}{2}$$ $$\Rightarrow t = 25 \, \mathrm{s}$$

Question 41

Physics · Gravitation · Single correct

Choose the incorrect statement from the following:

  1. The speed of satellite in a given circular orbit remains constant
  2. For a planet revolving around the sun in an elliptical orbit, the total energy of the planet remains constant
  3. The linear speed of a planet revolving around the sun remains constant
  4. When a body falls towards earth, the displacement of earth towards the body is negligible

Answer: (c)

Solution

A planet revolves round the Sun by the action of the gravitational force between the sun and the planet. Depending upon the distance from the sun in the elliptic orbit, the speed of revolution of the planet changes. The formula to calculate the linear speed of a planet in an elliptical orbit can be written as $$v = \sqrt{GM \left( \frac{2}{r} - \frac{1}{a} \right)}$$ From the above expression, it can be concluded that the linear speed of the planet is not constant during its revolution.

Question 42

Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Assertion A: Diffusion current in a $p-n$ junction is greater than the drift current in magnitude if the junction is forward biased. Reason R: Diffusion current in a $p-n$ junction is form the $n$-side to the $p$-side if the junction is forward biased. In the light of the above statements, choose the most appropriate answer from the options given below.

  1. Both A and R are correct but R is NOT the correct explanation of A
  2. A is correct but R is not correct
  3. A is not correct but R is correct
  4. Both A and R is correct and R is the correct explanation of A

Answer: (b)

Solution

The electric current due to the charge concentration gradient is known as diffusion current. When the charge carriers move in a semiconductor due to the applied electric field, the resulting current is known as drift current. If the positive terminal of the battery is connected to the p-type while the negative terminal of the battery is connected to the n-type, the movement of electrons is eased as they can travel to the positive terminal of the battery. This causes an increase in the diffusion current. Hence, the diffusion current is more than the drift current. So, A is correct. In an n-type semiconductor, the concentration of electrons is more than that of the holes. While in a p-type semiconductor, the concentration of holes is more than that of the electrons. During the formation of a p-n junction diffusion and drift are the two processes taking place. When a p-n junction is formed, holes diffuse from the p-side to the n-side while electrons diffuse from the n-side to the p-side. This result due to the concentration gradient across p and n sides, which gives rise to a diffusion current across the junction. The diffusion results in an electric field from p-side to n-side. Thus, R is incorrect as diffusion current in $p-n$ junction is from $p$ side to $n$-side.

Question 43

Physics · Electric Charges and Fields · Single correct

A dipole comprises of two charged particles of identical magnitude $q$ and opposite in nature. The mass $m$ of the positive charged particle is half of the mass of the negative charged particle. The two charges are separated by a distance $l$. If the dipole is placed in a uniform electric field $\vec{E}$; in such a way that dipole axis makes a very small angle with the electric field, $E$. The angular frequency of the oscillations of the dipole when released is given by:

  1. $\sqrt{\frac{3qE}{2ml}}$
  2. $\sqrt{\frac{8qE}{ml}}$
  3. $\sqrt{\frac{4qE}{ml}}$
  4. $\sqrt{\frac{8qE}{3ml}}$

Answer: (a)

Solution

The data given is $l =$ distance between the charges $q =$ charge $m =$ mass of the positive charge $2m =$ mass of negative charge The moment of inertia of the system is $$I = \left( \frac{m \times 2m}{m + 2m} \right) (l)^2 = \frac{2ml^2}{3}$$ The angular frequency can be written as $$\omega = \sqrt{\frac{pE}{I}} \cdots (i)$$ Substituting the value of moment of inertia in the equation (i) we get $$\omega = \sqrt{\frac{pE}{\frac{2ml^2}{3}}} = \sqrt{\frac{3pE}{2ml^2}}$$ The value of the dipole moment is $p = ql$ Hence, the angular frequency becomes $$\omega = \sqrt{\frac{3qE}{2ml}}$$ This question was given bonus by NTA as none of the options matched in the original paper.

Question 44

Physics · Electromagnetic Waves · Single correct

The energy density associated with electric field $\vec{E}$ and magnetic field $\vec{B}$ of an electromagnetic wave in free space is given by ($\varepsilon_0$ - permittivity of free space, $\mu_0$ - permeability of free space)

  1. $U_E = \frac{E^2}{2\varepsilon_0}, \ U_B = \frac{B^2}{2\mu_0}$
  2. $U_E = \frac{\varepsilon_0 E^2}{2}, \ U_B = \frac{B^2}{2\mu_0}$
  3. $U_E = \frac{\varepsilon_0 E^2}{2}, \ U_B = \frac{\mu_0 B^2}{2}$
  4. $U_E = \frac{E^2}{2\varepsilon_0}, \ U_B = \frac{\mu_0 B^2}{2}$

Answer: (b)

Solution

When an electromagnetic wave propagates from the source, it transfers energy to the objects in its path. Electric and magnetic fields serve as energy reservoirs for electromagnetic waves. An electromagnetic wave contains the same amount of energy as are contained in the electric and magnetic fields together. In such situation, the energy density of the electromagnetic wave is equal to the sum of the energies of the electric and magnetic fields. The average electric and magnetic energy densities are given by $$U_E = \frac{1}{2} \varepsilon_0 E^2$$ $$U_B = \frac{1}{2} \frac{B^2}{\mu_0}$$

Question 45

Physics · Kinetic Theory · Single correct

The temperature of an ideal gas is increased from 200 K to 800 K. If r.m.s. speed of gas at 200 K is $v_0$. Then, r.m.s. speed of the gas at 800 K will be:

  1. $\frac{v_0}{4}$
  2. $v_0$
  3. $4v_0$
  4. $2v_0$

Answer: (d)

Solution

At 200 K, the rms speed is given by $$v_0 = \sqrt{\frac{3R \times 200}{M}} \cdots (1)$$ At 800 K, the rms speed is given by $$v' = \sqrt{\frac{3R \times 800}{M}} \cdots (2)$$ Divide equation (2) by equation (1) and solve to calculate the required speed. $$\frac{v'}{v_0} = \frac{\sqrt{\frac{3R \times 800}{M}}}{\sqrt{\frac{3R \times 200}{M}}}$$ $$= \sqrt{\frac{800}{200}}$$ $$= 2$$ $$\Rightarrow v' = 2v_0$$

Question 46

Physics · Current Electricity · Single correct

A student is provided with a variable voltage source $V$, a test resistor $R_T = 10 \Omega$, two identical galvanometers $G_1$ and $G_2$ and two additional resistors, $R_1 = 10 \mathrm{M}\Omega$ and $R_2 = 0.001 \Omega$. For conducting an experiment to verify ohms law, the most suitable circuit is:

Answer: (c)

Solution

To convert galvanometer into ammeter, low resistances should be added in parallel, and for voltmeter conversion, a very high resistance should be added in series.

Question 47

Physics · Thermal Properties of Matter · Single correct

A body cools in 7 minutes from $60^\circ\mathrm{C}$ to $40^\circ\mathrm{C}$. The temperature of the surrounding is $10^\circ\mathrm{C}$. The temperature of the body after the next 7 minutes will be

  1. $30^\circ\mathrm{C}$
  2. $32^\circ\mathrm{C}$
  3. $34^\circ\mathrm{C}$
  4. $28^\circ\mathrm{C}$

Answer: (d)

Solution

Newton's law of cooling states that $$\frac{(T_1 - T_2)}{t} = K \left( \frac{T_1 + T_2}{2} - T_0 \right) \ldots (i)$$ where $T_0$ is the temperature of the surrounding. From equation (i), $$\frac{60 - 40}{7 \times 60} = K \left( \frac{60 + 40}{2} - 10 \right)$$ $$\Rightarrow \frac{20}{7 \times 60} = 40K$$ $$\Rightarrow K = \frac{20}{7 \times 60 \times 40}$$ Let the temperature of the body after the given time be $x \, ^\circ \mathrm{C}$. By Newton's law of cooling, $$\frac{40 - x}{7 \times 60} = K \left( \frac{40 + x}{2} - 10 \right)$$ $$\Rightarrow \frac{40 - x}{7 \times 60} = \frac{1}{14 \times 60} \left( \frac{20 + x}{2} \right)$$ $$\Rightarrow 160 - 4x = 20 + x$$ $$\Rightarrow x = 28 \, ^\circ \mathrm{C}$$

Question 48

Physics · Work, Energy and Power · Single correct

A small particle of mass $m$ moves in such a way that its potential energy $U = \frac{1}{2} m \omega^2 r^2$ where $\omega$ is constant and $r$ is the distance of the particle from origin. Assuming Bohr's quantization of momentum and circular orbit, the radius of $n^{th}$ orbit will be proportional to

  1. $\sqrt{n}$
  2. $\frac{1}{n}$
  3. $n^2$
  4. $n$

Answer: (a)

Solution

The data given is $$U = \frac{1}{2} m \omega^2 r^2$$ From Bohr's quantization, $$mvr = \frac{nh}{2\pi}$$ $$\Rightarrow v^2 = \left( \frac{nh}{2\pi rm} \right)^2 \cdots (i)$$ In an orbit the value of the kinetic energy is half of the potential energy, $$K = \frac{m \omega^2 r^2}{4}$$ Substituting the value of equation (i) in the kinetic energy, $$K = \frac{1}{2} m \left( \frac{n^2 h^2}{4\pi^2 m^2 r^2} \right) = \frac{m \omega^2 r^2}{4}$$ $$\Rightarrow \frac{n^2 h^2}{2\pi^2 m^2 \omega^2} = r^4$$ $$\Rightarrow r \propto \sqrt{n}$$

Question 49

Physics · Communication Systems · Single correct

For an amplitude modulated wave the minimum amplitude is $3 \, \mathrm{V}$, while the modulation index is $60\%$. The maximum amplitude of the modulated wave is:

  1. $5 \, \mathrm{V}$
  2. $15 \, \mathrm{V}$
  3. $12 \, \mathrm{V}$
  4. $10 \, \mathrm{V}$

Answer: (c)

Solution

Modulation index is the ratio of the difference in amplitudes to the sum of the amplitudes. The formula to calculate the modulation index of a wave is given by $$\mu = \frac{A_{\max} - A_{\min}}{A_{\max} + A_{\min}} \ldots (1)$$ Substitute the values of the known parameters into equation (1) and solve to calculate the required value of maximum amplitude. $$0.6 = \frac{A_{\max} - 3}{A_{\max} + 3}$$ $$\Rightarrow 0.6 A_{\max} + 1.8 = A_{\max} - 3$$ $$\Rightarrow 0.4 A_{\max} = 4.8$$ $$\Rightarrow A_{\max} = \frac{4.8}{0.4}$$ $$= 12 \, \mathrm{V}$$

Question 50

Physics · Gravitation · Single correct

The weight of a body on the surface of the earth is 100 $\,$ $\mathrm{N}$. The gravitational force on it when taken at a height, from the surface of earth, equal to one-fourth the radius of the earth is:

  1. 64 $\,$ $\mathrm{N}$
  2. 25 $\,$ $\mathrm{N}$
  3. 50 $\,$ $\mathrm{N}$
  4. 100 $\,$ $\mathrm{N}$

Answer: (a)

Solution

The acceleration due to gravity changes as one goes to a height from the surface of the earth. Let the new acceleration due to gravity be $g'$. The formula for acceleration due to gravity at a height is given by $g' = \frac{gR^2}{(R+h)^2}$. The weight of the body on surface is $W = mg = 100 \, \mathrm{N}$. The weight at the given height is $W = mg'$. $$\Rightarrow \, W' = 100 \times \frac{R^2}{\left(R + \frac{R}{4}\right)^2}$$ $$\Rightarrow \, W' = 100 \times \frac{R^2}{\frac{25R^2}{16}} = 64 \, \mathrm{N}$$

Question 51

Physics · Current Electricity · Fill in the blank

As shown in the figure the voltmeter reads $2 \, \mathrm{V}$ across $5 \, \Omega$ resistor. The resistance of the voltmeter is $\Omega$.

Answer: 20

Solution

Let the resistance of the voltmeter be $R \, \Omega$. The voltmeter is in parallel with the $5 \, \Omega$. So the total resistance in the circuit is $$\left( \frac{5R}{5+R} + 2 \right) \, \Omega$$ Applying Ohm's law in the whole circuit, $V = IR$, $$I = \left( \frac{3}{2 + \frac{5R}{5+R}} \right) \, \mathrm{A}$$ It is given that the potential difference across $5 \, \Omega$ is $2 \, \mathrm{V}$. Thus, by Ohm's law, $$\left( \frac{3}{2 + \frac{5R}{5+R}} \right) \times \left( \frac{5R}{R+5} \right) = 2$$ $$\Rightarrow \frac{15 + 3R}{10 + 7R} \times \frac{5R}{5+R} = 2$$ $$\Rightarrow 15R = 20 + 14R$$ $$\Rightarrow R = 20 \, \Omega$$

Question 52

Physics · Mechanical Properties of Solids · Numerical

A metal block of mass $m$ is suspended from a rigid support through a metal wire of diameter $14 \, \mathrm{mm}$. The tensile stress developed in the wire under equilibrium state is $7 \times 10^5 \, \mathrm{N} \, \mathrm{m}^{-2}$. The value of mass $m$ is kg. (Take $g = 9.8 \, \mathrm{m} \, \mathrm{s}^{-2}$ and $\pi = \frac{22}{7}$)

Answer: 11

Solution

The data given is $T = 7 \times 10^5 \, \mathrm{N \, m^{-2}}$ $r = 7 \times 10^{-3} \, \mathrm{m}$ Using the equation $$\frac{mg}{A} = T$$ $$\Rightarrow mg = TA$$ $$\Rightarrow mg = T \pi r^2$$ $$\Rightarrow mg = 7 \times 10^5 \times \frac{22}{7} \times 7^2 \times 10^{-6}$$ $$\Rightarrow mg = \frac{49 \times 22}{10}$$ $$\Rightarrow m = \frac{49 \times 22}{98} = 11 \, \mathrm{kg}$$

Question 53

Physics · Electrostatic Potential and Capacitance · Numerical

As shown in the figure, two parallel plate capacitors having equal plate area of $200 \, \mathrm{cm}^2$ are joined in such a way that $a \neq b$. The equivalent capacitance of the combination is $x \varepsilon_0 F$. The value of $x$ is _____.

Answer: 5

Solution

The given data is $A = 200 \times 10^{-4} \, \mathrm{m^2}$ d $d = 5 \times 10^{-3} \, \mathrm{m}$ The value of $a + b = 4 \times 10^{-3} \, \mathrm{m}$ The formula for a parallel plate capacitor is $$C = \frac{\varepsilon_0 A}{D}$$ Let the capacitor with gap $a$ be $C_1$ and capacitor with gap $b$ be $C_2$ $$C_1 = \frac{\varepsilon_0 A}{a}, C_2 = \frac{\varepsilon_0 A}{b}$$ The equivalent capacitance is $$\frac{1}{C_{eq}} = \frac{a}{\varepsilon_0 A} + \frac{b}{\varepsilon_0 A}$$ $$\Rightarrow C_{eq} = \frac{\varepsilon_0 A}{a+b}$$ It is given that $C_{eq} = x \varepsilon_0$ So, $$\frac{\varepsilon_0 A}{a+b} = x \varepsilon_0$$ $$\Rightarrow x = \frac{A}{a+b}$$ $$\Rightarrow x = \frac{200 \times 10^{-4}}{4 \times 10^{-3}} = 5$$

Question 54

Physics · System of Particles and Rotational Motion · Numerical

A ring and a solid sphere rotating about an axis passing through their centres have same radii of gyration. The axis of rotation is perpendicular to plane of ring. The ratio of radius of ring to that of sphere is $\sqrt{\frac{2}{x}}$. The value of $x$ is _____.

Answer: 5

Solution

The moment of inertia of the ring about an axis perpendicular to the plane of ring is $I_r = mk^2$. The moment of inertia of the sphere is $I_s = \frac{2}{5} m R_s^2$. It is given that $$mk^2 = m R_r^2 = \frac{2}{5} m R_s^2 \cdots (i)$$ From equation (i) $$R_r = \sqrt{\frac{2}{5}} R_s$$ From the question, it can be written that $$\frac{R_r}{R_s} = \sqrt{\frac{2}{x}}$$ $$\Rightarrow \frac{R_r}{R_s} = \sqrt{\frac{2}{5}}$$ $$\Rightarrow x = 5$$

Question 55

Physics · Oscillations · Numerical

A simple pendulum with length 100 cm and bob of mass 250 g is executing S.H.M of amplitude 10 cm. The maximum tension in the string is found to be $\frac{x}{40}$ N. The value of $x$ is _____.

Answer: 99

Solution

From the given figure we can see that $\sin \theta_0 = \frac{A}{l} = \frac{10}{100} = \frac{1}{10}$. From conservation of energy $\frac{mv^2}{2} = mgl \left(1 - \cos \theta_0 \right)$. Maximum tension occurs at mean position $$T = mg + \frac{mv^2}{l}$$ $$\Rightarrow T = mg + 2mg \left(1 - \cos \theta_0 \right)$$ Substituting the values, $$T = mg \left(1 + 2 \left(1 - \sqrt{1 - \sin^2 \theta_0} \right) \right)$$ $$\Rightarrow T = mg \left(3 - 2 \sqrt{1 - \frac{1}{100}} \right)$$ $$\Rightarrow T = 0.25 \times 9.8 \left(3 - 2 \left(1 - \frac{1}{200} \right) \right)$$ $$\Rightarrow T = 0.25 \times 9.8 \times 1.01 = 2.4745 \, \mathrm{N}$$ It is given that $$T = \frac{x}{40}$$ $$\Rightarrow x = 40 \times 2.4745 = 98.98 \approx 99$$

Question 56

Physics · Electromagnetic Induction · Numerical

Two concentric circular coils with radii 1 cm and 1000 cm and number of turns 10 and 200 respectively are placed coaxially with centers coinciding. The mutual inductance of this arrangement will be ____ $\times 10^{-8}$ H. (Take, $\pi^2 = 10$)

Answer: 4

Solution

Let the magnetic field of the 200 turns be $B_1$. The formula of magnetic field is given by $B = \frac{\mu_0 i}{2r}$. Let $r = 1000 \, \mathrm{cm}$. Thus, $$B_1 = \frac{n \mu_0 \times I}{2 \times 10} = \frac{200 \mu_0 I}{2 \times 10}$$ The flux through the coil of radius $r_1 = 1 \, \mathrm{cm}$ is $\phi = 10 \times \left( \vec{B} \cdot \vec{A} \right) = 10 \times B_1 \pi r_1^2$. $$\Rightarrow \phi = 10 \times \frac{200 \mu_0 I}{2 \times 10} \times \pi (0.01)^2$$ $$L = 10 \times \frac{200 \mu_0}{2 \times 10} \times \pi (0.01)^2$$ $$= 10 \times \frac{200 \left(4 \pi \times 10^{-7}\right)}{2 \times 10} \times \pi (0.01)^2$$ $$= 4 \times 10^{-8} \, \mathrm{H}$$

Question 57

Physics · Wave Optics · Numerical

A beam of light consisting of two wavelengths $7000 \, \mathrm{\AA}$ and $5500 \, \mathrm{\AA}$ is used to obtain interference pattern in Young's double slit experiment. The distance between the slits is $2.5 \, \mathrm{mm}$ and the distance between the plane of slits and the screen is $150 \, \mathrm{cm}$. The least distance from the central fringe, where the bright fringes due to both the wavelengths coincide, is $n \times 10^{-5} \, \mathrm{m}$. The value of $n$ is _____.

Answer: 462

Solution

The given data is $\lambda_1 = 7000 \, Å$, $\lambda_2 = 5500 \, Å$, $d = 2.5 \times 10^{-3} \, m$, $D = 1.5 \, m$. The path difference is given by $n \lambda_1 = m \lambda_2$. $7n = 5.5 \, m$ implies $14n = 11 \, m$, which implies $n = 11$ and $m = 14$. The formula for the distance of a bright fringe is $y = \frac{n \lambda_1 D}{d}$. Therefore, $$y = \frac{11 \times 7 \times 10^{-7} \times 1.5}{2.5 \times 10^{-3}}$$ $$= 46.2 \times 10^{-4} = 462 \times 10^{-5}$$ It is given that $n \times 10^{-5} = 462 \times 10^{-5}$, which implies $n = 462$.

Question 58

Physics · Work, Energy and Power · Numerical

A body is dropped on ground from a height $h_1$ and after hitting the ground, it rebounds to a height $h_2$. If the ratio of velocities of the body just before and after hitting ground is 4, then percentage loss in kinetic energy of the body is $\frac{x}{4}$. The value of $x$ is _____.

Answer: 375

Solution

The given ratio of the velocities is $\frac{v_1}{v_2} = 4$. The percentage loss in kinetic energy is $$\frac{\frac{mv_1^2}{2} - \frac{mv_2^2}{2}}{\frac{mv_1^2}{2}} \times 100 = \frac{x}{4}$$ $$\Rightarrow \frac{v_1^2 - v_2^2}{v_1^2} = \frac{x}{400}$$ $$\Rightarrow 1 - \frac{v_2^2}{v_1^2} = \frac{x}{400}$$ $$\Rightarrow 1 - \frac{1}{16} = \frac{x}{400}$$ $$\Rightarrow x = 375$$

Question 59

Physics · Atoms · Numerical

Experimentally it is found that $12.8$ eV energy is required to separate a hydrogen atom into a proton and an electron. So the orbital radius of the electron in a hydrogen atom is $\frac{9}{x}\times10^{-10}$ m. The value of $x$ is _____. $(1$ eV $=1.6\times10^{-19}$ J$)$ $\frac{1}{4\pi\epsilon_0}=9\times10^9$ N m$^2$/C$^2$ and electronic charge $=1.6\times10^{-19}$ C

Answer: 16

Solution

The given data is $q = 1.6 \times 10^{-19} \, \mathrm{C}$ and $\frac{1}{4 \pi \varepsilon_0} = 9 \times 10^9 \, \mathrm{N \, m^2 \, C^{-2}}$. The formula for the value of energy in a hydrogen atom is given by $$E = \frac{q^2}{8 \pi \varepsilon_0 r}$$ which implies $$E = \frac{q^2}{2(4 \pi \varepsilon_0)r}$$ Therefore, $$r = \frac{9 \times 10^9 \times 1.6 \times 10^{-19}}{12.8 \times 2}$$ which simplifies to $$r = \frac{9}{16} \times 10^{-10} \, \mathrm{m}$$ It is given that $$r = \frac{9}{x} \times 10^{-10} \, \mathrm{m}$$ Therefore, $$\frac{9}{16} \times 10^{-10} = \frac{9}{x} \times 10^{-10}$$ Solving for $x$, we find $$x = 16$$

Question 60

Physics · Moving Charges and Magnetism · Fill in the blank

A proton with a kinetic energy of 2.0 eV moves into a region of uniform magnetic field of magnitude (π/2) × 10$^{-3}$ T. The angle between the direction of magnetic field and velocity of proton is 60°. The pitch of the helical path taken by the proton is ____ cm. (Take mass of proton = 1.6 × 10$^{-27}$ kg and charge on proton = 1.6 × 10$^{-19}$ C.)

Answer: 40

Solution

The given data is $\mathrm{K.E} = 2 \, \mathrm{eV}$ $B = \frac{\pi}{2} \times 10^{-3} \, \mathrm{T}$ $\theta = 60^\circ$ The pitch of the proton is given by $$P = \frac{2\pi m}{qB} \times v \cos \theta \cdots (i)$$ By using $$K = \frac{mv^2}{2}$$ $$\Rightarrow v = \sqrt{\frac{2K}{m}}$$ Substituting the values in equation (i) $$\frac{2\pi \times \sqrt{2mK}E^{\frac{1}{2}} \times 2}{1.6 \times 10^{-19} \times \pi \times 10^{-3}}$$ $$= \frac{2 \times \sqrt{2 \times 1.6 \times 10^{-27} \times 2 \times 1.6 \times 10^{-19} \times 10^3}}{1.6 \times 10^{-19}}$$ $$= 2 \times 2 \times 10^{-1} = 0.4 \, \mathrm{m}$$

Chemistry

Question 61

Chemistry · The s-Block Elements · Single correct

Ion having highest hydration enthalpy among the given alkaline earth metal ions is:

  1. $\mathrm{Be}^{2+}$
  2. $\mathrm{Sr}^{2+}$
  3. $\mathrm{Ba}^{2+}$
  4. $\mathrm{Ca}^{2+}$

Answer: (a)

Solution

Smaller the size of the cation, more the hydration of ion, hence the more values of the hydration enthalpies. Now, as the down the group the size increases so the hydration enthalpies decreases, hence as the increasing order of the size of the ions is as follows: $$\mathrm{Be^{2+} } Mg^{2+} > Ca^{2+} > Sr^{2+} > Ba^{2+}$$

Question 62

Chemistry · Co-ordination Compounds · Single correct

The IUPAC name of $\mathrm{K_3[Co(C_2O_4)_3]}$ is:

  1. Potassium tris(oxalato)cobalttate(III)
  2. Potassium tris(oxalato)cobalt(III)
  3. Potassium trioxalatocobalt(III)
  4. Potassium trioxalatocobalttate(III)

Answer: (d)

Solution

Ligands that include a numerical prefix in the name use the prefixes bis for 2, tris for 3, or tetrakis for 4 to indicate their number. If the complex ion is an anion, we drop the ending of the metal name and add –ate. In the given coordination compound, Co is the cobalt metal, $\mathrm{C_2O_4^{2-}}$ are the ligands named as oxalato. The charge on $[\mathrm{Co(C_2O_4)_3}]$ is $-3$ and oxalate is having charge of $-2$. $$X + 3(-2) = -3$$ $$X = +3$$ Hence, the IUPAC name of the compound $\mathrm{K_3[Co(C_2O_4)_3]}$ is Potassium trioxalatocobaltate(III).

Question 63

Chemistry · General Principles and Processes of Isolation of Elements · Single correct

Match List-I with List-II. Choose the correct answer from the options given below:

  1. (A)--IV,\quad (B)--I,\quad (C )--II,\quad (D)--III
  2. (A)--I,\quad (B)--III,\quad (C )--IV,\quad (D)--II
  3. (A)--III,\quad (B)--I,\quad (C )--II,\quad (D)--IV
  4. (A)--IV,\quad (B)--I,\quad (C )--III,\quad (D)--II

Answer: (a)

Solution

The single letter amino acid codes is fairly easy to remember. In eleven cases out of twenty, it is just the first letter.

Question 64

Chemistry · Co-ordination Compounds · Single correct

Element not present in Nessler's reagent is

  1. N
  2. Hg
  3. I
  4. K

Answer: (a)

Solution

Nessler's reagent is an aqueous solution of potassium iodide, mercuric chloride, and potassium hydroxide. Its chemical formula is $\mathrm{K_2HgI_4}$. It is used to detect the presence of ammonia. It turns into pale brown colour in presence of ammonia. So, N is not present in Nessler's reagent.

Question 65

Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct

Structures of $BeCl_2$ in solid state, vapour phase and at very high temperature respectively are:

  1. Monomeric, Dimeric, Polymeric
  2. Dimeric, Polymeric, Monomeric
  3. Polymeric, Monomeric, Dimeric
  4. Polymeric, Dimeric, Monomeric

Answer: (d)

Solution

BeCl$_2$ is dimeric in vapour phase. The coordination number of beryllium is 3. BeCl$_2$ is monomeric at high temperature. The coordination number of beryllium is 2. BeCl$_2$ is polymeric in solid state. The coordination number of beryllium is 4.

Question 66

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

The strongest acid from the following is

Answer: (a)

Solution

In the case of substituted phenols, the acidity of phenols increases in the presence of the electron-withdrawing group. This is due to the stability of the phenoxide ion generated. In case of meta substituted phenols, the acidic nature can be explained on the basis of inductive effect. Among the given groups $-\mathrm{NO_2}$ and $-\mathrm{Cl}$ groups are electron withdrawing groups and methyl group is electron releasing group. Acidic strength order is: $$OH (with \mathrm{NO_2} ) > OH (with \mathrm{Cl} ) > OH (with \mathrm{CH_3} )$$

Question 67

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

Group-13 elements react with $O_2$ in amorphous form to form oxides of type $M_2O_3$ ($M$ = element). Which among the following is the most basic oxide?

  1. $Al_2 O_3$
  2. $B_2O_3$
  3. $Tl_2 O_3$
  4. $Ga_2 O_3$

Answer: (c)

Solution

The basicity of an oxide is closely related to the electropositive character of the element. The more electropositive the element, the more basic its oxide will be. This is because the oxide ion can react with a cation to form a basic oxide. As we move down Group 13, the electropositive character of the elements increases, and so does the basicity of their oxides. $$\mathrm{B_2O_3 < Al_2O_3 < Ga_2O_3 < In_2O_3 < Tl_2O_3}$$ So most basic oxide among the given options is $\mathrm{Tl_2O_3}$.

Question 68

Chemistry · Chemical Kinetics and Nuclear Chemistry · Single correct

Consider the following reaction that goes from A to B in three steps as shown below: Choose the correct option

  1. (1)
  2. (2)
  3. (3)
  4. (4)

Answer: (c)

Solution

The curve contains three activated complexes as shown below in the curve. In the curve, P and Q are the intermediates. The step with the highest activation energy is the rate determining step. Hence, in the given reaction, two intermediates, three activated complexes are involved and step-II is the rate determining step.

Question 69

Chemistry · Co-ordination Compounds · Single correct

Given below are two statements: one is labelled as "Assertion A" and the other is labelled as "Reason R" Assertion A : In the complex Ni(CO)_4 and Fe(CO)_5, the metals have zero oxidation state. Reason R : Low oxidation states are found when a complex has ligands capable of $\pi$-donor character in addition to the $\sigma$-bonding. In the light of the above statements, choose the most appropriate answer from the options given below

  1. A is correct but R is not correct
  2. A is not correct but R is correct
  3. Both A and R are correct but R is NOT the correct explanation of A
  4. Both A and R are correct and R is the correct explanation of A

Answer: (a)

Solution

The ligand carbon monoxide has no charge, hence metals have zero oxidation state in both $\mathrm{Ni(CO)_4}$ and $\mathrm{Fe(CO)_5}$. Low oxidation states are found when a complex has ligands capable of $\pi$-acceptor character in addition to the $\sigma$-bonding. In the complexes, $\mathrm{Ni(CO)_4}$ and $\mathrm{Fe(CO)_5}$, the ligand CO is $\pi$-acceptor character in addition to the $\sigma$-bonding.

Question 70

Chemistry · Redox Reactions · Single correct

During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs by value of 3. Identify which of the below medium will favour the reaction.

  1. Both aqueous acidic and neutral
  2. Aqueous neutral
  3. Both aqueous acidic and faintly alkaline
  4. Aqueous acidic

Answer: (b)

Solution

In neutral or weakly alkaline solution oxidation state of Mn changes by 3 unit. The reaction between permanganate and thiosulfate is a redox reaction, in which permanganate acts as an oxidizing agent and thiosulfate acts as a reducing agent. $$\mathrm{MnO_4^- + S_2O_3^{2-} \rightarrow MnO_2 + SO_4^{2-}}$$ This ionic mechanism is favoured in neutral aqueous medium.

Question 71

Chemistry · Haloalkanes and Haloarenes · Single correct

Find out the major product from the following reaction.

Answer: (a)

Solution

α, β-unsaturated carbonyl compounds undergo 1,4-addition reaction with Grignard reagent in the presence of cuprous iodide. Now the carbanion formed undergo nucleophilic substitution reaction with propyl iodide as shown below.

Question 72

Chemistry · Analytical Chemistry · Single correct

Formation of which complex, among the following, is not a confirmatory test of $\mathrm{Pb}^{2+}$ ions

  1. Lead sulphate
  2. Lead nitrate
  3. Lead chromate
  4. Lead iodide

Answer: (b)

Solution

On adding $\mathrm{H_2SO_4}$ to $\mathrm{Pb^{2+}}$, white precipitate of lead sulphate, $\mathrm{PbSO_4}$ is formed. By adding potassium iodide solution to $\mathrm{Pb^{2+}}$ - Yellow precipitate of lead iodide is formed. The ppt dissolves in boiling water and on cooling recrystallises. By adding potassium chromate solution to $\mathrm{Pb^{2+}}$ - Yellow precipitate of lead chromate is formed. But lead nitrate is a water soluble compound.

Question 73

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

From the figure of column chromatography given below, identify incorrect statements. A. Compound 'c' is more polar than 'a' and 'b' B. Compound 'a' is least polar C. Compound 'b' comes out of the column before 'c' and after 'a' D. Compound 'a' spends more time in the column Mark the correct answer from the given below.

  1. A, B and D only
  2. A, B and C only
  3. B and D only
  4. B, C and D only

Answer: (b)

Solution

Column chromatography separates compounds based on their polarity. The more polar a compound is, the more it interacts with the stationary phase and the slower it moves through the column. The less polar a compound is, the faster it moves through the column. As the chromatogram, degree of polarity $$\rightarrow a > b > c$$ Therefore, statements A, B are incorrect as b comes out before 'C' the statement C is also incorrect. As a is most polar, it spends most time. Hence, A, B and C are incorrect statements.

Question 74

Chemistry · Chemistry in Everyday Life · Single correct

Given below are two statements: Statement I: Morphine is a narcotic analgesic. It helps in relieving pain without producing sleep. Statement II: Morphine and its derivatives are obtained from opium poppy. In the light of the above statements, choose the correct answer from the options given below

  1. Both Statement I and Statement II are true
  2. Statement I is true but Statement II is false
  3. Both Statement I and Statement II are false
  4. Statement I is false but Statement II is true

Answer: (d)

Solution

Opioids (narcotic analgesics) are a class of medicines that are used to provide relief from moderate-to-severe acute or chronic pain. They may also be called opiates, opioid analgesics, or narcotics. Analgesic is another name for a medicine that relieves pain. Morphine is a narcotic analgesic. It helps in relieving pain with producing sleep.

Question 75

Chemistry · Some Basic Concepts of Chemistry · Single correct

The volume of 0.02 $\mathrm{M}$ aqueous $\mathrm{HBr}$ required to neutralize 10.0 $\mathrm{mL}$ of 0.01 $\mathrm{M}$ aqueous $\mathrm{Ba(OH)_2}$ is (Assume complete neutralization)

  1. 2.5 $\mathrm{mL}$
  2. 5.0 $\mathrm{mL}$
  3. 10.0 $\mathrm{mL}$
  4. 7.5 $\mathrm{mL}$

Answer: (c)

Solution

The balanced chemical equation for the reaction between HBr and Ba(OH)_2 is: $$2 \mathrm{HBr} + \mathrm{Ba(OH)_2} \rightarrow \mathrm{BaBr_2} + 2 \mathrm{H_2O}$$ From this equation, we can see that 2 moles of HBr react with 1 mole of Ba(OH)_2. Equal equivalents will react. Number of equivalents = Normality $\times$ Volume So, $$N_1 V_1 = N_2 V_2$$ $$0.02 \times V_1 = 0.02 \times 10$$ $$V_1 = 10 \, \mathrm{ml}$$

Question 76

Chemistry · Electrochemistry · Single correct

The product, which is not obtained during the electrolysis of brine solution is

  1. $\mathrm{H_2}$
  2. $\mathrm{HCl}$
  3. $\mathrm{NaOH}$
  4. $\mathrm{Cl_2}$

Answer: (b)

Solution

The aqueous solution of sodium chloride is known as brine solution. On electrolysis of brine solution, the following reactions are observed. Oxidation reaction takes place at anode and reduction reaction takes place at cathode. The reaction at the anode is: $$2 OH^- \rightarrow \frac{1}{2} O_2 + H_2O + 2e^-$$ At the cathode: $$H_2O + e^- \rightarrow \frac{1}{2} H_2 + OH^-$$ Hydrogen and oxygen are electrode products. The remaining solution contains NaOH. Hence, HCl is not obtained.

Question 77

Chemistry · Environmental Chemistry · Single correct

The group of chemicals used as pesticide is

  1. Aldrin, Sodium Chlorate, Sodium arsenite
  2. DDT, Aldrin
  3. Sodium chlorate, DDT, PAN
  4. Dieldrin, Sodium arsenite, Tetrachloroethene

Answer: (b)

Solution

DDT (dichlorodiphenyltrichloroethane) and Aldrin are two synthetic pesticides that were widely used for insect control. Pesticides are groups of chemicals used for destruction of insects, weeds, fungi, bacteria etc. They are generally called insecticides, fungicides, bactericides, herbicides and rodenticides.

Question 78

Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct

In the following reaction, 'B' is

Answer: (c)

Solution

The given reaction is an example of dehydration of alcohol. In this reaction the first step is protonation of alcohol which leads to the formation of carbocation. The carbocation formed undergoes rearrangement to get stability. The tertiary carbocation formed in this reaction is involved in ring closure, which loses a proton to form alkene. The steps are shown below.

Question 79

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

Which one of the following elements will remain as liquid inside pure boiling water?

  1. Ga
  2. Br
  3. Li
  4. Cs

Answer: (a)

Solution

Gallium (Ga) remains as liquid inside boiling water, and the other elements mentioned in options can react with water. Bromine is a halogen that reacts readily with water to form hydrobromic acid and hypobromous acid, which can further react to form bromic acid. Lithium and Caesium are alkali metals that react violently with water, producing hydrogen gas and the corresponding metal hydroxide.

Question 80

Chemistry · Structure of Atom · Single correct

If the radius of the first orbit of hydrogen atom is $a_0$, then de Broglie's wavelength of electron in $3^{rd}$ orbit is

  1. $\frac{\pi a_0}{6}$
  2. $\frac{\pi a_0}{3}$
  3. $6\pi a_0$
  4. $3\pi a_0$

Answer: (c)

Solution

According to Bohr's angular momentum equation, $$mvr = \frac{nh}{2\pi}$$ The angular momentum equation for third orbit is $$mvr = \frac{3h}{2\pi}$$ $$\frac{2\pi r}{3} = \frac{h}{mv}$$ According de Broglie's equation $$\lambda = \frac{h}{mv}$$ $$\therefore \lambda = \frac{2\pi 9 a_0}{3} = 6 \pi a_0$$

Question 81

Chemistry · Chemical Bonding and Molecular Structure · Fill in the blank

In an ice crystal, each water molecule is hydrogen bonded to _____ neighbouring molecules.

Answer: 4

Solution

Hydrogen bonding occurs between hydrogen and strongly electronegative atoms like F, N, O. In water or ice hydrogen bonding occurs as there is hydrogen as well as oxygen both are present. Water has 2 hydrogen atoms and 1 oxygen atom. The oxygen of one water molecule has two lone pairs of electrons, each of which can form hydrogen bonds with hydrogen on other two water molecules. Each water molecule is H-bonded to 4 neighbouring molecules.

Question 82

Chemistry · Equilibrium · Numerical

The equilibrium composition for the reaction $\mathrm{PCl_3+Cl_2\rightleftharpoons PCl_5}$ at $298$ K is given below. $[\mathrm{PCl_3}]_{\mathrm{eq}}=0.2$ mol L$^{-1}$, \quad $[\mathrm{Cl_2}]_{\mathrm{eq}}=0.1$ mol L$^{-1}$, $[\mathrm{PCl_5}]_{\mathrm{eq}}=0.40$ mol L$^{-1}$. If $0.2$ mol of $\mathrm{Cl_2}$ is added at the same temperature, the equilibrium concentration of $\mathrm{PCl_5}$ is _____ $\times10^{-2}$ mol L$^{-1}$. Given: $K_c$ for the reaction at $298$ K is $20$.

Answer: 49

Solution

Given the reaction $\mathrm{PCl_3(g)} + \mathrm{Cl_2(g)} \rightleftharpoons \mathrm{PCl_5(g)}$ with initial concentrations $0.2$, $0.1$, and $0.4$ respectively. The equilibrium constant $K_c$ is given by $$K_c = \frac{0.4}{0.2 \times 0.1} = 20.$$ If $0.2$ moles of $\mathrm{Cl_2}$ is added, the reaction takes place in the forward direction. We have $$20 = K_c = \frac{0.4 + X}{(0.3 - X)(0.2 - X)}.$$ This implies $$0.4 + X = 20(0.3 - X)(0.2 - X).$$ Therefore, $$0.4 + X = 20(0.06 + X^2 - 0.5X).$$ Simplifying, $$0.4 + X = 1.2 + 20X^2 - 10X.$$ Rearranging gives $$20X^2 - 11X + 0.8 = 0.$$ Solving for $X$, $$X = \frac{11 \pm \sqrt{121 - 64}}{40} = \frac{11 - 7.55}{40} \approx 0.08625.$$ Thus, the concentration of $\mathrm{PCl_5}$ is $$0.48625 \approx 48.625 \times 10^{-2} or 49 \times 10^{-2}.$$

Question 83

Chemistry · Solutions · Numerical

Consider the following pairs of solution which will be isotonic at the same temperature. The number of pairs of solutions is/are

  1. 1 M aq. NaCl and 2 M aq. urea
  2. 1 M aq. CaCl_2 and 1.5 M aq. KCl
  3. 1.5 M aq. AlCl_3 and 2 M aq. Na_2SO_4
  4. 2.5 M aq. KCl and 1 M aq. Al_2(SO_4)_3

Answer: (d)

Solution

A solution having the same solute and solvent concentration as a cell across the semipermeable membrane is referred to as isotonic solution. The effective concentration of each solution can be calculated as follows, Effective concentration = $i(Von't Hoff factor) \times C$ 1M NaCl has effective concentration = $2 \times 1 = 2\, M$ and hence it is isotonic with two molar urea solution. 1M CaCl$_2$ has effective concentration = $3\, M$ and 1.5M KCl has also $3\, M$, hence, both are isotonic. 1.5M AlCl$_3 \cong 6\, M$ and 2M Na$_2$SO$_4 \cong 6\, M$, Hence both are isotonic. 2.5M KCl $\cong 5\, M$ and 1M Al$_2$(SO$_4$)$_3 \cong 5\, M$, Hence both are isotonic.

Question 84

Chemistry · Redox Reactions · Numerical

The standard reduction potentials at 295 $\mathrm{K}$ for the following half cells are given below: The number of metal(s) which will be oxidised by $\mathrm{NO}_3^-$ in aqueous solution is

Answer: 3

Solution

For feasibility, check, $E^\circ_{cell} = E^\circ_{cathode (reduction)} - E^\circ_{anode (oxidation)} > 0$. The $E^\circ$ values when metal acts as anode and $\mathrm{NO_3^-}$ reaction is cathodic reaction. For Vanadium metal, $E^\circ_{cell} = 0.97 + 1.19 = 2.16\, \mathrm{V}$. For Iron metal, $E^\circ_{cell} = 0.97 + 0.04 = 1.01\, \mathrm{V}$. For silver metal, $E^\circ_{cell} = 0.97 - 0.80 = 0.17\, \mathrm{V}$. For Gold metal, $E^\circ_{cell} = 0.97 - 1.140 = -0.17\, \mathrm{V}$. For electrodes having oxidation potential greater than $-0.97\, \mathrm{V}$, $E^\circ_{cell} > 0$. Therefore, $\mathrm{Ag}$, $\mathrm{Fe}$ and $\mathrm{V}$ can be oxidised.

Question 85

Chemistry · Surface Chemistry · Numerical

The number of colloidal systems from the following, which will have 'liquid' as the dispersion medium, is _____. Gem stones, paints, smoke, cheese, milk, hair cream, insecticide sprays, froth, soap lather

Answer: 5

Solution

The phase that is scattered or present in the form of colloidal particles is called dispersed phase and the medium in which the colloidal particles are dispersed is called the dispersion medium. Coloured gemstones are solid sols, colloids in which solid particles are dispersed in solid medium. In paints, small amount of solid pigments are dispersed in a large amount of liquid solvent. So, it is an example of a solid in liquid mixture. Smoke is a solid aerosol-type colloid consisting of the solid dispersed phase in the gaseous dispersed medium. Cheese is an example of gel in the colloidal systems, in which the dispersed phase is a liquid while the dispersion medium is a solid. Milk is a type of 'liquid in liquid' colloid, also known as emulsion. Hair cream is an example of a colloidal system where dispersed Phase is Liquid and dispersion Medium is also Liquid. Insecticide sprays is an example of a colloidal solution in which liquid particles are dispersed in the gaseous phase. Froth is a colloidal solution of gas in liquid. Soap lather is an example of colloidal system foam in which the dispersed phase is gas and the dispersion medium is liquid. Paints, milk, froth, soap lather and hair cream have liquid as dispersion medium.

Question 86

Chemistry · Chemical Bonding and Molecular Structure · Numerical

The number of species having a square planar shape from the following is $\mathrm{XeF_4}$, $\mathrm{SF_4}$, $\mathrm{SiF_4}$, $\mathrm{BF_4^-}$, $\mathrm{BrF_4^-}$, $[\mathrm{Cu(NH_3)_4}]^{2+}$, $[\mathrm{FeCl_4}]^{2-}$, $[\mathrm{PtCl_4}]^{2-}$

Answer: 4

Solution

XeF_4 is $sp^3d^2$ hybridised with two lone pairs of electrons, hence, it is square planar. SF_4 is $sp^3d$ hybridised with one lone pair of electrons, hence, it is See saw. SiF_4 is $sp^3$ hybridised with zero lone pairs of electrons, hence, it is Tetrahedral. BF_4^- is $sp^3$ hybridised with zero lone pairs of electrons, hence, it is Tetrahedral. $[\mathrm{Cu(NH_3)_4}]^{2+}$ is $dsp^2$ hybridised and is Square planar. $[\mathrm{FeCl_4}]^{2-}$ is $sp^3$ hybridised and is Tetrahedral. $[\mathrm{PtCl_4}]^{2-}$ is $dsp^2$ hybridised and is Square planar. BrF_4^- is $sp^3d^2$ with Square planar geometry. So, 4 square planar shape compounds are present.

Question 87

Chemistry · Thermodynamics · Numerical

Consider the following data Heat of combustion of $\mathrm{H_2(g)} = -241.8 \, \mathrm{kJ \, mol^{-1}}$ Heat of combustion of $\mathrm{C(s)} = -393.5 \, \mathrm{kJ \, mol^{-1}}$ Heat of combustion of $\mathrm{C_2H_5OH(l)} = -1234.7 \, \mathrm{kJ \, mol^{-1}}$ The heat of formation of $\mathrm{C_2H_5OH(l)}$ is $(-) \, \, \mathrm{kJ \, mol^{-1}}$ (Nearest integer).

Answer: -278

Solution

The reaction is $\mathrm{C_2H_5OH(l)} \rightarrow 2 \mathrm{CO_2(g)} + 3 \mathrm{H_2O(l)} + 3/2 \mathrm{O_2(g)}$. Heat of combustion = Heat of formation of products - Heat of formation of reactants. Heat of combustion of hydrogen is equal to heat formation of water, and heat of combustion of carbon is equal to heat of formation of carbon dioxide. $$\Delta H_C = [2 \Delta H_f^\circ (\mathrm{CO_2}) + 3 \Delta H_f^\circ (\mathrm{H_2O})] - [\Delta H_f^\circ (\mathrm{C_2H_5OH(l)})]$$ $$-1234.7 = [2 \times (-393.5) + 3 \times (-241.8)] - [\Delta H_f^\circ (\mathrm{C_2H_5OH(l)})]$$ $$\Delta H_f^\circ \mathrm{C_2H_5OH} = -277.7 \, \mathrm{kJ/mol}$$ $$\simeq -278 \, \mathrm{kJ/mol}$$

Question 88

Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct

Among the following the number of compounds which will give positive iodoform reaction is .

  1. 1-Phenylbutan-2-one
  2. 2-Methylbutan-2-ol
  3. 3-Methylbutan-2-ol
  4. 1-Phenylethanol

Answer: (d)

Solution

Iodoform test is used to check the presence of carbonyl compounds with the structure \[ \mathrm{R-CO-CH_3} \] or alcohols with the structure \[ \mathrm{R-CH(OH)-CH_3} \] in a given unknown substance. The reaction of iodine, a base and a methyl ketone gives a yellow precipitate along with an “antiseptic” smell. Hence, (c), (d), (e) and (f) give iodoform reaction.

Question 89

Chemistry · Amines · Numerical

Number of isomeric aromatic amines with molecular formula $\mathrm{C_8H_{11}N}$, which can be synthesized by Gabriel Phthalimide synthesis is _____.

Answer: 5

Solution

$C_8H_{11}N$ Degree of unsaturation = 4. The degree of unsaturation indicates the total number of pi bonds and rings within a molecule which makes it easier for one to figure out the molecular structure. Aniline derivatives cannot be prepared by Gabriel phthalimide synthesis. So, number of aromatic amines = 5

Question 90

Chemistry · The Solid State · Numerical

Number of crystal systems from the following where body centred unit cell can be found, is _____. Cubic, tetragonal, orthorhombic, hexagonal, rhombohedral, monoclinic, triclinic

Answer: 3

Solution

Bravais Lattice refers to the 14 different 3-dimensional configurations into which atoms can be arranged in crystals. The smallest group of symmetrically aligned atoms which can be repeated in an array to make up the entire crystal is called a unit cell. Crystal systems where body centred unit cell can be found are Cubic, orthorhombic and tetragonal. Hence, correct answer is 3.