JEE Main 25 July 2022 Shift 2 question paper with solutions

JEE Main 25 July 2022 Shift 2: all 90 questions in paper order (Maths, Physics, Chemistry) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.

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Maths

Question 1

Maths · Complex Numbers and Quadratic Equations · Single correct

For $z \in \mathbb{C}$ if the minimum value of $$\left( |z - 3\sqrt{2}| + |z - p\sqrt{2}i| \right)$$ is $5\sqrt{2}$, then a value of $p$ is

  1. 3
  2. $\frac{7}{2}$
  3. 4
  4. $\frac{9}{2}$

Answer: (c)

Solution

4

Question 2

Maths · Determinants · Single correct

The number of real values $\lambda$, such that the system of linear equations $$2x - 3y + 5z = 9$$ $$x + 3y - z = -18$$ $$3x - y + (\lambda^2 - |\lambda|)z = 16$$ has no solution, is :-

  1. 0
  2. 1
  3. 2
  4. 4

Answer: (c)

Solution

2

Question 3

Maths · Permutations and Combinations · Single correct

The number of bijective functions $f : \{1, 3, 5, 7, \ldots, 99\} \to \{2, 4, 6, 8, \ldots, 100\}$, such that $f(3) \geq f(9) \geq f(15) \geq f(21) \geq \ldots \geq f(99)$, is

  1. $^{50}P_{17}$
  2. $^{50}P_{33}$
  3. $33! \times 17!$
  4. $\frac{50!}{2}$

Answer: (b)

Solution

{ "rawText": "", "answer": "b" }

Question 4

Maths · Binomial Theorem · Single correct

The remainder when $(11)^{1011} + (1011)^{11}$ is divided by 9 is

  1. 1
  2. 4
  3. 6
  4. 8

Answer: (d)

Solution

```json { "rawText": "", "answer": "d" } ```

Question 5

Maths · Sequences and Series · Single correct

The sum $$\sum_{n=1}^{21} \frac{3}{(4n-1)(4n+3)}$$ is equal to

  1. $\frac{7}{87}$
  2. $\frac{7}{29}$
  3. $\frac{14}{87}$
  4. $\frac{21}{29}$

Answer: (b)

Solution

{ "rawText": "", "answer": "b" }

Question 6

Maths · Limits and Derivatives · Single correct

$$\lim_{x \to \frac{\pi}{4}} \frac{8\sqrt{2} - (\cos x + \sin x)^7}{\sqrt{2} - \sqrt{2} \sin 2x}$$ is equal to

  1. 14
  2. 7
  3. 14$\sqrt{2}$
  4. 7$\sqrt{2}$
Solution

Answer is A

Question 7

Maths · Sequences and Series · Single correct

\[ \lim_{n\to\infty}\frac{1}{n} \left( \frac{1}{\sqrt{1-\frac{1}{2^n}}} + \frac{1}{\sqrt{1-\frac{2}{2^n}}} + \frac{1}{\sqrt{1-\frac{3}{2^n}}} +\cdots+ \frac{1}{\sqrt{1-\frac{2^n-1}{2^n}}} \right) \]

  1. $\frac{1}{2}$
  2. 1
  3. 2
  4. -2

Answer: (c)

Solution

2

Question 8

Maths · Probability · Single correct

If A and B are two events such that $$\mathrm{P}(A) = \frac{1}{3}, \mathrm{P}(B) = \frac{1}{5} and \mathrm{P}(A \cup B) = \frac{1}{2},$$ then $\mathrm{P}(A | B') + \mathrm{P}(B | A')$ is equal to

  1. $\frac{3}{4}$
  2. $\frac{5}{8}$
  3. $\frac{5}{4}$
  4. $\frac{7}{8}$

Answer: (b)

Solution

B

Question 9

Maths · Integrals · Single correct

Let [t] denote the greatest integer less than or equal to t. Then the value of the integral $$\int_{-3}^{101} ( [\sin(\pi x)] + e^{[\cos(2 \pi x)]} ) \, dx$$ is equal to

  1. $\frac{52(1-e)}{e}$
  2. $\frac{52}{e}$
  3. $\frac{52(2+e)}{e}$
  4. $\frac{104}{e}$

Answer: (b)

Solution

$\frac{52}{e}$

Question 10

Maths · Straight Lines and Pair of Straight Lines · Single correct

Let the point P $(\alpha, \beta)$ be at a unit distance from each of the two lines $L_1 : 3x - 4y + 12 = 0$, and $L_2 : 8x + 6y + 11 = 0$. If P lies below $L_1$ and above $L_2$, then $100\,(\alpha + \beta)$ is equal to

  1. $-14$
  2. $42$
  3. $-22$
  4. $14$

Answer: (d)

Solution

{ "rawText": "", "answer": "d" }

Question 11

Maths · Differential Equations · Single correct

Let a smooth curve $y = f(x)$ be such that the slope of the tangent at any point $(x, y)$ on it is directly proportional to $\($ ( $\frac{-y}{x}$ ) $\)$. If the curve passes through the point $(1, 2)$ and $(8, 1)$, then \[ |\, y\!(\frac{1}{8})| \] is equal to

  1. $2 \log_e 2$
  2. $4$
  3. $1$
  4. $4 \log_e 2$

Answer: (b)

Solution

{ "rawText": "", "answer": "b" }

Question 12

Maths · Conic Sections · Single correct

If the ellipse $\frac{x^2}{a^2} + \frac{y^2}{b^2} = 1$ meets the line $\frac{x}{7} + \frac{y}{2\sqrt{6}} = 1$ on the x-axis and the line $\frac{x}{7} - \frac{y}{2\sqrt{6}} = 1$ on the y-axis, then the eccentricity of the ellipse is

  1. $\frac{5}{7}$
  2. $\frac{2\sqrt{6}}{7}$
  3. $\frac{3}{7}$
  4. $\frac{2\sqrt{5}}{7}$

Answer: (a)

Solution

{ "rawText": "", "answer": "a" }

Question 13

Maths · Conic Sections · Single correct

The tangents at the point A(1, 3) and B(1, -1) on the parabola $y^2 - 2x - 2y = 1$ meet at the point P. Then the area (in unit$^2$) of the triangle PAB is :-

  1. 4
  2. 6
  3. 7
  4. 8

Answer: (d)

Solution

D

Question 14

Maths · Conic Sections · Single correct

Let the foci of the ellipse $\frac{x^2}{16} + \frac{y^2}{7} = 1$ and the hyperbola $\frac{x^2}{144} - \frac{y^2}{\alpha} = \frac{1}{25}$ coincide. Then the length of the latus rectum of the hyperbola is:-

  1. $\frac{32}{9}$
  2. $\frac{18}{5}$
  3. $\frac{27}{4}$
  4. $\frac{27}{10}$
Solution

answer is D

Question 15

Maths · Three Dimensional Geometry · Single correct

A plane E is perpendicular to the two planes $2x - 2y + z = 0$ and $x - y + 2z = 4$, and passes through the point $P(1, -1, 1)$. If the distance of the plane E from the point $Q(a, a, 2)$ is $3\sqrt{2}$, then $(PQ)^2$ is equal to

  1. 9
  2. 12
  3. 21
  4. 33

Answer: (c)

Solution

{ "rawText": "", "answer": "c" }

Question 16

Maths · Three Dimensional Geometry · Single correct

The shortest distance between the lines $\($ $\frac{x+7}{-6}$ = $\frac{y-6}{7}$ = z $\)$ and $\($ $\frac{7-x}{2}$ = y-2 = z-6 $\)$ is

  1. $2\sqrt{29}$
  2. 1
  3. $\sqrt{\frac{37}{29}}$
  4. $\frac{\sqrt{29}}{2}$

Answer: (a)

Solution

{ "rawText": "", "answer": "a" }

Question 17

Maths · Vector Algebra · Single correct

Let $\vec{a} = \hat{i} - \hat{j} + 2\hat{k}$ and $\vec{b}$ be a vector such that $\vec{a} \times \vec{b} = 2\hat{i} - \hat{k}$ and $\vec{a} \cdot \vec{b} = 3$. Then the projection of $\vec{b}$ on the vector $\vec{a} - \vec{b}$ is :-

  1. $\frac{2}{\sqrt{21}}$
  2. $2\sqrt{\frac{3}{7}}$
  3. $\frac{2}{3}\sqrt{\frac{7}{3}}$
  4. $\frac{2}{3}$

Answer: (a)

Solution

$\frac{2}{\sqrt{21}}$

Question 18

Maths · Statistics · Single correct

If the mean deviation about median for the number 3, 5, 7, 2k, 12, 16, 21, 24 arranged in the ascending order, is 6 then the median is

  1. 11.5
  2. 10.5
  3. 12
  4. 11

Answer: (d)

Solution

{ "rawText": "", "answer": "d" }

Question 19

Maths · Trigonometric Functions · Single correct

2 $\sin(\frac{\pi}{22}) \sin(\frac{3\pi}{22}) \sin(\frac{5\pi}{22}) \sin(\frac{7\pi}{22})$ $\sin(\frac{9\pi}{22})$ is equal to

  1. $\frac{3}{16}$
  2. $\frac{1}{16}$
  3. $\frac{1}{32}$
  4. $\frac{9}{32}$

Answer: (b)

Solution

$\frac{1}{16}$

Question 20

Maths · Mathematical Reasoning · Single correct

Consider the following statements : P : Ramu is intelligent Q : Ramu is rich R : Ramu is not honest The negation of the statement "Ramu is intelligent and honest if and only if Ramu is not rich" can be expressed as :

  1. $((P\land(\sim R))\land Q)$ $\land((\sim Q)\land((\sim P)\lor R))$
  2. $((P\land R)\land Q)$ $\lor((\sim Q)\land((\sim P)\lor(\sim R)))$
  3. $((P\land R)\land Q)$ $\land((\sim Q)\land((\sim P)\lor(\sim R)))$
  4. $((P\land(\sim R))\land Q)$ $\lor((\sim Q)\land((\sim P)\lor R))$
Solution

Answer is D

Question 21

Maths · Sets · Numerical

Let $A = \{1, 2, 3, 4, 5, 6, 7\}$. Define $B = \{T \subseteq A : \text{either } 1 \notin T \text{ or } 2 \in T\}$ and $C = \{T \subseteq A : \text{the sum of all the elements of } T \text{ is a prime number}\}$. Then the number of elements in the set $B \cup C$ is

Answer: 107

Solution

Q1 (107) (107)

Question 22

Maths · Complex Numbers and Quadratic Equations · Fill in the blank

Let f(x) be a quadratic polynomial with leading coefficient 1 such that f(0) = p, p $\neq$ 0 and f(1) = $\frac{1}{3}$. If the equation f(x) = 0 and fofofof(x) = 0 have a common real root, then f(-3) is equal to....................

Answer: 25

Question 23

Maths · Matrices · Numerical

Let $A = \begin{bmatrix} 1 & a & a \\ 0 & 1 & b \\ 0 & 0 & 1 \end{bmatrix}, a, b \in \mathbb{R}$. If for some $n \in \mathbb{N}$, $$A^n = \begin{bmatrix} 1 & 48 & 2160 \\ 0 & 1 & 96 \\ 0 & 0 & 1 \end{bmatrix}$$ then $n + a + b$ is equal to

Answer: 24

Solution

Answer is D

Question 24

Maths · Applications of Derivatives · Numerical

The sum of the maximum and minimum values of the function $f(x) = |5x - 7| + [x^2 + 2x]$ is the interval $\left[ \frac{5}{4}, 2 \right]$, where $[t]$ is the greatest integer $\leq t$ is ____________

Answer: 15

Solution

{ "rawText": "", "answer": "" }

Question 25

Maths · Differential Equations · Numerical

Let y = y(x) be the solution of the differential equation $\frac{dy}{dx} = \frac{4y^3 + 2yx^2}{3xy^2 + x^3}$, $y(1) = 1$. If for some $n \in \mathbb{N}, y(2) \in [n-1, n)$, then n is equal to

Answer: 3

Solution

{ "rawText": "", "answer": "3" }

Question 26

Maths · Integrals · Numerical

Let f be a twice differentiable function on R. If $f'(0) = 4$ and $$f(x) + \int_{0}^{x} (x-t) f'(t) \, dt = (e^{2x} + e^{-2x}) \cos 2x + \frac{2}{a} x,$$ then $(2a + 1)^5 \, a^2$ is equal to

Answer: 8

Question 27

Maths · Integrals · Numerical

Let $a_n = \int_{-1}^{n} \left( 1 + \frac{x}{2} + \frac{x^2}{3} + \frac{x^3}{4} + \ldots + \frac{x^{n-1}}{n} \right) \, dx$ for $n \in \mathbb{N}$. Then the sum of all the elements of the set $\{ n \in \mathbb{N} : a_n \in (2,30) \}$ is

Answer: 5

Question 28

Maths · Conic Sections · Numerical

If the circles $x^2 + y^2 + 6x + 8y + 16 = 0$ and $x^2 + y^2 + 2(3 - \sqrt{3})x + x + 2(4 - \sqrt{6})y = k + 6\sqrt{3} + 8\sqrt{6}, k > 0$, touch internally at the point $P(\alpha, \beta)$, then $(\alpha + \sqrt{3})^2 + (\beta + \sqrt{6})^2$ is equal to

Answer: 25

Solution

25

Question 29

Maths · Applications of Derivatives · Numerical

Let the area enclosed by the x-axis, and the tangent and normal drawn to the curve $4x^3 - 3xy^2 + 6x^2 - 5xy - 8y^2 + 9x + 14 = 0$ at the point $(-2, 3)$ be $A$. Then $8A$ is equal to

Answer: 170

Solution

(170)

Question 30

Maths · Inverse Trigonometric Functions · Numerical

Let $x = \sin(2 \tan^{-1} \alpha)$ and $y = \sin\left(\frac{1}{2} \tan^{-1} \frac{4}{3}\right)$. If $S = \{\alpha \in \mathbb{R} : y^2 = 1-x\}$, then $\sum_{\alpha \in S} 16\alpha^3$ is equal to

Answer: 130

Solution

answer is 130

Physics

Question 31

Physics · Current Electricity · Single correct

In AM modulation, a signal is modulated on a carrier wave such that maximum and minimum amplitude are found to be 6V and 2V respectively. The modulation index is

  1. 100%
  2. 80%
  3. 60%
  4. 50%

Answer: (d)

Solution

The modulation index is given by $$\frac{V_{max} - V_{min}}{V_{max} + V_{min}} \times 100\%$$ Substituting the values: $$= \frac{6 - 2}{6 + 2} \times 100\% = 50\%$$

Question 32

Physics · Moving Charges and Magnetism · Single correct

The electric current in a circular coil of 2 turns produces a magnetic induction $B_1$ at its centre. The coil is unwound and is rewound into a circular coil of 5 turns and the same current produces a magnetic induction $B_2$ at its centre. The ratio of $\frac{B_2}{B_1}$ is :

  1. $\frac{5}{2}$
  2. $\frac{25}{4}$
  3. $\frac{5}{4}$
  4. $\frac{25}{2}$

Answer: (b)

Solution

Given $B = \frac{N \mu_0 i}{2R}$. $B_1 = \frac{N_1 \mu_0 i}{2R_1}$. For $N_2 = 5$. Radius of coil $= R_2 = \frac{N_1 \times R_1}{N_2}$. $B_2 = \frac{N_2 \mu_0 i}{R_2}$. $$\frac{B_2}{B_1} = \frac{N_2}{N_1} \frac{R_1}{R_2} = \frac{N_2}{N_1} \times \frac{N_2}{N_1}; \frac{B_2}{B_1} = \frac{25}{4}$$

Question 33

Physics · Mechanical Properties of Fluids · Single correct

A drop of liquid of density $\rho$ is floating half immersed in a liquid of density $\sigma$ and surface tension $7.5 \times 10^{-4} \, \mathrm{N/cm}^{-1}$. The radius of drop in cm will be : (Take : $g = 10 \, \mathrm{m/s}^2$)

  1. $\frac{15}{\sqrt{2\rho - \sigma}}$
  2. $\frac{15}{\sqrt{\rho - \sigma}}$
  3. $\frac{3}{2\sqrt{\rho - \sigma}}$
  4. $\frac{3}{20\sqrt{2\rho - \sigma}}$

Answer: (a)

Solution

Buoyant force plus surface tension equals $mg$. $$\frac{\sigma V}{2} g + 2 \pi R T = \rho V g$$ $$2 \pi R T = \frac{(2 \rho - \sigma)}{2} \frac{4}{3} \pi R^3 g; \left[ V = \frac{4}{3} \pi R^3 \right]$$ $$R^3 = \frac{3 T}{(2 \rho - \sigma) g} \implies R = \sqrt{\frac{3 \times 7.5 \times 10^{-2} \, \mathrm{N} \, \mathrm{m}^{-1}}{(2 \rho - \sigma) \times 10}}$$ $$R = \frac{3}{20 \sqrt{(2 \rho - \sigma)}} m = \frac{15}{\sqrt{2 \rho - \sigma}} \, \mathrm{cm}$$

Question 34

Physics · Laws of Motion · Single correct

Two billiard balls of mass 0.05 kg each moving in opposite directions with 10 $\mathrm{ms}^{-1}$ collide and rebound with the same speed. If the time duration of contact is t = 0.005 $\mathrm{s}$, then what is the force exerted on the ball due to each other?

  1. 100 $\mathrm{N}$
  2. 200 $\mathrm{N}$
  3. 300 $\mathrm{N}$
  4. 400 $\mathrm{N}$

Answer: (b)

Solution

Change in momentum of any one ball $$|\Delta \vec{P}| = 2 \times 0.05 \times 10$$ $$|\Delta \vec{P}| = 1$$ $$|\vec{F}_{av}| = \frac{|\Delta \vec{P}|}{\Delta t}$$ $$F_{av} = 200 \, \mathrm{N}$$

Question 35

Physics · Laws of Motion · Single correct

For a free body diagram shown in the figure, the four forces are applied in the 'x' and 'y' directions. What additional force must be applied and at what angle with positive x-axis so that the net acceleration of body is zero?

  1. $\sqrt{2} \, \mathrm{N}, \, 45^\circ$
  2. $\sqrt{2} \, \mathrm{N}, \, 135^\circ$
  3. $\frac{2}{\sqrt{3}} \, \mathrm{N}, \, 30^\circ$
  4. $2 \, \mathrm{N}, \, 45^\circ$

Answer: (a)

Solution

Let addition force required is $\vec{F}$. $$\vec{F} + 5\hat{i} - 6\hat{i} + 7\hat{j} - 8\hat{j} = 0$$ $$\vec{F} = \hat{i} + \hat{j}, \; |\vec{F}| = \sqrt{2}$$ Angle with x-axis: $\tan \theta = \frac{y component}{x component} = \frac{1}{1}$ $\theta = 45^\circ$

Question 36

Physics · Electrostatic Potential and Capacitance · Single correct

Capacitance of an isolated conducting sphere of radius $R_1$ becomes $n$ times when it is enclosed by a concentric conducting sphere of radius $R_2$ connected to earth. The ratio of their radii $\left( \frac{R_2}{R_1} \right)$ is:

  1. $\frac{n}{n-1}$
  2. $\frac{2n}{2n+1}$
  3. $\frac{n+1}{n}$
  4. $\frac{2n+1}{n}$

Answer: (a)

Solution

Capacitance of isolated conducting sphere is $4\pi \varepsilon_0 R_1$. By enclosing inside another sphere of radius $R_2$, the new capacitance is $$\frac{4\pi \varepsilon_0 R_1 R_2}{(R_2 - R_1)}.$$ Given: $$\frac{4\pi \varepsilon_0 R_1 R_2}{(R_2 - R_1)} = n \times 4\pi \varepsilon_0 R_1$$ which implies $$\frac{R_2}{(R_2 - R_1)} = n \implies \frac{R_2}{R_1} - 1 = n$$ leading to $$\frac{R_2}{R_1} = n + 1.$$ Therefore, $$\frac{R_2}{R_1} = \frac{n}{(n-1)}.$$

Question 37

Physics · Dual Nature of Radiation and Matter · Single correct

The ratio of wavelengths of proton and deuteron accelerated by potential $V_p$ and $V_d$ is $1 : \sqrt{2}$. Then, the ratio of $V_p$ to $V_d$ will be

  1. 1 : 1
  2. $\sqrt{2}$ : 1
  3. 2 : 1
  4. 4 : 1

Answer: (d)

Solution

Kinetic energy gained by a charged particle accelerated by a potential $V$ is $qV$. KE = $qV$ $$\Rightarrow \frac{p^2}{2m} = qV \Rightarrow p = \sqrt{2mqV}$$ $$p = \frac{h}{\lambda}, thus \lambda = \frac{h}{\sqrt{2mqV}}$$ Now $$\frac{\lambda_p}{\lambda_d} = \sqrt{\frac{m_d V_d}{m_p V_p}}$$ $$\Rightarrow \frac{1}{\sqrt{2}} = \sqrt{\frac{2V_d}{V_p}} \Rightarrow \frac{V_p}{V_d} = 4$$

Question 38

Physics · Ray Optics and Optical Instruments · Single correct

For an object placed at a distance 2.4 m from a lens, a sharp focused image is observed on a screen placed at a distance 12 cm from the lens. A glass plate of refractive index 1.5 and thickness 1 cm is introduced between lens and screen such that the glass plate plane faces parallel to the screen. By what distance should the object be shifted so that a sharp focused image is observed again on the screen?

  1. 0.8 m
  2. 3.2 m
  3. 1.2 m
  4. 5.6 m

Answer: (b)

Solution

Applying lens formula $$\frac{1}{0.12} + \frac{1}{2.4} = \frac{1}{f} \implies \frac{1}{f} = \frac{210}{24}$$ Upon putting the glass slab, shift of image is $$\Delta x = t \left(1 - \frac{1}{\mu}\right) = \frac{1}{3} \, cm$$ Now $v = 12 - \frac{1}{3} = \frac{35}{3} \, cm$ Again apply lens formula $$\frac{1}{0.12} + \frac{1}{u} = \frac{1}{f} = \frac{210}{24}$$ Solving $u = -5.6 \, m$ Thus shift of object is $$5.6 - 2.4 = 3.2 \, m$$

Question 39

Physics · Electromagnetic Waves · Single correct

Light wave traveling in air along x-direction is given by $E_y = 540 \sin \pi \times 10^4(x - ct) \, \mathrm{Vm}^{-1}$. Then, the peak value of magnetic field of wave will be (Given $c = 3 \times 10^8 \, \mathrm{ms}^{-1}$)

  1. $18 \times 10^{-7}\,\mathrm{T}$
  2. $54 \times 10^{-7}\,\mathrm{T}$
  3. $54 \times 10^{-8}\,\mathrm{T}$
  4. $18 \times 10^{-8}\,\mathrm{T}$

Answer: (a)

Solution

Given $E_y = 540 \sin \pi \times 10^4 (x - ct) \, \mathrm{Vm^{-1}}$. $E_0 = 540 \, \mathrm{Vm^{-1}}$. $$B_0 = \frac{E_0}{C} = \frac{540}{3 \times 10^8} = 18 \times 10^{-7} \, \mathrm{T}$$

Question 40

Physics · Alternating Current · Single correct

When you walk through a metal detector carrying a metal object in your pocket, it raises an alarm. This phenomenon works on

  1. Electromagnetic induction
  2. Resonance in ac circuits
  3. Mutual induction in ac circuits
  4. interference of electromagnetic waves

Answer: (b)

Solution

Metal detector works on the principle of transmitting an electromagnetic signal and analyses a return signal from the target. So it works on the principle of resonance in AC circuit.

Question 41

Physics · Magnetism and Matter · Single correct

An electron with energy 0.1 keV moves at right angle to the earth's magnetic field of $1 \times 10^{-4} \, \mathrm{Wbm}^{-2}$. The frequency of revolution of the electron will be (Take mass of electron = $9.0 \times 10^{-31} \, \mathrm{kg}$)

  1. 1.6 $\times$ 10^{5} $\mathrm{Hz}$
  2. 5.6 $\times$ 10^{5} $\mathrm{Hz}$
  3. 2.8 $\times$ 10^{6} $\mathrm{Hz}$
  4. 1.8 $\times$ 10^{6} $\mathrm{Hz}$

Answer: (c)

Solution

The frequency $f$ is given by the equation $$f = \frac{1}{T} = \frac{eB}{2\pi m}$$ where $e$ is the charge, $B$ is the magnetic field, and $m$ is the mass. Substituting the given values, we have $$f = \frac{1.6 \times 10^{-19} \times 10^{-4}}{2\pi \times 9 \times 10^{-31}} = 2.8 \times 10^{6} \, \mathrm{Hz}$$

Question 42

Physics · Current Electricity · Single correct

A current of 15 $\mathrm{mA}$ flows in the circuit as shown in figure. The value of potential difference between the points A and B will be

  1. 50V
  2. 75V
  3. 150V
  4. 275V

Answer: (d)

Solution

Given $i = 15 \, \mathrm{mA}$. Calculate $i_1$ using the current division rule: $$i_1 = \frac{5}{10 + 5} \times 15 \, \mathrm{mA} = 5 \, \mathrm{mA}$$ Using Kirchhoff's voltage law: $$V_A - 5i - 10i_1 - 10i = V_B$$ Substitute the values: $$V_A - V_B = 75 + 50 + 150 = 275 \, \mathrm{V}$$

Question 43

Physics · Oscillations · Single correct

The length of a seconds pendulum at a height $h = 2R$ from earth surface will be: (Given: $R$ = Radius of earth and acceleration due to gravity at the surface of earth $g = \pi^2 \, \mathrm{m/s^2}$)

  1. $\frac{2}{9} \, \mathrm{m}$
  2. $\frac{4}{9} \, \mathrm{m}$
  3. $\frac{8}{9} \, \mathrm{m}$
  4. $\frac{1}{9} \, \mathrm{m}$

Answer: (d)

Solution

Given $T = 2\pi \sqrt{\frac{L}{g}}$, $g' = \frac{GM}{9R^2} = \frac{g}{9} = \frac{\pi^2}{9}$. Then, $$2 = 2\pi \sqrt{\frac{L}{\pi^2}} \times 9$$ This implies $$1 = \pi \sqrt{L} \times \frac{3}{\pi}$$ Therefore, $L = \frac{1}{9} \, \mathrm{m}$.

Question 44

Physics · Kinetic Theory · Single correct

Sound travels in a mixture of two moles of helium and $n$ moles of hydrogen. If rms speed of gas molecules in the mixture is $\sqrt{2}$ times the speed of sound, then the value of $n$ will be

  1. 1
  2. 2
  3. 3
  4. 4

Answer: (b)

Solution

Given $v_s = \sqrt{\frac{\gamma RT}{M}}$ and $v_{rms} = \sqrt{\frac{3RT}{M}}$. The ratio $\frac{v_s}{v_{rms}} = \frac{\sqrt{\frac{\gamma}{3}}}{\sqrt{1}} = \frac{1}{\sqrt{2}} \implies \frac{\gamma}{3} = \frac{1}{2} \implies \gamma = \frac{3}{2}$. We have $\gamma = 1 + \frac{2}{f_{mix}}$. For $f_{mix}$, $f_{mix} = \frac{2 \times 3 + n \times 5}{n + 2} = \frac{6 + n \times 5}{n + 2}$. Thus, $\gamma = 1 + \frac{2(n + 2)}{6 + n \times 5} = \frac{6 + 5n + 2n + 4}{6 + 5n}$. This simplifies to $\gamma = \frac{7n + 10}{6 + 5n} = \frac{3}{2}$. Solving $14n + 20 = 18 + 15n$ gives $n = 2$.

Question 45

Physics · Thermodynamics · Single correct

Let $\eta_1$ is the efficiency of an engine at $T_1 = 447^\circ C$ and $T_2 = 147^\circ C$ while $\eta_2$ is the efficiency at $T_1 = 947^\circ C$ and $T_2 = 47^\circ C$. The ratio $\frac{\eta_1}{\eta_2}$ will be:

  1. 0.41
  2. 0.56
  3. 0.73
  4. 0.70

Answer: (b)

Solution

Efficiency $\eta = 1 - \frac{T_L}{T_H}$ $$\eta_1 = 1 - \frac{147 + 273}{447 + 273} = 1 - \frac{420}{720}$$ $$\eta_1 = \frac{300}{720}$$ $$\eta_2 = 1 - \frac{47 + 273}{947 + 273} = 1 - \frac{320}{1220}$$ $$\eta_2 = \frac{900}{1220}$$ $$\frac{\eta_1}{\eta_2} = \frac{300}{720} \times \frac{1220}{900} = \frac{122}{72 \times 3}$$ $$\frac{\eta_1}{\eta_2} = 0.56$$

Question 46

Physics · Gravitation · Single correct

An object is taken to a height above the surface of earth at a distance $\frac{5}{4} R$ from the centre of the earth. Where radius of earth, $R = 6400 \, \mathrm{km}$. The percentage decrease in the weight of the object will be

  1. 36$\%$
  2. 50$\%$
  3. 64$\%$
  4. 25$\%$

Answer: (a)

Solution

Given $g_{eff} = \frac{g}{\left(1 + \frac{h}{R}\right)^2}$; $g_{eff} = \frac{g}{\left(1 + \frac{1}{4}\right)^2} = \frac{16g}{25}$. The change is $\frac{g_{eff} - g}{g} \times 100 = \frac{16}{25} - 1 \times 100$. $$= \frac{-9}{25} \times 100 = -36\%$$ Hence % decrease in the weight = 36$\%$.

Question 47

Physics · Work, Energy and Power · Single correct

A bag of sand of mass 9.8 kg is suspended by a rope. A bullet of 200 g travelling with speed 10 $\mathrm{ms}^{-1}$ gets embedded in it, then loss of kinetic energy will be

  1. 4.9 $\mathrm{J}$
  2. 9.8 $\mathrm{J}$
  3. 14.7
  4. 19.6 $\mathrm{J}$

Answer: (b)

Solution

Given $P_i = P_f$ (no any external force) $$0.2 \times 10 = 10 \times v$$ $$v = 0.2 \, \mathrm{m/s}$$ Loss in K.E. $$= \frac{1}{2} \times (0.2) \times 10^2 - \frac{1}{2} \times 10 (0.2)^2$$ $$= \frac{1}{2} \times 10 \times (0.2) [10 - 0.2]$$ $$= 9.8 \, \mathrm{J}$$

Question 48

Physics · Motion in a Plane · Single correct

A ball is projected from the ground with a speed 15 $\mathrm{ms^{-1}}$ at an angle $\theta$ with horizontal so that its range and maximum height are equal, then 'tan $\theta$' will be equal to

  1. $\frac{1}{4}$
  2. $\frac{1}{2}$
  3. 2
  4. 4

Answer: (d)

Solution

Given $R = H$. $$\frac{2v_x \times v_y}{g} = \frac{v_y^2}{2g}$$ $v_x = \frac{v_y}{4}$; $u \cos \theta = \frac{u \sin \theta}{4}$ $\tan \theta = 4$

Question 49

Physics · Mathematics in Physics · Single correct

The maximum error in the measurement of resistance, current and time for which current flows in an electrical circuit are 1$\%$, 2$\%$ and 3$\%$ respectively. The maximum percentage error in the detection of the dissipated heat will be:

  1. 2
  2. 4
  3. 6
  4. 8

Answer: (d)

Solution

Given $E_H = I^2 R \times t$. $$\frac{\Delta E}{E} \times 100 = \frac{2 \Delta I}{I} \times 100 + \frac{\Delta R}{R} \times 100 + \frac{\Delta T}{T} \times 100$$ $$= 2 \times 2 + 1 + 3 = 8$$

Question 50

Physics · Atoms · Single correct

Hydrogen atom from excited state comes to the ground by emitting a photon of wavelength $\lambda$. The value of principal quantum number 'n' of the excited state will be : (R : Rydberg constant)

  1. $\sqrt{\frac{\lambda R}{\lambda - 1}}$
  2. $\sqrt{\frac{\lambda R}{\lambda R - 1}}$
  3. $\sqrt{\frac{\lambda}{\lambda R - 1}}$
  4. $\sqrt{\frac{\lambda R^2}{\lambda R - 1}}$

Answer: (b)

Solution

The energy of the nth level is given by $$E_n = \frac{-Rch}{n^2} (1).$$ The energy of the first level is $$E_1 = \frac{-Rch}{(1)^2} (1).$$ The energy of the photon is $$E_{photon} = E_n - E_1.$$ Substituting the expressions for $E_n$ and $E_1$, we have $$\frac{-Rch}{(n)^2} + \frac{Rch}{1} = \frac{hc}{\lambda}.$$ Simplifying, we get $$\frac{-R}{n^2} + R = \frac{1}{\lambda}.$$ Rearranging terms gives $$R - \frac{1}{\lambda} = \frac{R}{n^2}.$$ Further simplification leads to $$\frac{\lambda R - 1}{\lambda} = \frac{R}{n^2}.$$ Solving for $n^2$, we find $$n^2 = \frac{\lambda R}{\lambda R - 1} \implies n = \sqrt{\frac{\lambda R}{\lambda R - 1}}.$$

Question 51

Physics · Motion in a Straight Line · Numerical

A particle is moving in a straight line such that its velocity is increasing at $5 \, \mathrm{ms^{-1}}$ per meter. The acceleration of the particle is $\mathrm{ms^{-2}}$ at a point where its velocity is $20 \, \mathrm{ms^{-1}}$.

Answer: 100

Solution

Given $\($ $\frac{dv}{ds}$ = 5 $\)$. \[ a = v \frac{dv}{ds} = 20 \times 5 = 100 \mathrm{m/sec^2} \]

Question 52

Physics · System of Particles and Rotational Motion · Numerical

Three identical spheres each of mass $M$ are placed at the corners of a right angled triangle with mutually perpendicular sides equal to $3 \, \mathrm{m}$ each. Taking point of intersection of mutually perpendicular sides as origin, the magnitude of position vector of centre of mass of the system will be $\sqrt{x} \, \mathrm{m}$. The value of $x$ is

Answer: 2

Solution

The position vectors of the masses are given as $(0, 3)$, $(0, 0)$, and $(3, 0)$. The center of mass $\vec{r}_{com}$ is calculated as: $$\vec{r}_{com} = \frac{M(0\hat{i} + 0\hat{j}) + M(3\hat{i}) + M(3\hat{j})}{3M}$$ Simplifying, we get: $$\vec{r}_{com} = \hat{i} + \hat{j}$$ The magnitude of $\vec{r}_{com}$ is: $$|\vec{r}_{com}| = \sqrt{2} = \sqrt{x}$$ Solving for $x$, we find: $$x = 2$$

Question 53

Physics · Thermal Properties of Matter · Numerical

A block of ice of mass $120\,\mathrm{g}$ at temperature $0^\circ\mathrm{C}$ is put in $300\,\mathrm{g}$ of water at $25^\circ\mathrm{C}$. The $x\,\mathrm{g}$ of ice melts as the temperature of the water reaches $0^\circ\mathrm{C}$. The value of $x$ is [Use: Specific heat capacity of water $= 4200\,\mathrm{J\,kg^{-1}\,K^{-1}}$, Latent heat of ice $= 3.5 \times 10^5\,\mathrm{J\,kg^{-1}}$]

Answer: 90

Solution

Energy released by water $$= 0.3 \times 25 \times 4200 = 31500 \, \mathrm{J}$$ Let $m$ kg ice melts $$m \times 3.5 \times 10^5 = 31500$$ $$m = \frac{31500 \times 10^{-5}}{3.5} = 9000 \times 10^{-5}$$ $$m = 0.09 \, \mathrm{kg} = 90 \, \mathrm{gm}$$ $$x = 90$$

Question 54

Physics · Atoms · Numerical

$\frac{x}{x+4}$ is the ratio of energies of photons produced due to transition of an electron of hydrogen atom from its (i) third permitted energy level to the second level and (ii) the highest permitted energy level to the second permitted level. The value of x will be

Answer: 5

Solution

Given the equation: $$\frac{13.6 \left( \frac{1}{2^2} - \frac{1}{3^2} \right)}{13.6 \left( \frac{1}{2^2} - 0 \right)} = \frac{x}{x+4}$$ Simplifying, we have: $$\frac{\frac{1}{4} - \frac{1}{9}}{\frac{1}{4}} = \frac{x}{x+4}$$ This simplifies to: $$\frac{5}{9} = \frac{x}{x+4}$$ Solving for $x$, we get: $$5x + 20 = 9x$$ $$4x = 20$$ $$x = 5$$

Question 55

Physics · Current Electricity · Numerical

In a potentiometer arrangement, a cell of emf 1.20 $\mathrm{V}$ gives a balance point at 36 $\mathrm{cm}$ length of wire. This cell is now replaced by another cell of emf 1.80 $\mathrm{V}$. The difference in balancing length of potentiometer wire in above conditions will be $\mathrm{cm}$.

Answer: 18

Solution

Given: $$1.2 = (Potential Gradient) \times 36$$ $$1.8 = (Potential Gradient) \times x$$ On dividing, we get $$\frac{2}{3} = \frac{36}{x}$$ Solving for $x$: $$x = 18 \times 3 = 54 \, cm$$ Hence difference $= 54 - 36 = 18 \, cm$

Question 56

Physics · Current Electricity · Numerical

Two ideal diodes are connected in the network as shown in figure. The equivalent resistance between A and B is _____ $\Omega$.

Answer: 25

Solution

The forward biased diode will conduct while the reverse biased will not. Therefore, equivalent resistance is $10 \, \Omega + 15 \, \Omega = 25 \, \Omega$.

Question 57

Physics · Oscillations · Numerical

Two waves executing simple harmonic motion travelling in the same direction with same amplitude and frequency are superimposed. The resultant amplitude is equal to the $\sqrt{3}$ times of amplitude of individual motions. The phase difference between the two motions is ______ (degree)

Answer: 60

Solution

The resultant amplitude is given by $$A_{resultant} = \sqrt{A_1^2 + A_2^2 + 2A_1A_2 \cos \phi}$$ Simplifying, we have $$\sqrt{3}A = \sqrt{A^2 + A^2 + 2A^2 \cos \phi}$$ This leads to $$3A^2 = 2A^2 + 2A^2 \cos \phi$$ Solving for $\cos \phi$, we get $$\cos \phi = \frac{1}{2}$$ Therefore, $$\phi = 60^\circ$$ Thus, the phase difference is 60 degrees.

Question 58

Physics · Electrostatic Potential and Capacitance · Numerical

Two parallel plate capacitors of capacity $C$ and $3C$ are connected in parallel combination and charged to a potential difference $18 \, \mathrm{V}$. The battery is then disconnected and the space between the plates of the capacitor of capacity $C$ is completely filled with a material of dielectric constant $9$. The final potential difference across the combination of capacitors will be _______ V

Answer: 6

Solution

Initial charge on $C = 18 \, \mathrm{CV}$. Initial charge on $3C = 54 \, \mathrm{CV}$. Let final common potential difference $= V'$. $$9CV' + 3CV' = 18 \, \mathrm{CV} + 54 \, \mathrm{CV}$$ $$\Rightarrow 12CV' = 72 \, \mathrm{CV} \Rightarrow V' = 6 \, \mathrm{V}$$

Question 59

Physics · Ray Optics and Optical Instruments · Numerical

A convex lens of focal length 20 cm is placed in front of convex mirror with principal axis coinciding each other. The distance between the lens and mirror is 10 cm. A point object is placed on principal axis at a distance of 60 cm from the convex lens. The image formed by combination coincides the object itself. The focal length of the convex mirror is _____ cm.

Answer: 10

Solution

For lens $$\frac{1}{v} - \frac{1}{u} = \frac{1}{f}$$ $$\Rightarrow \frac{1}{v} - \frac{1}{(-60)} = \frac{1}{20} \Rightarrow \frac{1}{v} + \frac{1}{60} = \frac{1}{20}$$ $$v = 30 \, cm$$ For final image to be formed on the object itself, after refraction from lens the ray should meet the mirror perpendicularly and the image by lens should be on the centre of curvature of mirror. $$R = 30 - 10 = 20 \, cm$$ Focal length of mirror = $R/2 = 10 \, cm$

Question 60

Physics · Electromagnetic Induction · Numerical

Magnetic flux (in weber) in a closed circuit of resistance $20 \, \Omega$ varies with time $t(\mathrm{s})$ as $\phi = 8t^2 - 9t + 5$. The magnitude of the induced current at $t = 0.25 \, \mathrm{s}$ will be

Answer: 250

Solution

Given $\phi = 8t^2 - 9t + 5$. The emf is given by $$emf = -\frac{d\phi}{dt} = -(16t - 9).$$ At $t = 0.25 \, s$, $$Emf = -[(16 \times 0.25) - 9] = 5 \, V.$$ The current is given by $$Current = \frac{Emf}{Resistance} = \frac{5 \, V}{20 \, \Omega}.$$ This simplifies to $$= \frac{1}{4} \, A = \frac{1000}{4} \, mA = 250 \, mA.$$

Chemistry

Question 61

Chemistry · Chemical Bonding and Molecular Structure · Single correct

Match List I with List II :\begin{tabular}{|c|c|c|c|} \hline \multicolumn{2}{|c|}{List-I} & \multicolumn{2}{c|}{List-II} \\ \multicolumn{2}{|c|}{(molecule)} & \multicolumn{2}{c|}{(hybridization; shape)} \\ \hline A. & XeO$_3$ & I. & $sp^3d$ ; linear \\ \hline B. & XeF$_2$ & II. & $sp^3$ ; pyramidal \\ \hline C. & XeOF$_4$ & III. & $sp^3d^3$ ; distorted octahedral \\ \hline D. & XeF$_5$ & IV. & $sp^3d^2$ ; square pyramidal \\ \hline \end{tabular} Choose the correct answer from the options given below:

  1. A-II, B-I, C-IV, D-III
  2. A-II, B-IV, C-III, D-I
  3. A-IV, B-II, C-III, D-I
  4. A-IV, B-III, C-I, D-III

Answer: (a)

Solution

Question 62

Chemistry · Solutions · Single correct

Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y, respectively in 1 kg of water. The ratio of depression in freezing points for A and B is found to be 1 : 4. The ratio of molar masses of X and Y is:

  1. 1 : 4
  2. 1 : 0.25
  3. 1 : 0.20
  4. 1 : 5

Answer: (b)

Solution

The ratio of $\Delta T_{fx}$ to $\Delta T_{fy}$ is given by: $$\frac{\Delta T_{fx}}{\Delta T_{fy}} = \frac{k_f \cdot m_x}{k_f \cdot m_y} = \frac{\frac{1}{M_x}}{\frac{1}{M_y}}$$ This simplifies to: $$\frac{1}{4} = \frac{M_y}{M_x}$$ Therefore, the ratio $M_x : M_y$ is $1 : 0.25$.

Question 63

Chemistry · Equilibrium · Single correct

$K_{a_1}$, $K_{a_2}$ and $K_{a_3}$ are the respective ionization constants for the following reactions (a), (b), and $(c)$. (a) $\mathrm{H_2C_2O_4} \rightleftharpoons \mathrm{H^+} + \mathrm{HC_2O_4^-}$ (b) $\mathrm{HC_2O_4^-} \rightleftharpoons \mathrm{H^+} + \mathrm{C_2O_4^{2-}}$ $(c)$ $\mathrm{H_2C_2O_4} \rightleftharpoons 2\mathrm{H^+} + \mathrm{C_2O_4^{2-}}$ The relationship between $K_{a_1}$, $K_{a_2}$ and $K_{a_3}$ is given as

  1. $K_{a_3} = K_{a_1} + K_{a_2}$
  2. $K_{a_3} = K_{a_1} - K_{a_2}$
  3. $K_{a_3} = K_{a_1} / K_{a_2}$
  4. $K_{a_3} = K_{a_1} \times K_{a_2}$

Answer: (d)

Solution

The dissociation of $\mathrm{H_2C_2O_4}$ is shown in the following steps: $$\mathrm{H_2C_2O_4 \rightleftharpoons H^+ + HC_2O_4^-} K_{a_1}$$ $$\mathrm{HC_2O_4^- \rightleftharpoons H^+ + C_2O_4^{2-}} K_{a_2}$$ Overall dissociation: $$\mathrm{H_2C_2O_4 \rightleftharpoons 2H^+ + C_2O_4^{2-}} K_{a_3} = K_{a_1} \times K_{a_2}$$

Question 64

Chemistry · Electrochemistry · Single correct

The molar conductivity of a conductivity cell filled with 10 moles of 20 mL NaCl solution is $\Lambda_{m1}$ and that of 20 moles another identical cell heaving 80 mL NaCl solution is $\Lambda_{m2}$, The conductivities exhibited by these two cells are same. The relationship between $\Lambda_{m2}$ and $\Lambda_{m1}$ is

  1. $\Lambda_{m2} = 2\Lambda_{m1}$
  2. $\Lambda_{m2} = \Lambda_{m1} / 2$
  3. $\Lambda_{m2} = \Lambda_{m1}$
  4. $\Lambda_{m2} = 4\Lambda_{m1}$

Answer: (a)

Solution

Given $\Lambda_m = \kappa \times \frac{1000}{M}$. Therefore, $\Lambda_m \propto \frac{1}{M}$. $$\frac{\Lambda_{m_1}}{\Lambda_{m_2}} = \frac{M_2}{M_1} = \frac{\frac{20}{80}}{\frac{10}{20}} = \frac{1}{4} \times \frac{2}{1} = \frac{1}{2}$$ Thus, $\Lambda_{m_2} = 2 \Lambda_{m_1}$.

Question 65

Chemistry · Surface Chemistry · Single correct

For micelle formation, which of the following statements are correct? (A) Micelle formation is an exothermic process. (B) Micelle formation is an endothermic process. $(C)$ The entropy change is positive. (D) The entropy change is negative.

  1. A and D only
  2. A and C only
  3. B and C only
  4. B and D only

Answer: (c)

Solution

For micelle formation, $\Delta S > 0$ (hydrophobic effect). This is possible because the decrease in entropy due to clustering is offset by increase in entropy due to desolvation of the surfactant. Also $\Delta H > 0$.

Question 66

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

The first ionization enthalpies of Be, B, N and O follow the order

  1. O < N < B < Be
  2. Be < B < N < O
  3. B < Be < N < O
  4. B < Be < O < N

Answer: (d)

Solution

The first ionization energy (1st I.E.) order is given as follows: $$N \,(2p^3) > O \,(2p^4) > Be \,(2s^2) > B \,(2p^1).$$

Question 67

Chemistry · General Principles and Processes of Isolation of Elements · Single correct

Given below are two statements. Statement I: Pig iron is obtained by heating cast iron with scrap iron. Statement II: Pig iron has a relatively lower carbon content than that of cast iron. In the light of the above statements, choose the correct answer from the options given below.

  1. Both Statement I and Statement II are correct.
  2. Both Statement I and Statement II are not correct.
  3. Statement I is correct but Statement II is not correct
  4. Statement I is not correct but Statement II is correct.

Answer: (b)

Solution

Statement–I is incorrect because cast iron is obtained by heating pig iron with scrap iron. Statement–II is also incorrect because pig iron has more carbon content (approximately 4$\%$) than cast iron (approximately 3$\%$).

Question 68

Chemistry · Hydrogen · Single correct

High purity (>99.95$\%$) dihydrogen is obtained by

  1. reaction of zinc with aqueous alkali.
  2. electrolysis of acidified water using platinum electrodes.
  3. electrolysis of warm aqueous barium hydroxide solution between nickel electrodes.
  4. reaction of zinc with dilute acid.

Answer: (c)

Solution

High purity (>99.95%) dihydrogen is obtained by electrolysis of warm aqueous $\mathrm{Ba(OH)_2}$ solution between Ni-electrodes.

Question 69

Chemistry · The s-Block Elements · Single correct

The correct order of density is

  1. Be > Mg > Ca > Sr
  2. Sr > Ca > Mg > Be
  3. Sr > Be > Mg > Ca
  4. Be > Sr > Mg > Ca

Answer: (c)

Solution

In IIA group density decreases down the group till Ca and after that it increases. Correct order of density is Sr > Be > Mg > Ca

Question 70

Chemistry · Chemical Bonding and Molecular Structure · Single correct

The total number of acidic oxides from the following list is: $NO, N_2O, B_2O_3, N_2O_5, CO, SO_3, P_4O_{10}$

  1. 3
  2. 4
  3. 5
  4. 6

Answer: (b)

Solution

Neutral Oxides — $\mathrm{N_2O}$, $\mathrm{NO}$, $\mathrm{CO}$ Acidic Oxides — $\mathrm{B_2O_3}$, $\mathrm{N_2O_5}$, $\mathrm{SO_3}$, $\mathrm{P_4O_{10}}$

Question 71

Chemistry · Co-ordination Compounds · Single correct

The correct order of energy of absorption for the following metal complexes is A: $[\mathrm{Ni(en)}_3]^{2+}$, B: $[\mathrm{Ni(NH}_3)_6]^{2+}$, C: $[\mathrm{Ni(H}_2\mathrm{O})_6]^{2+}$

  1. C < B < A
  2. B < C < A
  3. C < A < B
  4. A < C < B

Answer: (a)

Solution

Stronger the ligand, larger the splitting and higher the energy of absorption. $$[\mathrm{Ni(en)_3}]^{+2} > [\mathrm{Ni(NH_3)_6}]^{+2} > [\mathrm{Ni(H_2O)_6}]^{+2}$$

Question 72

Chemistry · Classification of Elements and Periodicity in Properties · Single correct

Match List I with List II. Choose the correct answer from the options given below:

  1. A-II, B-III. C-IV, D-I
  2. A-IV, B-III, C-II, D-I
  3. A-III, B-II, C-I, D-IV
  4. A-III, B-II, C-IV, D-I

Answer: (c)

Solution

A-Sulphate – III (Laxative effect) B-Fluoride – II (Bending of bones) C-Nictoine – I (pesticides) D-Sodium Arsinite – IV (herbicide)

Question 73

Chemistry · Alcohols, Phenols and Ethers · Single correct

Major product of the following reaction is

Answer: (d)

Solution

The reaction involves the addition of HBr to the given compound. The first step is the addition of HBr across the double bond, resulting in the formation of a bromo ketone. In the second step, another molecule of HBr adds to the remaining double bond, leading to the final product with two bromine atoms added.

Question 74

Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct

What is the major product of the following reaction?

Answer: (b)

Solution

The reaction begins with the deprotonation of the aldehyde by $\mathrm{OH}^-$, forming an enolate ion. This enolate ion is in equilibrium with its keto form. The enolate ion then attacks another molecule of the aldehyde, leading to the formation of a new carbon-carbon bond. After protonation, the aldol product is formed. Aldol formation takes place.

Question 75

Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct

Arrange the following in decreasing acidic strength.

  1. A > B > C > D
  2. B > A > C > D
  3. D > C > A > B
  4. D > C > B > A

Answer: (a)

Solution

The correct order of acid strength is

Question 76

Chemistry · Amines · Single correct

$CH_3CH_2CN \xrightarrow[\mathrm{Ether}]{CH_3MgBr} A \xrightarrow{H_3O^+} B \xrightarrow[\mathrm{HCl}]{Zn-Hg} C$ The correct structure of C is

  1. $\mathrm{CH_3-CH_2-CH_2-CH_3}$
  2. $\mathrm{CH_3-CH_2-CH=CH_2}$

Answer: (a)

Solution

Question 77

Chemistry · Polymers · Single correct

Match List I with List II : \begin{tabular}{|c|l|c|l|} \hline \multicolumn{2}{|c|}{List-I} & \multicolumn{2}{c|}{List-II} \\ \multicolumn{2}{|c|}{Polymer} & \multicolumn{2}{c|}{used for items} \\ \hline A. & Nylon 6,6 & I. & Buckets \\ \hline B. & Low density polythene & II. & Non-stick utensils \\ \hline C. & High density polythene & III. & Bristles of brushes \\ \hline D. & Teflon & IV. & Toys \\ \hline \end{tabular} Choose the correct answer from the options given below:

  1. A–III, B-I, C-IV, D-II
  2. A–III, B-IV, C-I, D-II
  3. A–II, B-I, C-IV, D-III
  4. A–II, B-IV, C-I, D-III

Answer: (b)

Solution

LDPE $\rightarrow$ Toys HDPE $\rightarrow$ Buckets (As per NCERT)

Question 78

Chemistry · Biomolecules · Single correct

Glycosidic linkage between $C_1$ of $\alpha$-glucose and $C_2$ of $\beta$-fructose is found in

  1. maltose
  2. sucrose
  3. lactose
  4. amylose

Answer: (b)

Solution

Theoretical

Question 79

Chemistry · Chemistry in Everyday Life · Single correct

Some drugs bind to a site other than, the active site of an enzyme. This site is known as

  1. non-active site
  2. allosteric site
  3. competitive site
  4. therapeutic site

Answer: (b)

Solution

Theoretical

Question 80

Chemistry · Redox Reactions · Single correct

In base vs. Acid titration, at the end point methyl orange is present as

  1. quinonoid form
  2. heterocyclic form
  3. phenolic form
  4. benzenoid form

Answer: (a)

Solution

The reaction involves the conversion of the azo compound to its quinonoid form upon the addition of $\mathrm{H}^+$. The structure changes from $\mathrm{Me_2N{-}C_6H_4{-}N{=}N{-}C_6H_4{-}SO_3^-Na^+}$ to $\mathrm{Me_2N^+{-}C_6H_4{-}N{=}NH{-}C_6H_4{-}SO_3^-Na^+}$, indicating the formation of the quinonoid form.

Question 81

Chemistry · Some Basic Concepts of Chemistry · Numerical

56.0 $\mathrm{L}$ of nitrogen gas is mixed with excess of hydrogen gas and it is found that 20 $\mathrm{L}$ of ammonia gas is produced. The volume of unused nitrogen gas is found to be _____ $\mathrm{L}$.

Answer: 46

Solution

Given the reaction: $\mathrm{N_2} + 3\mathrm{H_2} \rightarrow 2\mathrm{NH_3}$. Initially, there are $56 \, \mathrm{L}$ of $\mathrm{N_2}$ and an excess of $\mathrm{H_2}$. During the reaction, $10 \, \mathrm{L}$ of $\mathrm{N_2}$ is consumed and $30 \, \mathrm{L}$ of $\mathrm{H_2}$ is consumed. As a result, $20 \, \mathrm{L}$ of $\mathrm{NH_3}$ is produced. The remaining $\mathrm{N_2}$ is $46 \, \mathrm{L}$ and the remaining $\mathrm{NH_3}$ is $20 \, \mathrm{L}$.

Question 82

Chemistry · States of Matter · Numerical

A sealed flask with a capacity of 2 $\mathrm{dm}^3$ contains 11 $\mathrm{g}$ of propane gas. The flask is so weak that it will burst if the pressure becomes 2 $\mathrm{MPa}$. The minimum temperature at which the flask will burst is _______ $\degree \mathrm{C}$. [Nearest integer] (Given: R = 8.3 $\mathrm{J} \mathrm{K}^{-1} \mathrm{mol}^{-1}$. Atomic masses of C and H are 12u and 1u respectively.) (Assume that propane behaves as an ideal gas.)

Answer: 1655

Solution

Moles of $\mathrm{C_3H_8} = \frac{11}{44} = 0.25$ moles $PV = nRT$ $\Rightarrow \ 2 \times 10^6 \times 2 \times 10^{-3} = 0.25 \times 8.3 \times T$ $\Rightarrow \ T = 1927.710 \, \mathrm{K} = 1654.56 \, ^\circ \mathrm{C}$

Question 83

Chemistry · Structure of Atom · Numerical

When the excited electron of a H atom from $n = 5$ drops to the ground state, the maximum number of emission lines observed are

Answer: 4

Solution

Since only a single H atom is present, maximum number of spectral lines = 4

Question 84

Chemistry · Thermodynamics · Numerical

While performing a thermodynamics experiment, a student made the following observations, $$\mathrm{HCl} + \mathrm{NaOH} \rightarrow \mathrm{NaCl} + \mathrm{H_2O} \Delta H = -57.3 \, \mathrm{kJ \, mol^{-1}}$$ $$\mathrm{CH_3COOH} + \mathrm{NaOH} \rightarrow \mathrm{CH_3COONa} + \mathrm{H_2O} \Delta H = -55.3 \, \mathrm{kJ \, mol^{-1}}$$ The enthalpy of ionization of $\mathrm{CH_3COOH}$ as calculated by the student is ______ kJ mol$^{-1}$. (nearest integer)

Answer: 2

Solution

Question 85

Chemistry · Chemical Kinetics and Nuclear Chemistry · Numerical

For the decomposition of azomethane. $$\mathrm{CH_3N_2CH_3(g) \rightarrow CH_3CH_3(g) + N_2(g)}$$ a first order reaction, the variation in partial pressure with time at 600 K is given as The half life of the reaction is _____ $\times 10^{-5}$ s. [Nearest integer]

Answer: 2

Solution

For first order reaction $$k = \frac{1}{t} \ln \left( \frac{P_0}{P} \right)$$ $$\ln \left( \frac{P_0}{P} \right) = kt$$ $$t_{1/2} = \frac{\ln 2}{k} = \frac{0.693}{3.465 \times 10^4} = 2 \times 10^{-5}$$

Question 86

Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Fill in the blank

The sum of number of lone pairs of electrons present on the central atoms of ${XeO3}$, ${XeOF4}$ and ${XeF6}$ is ____________

Answer: 3

Solution

Question 87

Chemistry · The d-and f-Block Elements · Numerical

The spin-only magnetic moment value of $\mathrm{M}^{n+}$ ion (in gaseous state) from the pairs $\mathrm{Cr}^{3+}/\mathrm{Cr}^{2+}$, $\mathrm{Mn}^{3+}/\mathrm{Mn}^{2+}$, $\mathrm{Fe}^{3+}/\mathrm{Fe}^{2+}$ and $\mathrm{Co}^{3+}/\mathrm{Co}^{2+}$ that has negative standard electrode potential, is B.M. [Nearest integer]

Answer: 4

Solution

The standard electrode potential for the reaction is given by: $$E^0_{\mathrm{Cr^{+3}} | \mathrm{Cr^{+2}}} = -0.41 \, \mathrm{V}$$ The electronic configuration of $\mathrm{Cr^{+3}}$ is: $$[\mathrm{Cr^{+3}}] = 4s^0 \, 3d^3$$ The magnetic moment $\mu$ is calculated as: $$\mu = \sqrt{n(n+2)} \, \mathrm{B.M}$$ Substituting $n = 3$: $$= \sqrt{15} \, \mathrm{B.M} \approx 4 \, \mathrm{B.M}$$

Question 88

Chemistry · States of Matter · Numerical

A sample of 4.5 mg of an unknown monohydric alcohol, R–OH was added to methylmagnesium iodide. A gas is evolved and is collected and its volume measured to be 3.1 mL. The molecular weight of the unknown alcohol is ____ g/mol. [Nearest integer]

Answer: 33

Solution

ROH + $\mathrm{CH_3MgI}$ $\rightarrow$ $\mathrm{ROMgI}$ + $\mathrm{CH_4(g)}$ Moles of $\mathrm{CH_4}$ = moles of ROH $$\Rightarrow \frac{V}{22400} = \frac{m}{\mathrm{M.M}} (Assuming NTP Condition)$$ $$\Rightarrow \frac{3.1}{22400} = \frac{4.5 \times 10^{-3}}{\mathrm{M.M}}$$ $$\Rightarrow \mathrm{M.M} = 32.51$$ Nearest Integer = 33

Question 89

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Numerical

The separation of two coloured substances was done by paper chromatography. The distances travelled by solvent front, substance A and substance B from the base line are 3.25 cm, 2.08 cm and 1.05 cm respectively. The ratio of $R_f$ values of A to B is

Answer: 2

Solution

The ratio of $R_{FA}$ to $R_{FB}$ is calculated as follows: $$\frac{R_{FA}}{R_{FB}} = \frac{\frac{2.08}{3.25}}{\frac{1.05}{3.25}} = \frac{2.08}{1.05} \approx 2$$

Question 90

Chemistry · Organic Chemistry — Some Basic Principles & Techniques · Numerical

The total number of monobromo derivatives formed by the alkanes with molecular formula $C_5H_{12}$ is (excluding stereo isomers)_____

Answer: 8

Solution

The Alkanes and their monobromoderivative are: 1. Alkane: Hexane $\rightarrow$ 1-Bromohexane, 2-Bromohexane, 3-Bromohexane 2. Alkane: Isobutane $\rightarrow$ 1-Bromo-2-methylpropane, 2-Bromo-2-methylpropane, 1-Bromo-3-methylbutane 3. Alkane: Neopentane $\rightarrow$ 1-Bromo-2,2-dimethylpropane