JEE Main 31 August 2021 Shift 2 question paper with solutions
JEE Main 31 August 2021 Shift 2: all 90 questions in paper order (Maths, Physics, Chemistry) with the answer key and worked solutions. Free to read; attempt it as a timed 3-hour mock test.
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Maths
Question 1
Maths · Determinants · Single correct
If $\alpha + \beta + \gamma = 2\pi$, then the system of equations $$x + (\cos \gamma)y + (\cos \beta)z = 0$$ $$(\cos \gamma)x + y + (\cos \alpha)z = 0$$ $$(\cos \beta)x + (\cos \alpha)y + z = 0$$ has :
Let $\vec{a}, \vec{b}, \vec{c}$ be three vectors mutually perpendicular to each other and have same magnitude. If a vector $\vec{r}$ satisfies. $$\vec{a} \times \{ (\vec{r} - \vec{b}) \times \vec{a} \} + \vec{b} \times \{ (\vec{r} - \vec{c}) \times \vec{b} \} + \vec{c} \times \{ (\vec{r} - \vec{a}) \times \vec{c} \} = \vec{0},$$ then $\vec{r}$ is equal to :
Let S = {$1, 2, 3, 4, 5, 6$\}. Then the probability that a randomly chosen onto function g from S to S satisfies $$g(3) = 2g(1)$$ is :
$\frac{1}{10}$
$\frac{1}{15}$
$\frac{1}{5}$
$\frac{1}{30}$
Answer: (a)
Solution
Given $g(3) = 2$, $g(1)$ can be defined in 3 ways. The number of onto functions in this condition is $3 \times 4!$. The total number of onto functions is $6!$. The required probability is $$\frac{3 \times 4!}{6!} = \frac{1}{10}.$$
Question 5
Maths · Relations and Functions · Single correct
Let f : $\mathbb{N}$ $\to$ $\mathbb{N}$ be a function such that f(m + n) = f(m) + f(n) for every m, n $\in$ $\mathbb{N}$. If f(6) = 18, then f(2) $\cdot$ f(3) is equal to :
Maths · Three Dimensional Geometry · Single correct
The distance of the point $(-1, 2, -2)$ from the line of intersection of the planes $2x + 3y + 2z = 0$ and $x - 2y + z = 0$ is:
$\frac{1}{\sqrt{2}}$
$\frac{5}{2}$
$\frac{\sqrt{42}}{2}$
$\frac{\sqrt{34}}{2}$
Answer: (d)
Solution
Given $P_1: 2x + 3y + 2z = 0$ which implies $\vec{n}_1 = 2\hat{i} + 3\hat{j} + 2\hat{k}$. For $P_2: x - 2y + z = 0$, we have $\vec{n}_2 = \hat{i} - 2\hat{j} + \hat{k}$. The direction vector of line $L$, which is the line of intersection of $P_1$ and $P_2$, is $\vec{r} = \vec{n}_1 \times \vec{n}_2 = 7\hat{i} - 7\hat{k}$. The direction ratios of $L$ are $(1, 0, -1)$. Therefore, the equation of $L$ is $\frac{x}{1} = \frac{y}{0} = \frac{z}{-1} = \lambda$. The direction ratios of $\overrightarrow{PQ}$ are $(\lambda + 1, -2, 2 - \lambda)$. Since $\overrightarrow{PQ} \perp \vec{r}$, we have $(\lambda + 1)(1) + (-2)(0) + (2 - \lambda)(-1) = 0$. Solving gives $\lambda = \frac{1}{2}$, which implies $Q\left(\frac{1}{2}, 0, -\frac{1}{2}\right)$. Therefore, $PQ = \frac{\sqrt{34}}{2}$.
Question 7
Maths · Mathematical Reasoning · Single correct
Negation of the statement $(p \lor r) \Rightarrow (q \lor r)$ is:
$p \land \sim q \land \sim r$
$\sim p \land q \land \sim r$
$\sim p \land q \land r$
$p \land q \land r$
Answer: (a)
Solution
Given $\sim (A \Rightarrow B) = A \land \sim B$. Therefore, $\sim ((p \lor r) \Rightarrow (q \lor r))$ is equal to $(p \lor r) \land (\sim q \land \sim r)$. This simplifies to $((p \lor r) \land (\sim r)) \land (\sim q)$, which further simplifies to $p \land (\sim r) \land (\sim q)$.
Question 8
Maths · Limits and Derivatives · Single correct
If $\alpha = \lim_{x \to \pi/4} \frac{\tan^3 x - \tan x}{\cos \left( x + \frac{\pi}{4} \right)}$ and $\beta = \lim_{x \to 0} (\cos x)^{\cot x}$ are the roots of the equation, $ax^2 + bx - 4 = 0$, then the ordered pair $(a, b)$ is:
$(1, -3)$
$(-1, 3)$
$(-1, -3)$
$(1, 3)$
Answer: (d)
Solution
Given $\($ $\alpha$ = $\lim$_{x $\to$ $\frac{\pi}{4}$} $\frac{\tan^3 x - \tan x}{\cos \left( x + \frac{\pi}{4} \right)}$ $\)$; $\($ $\frac{0}{0}$ $\)$ form. Using L'Hopital's rule: $\[$ $\alpha$ = $\lim$_{x $\to$ $\frac{\pi}{4}$} $\frac{3 \tan^2 x \sec^2 x - \sec^2 x}{-\sin \left( x + \frac{\pi}{4} \right)}$ $\]$ $\($ $\Rightarrow$ $\alpha$ = -4 $\)$ $\($ $\beta$ = $\lim$_{x $\to$ 0} ($\cos$ x) $\cot$ x = e^{$\lim$_{x $\to$ 0} $\frac{(\cos x - 1)}{\tan x}$} $\)$ $\($ $\beta$ = e $\lim$_{x $\to$ 0} $\frac{-(1 - \cos x)}{x^2}$ , $\frac{x^2}{\left( \frac{\tan x}{x} \right) x}$ $\)$ $\($ $\beta$ = e $\lim$_{x $\to$ 0} $\left$( -$\frac{1}{2}$ $\right$) $\cdot$ $\frac{x}{1}$ = e^0 $\Rightarrow$ $\beta$ = 1 $\)$ $\($ $\alpha$ = -4; $\beta$ = 1 $\)$ If $\($ ax^2 + bx - 4 = 0 $\)$ are the roots then $\($ 16a - 4b - 4 = 0 $\)$ and $\($ a + b - 4 = 0 $\)$ $\($ $\Rightarrow$ a = 1 $\)$ and $\($ b = 3 $\)$
Question 9
Maths · Conic Sections · Single correct
The locus of mid-points of the line segments joining $(-3, -5)$ and the points on the ellipse $\frac{x^2}{4} + \frac{y^2}{9} = 1$ is :
$9x^2 + 4y^2 + 18x + 8y + 145 = 0$
$36x^2 + 16y^2 + 90x + 56y + 145 = 0$
$36x^2 + 16y^2 + 108x + 80y + 145 = 0$
$36x^2 + 16y^2 + 72x + 32y + 145 = 0$
Answer: (c)
Solution
General point on $\frac{x^2}{4} + \frac{y^2}{9} = 1$ is $A(2 \cos \theta, 3 \sin \theta)$. Given $B(-3, -5)$. Midpoint $C \left( \frac{2 \cos \theta - 3}{2}, \frac{3 \sin \theta - 5}{2} \right)$. Let $h = \frac{2 \cos \theta - 3}{2}$ and $k = \frac{3 \sin \theta - 5}{2}$. Therefore, $$\left( \frac{2h + 3}{2} \right)^2 + \left( \frac{2k + 5}{3} \right)^2 = 1$$ which simplifies to $$36x^2 + 16y^2 + 108x + 80y + 145 = 0.$$
Question 10
Maths · Differential Equations · Single correct
If $\frac{dy}{dx} = \frac{2^x y + 2^y \cdot 2^x}{2^x + 2^{x+y} \log_c 2}$, $y(0) = 0$, then for $y = 1$, the value of $x$ lies in the interval:
(1, 2)
$(\\frac{1}{2}, 1]$
(2, 3)
$(0, \\frac{1}{2}]$
Answer: (a)
Solution
Given $\($ $\frac{dy}{dx}$ = $\frac{2^x(y+2^y)}{2^x(1+2^y \ln 2)}$ $\)$. This implies $$ \int \frac{(1+2^y) \ln 2}{(y+2^y)} \, dy = \int \, dx $$ which leads to $$ \ln |y + 2^y| = x + c $$ Using the initial condition $\($ x = 0; y = 0 $\)$, we find $\($ c = 0 $\)$. Thus, $$ x = \ln |y + 2^y| $$ At $\($ y = 1 $\)$, we have $\($ x = $\ln$ 3 $\)$. Therefore, $\($ 3 $\in$ (e, e^2) $\Rightarrow$ x $\in$ (1, 2) $\)$.
Question 11
Maths · Applications of Derivatives · Single correct
An angle of intersection of the curves $\left(\dfrac{x^2}{a^2}+\dfrac{y^2}{b^2}=1\right)$ and $\left(x^2+y^2=ab,\; a>b\right)$ is:
Let $a_1, a_2, a_3, \ldots$ be an $\mathrm{A.P.}$ If $\frac{a_1 + a_2 + \ldots + a_{10}}{a_1 + a_2 + \ldots + a_p} = \frac{100}{p^2}$, $p \neq 10$, then $\frac{a_{11}}{a_{10}}$ is equal to:
Let A be the set of all points $(\alpha, \beta)$ such that the area of triangle formed by the points $(5, 6)$, $(3, 2)$ and $(\alpha, \beta)$ is 12 square units. Then the least possible length of a line segment joining the origin to a point in A, is :
$\frac{4}{\sqrt{5}}$
$\frac{16}{\sqrt{5}}$
$\frac{8}{\sqrt{5}}$
$\frac{12}{\sqrt{5}}$
Answer: (c)
Solution
Given the determinant: $$\begin{vmatrix} 1 & 5 & 6 \\ \frac{1}{2} & 3 & 2 \\ 1 & \alpha & \beta \end{vmatrix} = 12$$ We have the equation: $$4\alpha - 2\beta = \pm 24 + 8$$ This implies: $$4\alpha - 2\beta = +24 + 8 \Rightarrow 2\alpha - \beta = 16$$ Equation (1): $$2x - y - 16 = 0 \ldots (1)$$ Also: $$4\alpha - 2\beta = -24 + 8 \Rightarrow 2\alpha - \beta = -8$$ Equation (2): $$2x - y + 8 = 0 \ldots (2)$$ The perpendicular distance of (1) from $(0, 0)$ is $$\left| \frac{0 - 0 - 16}{\sqrt{5}} \right| = \frac{16}{\sqrt{5}}$$ The perpendicular distance of (2) from $(0, 0)$ is $$\left| \frac{0 - 0 + 8}{\sqrt{5}} \right| = \frac{8}{\sqrt{5}}$$
Question 17
Maths · Trigonometric Functions · Single correct
The number of solutions of the equation $32^{\tan^2 x} + 32^{\sec^2 x} = 81, 0 \leq x \leq \frac{\pi}{4}$ is:
3
1
0
2
Answer: (b)
Solution
Given $$(32)^{\tan^2 x} + (32)^{\sec^2 x} = 81$$ which implies $$(32)^{\tan^2 x} + (32)^{1 + \tan^2 x} = 81$$ leading to $$(32)^{\tan^2 x} = \frac{81}{33}.$$ In the interval $$\left[0, \frac{\pi}{4}\right]$$ there is only one solution.
Question 18
Maths · Applications of Derivatives · Single correct
Let f be any continuous function on $[0, 2]$ and twice differentiable on $(0, 2)$. If $f(0) = 0$, $f(1) = 1$ and $f(2) = 2$, then
$f''(x) = 0$ for all $x \in (0, 2)$
$f''(x) = 0$ for some $x \in (0, 2)$
$f'(x) = 0$ for some $x \in [0, 2]$
$f''(x) > 0$ for all $x \in (0, 2)$
Answer: (b)
Solution
Given $f(0) = 0$, $f(1) = 1$ and $f(2) = 2$. Let $h(x) = f(x) - x$ has three roots. By Rolle's theorem $h'(x) = f'(x) - 1$ has at least two roots. $h''(x) = f''(x) = 0$ has at least one root.
Question 19
Maths · Integrals · Single correct
If $[x]$ is the greatest integer $\leq x$, then $$\pi^2 \int_0^2 \left( \sin \frac{\pi x}{2} \right) (x - [x])^{[x]} \, dx$$ is equal to:
The mean and variance of 7 observations are 8 and 16 respectively. If two observations are 6 and 8, then the variance of the remaining 5 observations is:
$\frac{92}{5}$
$\frac{134}{5}$
$\frac{536}{25}$
$\frac{112}{5}$
Answer: (c)
Solution
Let 8, 16, $x_1, x_2, x_3, x_4, x_5$ be the observations. Now $$\frac{x_1 + x_2 + \cdots + x_5 + 14}{7} = 8$$ which implies $$\sum_{i=1}^{5} x_i = 42 \ldots (1)$$ Also $$\frac{x_1^2 + x_2^2 + \cdots + x_5^2 + 8^2 + 6^2}{7} - 64 = 16$$ which implies $$\sum_{i=1}^{5} x_i^2 = 560 - 100 = 460 \ldots (2)$$ So the variance of $x_1, x_2, \ldots, x_5$ is $$\frac{460}{5} - \left(\frac{42}{5}\right)^2 = \frac{2300 - 1764}{25} = \frac{536}{25}.$$
Question 21
Maths · Binomial Theorem · Numerical
If the coefficient of $a^7 b^8$ in the expansion of $(a + 2b + 4ab)^{10}$ is $K \cdot 2^{16}$, then $K$ is equal to.
Suppose the line $\frac{x-2}{\alpha} = \frac{y-2}{-5} = \frac{z+2}{2}$ lies on the plane $x + 3y - 2z + \beta = 0$. Then $(\alpha + \beta)$ is equal to .
The number of 4-digit numbers which are neither multiple of 7 nor multiple of 3 is .
Answer: 5143
Solution
A = 4-digit numbers divisible by 3 A = 1002, 1005, $\ldots$, 9999. 9999 = 1002 + (n - 1)3 $\Rightarrow$ (n - 1)3 = 8997 $\Rightarrow$ n = 3000 B = 4-digit numbers divisible by 7 B = 1001, 1008, $\ldots$, 9996 $\Rightarrow$ 9996 = 1001 + (n - 1)7 $\Rightarrow$ n = 1286 A $\cap$ B = 1008, 1029, $\ldots$, 9996 9996 = 1008 + (n - 1)21 $\Rightarrow$ n = 429 So, no divisible by either 3 or 7 = 3000 + 1286 - 429 = 3857 total 4-digits numbers = 9000 required numbers = 9000 - 3857 = 5143
Question 24
Maths · Integrals · Numerical
If $\int \frac{\sin x}{\sin^3 x + \cos^3 x} \, dx = \alpha \log_c \left| 1 + \tan x \right| + \beta \log_e \left| 1 - \tan x + \tan^2 x \right| + \gamma \tan^{-1} \left( \frac{2 \tan x - 1}{\sqrt{3}} \right) + C$, when $C$ is constant of integration, then the value of $18 (\alpha + \beta + \gamma^2)$ is .
Answer: 3
Solution
= $\int$ $\frac{\sin x}{\cos^3 x}$ dx = $\int$ $\frac{\tan x \cdot \sec^2 x}{(\tan x + 1)(1 + \tan^2 x - \tan x)}$ dx Let $\($ $\tan$ x = t $\Rightarrow$ $\sec$^2 x $\cdot$ dx = dt $\)$ = $\int$ $\frac{t}{(t+1)(t^2-t+1)}$ dt = $\int$ $\left$( $\frac{A}{t+1}$ + $\frac{B(2t-1)}{t^2-t+1}$ + $\frac{C}{t^2-t+1}$ $\right$) dx $\Rightarrow$ A(t^2 - t + 1) + B(2t - 1)(t^2 - t + 1) + C(t + 1) = t $\Rightarrow$ t^2(A + 2B) + t(-A + B + C) + A - B + C = 1 $\therefore$ A + 2B = 0 -A + B + C = 1 A - B + C = 0 $\Rightarrow$ C = $\frac{1}{2}$ $\Rightarrow$ A - B = -$\frac{1}{2}$ $\cdots$ (4) A + 2B = 0 A - B = -$\frac{1}{2}$ $\Rightarrow$ 3B = $\frac{1}{2}$ $\Rightarrow$ B = $\frac{1}{6}$ A = -$\frac{1}{3}$ I = -$\frac{1}{3}$ $\int$ $\frac{dt}{1+t}$ + $\frac{1}{6}$ $\int$ $\frac{2t-1}{t^2-t+1}$ dt + $\frac{1}{2}$ $\int$ $\frac{dt}{t^2-t+1}$ = -$\frac{1}{3}$ $\ln$ |(1 + $\tan$ x)| + $\frac{1}{6}$ $\ell$ $\tan$^2 x - $\tan$ x + 1| + $\frac{1}{2}$ $\cdot$ $\frac{2}{\sqrt{3}}$ $\tan$^{-1} $\left$( $\frac{\tan x - \frac{1}{2}}{\frac{\sqrt{3}}{2}}$ $\right$) = -$\frac{1}{3}$ $\ln$ |(1 + $\tan$ x)| + $\frac{1}{6}$ $\ell$ $\tan$^2 x - $\tan$ x + 1| + $\frac{1}{\sqrt{3}}$ $\tan$^{-1} $\left$( $\frac{2 \tan x - 1}{\sqrt{3}}$ $\right$) + C $\alpha$ = -$\frac{1}{3}$, $\beta$ = $\frac{1}{6}$, $\gamma$ = $\frac{1}{\sqrt{3}}$ 18 $\left$( $\alpha$ + $\beta$ + $\gamma$^2 $\right$) = 18 $\left$( -$\frac{1}{3}$ + $\frac{1}{6}$ + $\frac{1}{3}$ $\right$) = 3
Question 25
Maths · Conic Sections · Numerical
A tangent line $L$ is drawn at the point $(2, -4)$ on the parabola $y^2 = 8x$. If the line $L$ is also tangent to the circle $x^2 + y^2 = a$, then 'a' is equal to,
Answer: 2
Solution
The tangent of $y^2 = 8x$ is $y = mx + \frac{2}{m}$. At point $P(2, -4)$, we have $$-4 = 2m + \frac{2}{m}$$ which implies $$m + \frac{1}{m} = -2 \implies m = -1.$$ Therefore, the tangent is $y = -x - 2$. This gives $$x + y + 2 = 0 \ldots (1)$$ Equation (1) is also tangent to $x^2 + y^2 = a$. So $$\frac{2}{\sqrt{2}} = \sqrt{a} \implies \sqrt{a} = \sqrt{2}$$ Thus, $a = 2$.
Question 26
Maths · Sequences and Series · Numerical
If $S = \frac{7}{5} + \frac{9}{5^2} + \frac{13}{5^3} + \frac{19}{5^4} + \ldots$, then $160 \, S$ is equal to .
The number of elements in the set $$ \left\{ A = \begin{pmatrix} a & b \\ 0 & d \end{pmatrix} : a, b, d \in \{-1, 0, 1\} and (I - A)^3 = I - A^3 \right\}, $$ where $I$ is $2 \times 2$ identity matrix, is :
Answer: 8
Solution
$(I - A)^3 = I^3 - A^3 - 3A(I - A) = I - A^3$ $\Rightarrow 3A(I - A) = 0$ or $A^2 = A$ $\Rightarrow \begin{bmatrix} a^2 & ab + bd \\ 0 & d^2 \end{bmatrix} = \begin{bmatrix} a & b \\ 0 & d \end{bmatrix}$ $\Rightarrow a^2 = a, \quad b(a + d - 1) = 0, \quad d^2 = d$ If $b \neq 0$, $a + d = 1 \Rightarrow 4$ ways If $b = 0$, $a = 0, 1$ & $d = 0, 1 \Rightarrow 4$ ways $\Rightarrow$ Total $8$ matrices
Question 28
Maths · Applications of Integrals · Fill in the blank
If the line $y = mx$ bisects the area enclosed by the lines $x = 0$, $y = 0$, $x = \frac{3}{2}$ and the curve $y = 1 + 4x - x^2$, then $12 \, m$ is equal to .
Let $B$ be the centre of the circle $x^2 + y^2 - 2x + 4y + 1 = 0$. Let the tangents at two points $P$ and $Q$ on the circle intersect at the point $A(3, 1)$. Then $8 \cdot \left( \frac{area \Delta APQ}{area \Delta BPQ} \right)$ is equal to .
Answer: 18
Solution
Given $\tan \theta = \frac{3}{2}$. The ratio of the area of $\triangle APQ$ to the area of $\triangle BPQ$ is given by $$\frac{Area \triangle APQ}{Area \triangle BPQ} = \frac{AR}{RB} = \frac{3 \sin \theta}{2 \cos \theta} = \frac{9}{4}.$$ Therefore, $$8 \left( \frac{Area \triangle APQ}{Area \triangle BPQ} \right) = 18.$$
Question 30
Maths · Applications of Derivatives · Numerical
Let f(x) be a cubic polynomial with $f(1) = -10$, $f(-1) = 6$, and has a local minima at $x = 1$, and $f'(x)$ has a local minima at $x = -1$. Then $f(3)$ is equal to .
Physics · Mechanical Properties of Solids · Single correct
Four identical hollow cylindrical columns of mild steel support a big structure of mass $50 \times 10^3 \, \mathrm{kg}$. The inner and outer radii of each column are $50 \, \mathrm{cm}$ and $100 \, \mathrm{cm}$ respectively. Assuming uniform local distribution, calculate the compression strain of each column. [Use $Y = 2.0 \times 10^{11} \, \mathrm{Pa}$, $g = 9.8 \, \mathrm{m/s^2}$]
$3.60 \times 10^{-8}$
$2.60 \times 10^{-7}$
$1.87 \times 10^{-3}$
$7.07 \times 10^{-4}$
Answer: (b)
Solution
Force on each column $=\frac{mg}{4}$ Strain $=\frac{mg}{4AY}$ $=\frac{50 \times 10^3 \times 9.8}{4 \times \pi (1 - 0.25) \times 2 \times 10^{11}}$ $=2.6 \times 10^{-7}$
Question 32
Physics · Moving Charges and Magnetism · Single correct
A current of 1.5 A is flowing through a triangle, of side 9 cm each. The magnetic field at the centroid of the triangle is : (Assume that the current is flowing in the clockwise direction.)
3 $\times$ $10^{-7}$ $\mathrm{T}$, outside the plane of triangle
2$\sqrt{3}$ $\times$ $10^{-7}$ $\mathrm{T}$, outside the plane of triangle
2$\sqrt{3}$ $\times$ $10^{-5}$ $\mathrm{T}$, inside the plane of triangle
3 $\times$ $10^{-5}$ $\mathrm{T}$, inside the plane of triangle
Answer: (d)
Solution
Given the triangle, the magnetic field $B$ is calculated as follows: $$B = 3 \left[ \frac{\mu_0 i}{4 \pi} (\sin 60^\circ + \sin 60^\circ) \right]$$ The tangent of $60^\circ$ is given by: $$\tan 60^\circ = \frac{\ell/2}{r}$$ Where $r = \frac{9 \times 10^{-2}}{2 \sqrt{3}} \, \mathrm{M}$. Therefore, the magnetic field is: $$\therefore \, B = 3 \times 10^{-5} \, \mathrm{T}$$ The current is flowing in a clockwise direction, so $\vec{B}$ is inside the plane of the triangle by the right-hand rule.
Question 33
Physics · System of Particles and Rotational Motion · Single correct
A system consists of two identical spheres each of mass $1.5 \, \mathrm{kg}$ and radius $50 \, \mathrm{cm}$ at the end of light rod. The distance between the centres of the two spheres is $5 \, \mathrm{m}$. What will be the moment of inertia of the system about an axis perpendicular to the rod passing through its midpoint?
$18.75 \, \mathrm{kgm}^2$
$1.905 \times 10^5 \, \mathrm{kgm}^2$
$19.05 \, \mathrm{kgm}^2$
$1.875 \times 10^5 \, \mathrm{kgm}^2$
Answer: (c)
Solution
Given $M = 1.5 \, \mathrm{kg}$, $r = 0.5 \, \mathrm{m}$, $d = \frac{5}{2} \, \mathrm{m}$. The moment of inertia $I$ is given by $$I = 2 \left( \frac{2}{5} M r^2 + M d^2 \right)$$ Calculating, $$I = 19.05 \, \mathrm{kg \, m^2}$$
Question 34
Physics · Mathematics in Physics · Single correct
Statement I : Two forces $\left( \vec{P} + \vec{Q} \right)$ and $\left( \vec{P} - \vec{Q} \right)$ where $\vec{P} \perp \vec{Q}$, when act at an angle $\theta_1$ to each other, the magnitude of their resultant is $\sqrt{3 \left( P^2 + Q^2 \right)}$, when they act at an angle $\theta_2$, the magnitude of their resultant becomes $\sqrt{2 \left( P^2 + Q^2 \right)}$. This is possible only when $\theta_1 < \theta_2$. Statement II : In the situation given above. $\theta_1 = 60^\circ$ and $\theta_2 = 90^\circ$ In the light of the above statements, choose the most appropriate answer from the options given below :-
Statement-I is false but Statement-II is true
Both Statement-I and Statement-II are true
Statement-I is true but Statement-II is false
Both Statement-I and Statement-II are false.
Answer: (b)
Solution
Given $\vec{A} = \vec{P} + \vec{Q}$ and $\vec{B} = \vec{P} - \vec{Q}$ with $\vec{P} \perp \vec{Q}$. The magnitudes are $|\vec{A}| = |\vec{B}| = \sqrt{P^2 + Q^2}$. The magnitude of $\vec{A} + \vec{B}$ is $|\vec{A} + \vec{B}| = \sqrt{2 \left(P^2 + Q^2\right)(1 + \cos \theta)}$. For $|\vec{A} + \vec{B}| = \sqrt{3 \left(P^2 + Q^2\right)}$, $\theta_1 = 60^\circ$. For $|\vec{A} + \vec{B}| = \sqrt{2 \left(P^2 + Q^2\right)}$, $\theta_2 = 90^\circ$.
Question 35
Physics · Atoms · Single correct
A free electron of $2.6\,\mathrm{eV}$ energy collides with $\mathrm{H}^+$ ion. This results in the formation of a hydrogen atom in the first excited state and a photon is released. Find the frequency of the emitted photon $\left(h = 6.6 \times 10^{-34}\,\mathrm{Js}\right)$
1.45 $\times$ 10^{16} \, $\mathrm{MHz}$
0.19 $\times$ 10^{15} \, $\mathrm{MHz}$
1.45 $\times$ 10^{9} \, $\mathrm{MHz}$
9.0 $\times$ 10^{27} \, $\mathrm{MHz}$
Answer: (c)
Solution
For every large distance P.E. = 0 and total energy = 2.6 + 0 = 2.6 eV. Finally in first excited state of H atom total energy = -3.4 eV. Loss in total energy = 2.6 - (-3.4) = 6 eV. It is emitted as photon $$\lambda = \frac{1240}{6} = 206 \, nm$$ $$f = \frac{3 \times 10^8}{206 \times 10^{-9}} = 1.45 \times 10^{15} \, Hz$$ $$= 1.45 \times 10^9 \, Hz$$
Question 36
Physics · Thermal Properties of Matter · Single correct
Two thin metallic spherical shells of radii $r_1$ and $r_2$ ($r_1 < r_2$) are placed with their centres coinciding. A material of thermal conductivity $K$ is filled in the space between the shells. The inner shell is maintained at temperature $\theta_1$ and the outer shell at temperature $\theta_2$ ($\theta_1 < \theta_2$). The rate at which heat flows radially through the material is :-
Thermal resistance of spherical sheet of thickness $dr$ and radius $r$ is $$dR = \frac{dr}{K(4\pi r^2)}$$ $$R = \int_{r_1}^{r_2} \frac{dr}{K(4\pi r^2)}$$ $$R = \frac{1}{4\pi K} \left( \frac{1}{r_1} - \frac{1}{r_2} \right) = \frac{1}{4\pi K} \left( \frac{r_2 - r_1}{r_1 r_2} \right)$$ Thermal current $(i) = \frac{\theta_2 - \theta_1}{R}$ $$i = \frac{4\pi K r_1 r_2}{r_2 - r_1} (\theta_2 - \theta_1)$$
Question 37
Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct
If $V_A$ and $V_B$ are the input voltages (either $5 \, \mathrm{V}$ or $0 \, \mathrm{V}$) and $V_o$ is the output voltage then the two gates represented in the following circuit (A) and (B) are:-
AND and OR Gate
OR and NOT Gate
NAND and NOR Gate
AND and NOT Gate
Answer: (b)
Solution
Given $V_A = 5 \, \mathrm{V} \Rightarrow A = 1$, $V_A = 0 \, \mathrm{V} \Rightarrow A = 0$, $V_B = 5 \, \mathrm{V} \Rightarrow B = 1$, $V_B = 0 \, \mathrm{V} \Rightarrow B = 0$. If $A = B = 0$, there is no potential anywhere here $V_0 = 0$. If $A = 1$, $B = 0$, Diode $D_1$ is forward biased, here $V_0 = 5 \, \mathrm{V}$. If $A = 0$, $B = 1$, Diode $D_2$ is forward biased hence $V_0 = 5 \, \mathrm{V}$. If $A = 1$, $B = 1$, both diodes are forward biased hence $V_0 = 5 \, \mathrm{V}$. Truth table for 1st circuit: $$\begin{array}{ccc} A & B & Output \\ 0 & 0 & 0 \\ 0 & 1 & 1 \\ 1 & 0 & 1 \\ 1 & 1 & 1 \\ \end{array}$$ Thus, the given circuit is an OR gate. For the 2nd circuit, $V_B = 5 \, \mathrm{V}$, $A = 1$ and $V_B = 0 \, \mathrm{V}$, $A = 0$. When $A = 0$, the E-B junction is unbiased, there is no current through it, therefore $V_0 = 1$. When $A = 1$, the E-B junction is forward biased, $V_0 = 0$. Thus, this circuit is not a gate.
Question 38
Physics · Dual Nature of Radiation and Matter · Single correct
Consider two separate ideal gases of electrons and protons having same number of particles. The temperature of both the gases are same. The ratio of the uncertainty in determining the position of an electron to that of a proton is proportional to :-
$\left( \frac{m_p}{m_e} \right)^{3/2}$
$\sqrt{\frac{m_e}{m_p}}$
$\sqrt{\frac{m_p}{m_e}}$
$\frac{m_p}{m_e}$
Answer: (c)
Solution
Given the uncertainty principle: $$\Delta x \cdot \Delta p \geq \frac{h}{4\pi}$$ We have: $$\Delta x = \frac{h}{4\pi m \Delta v}$$ and $$v = \sqrt{\frac{3KT}{m}}$$ Therefore, $$\frac{\Delta x_e}{\Delta x_p} = \sqrt{\frac{m_p}{m_e}}$$
Question 39
Physics · Oscillations · Single correct
A bob of mass 'm' suspended by a thread of length $l$ undergoes simple harmonic oscillations with time period $T$. If the bob is immersed in a liquid that has density $\frac{1}{4}$ times that of the bob and the length of the thread is increased by $\frac{1}{3}$ of the original length, then the time period of the simple harmonic oscillations will be :-
$T$
$\frac{3}{2} \, T$
$\frac{3}{4} \, T$
$\frac{4}{3} \, T$
Answer: (d)
Solution
Given $T = 2\pi \sqrt{\ell/g}$. When bob is immersed in liquid, $mg_{eff} = mg - Buoyant force$. $mg_{eff} = mg - v \rho g$ ($\sigma$ = density of liquid$). $= mg - v \frac{\rho}{4} g$ $= mg - \frac{mg}{4} = \frac{3mg}{4}$ Therefore, $g_{eff} = \frac{3g}{4}$. $$T_1 = 2\pi \sqrt{\frac{\ell_1}{g_{eff}}}$$ $$\ell_1 = \ell + \frac{\ell}{3} = \frac{4\ell}{3}, \ell_{eff} = \frac{3g}{4}$$ By solving, $$T_1 = \frac{4}{3} 2\pi \sqrt{\ell/g}$$ $$T_1 = \frac{4}{3} T$$
Question 40
Physics · Mathematics in Physics · Single correct
Statement : I If three forces $\vec{F}_1$, $\vec{F}_2$ and $\vec{F}_3$ are represented by three sides of a triangle and $\vec{F}_1 + \vec{F}_2 = -\vec{F}_3$, then these three forces are concurrent forces and satisfy the condition for equilibrium. Statement : II A triangle made up of three forces $\vec{F}_1$, $\vec{F}_2$ and $\vec{F}_3$ as its sides taken in the same order, satisfy the condition for translatory equilibrium. In the light of the above statements, choose the most appropriate answer from the options given below:
Statement-I is false but Statement-II is true
Statement-I is true but Statement-II is false
Both Statement-I and Statement-II are false
Both Statement-I and Statement-II are true
Answer: (d)
Solution
Here $\vec{F}_1 + \vec{F}_2 + \vec{F}_3 = 0$ $$\vec{F}_1 + \vec{F}_2 = -\vec{F}_3$$ Since $\vec{F}_{nt} = 0$ (equilibrium) Both statements correct
Question 41
Physics · Physical World, Units and Measurements · Single correct
If velocity [V], time [T] and force [F] are chosen as the base quantities, the dimensions of the mass will be :
$\left[\mathrm{FT}^{-1} \mathrm{V}^{-1}\right]$
$\left[\mathrm{FTV}^{-1}\right]$
$\left[\mathrm{FT}^2 \mathrm{V}\right]$
$\left[\mathrm{FVT}^{-1}\right]$
Answer: (b)
Solution
Given $[M] = K[F]^a[T]^b[V]^c$. $$[M^1] = \left[M^1 L^1 T^{-2}\right]^a \left[T^1\right]^b \left[L^1 T^{-1}\right]^c$$ a = 1, b = 1, c = -1 Therefore, $[M] = \left[FTV^{-1}\right]$
Question 42
Physics · Electromagnetic Waves · Single correct
The magnetic field vector of an electromagnetic wave is given by $\mathbf{B} = B_0 \frac{\hat{i} + \hat{j}}{\sqrt{2}} \cos(kz - \omega t)$; where $\hat{i}, \hat{j}$ represents unit vector along $x$ and $y$-axis respectively. At $t = 0 \, \mathrm{s}$, two electric charges $q_1$ of $4\pi$ coulomb and $q_2$ of $2\pi$ coulomb located at $\left(0, 0, \frac{\pi}{k}\right)$ and $\left(0, 0, \frac{3\pi}{k}\right)$, respectively, have the same velocity of $0.5c\hat{i}$, (where $c$ is the velocity of light). The ratio of the force acting on charge $q_1$ to $q_2$ is :-
The equivalent resistance of the given circuit between the terminals A and B is:
$0\,\Omega$
$3\,\Omega$
$\frac{9}{2}\,\Omega$
$1\,\Omega$
Answer: (d)
Solution
The circuit is simplified by combining resistors in parallel and series. First, the two pairs of $2 \, \Omega$ resistors are combined in parallel, resulting in $2 \, \Omega$. Next, the $3 \, \Omega$ resistors are combined in parallel, resulting in $1.5 \, \Omega$. These results are then combined in series with the $2 \, \Omega$ resistor. Finally, the equivalent resistance is calculated as follows: $$R_{eq} = \frac{3 \times 3/2}{3 + 3/2} = \frac{9/2}{9/2} = 1 \, \Omega.$$
Question 44
Physics · Electric Charges and Fields · Single correct
Choose the incorrect statement : (a) The electric lines of force entering into a Gaussian surface provide negative flux. (b) A charge ' q ' is placed at the centre of a cube. The flux through all the faces will be the same. ($c$) In a uniform electric field net flux through a closed Gaussian surface containing no net charge, is zero. (d) When electric field is parallel to a Gaussian surface, it provides a finite non-zero flux. Choose the most appropriate answer from the options given below
and (d) only
and (d) only
only
and (c) only
Answer: (c)
Solution
Since $\phi = \vec{E} \cdot \vec{A} = EA \cos \theta$. $\theta = 90^\circ$ Therefore, $\phi = 0$
Question 45
Physics · Kinetic Theory · Single correct
A mixture of hydrogen and oxygen has volume $500 \, \mathrm{cm}^3$, temperature $300 \, \mathrm{K}$, pressure $400 \, \mathrm{kPa}$ and mass $0.76 \, \mathrm{g}$. The ratio of masses of oxygen to hydrogen will be :-
3 : 8
3 : 16
16 : 3
8 : 3
Answer: (c)
Solution
Given the equation $PV = nRT$, we have: $$400 \times 10^3 \times 500 \times 10^{-6} = n \left( \frac{25}{3} \right) (300)$$ Solving for $n$, we get: $$n = \frac{2}{25}$$ We also have $n = n_1 + n_2$: $$\frac{2}{25} = \frac{M_1}{2} + \frac{M_2}{32}$$ Additionally, $M_1 + M_2 = 0.76 \, \mathrm{gm}$. The ratio is given by: $$\frac{M_2}{M_1} = \frac{16}{3}$$
Question 46
Physics · Work, Energy and Power · Single correct
A block moving horizontally on a smooth surface with a speed of 40 $\mathrm{m/s}$ splits into two parts with masses in the ratio of 1 : 2. If the smaller part moves at 60 $\mathrm{m/s}$ in the same direction, then the fractional change in kinetic energy is :-
$\frac{1}{3}$
$\frac{2}{3}$
$\frac{1}{8}$
$\frac{1}{4}$
Answer: (c)
Solution
Given the equation $3MV_0 = 2MV_2 + MV_1$. We have $3 V_0 = 2 V_2 + V_1$. Solving for $V_2$, we get $120 = 2 V_2 + 60 \Rightarrow V_2 = 30 \, \mathrm{m/s}$. The change in kinetic energy is given by $$\frac{\Delta K.E.}{K.E} = \frac{\frac{1}{2}MV_1^2 + \frac{1}{2}2MV_2^2 - \frac{1}{2}3MV_0^2}{\frac{1}{2}3MV_0^2}$$ which simplifies to $$= \frac{V_1^2 + 2 V_2^2 - 3 V_0^2}{3 V_0^2}$$ $$= \frac{3600 + 1800 - 4800}{4800}$$ $$= \frac{1}{8}$$
Question 47
Physics · Electromagnetic Induction · Single correct
A coil is placed in a magnetic field $\vec{B}$ as shown below:
Outward and decreasing with time
Parallel to the plane of coil and decreasing with time
Outward and increasing with time
Parallel to the plane of coil and increasing with time
Answer: (a)
Solution
The vector $\vec{B}$ must not be parallel to the plane of the coil for non-zero flux, and according to Lenz's law, if $\vec{B}$ is outward, it should be decreasing for anticlockwise induced current.
Question 48
Physics · Oscillations · Single correct
For a body executing S.H.M.: $(a)$ Potential energy is always equal to its K.E. $(b)$ Average potential and kinetic energy over any given time interval are always equal. $(c)$ Sum of the kinetic and potential energy at any point of time is constant. $(d)$ Average K.E. in one time period is equal to average potential energy in one time period. Choose the most appropriate option from the options given below:
$(c)$ and $(d)$
only $(c)$
$(b)$ and $(c)$
only $(b)$
Answer: (a)
Solution
In S.H.M. total mechanical energy remains constant and also $\langle K.E. \rangle = \langle P.E. \rangle = \frac{1}{4} K A^2$ (for 1 time period)
Question 49
Physics · Semiconductor Electronics: Materials, Devices and Simple Circuits · Single correct
Statement-I : To get a steady dc output from the pulsating voltage received from a full wave rectifier we can connect a capacitor across the output parallel to the load $R_L$ Statement-II : To get a steady dc output from the pulsating voltage received from a full wave rectifier we can connect an inductor in series with $R_L$. In the light of the above statements, choose the most appropriate answer from the options given below :
Statement I is true but Statement II is false
Statement I is false but Statement II is true
Both Statement I and Statement II are false
Both Statement I and Statement II are true
Answer: (d)
Solution
To convert pulsating dc into steady dc both of mentioned method are correct.
Question 50
Physics · Gravitation · Single correct
If $R_E$ be the radius of Earth, then the ratio between the acceleration due to gravity at a depth 'r' below and a height 'r' above the earth surface is : (Given : $r < R_E$)
Given $$g_{up} = \frac{g}{\left(1 + \frac{r}{R}\right)^2}$$ $$g_{down} = g \left(1 - \frac{r}{R}\right)$$ The ratio is $$\frac{g_{down}}{g_{up}} = \left(1 - \frac{r}{R}\right) \left(1 + \frac{r}{R}\right)^2$$ Expanding the expression, we have $$= \left(1 - \frac{r}{R}\right) \left(1 + \frac{2r}{R} + \frac{r^2}{R^2}\right)$$ Simplifying further, $$= 1 + \frac{r}{R} - \frac{r^2}{R^2} - \frac{r^3}{R^3}$$
Question 51
Physics · Communication Systems · Numerical
A bandwidth of $6\,\mathrm{MHz}$ is available for A.M. transmission. If the maximum audio signal frequency used for modulating the carrier wave is not to exceed $6\,\mathrm{kHz}$. The number of stations that can be broadcasted within this band simultaneously without interfering with each other will be ....
Answer: 500
Solution
Signal bandwidth = 2fm = 12$\mathrm{kHz}$ Therefore, N = $\frac{6\,\mathrm{MHz}}{12\,\mathrm{kHz}}$ = $\frac{6 \times 10^6}{12 \times 10^3}$ = 500
Question 52
Physics · Electrostatic Potential and Capacitance · Numerical
A parallel plate capacitor of capacitance $200 \, \mu \mathrm{F}$ is connected to a battery of $200 \, \mathrm{V}$. A dielectric slab of dielectric constant $2$ is now inserted into the space between plates of capacitor while the battery remain connected. The change in the electrostatic energy in the capacitor will be .....J.
Answer: 4
Solution
Given $\Delta U = \frac{1}{2}(\Lambda C)V^2$. $$\Delta U = \frac{1}{2}(KC - C)V^2$$ $$\Delta U = \frac{1}{2}(2 - 1)CV^2$$ $$\Delta U = \frac{1}{2} \times 200 \times 10^{-6} \times 200 \times 200$$ $$\Delta U = 4 \, \mathrm{J}$$
Question 53
Physics · Magnetism and Matter · Numerical
A long solenoid with 1000 turns/m has a core material with relative permeability 500 and volume $10^3 \, \mathrm{cm}^3$. If the core material is replaced by another material having relative permeability of 750 with same volume maintaining same current of 0.75 A in the solenoid, the fractional change in the magnetic moment of the core would be approximately $\left( \frac{x}{499} \right)$. Find the value of ....x.
A particle is moving with constant acceleration 'a'. Following graph shows $v^2$ versus $x$ (displacement) plot. The acceleration of the particle is ..... m/s$^2$.
In a Young's double slit experiment, the slits are separated by 0.3 mm and the screen is 1.5 m away from the plane of slits. Distance between fourth bright fringes on both sides of central bright is 2.4 cm. The frequency of light used is .... $\times 10^{14} \, \mathrm{Hz}$
Physics · Experimental Physics · Fill in the blank
The diameter of a spherical bob is measured using a vernier callipers. 9 divisions of the main scale, in the vernier callipers, are equal to 10 divisions of vernier scale. One main scale division is 1 mm. The main scale reading is 10 mm and$8^{\text{th}}$ division of vernier scale was found to coincide exactly with one of the main scale division. If the given vernier callipers has positive zero error of 0.04 cm, then the radius of the bob is ..... $\times 10^{-2}\,\mathrm{cm}$
A sample of gas with $\gamma = 1.5$ is taken through an adiabatic process in which the volume is compressed from $1200 \, \mathrm{cm}^3$ to $300 \, \mathrm{cm}^3$. If the initial pressure is $200 \, \mathrm{kPa}$. The absolute value of the workdone by the gas in the process $= \, \mathrm{J}$.
Answer: 480
Solution
Question 58
Physics · Alternating Current · Numerical
At very high frequencies, the effective impendance of the given circuit will be .... $\Omega$
Answer: 2
Solution
Given $X_L = 2 \pi f L$. $f$ is very large. Therefore, $X_L$ is very large, hence open circuit. $X_C = \frac{1}{2 \pi f C}$. $f$ is very large. Therefore, $X_C$ is very small, hence short circuit. Final circuit $Z_{eq} = 1 + \frac{2 \times 2}{2 + 2} = 2$
Question 59
Physics · Ray Optics and Optical Instruments · Numerical
Cross-section view of a prism is the equilateral triangle ABC in the figure. The minimum deviation is observed using this prism when the angle of incidence is equal to the prism angle. The time taken by light to travel from P (midpoint of BC) to A is .... $\times 10^{-10}$ s. (Given, speed of light in vacuum $= 3 \times 10^8$ m/s and $\cos 30^\circ = \frac{\sqrt{3}}{2}$)
A resistor dissipates 192 J of energy in 1 s when a current of 4 A is passed through it. Now, when the current is doubled, the amount of thermal energy dissipated in 5 s in..... J.
Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct
The structures of A and B formed in the following reaction are: [Ph = -$C_6H_5$]
Answer: (a)
Solution
The reaction begins with the formation of an acylium ion in the presence of $AlCl_3$. This ion undergoes electrophilic aromatic substitution (E.A.S.) with benzene to form compound (A), which is $C_6H_5CH_2CH_2COOH$. Further reduction with $Zn-Hg$ and $HCl$ leads to compound (B), which is $Ph-CH_2-CH_2-CH_2-COOH$.
Question 64
Chemistry · Redox Reactions · Single correct
In which one of the following sets all species show disproportionation reaction?
$\mathrm{ClO_2^-}, \mathrm{F_2}, \mathrm{MnO_4^-} and \mathrm{Cr_2O_7^{2-}}$
$\mathrm{Cr_2O_7^{2-}}, \mathrm{MnO_4^-}, \mathrm{ClO_2^-} and \mathrm{Cl_2}$
$\mathrm{MnO_4^-}, \mathrm{ClO_2^-}, \mathrm{Cl_2} and \mathrm{Mn^{3+}}$
$\mathrm{ClO_4^-}, \mathrm{MnO_4^-}, \mathrm{ClO_2^-} and \mathrm{F_2}$
Answer: (c)
Solution
No option contains all species that show disproportionation reaction. $\mathrm{MnO_4^-}$ Mn is in $+7$ oxidation state (highest) hence cannot be simultaneously oxidized or reduced.
Question 65
Chemistry · Co-ordination Compounds · Single correct
Match List–I with List–II Choose the most appropriate answer from the options given below :
The major products A and B formed in the following reaction sequence are :
Answer: (b)
Solution
The reaction begins with the nucleophilic attack of the amine group $\mathrm{NH_2}$ on the carbonyl carbon of the ester $\mathrm{H_3C-C(=O)-O-C(=O)-CH_3}$. This forms an intermediate $\mathrm{Ph-NH_2^+-O-C-CH_3}$. The intermediate rearranges to form $\mathrm{Ph-NH-C-CH_3}$ and $\mathrm{O=C-CH_3}$. The proton transfer results in $\mathrm{Ph-NH-C-CH_3}$ (A). Upon treatment with $\mathrm{Br_2}$ and $\mathrm{CH_3COOH}$, the compound is transformed into $\mathrm{NH-C-CH_3}$ with a bromine substituent on the benzene ring, resulting in the major product (B).
Question 67
Chemistry · Biomolecules · Single correct
Which of the following is NOT an example of fibrous protein?
Keratin
Albumin
Collagen
Myosin
Answer: (b)
Solution
Keratin, collagen and myosin are examples of fibrous protein.
Question 68
Chemistry · Environmental Chemistry · Single correct
The deposition of X and Y on ground surfaces is referred as wet and dry depositions, respectively. X and Y are :
X = Ammonium salts, Y = CO_2
X = SO_2, Y = Ammonium salts
X = Ammonium salts, Y = SO_2
X = CO_2, Y = SO_2
Answer: (c)
Solution
Oxides of nitrogen and sulphur are acidic and settle down on ground as dry deposition. Ammonium salts in rain drops result in wet deposition.
Question 69
Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct
For the reaction given below : The compound which is not formed as a product in the reaction is a :
compound with both alcohol and acid functional groups
monocarboxylic acid
dicarboxylic acid
diol
Answer: (c)
Solution
The reaction involves the conversion of an aldehyde group to a carboxylate ion using $\mathrm{NaOH}$ and heat ($\Delta$). The reaction proceeds as follows: The starting compound is a benzene ring with an aldehyde group ($\mathrm{CHO}$) and a hydroxymethyl group ($\mathrm{CH_2OH}$). Upon treatment with $\mathrm{NaOH}$ and heat, the aldehyde group is converted to a carboxylate ion ($\mathrm{COO^-Na^+}$), resulting in the formation of a benzene ring with a hydroxymethyl group and a sodium carboxylate group. The reaction is then treated with $\mathrm{H_3O^+}$, which converts the sodium carboxylate group to a carboxylic acid group ($\mathrm{COOH}$). The final products are a benzene ring with two hydroxymethyl groups and a benzene ring with a hydroxymethyl group and a carboxylic acid group.
Question 70
Chemistry · Co-ordination Compounds · Single correct
Spin only magnetic moment in BM of $[\mathrm{Fe(CO)_4 (C_2O_4)]^+}$ is :
5.92
0
1
1.73
Answer: (d)
Solution
One unpaired electron. Spin only magnetic moment is given by $$\sqrt{3} \, \mathrm{B.M.} = 1.73 \, \mathrm{BM}$$
Question 71
Chemistry · The s-Block Elements · Single correct
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R ). Assertion (A) : Lithium salts are hydrated. Reason (R ) : Lithium has higher polarising power than other alkali metal group members. In the light of the above statements, choose the most appropriate answer from the options given below:
Both (A) and (R ) are correct but (R ) is NOT the correct explanation of (A).
(A) is correct but (R ) is not correct.
(A) is not correct but (R ) is correct.
Both (A) and (R ) are correct and (R ) is the correct explanation of (A).
Answer: (a)
Solution
Lithium salts are hydrated due to high hydration energy of $\mathrm{Li^+}$. $\mathrm{Li^+}$ due to smallest size in IA group has highest polarizing power.
Question 72
Chemistry · Thermodynamics · Single correct
The incorrect expression among the following is:
$\frac{\Delta G_{System}}{\Delta S_{Total}} = -T ( at constant P)$
$\ln K = \frac{\Delta H^\circ - T \Delta S^\circ}{RT}$
$K = e^{-\Delta G^\circ / RT}$
For isothermal process $w_{reversible} = -nRT \ln \frac{V_f}{V_i}$
Answer: (b)
Solution
Option (2) is incorrect $$\Delta G^\circ = -RT \ln K$$ $$\Delta H^\circ - T \Delta S^\circ = -RT \ln K$$ $$\ln K = -\left[ \frac{\Delta H^\circ - \Delta S^\circ}{RT} \right]$$
Question 73
Chemistry · Hydrogen · Single correct
Which one of the following statements is incorrect ?
Atomic hydrogen is produced when $\mathrm{H}_2$ molecules at a high temperature are irradiated with UV radiation.
At around $2000 \, \mathrm{K}$, the dissociation of dihydrogen into its atoms is nearly $8.1\%$.
Bond dissociation enthalpy of $\mathrm{H}_2$ is highest among diatomic gaseous molecules which contain a single bond .
Dihydrogen is produced on reacting zinc with $\mathrm{HCl}$ as well as $\mathrm{NaOH}_{(aq)}$.
Answer: (b)
Solution
Atomic hydrogen is produced at high temperature in an electric arc or under ultraviolet radiations. The dissociation of dihydrogen at 2000 K is only 0.081%. H-H bond dissociation enthalpy is highest for a single bond for any diatomic molecule. Dihydrogen can be produced on reacting Zn with dil. HCl as well as NaOH (aq.).
Question 74
Chemistry · Polymers · Single correct
Which among the following is not a polyester?
Novolac
PHBV
Dacron
Glyptal
Answer: (a)
Solution
Novalac is a linear polymer of $[\mathrm{Ph} - \mathrm{OH} + \mathrm{HCHO}]$. So ester linkage not present. So novalac is not a polyester.
Question 75
Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct
Which one of the following correctly represents the order of stability of oxides, $X_2O$; ( $X$ = halogen )?
Br > Cl > I
Br > I > Cl
Cl > I > Br
I > Cl > Br
Answer: (d)
Solution
Stability of oxides of Halogens is $$\mathrm{I} > \mathrm{Cl} > \mathrm{Br}$$
Question 76
Chemistry · Co-ordination Compounds · Single correct
Match List-I with List-II : Choose the most appropriate answer from the options given below :
(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
(a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
(a)-(i), (b)-(iv), (c)-(ii), (d)-(iii)
(a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)
Answer: (b)
Solution
$\text{Mn}^{2+} \rightarrow \text{III group}$ $\text{As}^{3+} \rightarrow \text{II B group}$ $\text{Cu}^{2+} \rightarrow \text{II A group}$ $\text{Al}^{3+} \rightarrow \text{IV group}$
Question 77
Chemistry · Aldehydes, Ketones and Carboxylic Acids · Single correct
The major product of the following reaction is :
Answer: (c)
Solution
NaOH + EtOH is known as alcoholic NaOH, so it gives $\mathrm{E^2}$ reaction with given alkyl halide.
Question 78
Chemistry · Hydrocarbons · Single correct
For the following:
Answer: (b)
Solution
The reaction sequence begins with benzene reacting with $\mathrm{Br_2}$ and $\mathrm{Fe}$ under heat $\Delta$ to form bromobenzene. Bromobenzene then reacts with $\mathrm{Mg}$ in dry ether to form phenylmagnesium bromide ($\mathrm{PhMgBr}$). This Grignard reagent reacts with $\mathrm{CH_3OH}$ to form a compound with $\mathrm{Br}$ and $\mathrm{MgOCH_3}$ groups.
Question 79
Chemistry · Hydrocarbons · Single correct
Identify correct A, B and C in the reaction sequence given below:
Answer: (a)
Solution
The reaction sequence starts with benzene. It undergoes nitration with $\mathrm{HNO_3}$ and $\mathrm{H_2SO_4}$ under heat $\Delta$ to form nitrobenzene $[A]$. Then, $[A]$ reacts with $\mathrm{Cl_2}$ in the presence of anhydrous $\mathrm{AlCl_3}$ to form $[B]$, which is chloronitrobenzene. Finally, $[B]$ is reduced with $\mathrm{Fe/HCl}$ to form $[C]$, which is chloroaniline.
Question 80
Chemistry · The p-Block Elements (Group 15, 16, 17 & 18) · Single correct
The number of $\mathrm{S} = \mathrm{O}$ bonds present in sulphurous acid, peroxodisulphuric acid and pyrosulphuric acid, respectively are:
2,3 and 4
1,4 and 3
2,4 and 3
1,4 and 4
Answer: (d)
Solution
Sulphurous acid has 1 S=O bond. Peroxodisulphuric acid has 4 S=O bonds. Pyrosulphuric acid has 4 S=O bonds.
Question 81
Chemistry · Surface Chemistry · Numerical
$\mathrm{CH_4}$ is adsorbed on $1\,\mathrm{g}$ charcoal at $0^\circ\mathrm{C}$ following the Freundlich adsorption isotherm. $10.0\,\mathrm{mL}$ of $\mathrm{CH_4}$ is adsorbed at $100\,\mathrm{mm}$ of Hg, whereas $15.0\,\mathrm{mL}$ is adsorbed at $200\,\mathrm{mm}$ of Hg. The volume of $\mathrm{CH_4}$ adsorbed at $300\,\mathrm{mm}$ of Hg is $10^x\,\mathrm{mL}$. The value of $x$ is ____ $\times 10^{-2}$. (Nearest integer) [Use $\log_{10}2 = 0.3010$, $\log_{10}3 = 0.4771$]
1.22 g of an organic acid is separately dissolved in 100 g of benzene ($K_b = 2.6\ K\ kg\ mol^{-1}$) and 100 g of acetone ($K_b = 1.7\ K\ kg\ mol^{-1}$). The acid is known to dimerize in benzene but remains as a monomer in acetone. The boiling point of the solution in acetone increases by 0.17°C. The increase in boiling point of the solution in benzene is $x \times 10^{-2}$ °C. The value of $x$ is ____ (nearest integer). [Atomic masses: C = 12.0, H = 1.0, O = 16.0.]
Answer: 13
Solution
With benzene as solvent $$\Delta T_b = i K_b m$$ $$\Delta T_b = \frac{1}{2} \times 2.6 \times \frac{1.22/M_w}{100/1000} \ldots (1)$$ With Acetone as solvent $$\Delta T_b = i K_b m$$ $$0.17 = 1 \times 1.7 \times \frac{1.22/M_w}{100/1000} \ldots (2)$$ (1) / (2) $$\frac{\Delta T_b}{0.17} = \frac{\frac{1}{2} \times 2.6 + \frac{1.22/M_w}{100/1000}}{1 \times 1.7 \times \frac{1.22/M_w}{100/1000}}$$ $$\Delta T_b = \frac{0.26}{2}$$ $$\Delta T_b = 13 \times 10^2$$ $$\Rightarrow x = 13$$
Question 83
Chemistry · Structure of Atom · Fill in the blank
The value of magnetic quantum number of the outermost electron of $\mathrm{Zn}^{+}$ ion is .
Answer: 0
Solution
The electron configuration for $\mathrm{Zn}^+$ is $1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 3d^{10} \, 4s^1$. The outermost electron is in the $4s$ subshell. Therefore, $m = 0$.
Question 84
Chemistry · The Solid State · Numerical
The empirical formula for a compound with a cubic close packed arrangement of anions and with cations occupying all the octahedral sites in $A_x B$. The value of $x$ is ____.
Answer: 1
Solution
Anions from CCP or FCC ($A^-$) $= 4A^-$ per unit cell. Cations occupy all octahedral voids ($B^+$) $= 4B^+$ per unit cell. Cell formula $\rightarrow A_4 B_4$ Empirical formula $\rightarrow AB$ $\rightarrow (x = 1)$
Question 85
Chemistry · General Principles and Processes of Isolation of Elements · Numerical
In the electrolytic refining of blister copper, the total number of main impurities, from the following, removed as anode mud is ____ Pb, Sb, Se, Te, Ru, Ag, Au and Pt
Answer: 6
Solution
Anode mud contains Sb, Se, Te, Ag, Au and Pt.
Question 86
Chemistry · Equilibrium · Numerical
The pH of a solution obtained by mixing $50 \, \mathrm{mL}$ of $1 \, \mathrm{M}$ HCl and $30 \, \mathrm{mL}$ of $1 \, \mathrm{M}$ NaOH is $x \times 10^{-4}$. The value of $x$ is ____. (Nearest integer) [$\log 2.5 = 0.3979$]
Answer: 6021
Solution
The reaction is given by: $$\mathrm{HCl(aq) + NaOH(aq) \rightarrow NaCl(aq) + H_2O(\ell)}$$ At $t = 0$, the volumes and concentrations are $50 \, \mathrm{ml}, 1 \, \mathrm{M}$ for HCl and $30 \, \mathrm{ml}, 1 \, \mathrm{M}$ for NaOH. At $t = \infty$, the volumes are $20 \, \mathrm{mm}$ for HCl and none for NaOH. The concentration of HCl is calculated as: $$[\mathrm{HCl}] = \frac{20}{80} = \frac{1}{4} \, \mathrm{M} = 2.5 \times 10^{-1} \, \mathrm{M}$$ The pH is calculated as: $$\mathrm{pH} = -\log 2.15 \times 10^{-1} = 1 - 0.3979 = 0.6021$$ Finally, the pH is: $$\mathrm{pH} = 6021 \times 10^{-4}$$
Question 87
Chemistry · Chemical Kinetics and Nuclear Chemistry · Numerical
For the reaction $\mathrm{A \rightarrow B}$, the rate constant $k$ (in $\mathrm{s^{-1}}$) is given by $\log_{10} k = 20.35 - \dfrac{2.47 \times 10^3}{T}$ The energy of activation in $\mathrm{kJ\,mol^{-1}}$ is __. (Round off to the nearest integer.) Given: $R = 8.314\,\mathrm{J\,K^{-1}\,mol^{-1}}$
Answer: 47
Solution
Given $\log K = 20.35 - \frac{2.47 \times 10^3}{T}$. We know $\log K = \log A - \frac{E_a}{2.303RT}$. Therefore, $$\frac{E_a}{2.303RT} = 2.47 \times 10^3$$ $$E_a = 2.47 \times 10^3 \times 2.303 \times \frac{8.314}{1000} KJ/mole$$ $$= 47.29 = 47 (Nearest integer)$$
Question 88
Chemistry · Solutions · Numerical
Sodium oxide reacts with water to produce sodium hydroxide. $20.0\ \mathrm{g}$ of sodium oxide is dissolved in $500\ \mathrm{mL}$ of water. Neglecting the change in volume, the concentration of the resulting $\mathrm{NaOH}$ solution is ______ $\times10^{-1}\ \mathrm{M}$. (Nearest integer) [Atomic mass : $\mathrm{Na}=23.0,\ \mathrm{O}=16.0,\ \mathrm{H}=1.0$]
Answer: 13
Solution
$\mathrm{Na_2O+H_2O\rightarrow2NaOH}$ $\frac{20}{62}\ \text{moles}$ Moles of $\mathrm{NaOH}$ formed $=\frac{20}{62}\times2$ $[\mathrm{NaOH}]=\frac{\frac{40}{62}}{\frac{500}{1000}}=1.29\,\mathrm{M}=13\times10^{-1}\,\mathrm{M}$ (Nearest integer)
Question 89
Chemistry · Chemical Bonding and Molecular Structure · Numerical
According to molecular orbital theory, the number of unpaired electron(s) in $\mathrm{O}_2^{2-}$ is:
Answer: 0
Solution
Molecular orbital configuration of $\mathrm{O_2^{2-}}$ is $$\sigma_{1s}^2 \sigma_{1s}^{*2} \sigma_{2s}^2 \sigma_{2s}^{*2} (\pi 2p_x^2 = \pi 2p_y^2) (\pi_{2p_x}^{*2} = \pi_{2p_y}^{*2})$$ Zero unpaired electron
The transformation occurring in Duma's method is given below: $$\mathrm{C_2H_7N} + \left(2x + \frac{y}{2}\right)\mathrm{CuO} \rightarrow x\mathrm{CO_2} + \frac{y}{2}\mathrm{H_2O} + \frac{z}{2}\mathrm{N_2} + \left(2x + \frac{y}{2}\right)\mathrm{Cu}$$ The value of $y$ is ____. (Integer answer)
Answer: 7
Solution
Given the reaction: $$\mathrm{C_2H_7N} + \left(2x + \frac{y}{2}\right) \mathrm{CuO} \rightarrow x \mathrm{CO_2} + \frac{y}{2} \mathrm{H_2O} + \frac{z}{2} \mathrm{N_2} + \left(2x + \frac{y}{2}\right) \mathrm{Cu}$$ On balancing $$\mathrm{C_2H_7N} + \frac{15}{2} \mathrm{CuO} \rightarrow 2 \mathrm{CO_2} + \frac{7}{2} \mathrm{H_2O} + \frac{1}{2} \mathrm{N_2} + \frac{15}{2} \mathrm{Cu}$$ On comparing $$y = 7$$