JEE Main 28 June 2022 Shift 2 question paper with solutions

JEE Main 28 June 2022 Shift 2: all 90 questions in paper order (Maths, Physics, Chemistry) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.

Register free to attempt this shift as a timed 180-minute test with instant scoring and chapter-wise analysis.

Maths

Question 1

Maths · Relations and Functions · Single correct

Let $R_1 = \{(a, b) \in \mathbb{N} \times \mathbb{N} : |a - b| \leq 13\}$ and $R_2 = \{(a, b) \in \mathbb{N} \times \mathbb{N} : |a - b| \neq 13\}$. Then on $\mathbb{N}$:

  1. Both $R_1$ and $R_2$ are equivalence relations
  2. Neither $R_1$ nor $R_2$ is an equivalence relation
  3. $R_1$ is an equivalence relation but $R_2$ is not
  4. $R_2$ is an equivalence relation but $R_1$ is not

Answer: (b)

Solution

For $R_1$: i) Reflexive relation: $(a, a) \in \mathbb{N} \times \mathbb{N} : |a - a| \leq 13$ ii) Symmetric relation: $(a, b) \in R_1,\ (b, a) \in R_1 : |b - a| \leq 13$ iii) Transitive relation: $(a, b) \in R_1,\ (b, c) \in R_1,\ (a, c) \in R_1$: $(1, 3) \in R_1,\ (3, 16) \in R_1,\ \text{but } (1, 16) \notin R_1$ For $R_2$: i) Reflexive relation: $(a, a) \in \mathbb{N} \times \mathbb{N} : |a - a| \neq 13$ ii) Symmetric relation: $(b, a) \in \mathbb{N} \times \mathbb{N} : |b - a| \neq 13$ iii) Transitive relation: $(a, b) \in R_2,\ (b, c) \in R_2,\ (a, c) \in R_2$: $(1, 3) \in R_2,\ (3, 14) \in R_2,\ \text{but } (1, 14) \notin R_2$

Question 2

Maths · Complex Numbers and Quadratic Equations · Single correct

Let f(x) be a quadratic polynomial such that f(-2) + f(3) = 0. If one of the roots of f(x) = 0 is -1, then the sum of the roots of f(x) = 0 is equal to:

  1. $\frac{11}{3}$
  2. $\frac{7}{3}$
  3. $\frac{13}{3}$
  4. $\frac{14}{3}$

Answer: (a)

Solution

Given $f(-2) + f(3) = 0$. $f(x) = (x + 1)(ax + b)$. $f(-2) + f(3) = -1(-2a + b) + 4(3a + b) = 0$. $2a - b + 12a + 4b = 0$. $14a + 3b = 0$. $$\frac{-b}{a} = \frac{14}{3}$$ Sum of roots = $$\left(-1 + \frac{-b}{a}\right) = -1 + \frac{14}{3} = \frac{11}{3}$$

Question 3

Maths · Permutations and Combinations · Single correct

The number of ways to distribute 30 identical candies among four children $C_1$, $C_2$, $C_3$ and $C_4$ so that $C_2$ receives atleast 4 and atmost 7 candies, $C_3$ receives atleast 2 and atmost 6 candies, is equal to

  1. 205
  2. 615
  3. 510
  4. 430

Answer: (d)

Solution

Given $t_1 + t_2 + t_3 + t_4 = 30$. Coefficient of $x^{30}$ in $(1 + x + x^2 + \ldots + x^{30})^2$ is given by $(x^4 + x^5 + x^6 + x^7)(x^2 + x^3 + x^4 + x^5 + x^6)$. $$x^6 \left( \frac{1 - x^{31}}{1 - x} \right)^2 (1 + x + x^2 + x^3)(1 + x + x^2 + x^3 + x^4)$$ $$x^6 (1 - x^{31})^2 (1 - x)^{-6} (1 - x)^4$$ $$x^6 (1 - x^4 - x^5 + x^9) \left( 1 + x^{62} - 2x^{31} (1 - x)^{-4} \right)$$ $$x^6 (1 - x - x^5 + x^9) (1 - x)^{-4}$$ Coefficient of $x^n$ in $(1 - x)^{-r}$ is $\binom{n + r - 1}{r - 1}$. $$\Rightarrow \binom{27}{3} - \binom{23}{3} - \binom{22}{3} + \binom{18}{3}$$ $$2925 - 1771 - 1540 + 816$$ $$= 430$$ OR $x_2 \in [4, 7], x_3 \in [2, 6]$ $$\Rightarrow t_1 + t_2 + t_3 + t_4 = 24$$ Total ways = $$\binom{24 + 4 - 1}{4 - 1} - \binom{20 + 4 - 1}{4 - 1} - \binom{19 + 4 - 1}{4 - 1} + \binom{15 + 4 - 1}{4 - 1}$$ $$= \binom{27}{3} - \binom{23}{3} - \binom{22}{3} + \binom{18}{3} = 430$$

Question 4

Maths · Binomial Theorem · Single correct

The term independent of $x$ in the expression of $$\left(1 - x^2 + 3x^3\right) \left(\frac{5}{2} x^3 - \frac{1}{5x^2}\right)^{11}, x \neq 0$$ is

  1. $\frac{7}{40}$
  2. $\frac{33}{200}$
  3. $\frac{39}{200}$
  4. $\frac{11}{50}$

Answer: (b)

Solution

The expression $\left(1 - x^2 + 3x^3\right) \left(\frac{5}{2} x^3 - \frac{1}{5x^2}\right)^{11}$ is given. The general term of $\left(\frac{5}{2} x^3 - \frac{1}{5x^2}\right)^{11}$ is $$^{11}C_r \left(\frac{5}{2} x^3\right)^{11-r} \left(-\frac{1}{5x^2}\right)^r.$$ Simplifying, the general term is $$^{11}C_r \left(\frac{5}{2}\right)^{11-r} \left(-\frac{1}{5}\right)^r x^{33-5r}.$$ Now, consider the term independent of $x$. The coefficient of $x^0$ in $\left(\frac{5}{2} x^3 - \frac{1}{5x^2}\right)^{11}$ is $$1 \times coefficient of x^0$$ The coefficient of $x^{-2}$ in $\left(\frac{5}{2} x^3 - \frac{1}{5x^2}\right)^{11}$ is $$-1 \times coefficient of x^{-2}$$ The coefficient of $x^{-3}$ in $\left(\frac{5}{2} x^3 - \frac{1}{5x^2}\right)^{11}$ is $$3 \times coefficient of x^{-3}$$ For the coefficient of $x^0$, $33 - 5r = 0$, which is not possible. For the coefficient of $x^{-2}$, $33 - 5r = -2$, which gives $r = 7$. For the coefficient of $x^{-3}$, $33 - 5r = -3$, which is not possible. Thus, the term independent of $x$ is $$(-1)^{11}C_7 \left(\frac{5}{2}\right)^4 \left(-\frac{1}{5}\right)^7 = \frac{33}{200}.$$

Question 5

Maths · Sequences and Series · Single correct

If n arithmetic means are inserted between a and 100 such that the ratio of the first mean to the last mean is 1 : 7 and a + n = 33, then the value of n is

  1. 21
  2. 22
  3. 23
  4. 24

Answer: (c)

Solution

Given $\($ d = $\frac{100-a}{n+1}$ $\)$ $\($ A_1 = a + d $\)$ $\($ A_n = 100 - d $\)$ $\($ $\Rightarrow$ $\frac{A_1}{A_n}$ = $\frac{1}{7}$ $\Rightarrow$ $\frac{a+d}{100-d}$ = $\frac{1}{7}$ $\)$ $\($ $\Rightarrow$ 7a + 8d = 100 $\)$ $\($ $\Rightarrow$ 7a + 8 $\left$( $\frac{100-a}{n+1}$ $\right$) = 100 $\)$ $\($ $\ldots$ (1) $\)$ $\($ $\therefore$ a + n = 33 $\)$ $\($ $\ldots$ (2) $\)$ Now, by Eq. (1) and (2) $\($ 7n^2 - 132n - 667 = 0 $\)$ $\($ n = 23 $\)$ and $\($ n = $\frac{-29}{7}$ $\)$ reject.

Question 6

Maths · Continuity and Differentiability · Single correct

Let $f, g : \mathbb{R} \to \mathbb{R}$ be functions defined by $$f(x) = \begin{cases} \lfloor x \rfloor, & x < 0 \\ |1 - x|, & x \geq 0 \end{cases}$$ and $$g(x) = \begin{cases} e^x - x, & x < 0 \\ (x - 1)^2 - 1, & x \geq 0 \end{cases}$$ where $[x]$ denote the greatest integer less than or equal to $x$. Then, the function $f \circ g$ is discontinuous at exactly:

  1. one point
  2. two points
  3. three points
  4. four points

Answer: (b)

Solution

Check continuity at $x = 0$ and also check continuity at those $x$ where $g(x) = 0$. $g(x) = 0$ at $x = 0, 2$. $$\mathrm{fog}(0^+) = -1$$ $$\mathrm{fog}(0) = 0$$ Hence, discontinuous at $x = 0$. $$\mathrm{fog}(2^+) = 1$$ $$\mathrm{fog}(2^-) = -1$$ Hence, discontinuous at $x = 2$.

Question 7

Maths · Applications of Integrals · Single correct

Let $f : \mathbb{R} \rightarrow \mathbb{R}$ be a differentiable function such that $f \left( \frac{\pi}{4} \right) = \sqrt{2}$, $f \left( \frac{\pi}{2} \right) = 0$ and $f' \left( \frac{\pi}{2} \right) = 1$ and let $g(x) = \int_{x}^{\pi/4} \left( f'(t) \sec t + \tan t \sec t \ f(t) \right) dt$ for $x \in \left[ \frac{\pi}{4}, \frac{\pi}{2} \right)$. Then $\lim_{x \to \left( \frac{\pi}{2} \right)^{-}} g(x)$ is equal to

  1. 2
  2. 3
  3. 4
  4. -3

Answer: (b)

Solution

Given $$g(x) = \int_{x}^{\pi/4} \left( f'(t) \sec t + \tan t \sec t f(t) \right) \, dt$$ We have $$g(x) = \int_{x}^{\pi/4} d(f(t) \cdot \sec t) = f(t) \sec t \bigg|_{x}^{\pi/4}$$ Thus, $$g(x) = f\left(\frac{\pi}{4}\right) \sec \frac{\pi}{4} - f(x) \cdot \sec x$$ Simplifying, $$g(x) = 2 - f(x) \sec x = 2 - \left( \frac{f(x)}{\cos x} \right)$$ Taking the limit as $x$ approaches $\frac{\pi}{2}$, $$\lim_{x \to \frac{\pi}{2}} g(x) = 2 - \lim_{x \to \frac{\pi}{2}} \left( \frac{f(x)}{\cos x} \right)$$ Using L'Hopital's Rule, $$= 2 - \lim_{x \to \frac{\pi}{2}} \frac{f'(x)}{-\sin x}$$ This simplifies to $$= 2 + \frac{f'\left(\frac{\pi}{2}\right)}{\sin \frac{\pi}{2}} = 2 + \frac{1}{1} = 3$$

Question 8

Maths · Integrals · Single correct

Let $f : \mathbb{R} \to \mathbb{R}$ be continuous function satisfying $f(x) + f(x + k) = n$, for all $x \in \mathbb{R}$ where $k > 0$ and $n$ is a positive integer. If $I_1 = \int_{0}^{4nk} f(x) \, dx$ and $I_2 = \int_{-k}^{3k} f(x) \, dx$, then

  1. $I_1 + 2I_2 = 4nk$
  2. $I_1 + 2I_2 = 2nk$
  3. $I_1 + nI_2 = 4n^2k$
  4. $I_1 + nI_2 = 6n^2k$

Answer: (c)

Solution

Given $f(x) + f(x+k) = n$. This implies $f(x) = f(x+2k)$. Therefore, $f(x)$ is periodic with period $2k$. $$I_1 = \int_0^{4nk} f(x) \, dx = 2n \int_0^{2k} f(x) \, dx$$ $$I_2 = \int_{-k}^{3k} f(x) \, dx = 2 \int_0^{2k} f(x) \, dx$$ Now, $f(x) + f(x+k) = n$ $$\Rightarrow \int_0^k f(x) \, dx + \int_0^k f(x+k) \, dx = nk$$ $$\Rightarrow \int_0^k f(x) \, dx + \int_k^{2k} f(x) \, dx = nk$$ $$\Rightarrow \int_0^{2k} f(x) \, dx = nk$$ $$\Rightarrow I_1 = 2n^2k, \ I_2 = 2nk$$ $$\Rightarrow I_1 + nI_2 = 4n^2k$$

Question 9

Maths · Applications of Integrals · Single correct

The area of the bounded region enclosed by the curve $y = 3 - \left| x - \frac{1}{2} \right| - |x + 1|$ and the x-axis is

  1. $\frac{9}{4}$
  2. $\frac{45}{16}$
  3. $\frac{27}{8}$
  4. $\frac{63}{16}$

Answer: (c)

Solution

Given $$y = \begin{cases} 3 + (x + 1) + \left(x - \frac{1}{2}\right), & x < -1 \\ 3 - (x + 1) + \left(x - \frac{1}{2}\right), & -1 \leq x < \frac{1}{2} \\ 3 - (x + 1) - \left(x - \frac{1}{2}\right), & \frac{1}{2} \leq x \end{cases}$$ Simplifying, we have $$y = \begin{cases} \frac{7}{2} + 2x, & x < -1 \\ \frac{3}{2}, & -1 \leq x < \frac{1}{2} \\ \frac{5}{2} - 2x, & \frac{1}{2} \leq x \end{cases}$$ The area bounded is ar ABF + ar BCEF + ar CDE. $$= \frac{1}{2} \left(\frac{3}{4}\right) \left(\frac{3}{2}\right) + \left(\frac{3}{2}\right) \left(\frac{3}{2}\right) + \frac{1}{2} \left(\frac{3}{4}\right) \left(\frac{3}{2}\right)$$ $$= \frac{27}{8}$$ sq. units.

Question 10

Maths · Differential Equations · Single correct

Let $x = x(y)$ be the solution of the differential equation $2y e^{x/y^2} \, dx + \left( y^2 - 4x e^{x/y^2} \right) \, dy = 0$ such that $x(1) = 0$. Then, $x(e)$ is equal to

  1. $e \log_e (2)$
  2. $-e \log_e (2)$
  3. $e^2 \log_e (2)$
  4. $-e^2 \log_e (2)$

Answer: (d)

Solution

$2ye^{x/y^2}\,dx + (y^2 - 4xe^{x/y^2})\,dy = 0$ $2e^{x/y^2}[y\,dx - 2x\,dy] + y^2\,dy = 0$ $2e^{x/y^2}\left[\dfrac{y^2\,dx - x\cdot(2y)\,dy}{y}\right] + y^2\,dy = 0$ Divide by $y^3$ $2e^{x/y^2}\left[\dfrac{y^2\,dx - x\cdot(2y)\,dy}{y^4}\right] + \dfrac{1}{y}\,dy = 0$ $2e^{x/y^2}\,d\left(\dfrac{x}{y^2}\right) + \dfrac{1}{y}\,dy = 0$ Integrating $\int 2e^{x/y^2}\,d\left(\dfrac{x}{y^2}\right) + \int\dfrac{1}{y}\,dy = 0$ $2e^{x/y^2} + \ln y + c = 0$ $(0, 1)$ lies on it. $2e^0 + \ln 1 + c = 0 \Rightarrow c = -2$ Required curve : $\boxed{2e^{x/y^2} + \ln y - 2 = 0}$ For $x(e)$ $2e^{x/e^2} + \ln e - 2 = 0 \Rightarrow x = -e^2\log_e 2$

Question 11

Maths · Applications of Derivatives · Single correct

Let the slope of the tangent to a curve $y=f(x)$ at $(x,y)$ be given by \[ 2\tan x\,(\cos x-y). \] If the curve passes through the point $\left(\frac{\pi}{4},0\right)$, then the value of \[ \int_{0}^{\pi/2} y\,dx \] is equal to

  1. $(2-\sqrt{2})+\frac{\pi}{\sqrt{2}}$
  2. $2-\frac{\pi}{\sqrt{2}}$
  3. $(2+\sqrt{2})+\frac{\pi}{\sqrt{2}}$
  4. $2+\frac{\pi}{\sqrt{2}}$

Answer: (b)

Solution

Given $\($ $\frac{dy}{dx}$ = 2 $\tan$ x $\cos$ x - 2 $\tan$ x $\cdot$ y $\)$ $\($ $\frac{dy}{dx}$ + (2 $\tan$ x) y = 2 $\sin$ x $\)$ Integrating factor $\($ = e^{$\int$ 2 $\tan$ x $\,$ dx} = $\frac{1}{\cos^2 x}$ $\)$ $\($ y $\left$( $\frac{1}{\cos^2 x}$ $\right$) = $\int$ $\frac{2 \sin x}{\cos^2 x}$ $\,$ dx $\)$ $\($ y $\sec$^2 x = $\frac{2}{\cos x}$ + C $\)$ $\($ y = 2 $\cos$ x + C $\cos$^2 x $\)$ Passes through $\($ $\left$( $\frac{\pi}{4}$, 0 $\right$) $\)$ $\($ 0 = $\sqrt{2}$ + $\frac{C}{2}$ $\Rightarrow$ C = -2 $\sqrt{2}$ $\)$ $\($ f(x) = 2 $\cos$ x - 2 $\sqrt{2}$ $\cos$^2 x $\)$ : Required curve $\($ $\int$_{0}^{$\pi$/2} y $\,$ dx = 2 $\int$_{0}^{$\pi$/2} $\cos$ x $\,$ dx - 2 $\sqrt{2}$ $\int$_{0}^{$\pi$/2} $\cos$^2 x $\,$ dx $\)$ $\($ = $\left$[ 2 $\sin$ x $\right$]_{0}^{$\pi$/2} - 2 $\sqrt{2}$ $\left$[ $\frac{x}{2}$ + $\frac{\sin 2x}{4}$ $\right$]_{0}^{$\pi$/2} $\)$ $\($ = 2 - $\frac{\pi}{\sqrt{2}}$ $\)$

Question 12

Maths · Straight Lines and Pair of Straight Lines · Single correct

Let a triangle be bounded by the lines $L_1 : 2x + 5y = 10$; $L_2 : -4x + 3y = 12$ and the line $L_3$, which passes through the point $P(2, 3)$, intersect $L_2$ at $A$ and $L_1$ at $B$. If the point $P$ divides the line-segment $AB$, internally in the ratio $1 : 3$, then the area of the triangle is equal to

  1. $\($ $\frac{110}{13}$ $\)$
  2. $\($ $\frac{132}{13}$ $\)$
  3. $\($ $\frac{142}{13}$ $\)$
  4. $\($ $\frac{151}{13}$ $\)$

Answer: (b)

Solution

Points $A$ lies on $L_2$ $$A\left(\alpha,\ 4 + \frac{4}{3}\alpha\right)$$ Points $B$ lies on $L_1$ $$B\left(\beta,\ 2 - \frac{2}{5}\beta\right)$$ Points $P$ divides $AB$ internally in the ratio $1:3$ $$\Rightarrow P(2,3) = P\left(\frac{3\alpha + \beta}{4},\ \frac{3\left(4 + \frac{4}{3}\alpha\right) + 1\left(2 - \frac{2}{5}\beta\right)}{4}\right)$$ $$\Rightarrow \alpha = \frac{3}{13},\quad \beta = \frac{95}{13}$$ $$A\left(\frac{3}{13},\ \frac{56}{13}\right), \quad B\left(\frac{95}{13},\ \frac{-12}{13}\right)$$ Vertex $C$ of triangle is the point of intersection of $L_1$ and $L_2$ $$\Rightarrow C\left(\frac{-15}{13},\ \frac{32}{13}\right)$$ $$\text{Area } \triangle ABC = \frac{1}{2} \begin{vmatrix} \dfrac{3}{13} & \dfrac{56}{13} & 1 \\[8pt] \dfrac{95}{13} & \dfrac{-12}{13} & 1 \\[8pt] \dfrac{-15}{13} & \dfrac{32}{13} & 1 \end{vmatrix}$$ $$= \frac{1}{2 \times 13^3} \begin{vmatrix} 3 & 56 & 13 \\ 95 & -12 & 13 \\ -15 & 32 & 13 \end{vmatrix}$$ $$\text{Area } \triangle ABC = \frac{132}{13} \text{ sq. units}$$

Question 13

Maths · Conic Sections · Single correct

Let $a > 0$, $b > 0$. Let $e$ and $\ell$ respectively be the eccentricity and length of the latus rectum of the hyperbola $\frac{x^2}{a^2} - \frac{y^2}{b^2} = 1$. Let $e'$ and $\ell'$ respectively the eccentricity and length of the latus rectum of its conjugate hyperbola. If $e^2 = \frac{11}{14} \ell$ and $(e')^2 = \frac{11}{8} \ell'$, then the value of $77a + 44b$ is equal to

  1. 100
  2. 110
  3. 120
  4. 130

Answer: (d)

Solution

Given $e = \sqrt{1 + \frac{b^2}{a^2}}, \ell = \frac{2b^2}{a}$. Given $e^2 = \frac{11}{14} \ell$. $$1 + \frac{b^2}{a^2} = \frac{11}{14} \cdot \frac{2b^2}{a}$$ $$\frac{a^2 + b^2}{a^2} = \frac{11}{7} \cdot \frac{b^2}{a} ......(1)$$ Also $e' = \sqrt{1 + \frac{a^2}{b^2}}, \ell' = \frac{2a^2}{b}$. Given $(e')^2 = \frac{11}{8} \ell'$. $$1 + \frac{a^2}{b^2} = \frac{11}{8} \cdot \frac{2a^2}{b}$$ $$\frac{a^2 + b^2}{b^2} = \frac{11}{4} \cdot \frac{a^2}{b} ......(2)$$ New (1) $\div$ (2) $$\frac{b^2}{a^2} = \frac{4}{7} \cdot \frac{b^3}{a^3}$$ $$\therefore 7a = 4b ...... (3)$$ From (2) $$\frac{16b^2}{49} + b^2 = \frac{11}{4} \cdot \frac{16b^2}{49b}$$ $$\frac{65}{49} = \frac{11}{4} \cdot \frac{16}{49} \cdot b$$ $$\therefore b = \frac{4 \times 65}{11 \times 16} ..... (4)$$ We have to find value of $77a + 44b$

Question 14

Maths · Vector Algebra · Single correct

Let $\vec{a}=\alpha\hat{i}+2\hat{j}-\hat{k}$ and $\vec{b}=-2\hat{i}+\alpha\hat{j}+\hat{k},$ where $\alpha\in\mathbb{R}$. If the area of the parallelogram whose adjacent sides are represented by the vectors $\vec{a}$ and $\vec{b}$ is $\sqrt{15(\alpha^2+4)}$, then the value of $2|\vec{a}|^2+(\vec{a}\cdot\vec{b})|\vec{b}|^2$ is equal to $\underline{\hspace{2cm}}$

  1. 10
  2. 7
  3. 9
  4. 14

Answer: (d)

Solution

Given $\vec{a} = \alpha \hat{i} + 2 \hat{j} - \hat{k}$, $\vec{b} = -2 \hat{i} + \alpha \hat{j} + \hat{k}$. The area of the parallelogram is $|\vec{a} \times \vec{b}|$. $$|\vec{a} \times \vec{b}| = \sqrt{(\alpha + 2)^2 + (\alpha - 2)^2 + (\alpha^2 + 4)^2}$$ Given $|\vec{a} \times \vec{b}| = \sqrt{15(\alpha^2 + 4)}$. $$2(\alpha^2 + 4) + (\alpha^2 + 4)^2 = 15(\alpha^2 + 4)$$ $$(\alpha^2 + 4)^2 = 13(\alpha^2 + 4)$$ $$\Rightarrow \alpha^2 + 4 = 13 \therefore \alpha^2 = 9$$ $$2 |\vec{a}|^2 + (\vec{a} \cdot \vec{b}) |\vec{b}|^2$$ $$|\vec{a}|^2 = \alpha^2 + 4 + 1 = \alpha^2 + 5$$ $$|\vec{b}|^2 = 4 + \alpha^2 + 1 = \alpha^2 + 5$$ $$\vec{a} \cdot \vec{b} = -2 \alpha + 2 \alpha - 1 = -1$$ $$\therefore 2 |\vec{a}|^2 + (\vec{a} \cdot \vec{b}) |\vec{b}|^2$$ $$2(\alpha^2 + 5) - 1(\alpha^2 + 5) = \alpha^2 + 5 = 14$$

Question 15

Maths · Conic Sections · Single correct

If vertex of a parabola is $(2, -1)$ and the equation of its directrix is $4x - 3y = 21$, then the length of its latus rectum is

  1. 2
  2. 8
  3. 12
  4. 16

Answer: (b)

Solution

Given the equation $4x - 3y = 21$ and the point $(2, -1)$. Calculate $a$ using the formula: $$a = \frac{|18 + 3 - 21|}{5} = \frac{10}{5} = 2$$ Therefore, the latus rectum is $4a = 8$.

Question 16

Maths · Three Dimensional Geometry · Single correct

Let the plane ax + by + cz = d pass through (2, 3, -5) and is perpendicular to the planes 2x + y - 5z = 10 and 3x + 5y - 7z = 12. If a, b, c, d are integers d > 0 and gcd (|a|, |b|, |c|, d) = 1, then the value of a + 7b + c + 20d is equal to

  1. 18
  2. 20
  3. 24
  4. 22

Answer: (d)

Solution

DR'S normal of plane $$\begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ 2 & 1 & -5 \\ 3 & 5 & -7 \end{vmatrix} = 18\hat{i} - \hat{j} + 7\hat{k}$$ Therefore, equation of plane $$18x - y + 7z = d$$ It passes through $(2, 3, -5)$ $$36 - 3 - 35 = d \therefore d = -2$$ Therefore, equation of plane $$18x - y + 7z = -2$$ $$-18x + y - 7z = 2$$ Therefore, $a = -18$, $b = 1$, $c = -7$, $d = 2$ $$a + 7b + c + 20d = -18 + 7 - 7 + 40 = 22$$

Question 17

Maths · Probability · Single correct

The probability that a randomly chosen one-one function from the set {a, b, c, d} to the set {1, 2, 3, 4, 5} satisfies $f(a) + 2f(b) - f(c) = f(d)$ is :

  1. $\frac{1}{24}$
  2. $\frac{1}{40}$
  3. $\frac{1}{30}$
  4. $\frac{1}{20}$

Answer: (d)

Solution

The number of sample points is given by $n(s) = \binom{5}{4} \times 4! = 120$. The table shows the values for $f(a)$, $2f(b)$, $f(c)$, and $f(d)$. The calculations are as follows: For $f(a) = 5$, $2f(b) = 2 \times 1$, $f(c) = 3$, $f(d) = 4$. For $f(a) = 4$, $2f(b) = 2 \times 2$, $f(c) = 3$, $f(d) = 5$. For $f(a) = 1$, $2f(b) = 2 \times 3$, $f(c) = 2$, $f(d) = 5$. The number of favorable outcomes is $n(A) = 2 \times 3 = 6$. Therefore, the probability $P(A)$ is given by $$P(A) = \frac{n(A)}{n(s)} = \frac{6}{120} = \frac{1}{20}.$$

Question 18

Maths · Limits and Derivatives · Single correct

The value of $\lim_{n \to \infty} 6 \tan \left\{ \sum_{r=1}^{n} \tan^{-1} \left( \frac{1}{r^2 + 3r + 3} \right) \right\}$ is equal to

  1. 1
  2. 2
  3. 3
  4. 6
Solution

Given $T_r = \tan^{-1} \left[ \frac{(r+2) - (r+1)}{1 + (r+2)(r+1)} \right]$. This simplifies to $\tan^{-1}(r+2) - \tan^{-1}(r+1)$. For $T_1$, we have $T_1 = \tan^{-1} 3 - \tan^{-1} 2$. For $T_2$, we have $T_2 = \tan^{-1} 4 - \tan^{-1} 3$. For $T_n$, we have $T_n = \tan^{-1} (n+2) - \tan^{-1} (n+1)$. The sum $S_n = \tan^{-1} (n+2) - \tan^{-1} 2$ $= \tan^{-1} \left( \frac{n+2-2}{1+2(n+2)} \right)$. This simplifies to $\tan^{-1} \left( \frac{n}{2n+5} \right)$. We then evaluate $\lim_{n \to \infty} 6 \tan \left( \tan^{-1} \left( \frac{n}{2n+5} \right) \right)$. This limit is $\lim_{n \to \infty} \frac{6n}{2n+5} = \frac{6}{2} = 3$.

Question 19

Maths · Vector Algebra · Single correct

Let $\vec{a}$ be a vector which is perpendicular to the vector $3\hat{i} + \frac{1}{2}\hat{j} + 2\hat{k}$. If $\vec{a} \times (2\hat{i} + \hat{k}) = 2\hat{i} - 13\hat{j} - 4\hat{k}$, then the projection of the vector $\vec{a}$ on the vector $2\hat{i} + 2\hat{j} + \hat{k}$ is

  1. $\frac{1}{3}$
  2. 1
  3. $\frac{5}{3}$
  4. $\frac{7}{3}$

Answer: (c)

Solution

Given $\left( \vec{a} \times (2\hat{i} + \hat{k}) \right) \times \left( 3\hat{i} + \frac{1}{2} \hat{j} + 2\hat{k} \right)$. $$= (2\hat{i} - 13\hat{j} - 4\hat{k}) \times \left( 3\hat{i} + \frac{1}{2} \hat{j} + 2\hat{k} \right)$$ $$= -(6 + 2) \vec{a} = \begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ 2 & -13 & -4 \\ 3 & \frac{1}{2} & 2 \end{vmatrix}$$ $$\vec{a} = 3\hat{i} + 2\hat{j} - 5\hat{k}$$ Projection of $\vec{a}$ on vector $2\hat{i} + 2\hat{j} + \hat{k}$ is $$\frac{\vec{a} \cdot (2\hat{i} + 2\hat{j} + \hat{k})}{3} = \frac{5}{3}$$

Question 20

Maths · Trigonometric Functions · Single correct

If $\cot \alpha = 1$ and $\sec \beta = -\frac{5}{3}$, where $\pi < \alpha < \frac{3\pi}{2}$ and $\frac{\pi}{2} < \beta < \pi$, then the value of $\tan(\alpha + \beta)$ and the quadrant in which $\alpha + \beta$ lies, respectively are

  1. $-\frac{1}{7}$ and IV$^{th}$ quadrant
  2. 7 and I$^{st}$ quadrant
  3. $-7$ and IV$^{th}$ quadrant
  4. $\frac{1}{7}$ and I$^{st}$ quadrant

Answer: (a)

Solution

Given $\cot \alpha = 1$, $\sec \beta = \frac{-5}{3}$, $\cos \beta = \frac{-3}{5}$, $\tan \beta = \frac{-4}{3}$. $$\tan(\alpha + \beta) = \frac{1 - \frac{4}{3}}{1 + \frac{4}{3} \times 1} = \frac{-1}{7}$$

Question 21

Maths · Three Dimensional Geometry · Numerical

Let the image of the point P(1, 2, 3) in the line $$L: \frac{x-6}{3} = \frac{y-1}{2} = \frac{z-2}{3}$$ be Q. let $$R(\alpha, \beta, \gamma)$$ be a point that divides internally the line segment PQ in the ratio 1 : 3. Then the value of $$22(\alpha + \beta + \gamma)$$ is equal to

Answer: 125

Solution

Let M be the mid-point of PQ. Therefore, $\mathrm{M} = (3\lambda + 6, \, 2\lambda + 1, \, 3\lambda + 2)$. Now, $\overrightarrow{\mathrm{PM}} = (3\lambda + 5)\hat{i} + (2\lambda - 1)\hat{j} + (3\lambda - 1)\hat{k}$. Therefore, $\overrightarrow{\mathrm{PM}} \perp (3\hat{i} + 2\hat{j} + 3\hat{k})$. Thus, $3(3\lambda + 5) + 2(2\lambda - 1) + 3(3\lambda - 1) = 0$. $\lambda = \frac{-5}{11}$. Therefore, $\mathrm{M} \left( \frac{51}{11}, \frac{1}{11}, \frac{7}{11} \right)$. Since R is mid-point of PM, $22(\alpha + \beta + \gamma) = 125$.

Question 22

Maths · Mathematical Reasoning · Numerical

Suppose a class has 7 students. The average marks of these students in the mathematics examination is 62, and their variance is 20. A student fails in the examination if he/she gets less than 50 marks, then in worst case, the number of students can fail is

Answer: 0

Solution

Given $$20 = \frac{\sum_{i=1}^{7} |x_i - 62|^2}{7}$$ which implies $$|x_1 - 62|^2 + |x_2 - 62|^2 + \ldots + |x_7 - 62|^2 = 140$$ If $$x_1 = 49$$ then $$|49 - 62|^2 = 169$$ Therefore, $$|x_2 - 62|^2 + \ldots + |x_7 - 62|^2 = $$ Negative Number which is not possible, therefore, no student can fail.

Question 23

Maths · Conic Sections · Numerical

If one of the diameters of the circle \[ x^2 + y^2 - 2\sqrt{2}\,x - 6\sqrt{2}\,y + 14 = 0 \] is a chord of the circle \[ (x - 2\sqrt{2})^2 + (y - 2\sqrt{2})^2 = r^2, \] then the value of \(r^2\) is equal to

Answer: 10

Solution

PQ is the diameter of the circle. The equation of the circle is given by $S: x^2 + y^2 - 2\sqrt{2}x - 6\sqrt{2}y + 14 = 0$. The coordinates of $C$ and $O$ are $C(\sqrt{2}, 3\sqrt{2})$ and $O(2\sqrt{2}, 2\sqrt{2})$. The radius $r_1$ is $\sqrt{6}$. The equation of the circle $S_1$ is $(x - 2\sqrt{2})^2 + (y - 2\sqrt{2})^2 = r^2$. Now, in $\triangle OCQ$, we have $|OC|^2 + |CQ|^2 = |OQ|^2$. Therefore, $4 + 6 = r^2$, which gives $r^2 = 10$.

Question 24

Maths · Limits and Derivatives · Numerical

If $\lim_{{x \to 1}} \frac{{\sin(3x^2 - 4x + 1) - x^2 + 1}}{{2x^3 - 7x^2 + ax + b}} = -2$, then the value of $(a - b)$ is equal to

Answer: 11

Solution

Given $\($ $\lim$_{{x $\to$ 1}} $\frac{\sin(3x^2 - 4x + 1) - x^2 + 1}{2x^3 - 7x^2 + ax + b}$ = -2 $\)$. For finite limit $\($ a + b - 5 = 0 $\)$ $\ldots$(1) Apply L'Hôpital's rule $\($ $\lim$_{{x $\to$ 1}} $\frac{\cos(3x^2 - 4x + 1)(6x - 4) - 2x}{(6x^2 - 14x + a)}$ = -2 $\)$ For finite limit $\($ 6 - 14 + a = 0 $\)$ $\($ a = 8 $\)$ From (1) $\($ b = -3 $\)$ Now $\($ (a - b) = 11 $\)$

Question 25

Maths · Sequences and Series · Numerical

Let for $n = 1, 2, \ldots, 50$, $S_n$ be the sum of the infinite geometric progression whose first term is $n^2$ and whose common ratio is $\frac{1}{(n+1)^2}$. Then the value of $$\frac{1}{26} + \sum_{n=1}^{50} \left( S_n + \frac{2}{n+1} - n - 1 \right)$$ is equal to

Answer: 41651

Solution

Given $\($ S_n = $\frac{n^2}{1 - \frac{1}{(n+1)^2}}$ = $\frac{n(n+1)^2}{(n+2)}$ $\)$ $\($ S_n = $\frac{n(n^2 + 2n + 1)}{(n+2)}$ $\)$ $\($ S_n = $\frac{n[n(n+2) + 1]}{(n+2)}$ $\)$ $\($ S_n = n $\left$[ n + $\frac{1}{n+2}$ $\right$] $\)$ $\($ S_n = n^2 + $\frac{n + 2 - 2}{(n+2)}$ $\)$ $\($ S_n = n^2 + 1 - $\frac{2}{(n+2)}$ $\)$ Now $\($ $\frac{1}{26}$ + $\sum$_{n=1}^{50} $\left$[ (n^2 - n) - 2 $\left$( $\frac{1}{n+2}$ - $\frac{1}{n+1}$ $\right$) $\right$] $\)$ $\($ = $\frac{1}{26}$ $\left$[ $\frac{50 \times 51 \times 101}{6}$ - $\frac{50 \times 51}{2}$ - 2 $\left$( $\frac{1}{52}$ - $\frac{1}{2}$ $\right$) $\right$] $\)$ $\($ = 41651 $\)$

Question 26

Maths · Determinants · Numerical

If the system of linear equations $$2x - 3y = \gamma + 5,$$ $$\alpha x + 5y = \beta + 1,$$ where $\alpha, \beta, \gamma \in \mathbb{R}$ has infinitely many solutions, then the value of $|9\alpha + 3\beta + 5\gamma|$ is equal to

Answer: 58

Solution

Given the equations: $$2x - 3y = \gamma + 5$$ $$\alpha x + 5y = \beta + 1$$ For infinite many solutions: $$\frac{\alpha}{2} = \frac{5}{-3} = \frac{\beta + 1}{\gamma + 5}$$ Solving for $\alpha$: $$\alpha = \frac{-10}{3}$$ And for $\gamma$: $$5\gamma + 25 = -3\beta - 3$$ Simplifying: $$9\alpha = -30, 3\beta + 5\gamma = -28$$ Now: $$9\alpha + 3\beta + 5\gamma = -58$$ Taking the absolute value: $$|9\alpha + 3\beta + 5\gamma| = 58$$

Question 27

Maths · Matrices · Numerical

Let $A = \begin{pmatrix} 1+i & 1 \\ -i & 0 \end{pmatrix}$ where $i = \sqrt{-1}$. Then, the number of elements in the set $$\{ n \in \{1,2,\ldots,100\} : A^n = A \}$$ is

Answer: 25

Solution

Given $$A = \begin{bmatrix} 1+i & 1 \\ -i & 0 \end{bmatrix}$$ Calculate $$A^2 = \begin{bmatrix} 1+i & 1 \\ -i & 0 \end{bmatrix} \begin{bmatrix} 1+i & 1 \\ -i & 0 \end{bmatrix}$$ This results in $$A^2 = \begin{bmatrix} i & 1+i \\ -i+1 & -i \end{bmatrix}$$ Next, calculate $$A^4 = \begin{bmatrix} i & 1+i \\ -i+1 & -i \end{bmatrix} \begin{bmatrix} i & 1+i \\ -i+1 & -i \end{bmatrix}$$ This results in $$A^4 = \begin{bmatrix} 1 & 0 \\ 0 & 1 \end{bmatrix} = I$$ Therefore, $$A^{4n+1} = A$$ For $$n = 1, 5, 9, \ldots, 97$$ The total elements in the set is 25.

Question 28

Maths · Complex Numbers and Quadratic Equations · Numerical

Sum of squares of modulus of all the complex numbers $z$ satisfying $\overline{z} = i z^2 + z^2 - z$ is equal to

Answer: 2

Solution

Given $z + \overline{z} = i \overline{z}^2 + z^2$. Consider $z = x + iy$. Then $2x = (i + 1)(x^2 - y^2 + 2xyi)$. This implies $2x = x^2 - y^2 - 2xy$ and $x^2 - y^2 + 2xy = 0$. Therefore, $2x = -4xy$. This implies $x = 0$ or $y = -\frac{1}{2}$. Case 1: $x = 0$ implies $y = 0$, hence $z = 0$. Case 2: $y = -\frac{1}{2}$. This gives $4x^2 - 4x - 1 = 0$. $$(2x - 1)^2 = 2$$ $2x - 1 = \pm \sqrt{2}$. Thus, $x = \frac{1 \pm \sqrt{2}}{2}$. Here $z = \frac{1 + \sqrt{2}}{2} - \frac{i}{2}$ or $z = \frac{1 - \sqrt{2}}{2} - \frac{i}{2}$. Sum of squares of modulus of $z$ is $$0 + \frac{(1 + \sqrt{2})^2 + 1}{4} + \frac{(1 - \sqrt{2})^2 + 1}{4} = \frac{8}{4} = 2$$

Question 29

Maths · Relations and Functions (Advanced) · Numerical

Let S = {1, 2, 3, 4}. Then the number of elements in the set $\{$f : S $\times$ S $\to$ S : f is onto and f(a, b) = f(b, a) $\ge$ a $\forall$ (a, b) $\in$ S $\times$ S$\}$ is

Answer: 37

Solution

(1, 1), (1, 4), (4, 1), (2, 4), (4, 2), (3, 4), (4, 3), (4, 4) – all have one choice for image. (2, 1), (1, 2), (2, 2) – all have three choices for image (3, 2), (2, 3), (3, 1), (1, 3), (3, 3) – all have two choices for image. So the total functions = 3 $\times$ 3 $\times$ 2 $\times$ 2 $\times$ 2 = 72. Case 1: None of the pre-images have 3 as image. Total functions = 2 $\times$ 2 $\times$ 1 $\times$ 1 $\times$ 1 = 4. Case 2: None of the pre-images have 2 as image. Total functions = 2 $\times$ 2 $\times$ 2 $\times$ 2 $\times$ 2 = 32. Case 3: None of the pre-images have either 3 or 2 as image. Total functions = 1 $\times$ 1 $\times$ 1 $\times$ 1 $\times$ 1 = 1. Therefore, total onto functions = 72 - 4 - 32 + 1 = 37.

Question 30

Maths · Mathematical Reasoning · Numerical

The maximum number of compound propositions, out of $p \lor r \lor s$, $p \lor r \lor \sim s$, $p \lor \sim q \lor s$, $\sim p \lor \sim r \lor s$, $\sim p \lor \sim r \lor \sim s$, $\sim p \lor q \lor \sim s$, $q \lor r \lor \sim s$, $q \lor \sim r \lor \sim s$, $\sim p \lor \sim q \lor \sim s$ that can be made simultaneously true by an assignment of the truth values to $p$, $q$, $r$ and $s$, is equal to

Answer: 9

Solution

If we take The truth value of all the propositions will be true.

Physics

Question 31

Physics · Motion in a Straight Line · Single correct

Velocity (v) and acceleration (a) in two systems of units 1 and 2 are related as $v_2 = \frac{n}{m^2} v_1$ and $a_2 = \frac{a_1}{mn}$ respectively. Here $m$ and $n$ are constants. The relations for distance and time in two systems respectively are:

  1. $\frac{n^3}{m^3} L_1 = L_2$ and $\frac{n^2}{m} T_1 = T_2$
  2. $\frac{n^4}{m^2} L_2 = L_2$ and $T_1 = \frac{n^2}{m} T_2$
  3. $L_1 = \frac{n^2}{m} L_2$ and $T_1 = \frac{n^4}{m^2} T_2$
  4. $\frac{n^2}{m} L_1 = L_2$ and $\frac{n^4}{m^2} T_1 = T_2$

Answer: (a)

Solution

Given $\($ $\frac{L_2}{T_2}$ = $\frac{n}{m^2}$ $\frac{L_1}{T_1}$ $\)$. \[ \frac{L_2}{T_2^2} = \frac{L_1}{T_1^2 \times mn} \] \[ \frac{n}{m^2} \times \frac{T_2}{T_1} = \frac{T_2^2}{T_1^2 \times mn} \] \[ \frac{n^2}{m} = \frac{T_2}{T_1} \] \[ \frac{L_2}{L_1} = \frac{n^4}{m^2} \times \frac{1}{mn} \] \[\frac{L_2}{L_1} = \frac{n^3}{m^3} \]

Question 32

Physics · Motion in a Plane · Single correct

A ball is spun with angular acceleration $\alpha = 6t^2 - 2t$ where $t$ is in second and $\alpha$ is in $\mathrm{rads}^{-2}$. At $t = 0$, the ball has angular velocity of $10 \, \mathrm{rads}^{-1}$ and angular position of $4 \, \mathrm{rad}$. The most appropriate expression for the angular position of the ball is:

  1. $\frac{3}{2} t^4 - t^2 + 10t$
  2. $\frac{t^4}{2} - \frac{t^3}{3} + 10t + 4$
  3. $\frac{2t^4}{3} - \frac{t^3}{6} + 10t + 12$
  4. $2t^4 - \frac{t^3}{2} + 5t + 4$

Answer: (b)

Solution

Given $\($ $\frac{dw}{dt}$ = 6t^2 - 2t $\)$. Integrating from 10 to $\($ w $\)$: $$ \int_{10}^{w} dw = 2t^3 - t^2 $$ $\($ w = 10 + 2t^3 - t^2 $\)$. Now, $\($ $\frac{d\theta}{dt}$ = 10 + 2t^3 - t^2 $\)$. Integrating from 4 to $\($ $\theta$ $\)$: $$ \int_{4}^{\theta} d\theta = 10 + 2t^3 - t^2 $$ $$ \int_{4}^{\theta} d\theta = 10t + \frac{t^4}{2} - \frac{t^3}{3} $$ $\($ $\theta$ = 4 + 10t + $\frac{t^4}{2}$ - $\frac{t^3}{3}$ $\)$

Question 33

Physics · Work, Energy and Power · Single correct

A block of mass 2 kg moving on a horizontal surface with speed of 4 $\mathrm{m\,s^{-1}}$ enters a rough surface ranging from $x = 0.5 \mathrm{\, m}$ to $x = 1.5 \mathrm{\, m}$. The retarding force in this range of rough surface is related to distance by $F = -kx$ where $k = 12 \mathrm{\, Nm^{-1}}$. The speed of the block as it just crosses the rough surface will be:

  1. Zero
  2. 1.5 $\mathrm{m\,s^{-1}}$
  3. 2.0 $\mathrm{m\,s^{-1}}$
  4. 2.5 $\mathrm{m\,s^{-1}}$

Answer: (c)

Solution

Given $a = \frac{-kx}{2} = \frac{-12x}{2} = -6x$. We have $v \frac{dv}{dx} = -6x$. Integrating both sides: $$\int_{4}^{v} v \, dv = -\int_{\frac{1}{2}}^{\frac{3}{2}} 6x \, dx$$ This gives: $$\frac{v^2 - 4^2}{2} = -\frac{6}{2} \left[ \left( \frac{3}{2} \right)^2 - \left( \frac{1}{2} \right)^2 \right]$$ Simplifying, we get: $$v^2 - 16 = -6 \left( \frac{9}{4} - \frac{1}{4} \right)$$ Further simplification gives: $$v^2 = 16 - 6 \times 2 = 4$$ Thus, $V = 2 \, \mathrm{m/s}$.

Question 34

Physics · System of Particles and Rotational Motion · Single correct

A $\sqrt{34}$ $\,$ $\mathrm{m}$ long ladder weighing 10 \, $\mathrm{kg}$ leans on a frictionless wall. Its feet rest on the floor 3 \, $\mathrm{m}$ away from the wall as shown in the figure. If F_f and F_w are the reaction forces of the floor and the wall, then ratio of $\frac{F_w}{F_f}$will be: (Use g = 10 \, $\mathrm{m/s^2}$)

  1. $\frac{6}{\sqrt{110}}$
  2. $\frac{3}{\sqrt{113}}$
  3. $\frac{3}{\sqrt{109}}$
  4. $\frac{2}{\sqrt{109}}$

Answer: (c)

Solution

Given $f = N_2$ and $N_1 = mg$. The equation $N_2 \times \ell \sin \theta = mg \frac{\ell}{2} \cos \theta$ gives $$N_2 = \frac{mg}{2} \cot \theta$$ The ratio of forces is $$\frac{F_w}{F_f} = \frac{\frac{mg}{2} \cot \theta}{\sqrt{(mg)^2 + \left(\frac{mg}{2} \cot \theta\right)^2}}$$ Simplifying, we have $$= \frac{1}{\sqrt{1 + \frac{4}{\cot^2 \theta}}}$$ Finally, $$= \frac{3}{\sqrt{109}}$$

Question 35

Physics · Gravitation · Single correct

Water fall from a 40 m high dam at the rate of $9 \times 10^4 \, \mathrm{kg}$ per hour. Fifty percentage of gravitational potential energy can be converted into electrical energy. Using this hydroelectric energy number of 100W lamps, that can be lit, is: (Take $g = 10 \, \mathrm{ms^{-2}}$)

  1. 25
  2. 50
  3. 100
  4. 18

Answer: (b)

Solution

Given $$\frac{9 \times 10^4 \times g \times 40}{3600} \times 0.5 = n \times 100$$. Simplifying, we have: $$\frac{10^4 \times 0.5}{100} = n$$ $$100 \times 0.5 = n$$ $$n = 50$$

Question 36

Physics · Gravitation · Single correct

Two objects of equal masses placed at certain distance from each other attracts each other with a force of $F$. If one-third mass of one object is transferred to the other object, then the new force will be:

  1. $\frac{2}{9} F$
  2. $\frac{16}{9} F$
  3. $\frac{8}{9} F$
  4. $F$

Answer: (c)

Solution

Given the formula for force: $$F = \frac{Gm^2}{r^2}$$ The modified force is: $$F' = \frac{G \left( \frac{4m}{3} \right) \times \left( \frac{2m}{3} \right)}{r^2}$$ Simplifying gives: $$F' = \frac{8}{9} F$$

Question 37

Physics · Mechanical Properties of Fluids · Single correct

A water drop of radius 1 $\mu \mathrm{m}$ falls in a situation where the effect of buoyant force is negligible. Coefficient of viscosity of air is $1.8 \times 10^{-5} \, \mathrm{Nsm^{-2}}$ and its density is negligible as compared to that of water $10^{6} \, \mathrm{gm^{-3}}$. Terminal velocity of the water drop is: (Take acceleration due to gravity $= 10 \, \mathrm{ms^{-2}}$)

  1. 145.4 \times 10^{-6}\,\mathrm{m\,s^{-1}}
  2. 118.0 \times 10^{-6}\,\mathrm{m\,s^{-1}}
  3. 132.6 \times 10^{-6}\,\mathrm{m\,s^{-1}}
  4. 123.4 \times 10^{-6}\,\mathrm{m\,s^{-1}}

Answer: (d)

Solution

The force due to viscosity is given by $F_v = 6 \pi \eta r v_t$. The gravitational force is $mg = \frac{4}{3} \pi r^3 \rho g$. Equating the forces, we have: $$6 \pi \eta r v_t = \frac{4}{3} \pi r^3 \rho g$$ Solving for $v_t$, we get: $$v_t = \frac{4}{3} \times \frac{\pi r^3 \rho g}{6 \pi \eta r}$$ Substituting the given values: $$v_t = \frac{4}{3} \times \frac{\pi r^3 \rho g}{6 \pi \eta r} = \frac{2 \times 10^{-12} \times 10^3 \times 10}{9 \times 1.8 \times 10^{-5}}$$ This simplifies to: $$= 123.4 \times 10^{-6} \, \mathrm{m/s}$$

Question 38

Physics · Thermodynamics · Single correct

A sample of an ideal gas is taken through the cyclic process ABCA as shown in figure. It absorbs, 40 \, $\mathrm{J}$ of heat during the part AB, no heat during BC and rejects 60 \, $\mathrm{J}$ of heat during CA. A work 50 \, $\mathrm{J}$ is done on the gas during the part BC. The internal energy of the gas at A is 1560 \, $\mathrm{J}$. The work done by the gas during the part CA is:

  1. 20 \, $\mathrm{J}$
  2. 30 \, $\mathrm{J}$
  3. -30 \, $\mathrm{J}$
  4. -60 \, $\mathrm{J}$

Answer: (b)

Solution

Question 39

Physics · Kinetic Theory · Single correct

What will be the effect on the root mean square velocity of oxygen molecules if the temperature is doubled and oxygen molecule dissociates into atomic oxygen?

  1. The velocity of atomic oxygen remains same
  2. The velocity of atomic oxygen doubles
  3. The velocity of atomic oxygen becomes half
  4. The velocity of atomic oxygen becomes four times

Answer: (b)

Solution

Given $V_{rms} = \sqrt{\frac{3RT}{M}}$. $T \to 2T$ $M \to \frac{M}{2}$ $V_{rms} \propto \sqrt{\frac{T}{M}}$ Therefore, $\Rightarrow (V_{rms})_{atomic} = (V_{rms})_{molecular} \times \sqrt{\frac{2}{1/2}} = 2(V_{rms})_{molecular}$

Question 40

Physics · Electric Charges and Fields · Single correct

Two point charges A and B of magnitude $+8 \times 10^{-6} \, \mathrm{C}$ and $-8 \times 10^{-6} \, \mathrm{C}$ respectively are placed at a distance $d$ apart. The electric field at the middle point $O$ between the charges is $6.4 \times 10^{4} \, \mathrm{NC}^{-1}$. The distance ‘$d$’ between the point charges A and B is:

  1. 2.0 m
  2. 3.0 m
  3. 1.0 m
  4. 4.0 m

Answer: (b)

Solution

Given $E_0 = 2 \times \frac{Kq}{(d/2)^2}$. Therefore, $$E_0 = 8 \frac{Kq}{d^2}$$ implies $$d^2 = \frac{8 \times 9 \times 10^9 \times 8 \times 10^{-6}}{6.4 \times 10^4}$$ which gives $d = 3 \, \mathrm{m}$.

Question 41

Physics · Current Electricity · Single correct

Resistance of the wire is measured as $2\, \Omega$ and $3\, \Omega$ at $10^\circ \mathrm{C}$ and $30^\circ \mathrm{C}$ respectively. Temperature coefficient of resistance of the material of the wire is:

  1. $0.033^\circ \mathrm{C}^{-1}$
  2. $-0.033^\circ \mathrm{C}^{-1}$
  3. $0.011^\circ \mathrm{C}^{-1}$
  4. $0.055^\circ \mathrm{C}^{-1}$

Answer: (a)

Solution

Given the equation for resistance, $R = R_0 (1 + \alpha \Delta T)$. For the first condition, $3 = R_0 \left(1 + \alpha (30 - 0)\right)$. For the second condition, $2 = R_0 \left(1 + \alpha (10 - 0)\right)$. Equating the two conditions, we have: $$\frac{3}{2} = \frac{1 + 30\alpha}{1 + 10\alpha}$$ Solving for $\alpha$, we find: $$\alpha = \frac{1}{30} = 0.033$$

Question 42

Physics · Magnetism and Matter · Single correct

The space inside a straight current carrying solenoid is filled with a magnetic material having magnetic susceptibility equal to $1.2 \times 10^{-5}$. What is fractional increase in the magnetic field inside solenoid with respect to air as medium inside the solenoid?

  1. $1.2 \times 10^{-5}$
  2. $1.2 \times 10^{-3}$
  3. $1.8 \times 10^{-3}$
  4. $2.4 \times 10^{-5}$

Answer: (a)

Solution

Given $\chi = 1.2 \times 10^{-5}$. $\mu_r = 1 + \chi = 1 + 1.2 \times 10^{-5}$. Fractional Change $$\frac{\Delta B}{B} = \frac{\mu_0 \mu_r n i - \mu_0 n i}{\mu_0 n i} = (\mu_r - 1)$$ $$= 1.2 \times 10^{-5}$$

Question 43

Physics · Moving Charges and Magnetism · Single correct

Two parallel, long wires are kept 0.20 m apart in vacuum, each carrying current of $x$ A in the same direction. If the force of attraction per meter of each wire is $2 \times 10^{-6} \, \mathrm{N}$, then the value of $x$ is approximately:

  1. 1
  2. 2.4
  3. 1.4
  4. 2

Answer: (c)

Solution

Force per unit length = $\frac{\mu_0 i_1 i_2}{2 \pi d}$ = $\frac{\mu_0 \cdot x^2}{2 \pi \times 0.2}$ F = 2 $\times$ 10^{-6} = $\frac{4 \pi \times 10^{-7} \times x^2}{2 \pi \times 0.2}$ $\implies$ 10^{-6} = 10^{-7} $\frac{x^2}{0.2}$ $\implies$ x^2 = 10 $\times$ 0.2 = 2 $\implies$ x = $\sqrt{2}$ $\approx$ 1.4 $\,$ Amp.

Question 44

Physics · Moving Charges and Magnetism · Single correct

A coil is placed in a time varying magnetic field. If the number of turns in the coil were to be halved and the radius of wire doubled, the electrical power dissipated due to the current induced in the coil would be: (Assume the coil to be short circuited.)

  1. Halved
  2. Quadrupled
  3. The same
  4. Doubled

Answer: (b)

Solution

Given $$P = \frac{\varepsilon^2}{R} = \frac{\left( \frac{NA \, \mathrm{dB}}{\mathrm{dt}} \right)^2 \times A_C}{\rho \ell}$$ Then, $$P' = \frac{\left( \frac{NA}{2} \frac{\mathrm{dB}}{\mathrm{dt}} \right)^2 \times 4A_C}{\rho \ell / 2}$$ Therefore, $$P' = 2P$$

Question 45

Physics · Electromagnetic Waves · Single correct

An EM wave propagating in x-direction has a wavelength of 8 mm. The electric field vibrating y-direction has maximum magnitude of 60 $\,$ $\mathrm{Vm}$^{-1}. Choose the correct equations for electric and magnetic fields if the EM wave is propagating in vacuum:

  1. $E_y = 60 \sin \left[ \frac{\pi}{4} \times 10^3 \left( x - 3 \times 10^8 t \right) \right] \hat{\jmath} \, \mathrm{Vm}^{-1}$, $B_z = 2 \sin \left[ \frac{\pi}{4} \times 10^3 \left( x - 3 \times 10^8 t \right) \right] \hat{k} \, \mathrm{T}$
  2. $E_y = 60 \sin \left[ \frac{\pi}{4} \times 10^3 \left( x - 3 \times 10^8 t \right) \right] \hat{\jmath} \, \mathrm{Vm}^{-1}$, $B_z = 2 \times 10^{-7} \sin \left[ \frac{\pi}{4} \times 10^3 \left( x - 3 \times 10^8 t \right) \right] \hat{k} \, \mathrm{T}$
  3. $E_y = 2 \times 10^{-7} \sin \left[ \frac{\pi}{4} \times 10^3 \left( x - 3 \times 10^8 t \right) \right] \hat{\jmath} \, \mathrm{Vm}^{-1}$, $B_z = 60 \sin \left[ \frac{\pi}{4} \times 10^3 \left( x - 3 \times 10^8 t \right) \right] \hat{k} \, \mathrm{T}$
  4. $E_y = 2 \times 10^{-7} \sin \left[ \frac{\pi}{4} \times 10^4 \left( x - 4 \times 10^8 t \right) \right] \hat{\jmath} \, \mathrm{Vm}^{-1}$, $B_z = 60 \sin \left[ \frac{\pi}{4} \times 10^4 \left( x - 4 \times 10^8 t \right) \right] \hat{k} \, \mathrm{T}$

Answer: (b)

Solution

Given $B_0 = \frac{E_0}{c} = \frac{60}{3 \times 10^8} = 2 \times 10^{-7} \, \mathrm{T}$. $\hat{\mathbf{E}} \times \hat{\mathbf{B}}$ must be the direction of propagation. So, $\hat{\mathbf{B}} \rightarrow z-axis$. $$\mathbf{k} = \frac{2\pi}{\lambda} = \frac{\pi}{4} \times 10^3 \, \mathrm{m}^{-1}$$ $$E_y = 60 \sin \left[ \frac{\pi}{4} \times 10^3 \left( x - 3 \times 10^8 t \right) \right] \hat{\mathbf{j}} \, \mathrm{V/m}$$ $$B_z = 2 \times 10^{-7} \sin \left[ \frac{\pi}{4} \times 10^3 \left( x - 3 \times 10^8 t \right) \right] \hat{\mathbf{k}} \, \mathrm{T}$$

Question 46

Physics · Wave Optics · Single correct

In young's double slit experiment performed using a monochromatic light of wavelength $\lambda$, when a glass plate $(\mu = 1.5)$ of thickness $x\lambda$ is introduced in the path of the one of the interfering beams, the intensity at the position where the central maximum occurred previously remains unchanged. The value of $x$ will be:

  1. 3
  2. 2
  3. 1.5
  4. 0.5

Answer: (b)

Solution

Path difference at O = $(\mu - 1)t$. If the intensity at O remains (maximum) unchanged, path difference must be $n \lambda$. $$\Rightarrow (\mu - 1)t = n \lambda$$ $$(1.5 - 1)x \lambda = n \lambda$$ $$\Rightarrow x = 2n$$ For $n = 1$, $x = 2$

Question 47

Physics · Dual Nature of Radiation and Matter · Single correct

Let $K_1$ and $K_2$ be the maximum kinetic energies of photo-electrons emitted when two monochromatic beams of wavelength $\lambda_1$ and $\lambda_2$, respectively are incident on a metallic surface. If $\lambda_1 = 3\lambda_2$ then:

  1. $K_1 > \frac{K_2}{3}$
  2. $K_1 < \frac{K_2}{3}$
  3. $K_1 = \frac{K_2}{3}$
  4. $K_2 = \frac{K_1}{3}$

Answer: (b)

Solution

Given the equations: $$\frac{hc}{\lambda_1} - \phi = K_1$$ $$\frac{hc}{\lambda_2} - \phi = K_2$$ We know that $\lambda_1 = 3\lambda_2$. Substituting, we have: $$3K_1 = \frac{hc}{\lambda_2} - 3\phi$$ $$3K_1 = K_2 - 2\phi$$ Thus, $$3K_1 < K_2$$ Therefore, $$K_1 < \frac{K_2}{3}$$

Question 48

Physics · Nuclei · Single correct

Following statements related to radioactivity are given below: (A) Radioactivity is a random and spontaneous process and is dependent on physical and chemical conditions. (B) The number of un-decayed nuclei in the radioactive sample decays exponentially with time. ($C$) Slope of the graph of $\log_e$(no. of undecayed nuclei) Vs. time represents the reciprocal of mean life time ($\tau$). (D) Product of decay constant ($\lambda$) and half-life time ($T_{1/2}$) is not constant. Choose the most appropriate answer from the options given below:

  1. (A) and (B) only
  2. (B) and (D) only
  3. (B) and ($C$) only
  4. ($C$) and (D) only

Answer: (c)

Solution

c

Question 49

Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct

In the given circuit the input voltage $V_{in}$ is shown in figure. The cut-in voltage of p–n junction diode ($D_1$ or $D_2$) is $0.6 \, \mathrm{V}$. Which of the following output voltage ($V_0$) waveform across the diode is correct?

Answer: (d)

Solution

In +ve half cycle $D_1 \rightarrow F.B.; D_2 \rightarrow R.B.$ $0 - 0.6 \, V$ $V_{out}$ same as $V_{in}$ In -ve half cycle $D_2 \rightarrow F.B.; D_1 \rightarrow R.B.$

Question 50

Physics · Communication Systems · Single correct

Amplitude modulated wave is represented by $$V_{AM} = 10 \left[ 1 + 0.4 \cos \left( 2 \pi \times 10^4 t \right) \right] \cos \left( 2 \pi \times 10^7 t \right).$$ The total bandwidth of the amplitude modulated wave is :

  1. 10 kHz
  2. 20 MHz
  3. 20 kHz
  4. 10 MHz

Answer: (c)

Solution

Bandwidth = 2 f_m = 2 $\times$ 10^4 $\,$ $\mathrm{Hz}$ = 20 $\times$ 10^3 $\,$ $\mathrm{Hz}$ = 20 $\,$ $\mathrm{kHz}$

Question 51

Physics · Experimental Physics · Numerical

A student in the laboratory measures thickness of a wire using screw gauge. The readings are 1.22 mm, 1.23 mm, 1.19 mm and 1.20 mm. The percentage error is $\frac{x}{121}\%$. The value of $x$ is

Answer: 150

Solution

Given $$X = \frac{1.22 \, \mathrm{mm} + 1.23 \, \mathrm{mm} + 1.19 \, \mathrm{mm} + 1.20 \, \mathrm{mm}}{4}$$ We find $$X = 1.21 \, \mathrm{mm}$$ The uncertainty is $$\Delta x = \frac{0.01 + 0.02 + 0.02 + 0.01}{4} = \frac{0.06}{4} = 0.015$$ The percentage error is $$Percentage error = \frac{0.015}{1.21} \times 100$$ Finally, $$X = 150$$

Question 52

Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Fill in the blank

A Zener of breakdown voltage $V_Z = 8 \, \mathrm{V}$ and maximum zener current, $I_{ZM} = 10 \, \mathrm{mA}$ is subjected to an input voltage $V_i = 10 \, \mathrm{V}$ with series resistance $R = 100 \, \Omega$. In the given circuit $R_L$ represents the variable load resistance. The ratio of maximum and minimum value of $R_L$ is ________

Answer: 2

Solution

Given $I = \frac{2}{100} = 20 \, \mathrm{mA}$. The voltage across the load is $V_L = I_L R_L$. Therefore, $8 = 10 \times 10^{-3} \times R_{L_{max}}$. Solving for $R_{L_{max}}$ gives: $$\frac{4}{5} \times 10^3 = R_{L_{max}}$$ $$800 = R_{L_{max}}$$ For the minimum load resistance, $I = I_Z + I_L$ where $I_L = 10 \, \mathrm{mA}$. If $I_Z = 0$, then $I_{L_{max}} = 20 \, \mathrm{mA}$. The voltage across the load is $V_L = I_{L_{max}} \times R_{L_{min}}$. Therefore, $$\frac{8}{20} \times 10^3 = R_{L_{min}}$$ $$400 = R_{L_{min}}$$ The ratio of maximum to minimum load resistance is: $$\frac{R_{L_{max}}}{R_{L_{min}}} = \frac{800}{400} = 2$$

Question 53

Physics · Wave Optics · Numerical

In a Young's double slit experiment, an angular width of the fringe is $0.35^\circ$ on a screen placed at $2 \, \mathrm{m}$ away for particular wavelength of $450 \, \mathrm{nm}$. The angular width of the fringe, when whole system is immersed in a medium of refractive index $7/5$, is $\frac{1}{\alpha}$. The value of $\alpha$ is

Answer: 4

Solution

$\beta = \dfrac{0.35 \times 5}{7} = 0.25$ $\dfrac{1}{\alpha} = \dfrac{25}{100}$ $\boxed{\alpha = 4}$

Question 54

Physics · Alternating Current · Numerical

In the given circuit, the magnitude of $V_L$ and $V_C$ are twice that of $V_R$. Given that $f = 50 \, \mathrm{Hz}$, the inductance of the coil is $\frac{1}{K \pi} \, \mathrm{mH}$. The value of $K$ is ______.

Answer: 0

Solution

Given $V_L = V_C = 2V_R$ and $X_L = X_C = 2R$. We have $X_L = 10 \, \Omega$. Therefore, $\omega L = 10$ and $2 \pi f L = 10$. Solving for $L$, we get $$L = \frac{10}{2 \pi f} = \frac{1}{10 \pi} \, \mathrm{H} = \frac{1000}{10 \pi} \, \mathrm{mH}.$$ Further simplifying, $$L = \frac{1}{100 \pi}; K = \frac{1}{100} = 0.01 \approx 0.$$

Question 55

Physics · Current Electricity · Numerical

All resistances in figure are $1\,\Omega$ each. The value of current ‘I’ is $\frac{a}{5}$ A. The value of $a$ is

Answer: 8

Solution

The equivalent resistance is given by $$R_{eq} = \frac{15R}{8} = \frac{15}{8} \, \Omega$$ The current is calculated as $$I = \frac{3}{\frac{15}{8}} = \frac{8}{5} \, A$$ Therefore, $a = 8$.

Question 56

Physics · Electrostatic Potential and Capacitance · Numerical

A capacitor $C_1$ of capacitance $5\,\mu\mathrm{F}$ is charged to a potential of $30\,\mathrm{V}$ using a battery. The battery is then removed and the charged capacitor is connected to an uncharged capacitor $C_2$ of capacitance $10\,\mu\mathrm{F}$ as shown in figure. When the switch is closed charge flows between the capacitors. At equilibrium, the charge on the capacitor $C_2$ is $\mu\mathrm{C}$.

Answer: 100

Solution

Before closing the switch $Q = C_1 V_0 = 5 \times 30 = 150 \, \mu \mathrm{C}$ After closing the switch $$V = \frac{Q}{C_1 + C_2} = \frac{150}{10 + 5} = 10 \, \mathrm{V}$$ $Q_2 = C_2 V = 10 \times 10 = 100 \, \mu \mathrm{C}$

Question 57

Physics · Waves · Fill in the blank

A tuning fork of frequency 340 Hz resonates in the fundamental mode with an air column of length 125 cm in a cylindrical tube closed at one end. When water is slowly poured in it, the minimum height of water required for observing resonance once again is $\underline{\hspace{1cm}}$ cm. (Velocity of sound in air is 340 ms$^{-1}$)

Answer: 50

Solution

Assumption: Ignore word "fundamental mode" in question. $$\lambda = \frac{V}{f} = \frac{340}{340} = 1 \, \mathrm{m}$$ First resonating length = $$\frac{\lambda}{4} = 25 \, \mathrm{cm}$$ Second resonating length = $$\frac{3\lambda}{4} = 75 \, \mathrm{cm}$$ Third resonating length = $$\frac{5\lambda}{4} = 125 \, \mathrm{cm}$$ Height of water required = $$125 - 75 = 50 \, \mathrm{cm}$$

Question 58

Physics · Mechanical Properties of Fluids · Numerical

A liquid of density $750 \, \mathrm{kg/m^3}$ flows smoothly through a horizontal pipe that tapers in cross-sectional area from $A_1 = 1.2 \times 10^{-2} \, \mathrm{m^2}$ to $A_2 = \frac{A_1}{2}$. The pressure difference between the wide and narrow sections of the pipe is $4500 \, \mathrm{Pa}$. The rate of flow of liquid is ______ $\times 10^{-3} \, \mathrm{m^3/s}$.

Answer: 24

Solution

Given $A_2 = \frac{A_1}{2}$. The pressure difference is $P_1 - P_2 = 4500 \, \mathrm{Pa}$. Using Bernoulli's equation: $$P_1 + \frac{1}{2} \rho V_1^2 + \rho gh = P_2 + \frac{1}{2} \rho V_2^2 + \rho gh$$ $$P_1 - P_2 = \frac{1}{2} \rho (V_2^2 - V_1^2) ...(1)$$ And $A_1 V_1 = A_2 V_2$ $$\Rightarrow V_2 = 2V_1 ...(2)$$ Substituting into equation (1): $$4500 = \frac{1}{2} \times 750 \times 3V_1^2$$ Solving for $V_1$: $$V_1 = 2 \, \mathrm{m/s}$$ The volume flow rate is $A_1 V_1 = 24 \times 10^{-3} \, \mathrm{m^3 \, s^{-1}}$

Question 59

Physics · System of Particles and Rotational Motion · Fill in the blank

A uniform disc with mass $M = 4 \, \mathrm{kg}$ and radius $R = 10 \, \mathrm{cm}$ is mounted on a fixed horizontal axle as shown in figure. A block with mass $m = 2 \, \mathrm{kg}$ hangs from a massless cord that is wrapped around the rim of the disc. During the fall of the block, the cord does not slip and there is no friction at the axle. The tension in the cord is _______N. (Take $g = 10 \, \mathrm{ms^{-2}}$)

Answer: 10

Solution

Given the equations: $$2g - T = 2a ...(1)$$ $$TR = \frac{MR^2}{2} \alpha ...(2)$$ $$\alpha = \frac{a}{R} ...(3)$$ From equation (1), we have: $$T = 2a$$ Substituting back into equation (1): $$2g - T = 2a$$ Solving for $T$, we get: $$T = g = 10 \, \mathrm{N}$$

Question 60

Physics · Motion in a Straight Line · Numerical

A car covers $AB$ distance with first one–third at velocity $v_1 \, \mathrm{ms^{-1}}$, second one–third at $v_2 \, \mathrm{ms^{-1}}$ and last one–third at $v_3 \, \mathrm{ms^{-1}}$. If $v_3 = 3v_1$, $v_2 = 2v_1$ and $v_1 = 11 \, \mathrm{ms^{-1}}$ then the average velocity of the car is ________ $\mathrm{ms^{-1}}$.

Answer: 18

Solution

The average velocity is given by the formula: $$ \vec{v} = \frac{Displacement}{time} $$ Let the displacement be $l$. The expression becomes: $$ = \frac{l}{\left( \frac{l}{V_3} + \frac{l}{V_2} + \frac{l}{V_1} \right) \frac{1}{3}} $$ Simplifying further: $$ = \frac{3}{\frac{1}{V_1} + \frac{1}{V_2} + \frac{1}{V_3}} = \frac{3}{\frac{1}{11} + \frac{1}{22} + \frac{1}{33}} $$ The result is: $$ = 18 \, m/s $$

Chemistry

Question 61

Chemistry · Some Basic Concepts of Chemistry · Single correct

Compound A contains 8.7$\%$ Hydrogen, 74$\%$ Carbon and 17.3$\%$ Nitrogen. The molecular formula of the compound is, Given : Atomic masses of C, H and N are 12, 1 and 14 amu respectively. The molar mass of the compound A is 162 $\mathrm{g}$ $\mathrm{mol^{-1}}$.

  1. C_4H_6N_2
  2. C_2H_3N
  3. C_5H_7N
  4. C_{10}H_{14}N_2

Answer: (d)

Solution

C: 74$\%$ $\frac{74}{12}$ = 6.16 $\frac{6.16}{1.23}$ = 5 N: 17.3$\%$ $\frac{17.3}{14}$ = 1.23 $\frac{1.23}{1.23}$ = 1 H: 8.7$\%$ $\frac{8.7}{1}$ = 8.7 $\frac{8.7}{1.23}$ = 7 Empirical formula = $\mathrm{C_5NH_7}$ Empirical weight = 81 Multiplying factor = $\frac{162}{81}$ = 2 Molecular formula = $\mathrm{C_{10}N_2H_{14}}$

Question 62

Chemistry · Structure of Atom · Single correct

Consider the following statements : (A) The principal quantum number ‘n’ is a positive integer with values of ‘n’ = 1, 2, 3, …. (B) The azimuthal quantum number ‘l’ for a given ‘n’ (principal quantum number) can have values as ‘l’ = 0, 1, 2, …. n $(C)$ Magnetic orbital quantum number ‘m’ for a particular ‘l’ (azimuthal quantum number) has (2l + 1) values. (D) ±1/2 are the two possible orientations of electron spin. (E) For l = 5, there will be a total of 9 orbital. Which of the above statements are correct?

  1. $(A), (B)$ and $(C)$
  2. $(A), (C), (D)$ and $(E)$
  3. $(A), (C)$ and $(D)$
  4. $(A), (B), (C)$ and $(D)$

Answer: (c)

Solution

Number of values of $n = 1, 2, 3, \ldots, \infty$. Number of values of $\ell = 0$ to $(n-1)$. Number of values of $m = -\ell$ to $+\ell$. Total values $= 2\ell + 1$. Values of spin $= \pm \frac{1}{2}$. For $\ell = 5$, number of orbitals $= 2\ell + 1 = 11$.

Question 63

Chemistry · Chemical Bonding and Molecular Structure · Single correct

In the structure of $\mathrm{SF}_4$, the lone pair of electrons on S is in.

  1. equatorial position and there are two lone pair-bond pair repulsions at $90^\circ$
  2. equatorial position and there are three lone pair-bond pair repulsions at $90^\circ$
  3. axial position and there are three lone pair-bond pair repulsion at $90^\circ$
  4. axial position and there are two lone pair-bond pair repulsion at $90^\circ$

Answer: (a)

Solution

The molecular geometry is see-saw with hybridization $sp^3d$.

Question 64

Chemistry · Equilibrium · Single correct

A student needs to prepare a buffer solution of propanoic acid and its sodium salt with pH 4. The ratio of $\frac{[\mathrm{CH}_3\mathrm{CH}_2\mathrm{COO}^-]}{[\mathrm{CH}_3\mathrm{CH}_2\mathrm{COOH}]}$ required to make buffer is .......... Given : $K_a(\mathrm{CH}_3\mathrm{CH}_2\mathrm{COOH}) = 1.3 \times 10^{-5}$

  1. 0.03
  2. 0.13
  3. 0.23
  4. 0.33

Answer: (b)

Solution

pH = pK_a + $\log$ $\frac{[Salt]}{[Acid]}$ 4 = 5 - $\log$ 1.3 + $\log$ $\frac{[CH_3CH_2COO^-]}{[CH_3CH_2COOH]}$ $\log$ $\frac{[CH_3CH_2COO^-]}{[CH_3CH_2COOH]}$ = $\log$ 1.3 - 1 = $\log$ $\frac{1.3}{10}$ $\frac{[CH_3CH_2COO^-]}{[CH_3CH_2COOH]}$ = 0.13

Question 65

Chemistry · Co-ordination Compounds · Single correct

Match List-I with List-II. Choose the correct answer from the options given below :

  1. $(A)- (II), (B) - (III), (C) - (IV), (D) - (I)$
  2. $(A)- (II), (B) - (I), (C) - (III), (D) - (IV)$
  3. $(A)- (II), (B) - (III), (C) - (I), (D) - (IV)$
  4. $(A)- (I), (B) - (III), (C) - (II), (D) - (IV)$

Answer: (c)

Solution

Negative charged sol = CdS (II) Macromolecular colloid = starch (III) Positively charged sol = $Fe_2O_3.xH_2O$ (I) Cheese = gel (IV)

Question 66

Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct

Match List-I with List-II. \begin{tabular}{|c|c|} \hline List-I (Oxide) & List-II (Nature) \\ \hline (A) $\mathrm{Cl_2O_7}$ & (I) Amphoteric \\ \hline (B) $\mathrm{Na_2O}$ & (II) Basic \\ \hline (C) $\mathrm{Al_2O_3}$ & (III) Neutral \\ \hline (D) $\mathrm{N_2O}$ & (IV) Acidic \\ \hline \end{tabular} Choose the correct answer from the options given below:

  1. (A) - (IV), (B) - (III), (C) - (I), (D) - (II)
  2. (A) - (IV), (B) - (II), (C) - (I), (D) - (III)
  3. (A) - (II), (B) - (IV), (C) - (III), (D) - (I)
  4. (A) - (I), (B) - (II), (C) - (III), (D) - (IV)

Answer: (b)

Solution

The properties of the given oxides are as follows: $\mathrm{Cr_2O_7}$ is acidic, $\mathrm{Na_2O}$ is basic, $\mathrm{Al_2O_3}$ is amphoteric, and $\mathrm{N_2O}$ is neutral.

Question 67

Chemistry · General Principles and Processes of Isolation of Elements · Single correct

In the metallurgical extraction of copper, following reaction is used: $$\mathrm{FeO} + \mathrm{SiO}_2 \rightarrow \mathrm{FeSiO}_3$$ FeO and FeSiO$_3$ respectively are.

  1. gangue and flux
  2. flux and slag
  3. slag and flux
  4. gangue and slag

Answer: (d)

Solution

FeO = Gangue , FeSiO_3 = Slag

Question 68

Chemistry · Hydrogen · Single correct

Hydrogen has three isotopes : protium ($^1\mathrm{H}$), deuterium ($^2\mathrm{H}$ or D) and tritium ($^3\mathrm{H}$ or T). They have nearly same chemical properties but different physical properties. They differ in

  1. number of protons
  2. atomic number
  3. electronic configuration
  4. atomic mass

Answer: (d)

Solution

They have different neutrons and mass number.

Question 69

Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct

Among the following basic oxide is :

  1. $\mathrm{SO}_3$
  2. $\mathrm{SiO}_2$
  3. $\mathrm{CaO}$
  4. $\mathrm{Al}_2\mathrm{O}_3$

Answer: (c)

Solution

$\mathrm{SO_3}$, $\mathrm{SiO_2} = Acidic$ $\mathrm{CaO} = Basic$ $\mathrm{Al_2O_3} = Amphoteric$

Question 70

Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct

Among the given oxides of nitrogen; $\mathrm{N_2O}$, $\mathrm{N_2O_3}$, $\mathrm{N_2O_4}$ and $\mathrm{N_2O_5}$, the number of compound(s) having $\mathrm{N{-}N}$ bond is :

  1. 1
  2. 2
  3. 3
  4. 4

Answer: (c)

Solution

Question 71

Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct

Which of the following oxoacids of sulphur contains "S" in two different oxidation states?

  1. H_2S_2O_3
  2. H_2S_2O_6
  3. H_2S_2O_7
  4. H_2S_2O_8

Answer: (a)

Solution

Question 72

Chemistry · Environmental Chemistry · Single correct

Correct statement about photo-chemical smog is:

  1. It occurs in humid climate.
  2. It is a mixture of smoke, fog and $\mathrm{SO}_2$
  3. It is reducing smog.
  4. It results from reaction of unsaturated hydrocarbons.

Answer: (d)

Solution

Photochemical smog results from the action of sunlight on unsaturated hydrocarbons and nitrogen oxide.

Question 73

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Single correct

The correct IUPAC name of the following compound is :

  1. 4-methyl-2-nitro-5-oxohept-3-enal
  2. 4-methyl-5-oxo-2-nitrohept-3-enal
  3. 4-methyl-6-nitro-3-oxohept-4-enal
  4. 6-formyl-4-methyl-2-nitrohex-3-enal

Answer: (c)

Solution

4-Methyl-6-nitro-3-oxohept-4-enal

Question 74

Chemistry · Alcohols, Phenols and Ethers · Single correct

The major product (P) of the given reaction is (where, Me is $-CH_3$)

Answer: (c)

Solution

The reaction begins with the protonation of the alcohol group, forming a good leaving group. This leads to the formation of a carbocation after the departure of water. A 1,2-methyl shift occurs to stabilize the carbocation, resulting in a more stable carbocation. Finally, deprotonation leads to the formation of the final product, which is an alkene.

Question 75

Chemistry · Haloalkanes and Haloarenes · Single correct

A $\xrightarrow{(i) \mathrm{Cl_2, \Delta} (ii) \mathrm{CN^-} (iii) \mathrm{H_2O/H^+}}$ 4-Bromophenyl acetic acid. In the above reaction 'A' is

Answer: (c)

Solution

The reaction sequence starts with the bromination of toluene using $\mathrm{Cl_2/\Delta}$ to form benzyl chloride. This is followed by a nucleophilic substitution reaction with $\mathrm{CN^-}$ to form benzyl cyanide. Finally, hydrolysis with $\mathrm{H_3O^+}$ converts the cyanide group to a carboxylic acid, resulting in the formation of phenylacetic acid.

Question 76

Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct

Isobutyraldehyde on reaction with formaldehyde and $K_2CO_3$ gives compound ‘A’. Compound ‘A’ reacts with KCN and yields compound ‘B’, which on hydrolysis gives a stable compound ‘C’. The compound ‘C’ is :

Answer: (c)

Solution

Question 77

Chemistry · Amines · Single correct

With respect to the following reaction, consider the given statements:

  1. o-Nitroaniline and p-nitroaniline are the predominant products
  2. p-Nitroaniline and m-nitroaniline are the predominant products
  3. HNO$_3$ acts as an acid
  4. H$_2$SO$_4$ acts as an acid

Answer: (c)

Solution

Question 78

Chemistry · Polymers · Single correct

Given below are two statements, one is Assertion (A) and other is Reason ( R). Assertion (A): Natural rubber is a linear polymer of isoprene called cis-polyisoprene with elastic properties. Reason ( R): The cis-polyisoprene molecules consist of various chains held together by strong polar interactions with coiled structure. In the light of the above statements, choose the correct one from the options given below:

  1. Both (A) and (R ) are true and ( R) is the correct explanation of (A)
  2. Both (A) and (R ) are true but (R ) is not the correct explanation of (A).
  3. is true but (R ) is false.
  4. is false but (R ) is true.

Answer: (c)

Solution

Natural rubber is a linear polymer of isoprene (2-methyl-1,3-butadiene) and is also called cis-1,4-polyisoprene. The cis-polyisoprene molecules consist of various chains held together by weak Van der Waal's interactions and has a coiled structure.

Question 79

Chemistry · Biomolecules · Single correct

When sugar 'X' is boiled with dilute $\mathrm{H_2SO_4}$ in alcoholic solution, two isomers 'A' and 'B' are formed. 'A' on oxidation with $\mathrm{HNO_3}$ yields saccharic acid where as 'B' is laevorotatory. The compound 'X' is :

  1. Maltose
  2. Sucrose
  3. Lactose
  4. Strach

Answer: (b)

Solution

Question 80

Chemistry · Chemistry in Everyday Life · Single correct

The drug tegamet is :

Answer: (c)

Solution

Tegamet is the brand name of Cimetidine.

Question 81

Chemistry · States of Matter · Numerical

100 $\mathrm{g}$ of an ideal gas is kept in a cylinder of 416 $\mathrm{L}$ volume at $27^\circ$ $\mathrm{C}$ under 1.5 $\mathrm{bar}$ pressure. The molar mass of the gas is _____ $\mathrm{g}$ \, $\mathrm{mol^{-1}}$. (Nearest integer) (Given : R = 0.083 $\mathrm{L}$ \, $\mathrm{bar}$ \, $\mathrm{K^{-1}}$ \, $mol^{-1}$)

Answer: 4

Solution

Given the equation: $$1.5 \times 416 = \frac{100}{M} \times 0.083 \times 300$$ Solving for $M$ gives: $$M = 3.99$$

Question 82

Chemistry · Thermodynamics · Numerical

For combustion of one mole of magnesium in an open container at 300 K and 1 bar pressure, $\Delta_C$ $H^\Theta$ = -601.70 \, $\mathrm{kJ}$ \, $\mathrm{mol}^{-1}$, the magnitude of change in internal energy for the reaction is _____ kJ. (Nearest integer) (Given : R = 8.3 J $K^{-1}$ $mol^{-1}$)

Answer: 600

Solution

The reaction is given by: $$\mathrm{Mg(s) + \frac{1}{2}O_2(g) \rightarrow MgO(s)}$$ The relation is: $$\Delta H = \Delta U + \Delta n_g RT$$ Substituting the values: $$-601.70 \times 10^3 = \Delta U - \frac{1}{2} \times 8.3 \times 300$$ Simplifying: $$-601.70 \, \mathrm{kJ} = \Delta U - 1.245 \, \mathrm{kJ}$$ Therefore: $$\Delta U = -600.455 \, \mathrm{kJ}$$ The answer is 600.

Question 83

Chemistry · Solutions · Numerical

2.5 $\mathrm{g}$ of protein containing only glycine ($\mathrm{C_2H_5NO_2}$) is dissolved in water to make 500 $\mathrm{mL}$ of solution. The osmotic pressure of this solution at 300 $\mathrm{K}$ is found to be 5.03 $\times 10^{-3}$ $\mathrm{bar}$. The total number of glycine units present in the protein is (Given: R=0.083 L bar $k^{-1}$ $mol^{-1}$)

Answer: 330

Solution

Given $\pi = CRT$. $$5.03 \times 10^{-3} = C \times 0.083 \times 300$$ $$C = 0.202 \times 10^{-3} \, \mathrm{M}$$ Moles of protein $= 0.202 \times 10^{-3} \times 0.5$ $$= 10^{-4} \times 1.01$$ $$1.01 \times 10^{-4} = \frac{2.5}{M}$$ M (molar mass of protein) $= 24752$ Therefore, the number of glycine units $= \frac{24752}{75} = 330.03$

Question 84

Chemistry · Electrochemistry · Numerical

For the given reactions $$\mathrm{Sn^{2+} + 2e^- \rightarrow Sn}$$ $$\mathrm{Sn^{4+} + 4e^- \rightarrow Sn}$$ The electrode potentials are; $E^\circ_{\mathrm{Sn^{2+}/Sn}} = -0.140 \, \mathrm{V}$ and $E^\circ_{\mathrm{Sn^{4+}/Sn}} = 0.010 \, \mathrm{V}$. The magnitude of standard electrode potential for $\mathrm{Sn^{4+}/Sn^{2+}}$ i.e. $E^\circ_{\mathrm{Sn^{4+}/Sn^{2+}}}$ is ______ $\times \, 10^{-2} \, \mathrm{V}$. (Nearest integer)

Answer: 16

Solution

For the reaction $\mathrm{Sn^{2+} + 2e^- \rightarrow Sn}$, $\Delta G_1^0 = +2 \times 0.140 \times \mathrm{F}$. For the reaction $\mathrm{Sn^{4+} + 4e^- \rightarrow Sn}$, $\Delta G_2^0 = -4 \times 0.01 \times \mathrm{F}$. For the reaction $\mathrm{Sn^{4+} + 2e^- \rightarrow Sn^{2+}}$, $\Delta G_3^0 = -2 \times E^0_{\mathrm{Sn^{4+}/Sn^{2+}}} \times \mathrm{F}$. We have $\Delta G_3^0 = \Delta G_2^0 - \Delta G_1^0$. Therefore, $-2 \times E^0 \times \mathrm{F} = -(0.04 + 0.28) \times \mathrm{F}$. Solving for $E^0$, we get $E^0 = 0.16 volt = 16 \times 10^{-2} V$.

Question 85

Chemistry · Chemical Kinetics and Nuclear Chemistry · Numerical

A radioactive element has a half life of 200 days. The percentage of original activity remaining after 83 days is _______. (Nearest integer) (Given : antilog 0.125 = 1.333, antilog 0.693 = 4.93)

Answer: 75

Solution

Given the equation: $$t = \frac{t_{1/2}}{0.3} \log \frac{[A]_0}{[A]_t}$$ Substitute the values: $$83 = \frac{200}{0.3} \log \frac{[A]_0}{[A]_t}$$ Solve for the logarithm: $$0.125 = \log \frac{[A]_0}{[A]_t}$$ Convert the logarithm to a fraction: $$\frac{[A]_0}{[A]_t} = 1.333 \approx \frac{4}{3}$$ Calculate the percentage: $$\therefore \frac{[A]_t}{[A]_0} \times 100 = \frac{3}{4} \times 100 = 75\%$$

Question 86

Chemistry · Co-ordination Compounds · Numerical

[$\mathrm{Fe(CN)}_6]^{4-}$ [$\mathrm{Fe(CN)}_6]^{3-}$ [$\mathrm{Ti(CN)}_6]^{3-}$ [$\mathrm{Ni(CN)}_4]^{2-}$ [$\mathrm{Co(CN)}_6]^{3-}$ Among the given complexes, number of paramagnetic complexes is .

Answer: 2

Solution

The complex $[\mathrm{Fe(CN)_6}]^{4-}$ is diamagnetic. The complex $[\mathrm{Fe(CN)_6}]^{3-}$ is paramagnetic with 1 unpaired electron. The complex $[\mathrm{Ti(CN)_6}]^{3-}$ is paramagnetic with 1 unpaired electron. The complex $[\mathrm{Ni(CN)_4}]^{2-}$ is diamagnetic. The complex $[\mathrm{Co(CN)_6}]^{3-}$ is diamagnetic.

Question 87

Chemistry · Co-ordination Compounds · Numerical

Number of complex(es) which will exist in cis-trans is/are

  1. CoCl$_3\cdot 4$ NH$_3$
  2. CoCl$_3\cdot 5$NH$_3$
  3. CoCl$_3\cdot 6$NH$_3$
  4. CoCl(NO$_3$)$_2\cdot 5$NH$_3$

Answer: a

Solution

(a) CoCl$_3$·4 NH$_3$ = [Co(NH$_3$)$_4$ Cl$_2$]Cl Can exhibit G.I. (b) CoCl$_3$·5NH$_3$ = [Co(NH$_3$)$_5$ Cl]Cl$_2$ Can't exhibit G.I. (c) CoCl$_3$·6NH$_3$ = [Co(NH$_3$)$_6$]Cl$_3$ Can't exhibit G.I. (d) CoCl(NO$_3$)$_2$·5NH$_3$ = [Co(NH$_3$)$_5$ Cl](NO$_3$)$_2$ OR = [Co(NH$_3$)$_5$ (NO$_3$)]Cl(NO$_3$) Both can't exhibit G.I.

Question 88

Chemistry · Some Basic Concepts of Chemistry · Numerical

The complete combustion of $0.492\ \mathrm{g}$ of an organic compound containing 'C', 'H' and 'O' gives $0.793\ \mathrm{g}$ of $\mathrm{CO_2}$ and $0.442\ \mathrm{g}$ of $\mathrm{H_2O}$. The percentage of oxygen composition in the organic compound is ________. (nearest integer)

Answer: 46

Solution

Mole of CO$_2$ = Moles of C = $\frac{0.793}{44}$ Weight of 'C' = $\frac{0.793}{44} \times 12 = 0.216$ gm Moles of 'H' = $\frac{0.442}{18} \times 2$ Weight of 'H' = $\frac{0.442}{18} \times 2 \times 1 = 0.049$ gm Therefore, Weight of 'O' = $0.492 - 0.216 - 0.049 = 0.227$ gm % of 'O' = $\frac{0.227}{0.492} \times 100 = 46.13\%$

Question 89

Chemistry · Alcohols, Phenols and Ethers · Numerical

The major product of the following reaction contains bromine atom(s).

Answer: 1

Solution

No. of Br atoms = 1

Question 90

Chemistry · Redox Reactions · Numerical

$0.01\,\mathrm{M}$ $\mathrm{KMnO_4}$ solution was added to $20.0\,\mathrm{mL}$ of $0.05\,\mathrm{M}$ Mohr's salt solution through a burette. The initial reading of $50\,\mathrm{mL}$ burette is zero. The volume of $\mathrm{KMnO_4}$ solution left in the burette after the end point is \_\_\_\_ $\mathrm{mL}$. (nearest integer)

Answer: 30

Solution

Given $N_1 V_1 = N_2 V_2$. $$0.01 \times 5 \times V_1 = 0.05 \times 1 \times 20$$ $V_1 = 20 \, \mathrm{ml}$ used. Therefore, volume left $= 50 - 20 = 30 \, \mathrm{ml}$.